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    • 4. 发明授权
    • Silver halide photographic photosensitive materials
    • 卤化银感光材料
    • US5242787A
    • 1993-09-07
    • US783337
    • 1991-10-28
    • Tomokazu YasudaShunichi Aida
    • Tomokazu YasudaShunichi Aida
    • G03C1/043G03C1/053G03C1/10G03C1/295
    • G03C1/295G03C1/043G03C1/053Y10S430/151
    • Disclosed is silver halide photographic photosensitive material comprising a support, having thereon at least one silver halide photosensitive emulsion layer, wherein a polymer which can be represented by the following general formula (I) is included in at least one of the structural layers of the photographic photosensitive material: ##STR1## The term A represents a repeating unit obtained by polymerizing a monomer which has at least two polymerizable ethylenically unsaturated groups of which at least one is in a side chain; B represents a repeating monomer unit obtained by the polymerization of a monomer which has one polymerizable ethylenically unsaturated group; R.sup.1 represents a hydrogen atom or an alkyl group; R.sup.2 and R.sup.3 each represents a hydrogen atom or a methyl group; R.sup.4 represents a hydrogen atom or an organic group; L.sub.1 represents a divalent group comprising at least three atoms by which the main macromolecular chain and the poly(ethylene oxide) unit are linked; m represents an integer of at least 10, and x, y and z indicate percentages by weight wherein x is from 0 to 30, y is from 0 to 95 and z is from 5 to 100, based on the total weight of the polymer.
    • 公开了包含支持体的卤化银照相感光材料,其上具有至少一个卤化银感光乳剂层,其中可以由以下通式(I)表示的聚合物包括在摄影结构层中的至少一个中 (I)术语A表示通过聚合具有至少两个可聚合的烯键式不饱和基团的单体获得的重复单元,其中至少一个在侧链中; B表示通过聚合具有一个可聚合的烯属不饱和基团的单体获得的重复单体单元; R1表示氢原子或烷基; R2和R3各自表示氢原子或甲基; R4代表氢原子或有机基团; L1表示包含主要大分子链和聚(环氧乙烷)单元连接的至少三个原子的二价基团; m表示至少10的整数,x,y和z表示基于聚合物总重量的重量百分比,其中x为0至30,y为0至95,z为5至100。
    • 6. 发明授权
    • Silver halide photographic materials containing tabular silver halide
grains and a specified sensitizing dye
    • 含有片状卤化银颗粒和特定敏化染料的卤化银照相材料
    • US4675279A
    • 1987-06-23
    • US758622
    • 1985-07-24
    • Sadanobu ShutoToshinao UkaiShunichi Aida
    • Sadanobu ShutoToshinao UkaiShunichi Aida
    • G03C1/005G03C1/035G03C1/18G03C1/28G03C1/02G03C7/26
    • G03C1/18G03C1/28
    • A silver halide photographic light-sensitive material is described, which comprises a support having thereon at least one layer comprising a silver halide emulsion containing tabular silver halide particles wherein at least 50% of the total projected area of silver halide particles contained in the silver halide emulsion in said at least one layer is occupied by the tabular silver halide particles having an average aspect ratio of 5:1 or more, and wherein said silver halide emulsion contains a compound represented by general formula (I) or (II): ##STR1## wherein a is an integer of 1 to 8;R.sub.1, R.sub.2 and R.sub.3, which are the same or different, each represents a group of the formula --CH.sub.2 (CF.sub.2).sub.b H or a substituted or unsubstituted alkyl group, with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 has an acid radical;b, which is the same as or different from a, is an integer of 1 to 8;l is 0 or an integer of 1 to 8; m is 0 or an integer of 1 to 8; with the proviso that l+m>0;R.sub.4, R.sub.5 and R.sub.6, which are the same or different, each represents a group of the formula --(CH.sub.2).sub.j (CF.sub.2).sub.k F or a substituted or unsubstituted alkyl group, with the proviso that at least one or R.sub.4, R.sub.5 and R.sub.6 has an acid radical;j is 0 or an integer of 1 to 8; k is 0 or an integer of 1 to 8; with the proviso that j+k>0;V.sub.1, V.sub.2, V.sub.3, V.sub.4, V.sub.5, V.sub.6, V.sub.7 and V.sub.8, which are the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, an alkoxy group, an acyl group, an acyloxy group, an alkoxycarbonyl group, a carbamoyl group, a sulfamoyl group, a cyano group or a trifluoromethyl group;X is an anion; andn is 1 to 2; with the proviso that when said compound forms an internal salt, n is 1.
    • 描述了一种卤化银照相感光材料,其包括其上具有至少一层包含含有片状卤化银颗粒的卤化银乳剂的载体的载体,其中卤化银颗粒中包含的卤化银颗粒总投影面积的至少50% 所述至少一层中的乳液被具有5:1或更高的平均纵横比的片状卤化银颗粒占据,并且其中所述卤化银乳剂含有由通式(I)或(II)表示的化合物: 0; R 4,R 5和R 6相同或不同,各自表示式 - (CH 2)j(CF 2)k F或取代或未取代的烷基的基团,条件是至少一个或R 4,R 5和R 6 有酸根; j为0或1〜8的整数; k为0或1〜8的整数, 条件是j + k> 0; V1,V2,V3,V4,V5,V6,V7和V8各自表示氢原子,卤素原子,取代或未取代的烷基,烷氧基,酰基,酰氧基 烷氧基羰基,氨基甲酰基,氨磺酰基,氰基或三氟甲基; X是阴离子; n为1〜2; 条件是当所述化合物形成内盐时,n为1。
    • 7. 发明授权
    • Silver halide color photographic lightsensitive material
    • 卤化银彩色照相感光材料
    • US06537740B1
    • 2003-03-25
    • US09662495
    • 2000-09-15
    • Norihiro OmaeShunichi Aida
    • Norihiro OmaeShunichi Aida
    • G03C146
    • G03C1/46G03C1/0051G03C7/3029G03C7/3041G03C7/421G03C2003/006G03C2007/3025G03C2007/3034Y10S430/156
    • A silver halide color negative photographic lightsentive material comprises at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer on a support. The lightsensitive material has an ISO speed of 640 or more, the total silver content of 3.0 to 9.0 g/m2. Each of the red-sensitive emulsion layer, green-sensitive emulsion layer and blue-sensitive emulsion layer comprises two or more silver halide emulsion sub-layers having the same color sensitivity but different in speed to each other, and each of the red-sensitive sub-layer having the highest speed, green-sensitive sub-layer having the highest speed and blue-sensitive emulsion sub-layer having the highest speed has a silver content of 0.3 to 1.3 g/m2. At least two sub-layers selected from the red-sensitive sub-layer having the highest sensitivity, green-sensitive sub-layer having the highest sensitivity and blue-sensitive sub-layer having the highest speed contain silver halide grains in which tabular silver halide grains occupy 50% or more of the total projected area of all the silver halide grains in the sub-layer, and the tabular grains have an average aspect ratio of 8 or more.
    • 卤化银彩色负型照相照明材料包含至少一种感红卤化银乳剂层,至少一种感绿卤化银乳剂层和载体上至少一种蓝敏感卤化银乳剂层。 感光材料的ISO感光度为640以上,总银含量为3.0〜9.0g / m2。 感红乳剂层,感绿乳剂层和感蓝乳剂层中的每一个包含具有相同颜色灵敏度但彼此不同速度的两个或更多个卤化银乳剂子层,并且每个红色敏感乳剂层 具有最高速度的最高速度的绿色敏感性亚层和具有最高速度的感蓝乳剂亚层的亚层的银含量为0.3至1.3g / m 2。 选自具有最高灵敏度的感光性亚层,具有最高灵敏度的感绿子层和具有最高速度的蓝敏感亚层的至少两个子层含有卤化银颗粒,其中平板状卤化银 晶粒占子层中所有卤化银颗粒的总投影面积的50%或更多,并且片状颗粒的平均纵横比为8以上。
    • 8. 发明授权
    • Silver halide color photographic material
    • 卤化银彩色照相材料
    • US5298383A
    • 1994-03-29
    • US840949
    • 1992-02-25
    • Keiji MihayashiNaoki SaitoShunichi Aida
    • Keiji MihayashiNaoki SaitoShunichi Aida
    • G03C1/035G03C1/34G03C7/30G03C7/36G03C1/08G03C7/26G03C7/32
    • G03C7/365G03C7/3022
    • Disclosed is a silver halide color photographic material having at least one light-sensitive emulsion layer on a support, in which at least 50%, as the total projected area, of all the silver halide grains in at least one light-sensitive emulsion layer are tabular grains having a mean aspect ratio of 2 or more and at least one layer constituting the material contains a coupler of the following formula (I) and/or a coupler of the following formula (II): ##STR1## where X.sup.1 and X.sup.2 each represents an alkyl group, an aryl group, or a heterocyclic group; X.sup.3 represents an organic residue forming a nitrogen-containing heterocyclic group along with >N-- in the formula; Y represents an aryl group or a heterocyclic group; and Z represents a group capable of being released from the formula when the coupler of the formula reacts with an oxidation product of a developing agent. The material preferably contains a compound of formula (A):Q--SM.sup.1 (A)where Q represents a heterocyclic residue having at least one substituent selected from the group consisting of --SO.sub.3 M.sup.2, --COOM.sup.2, --OH and --NR.sup.1 R.sup.2 bonded thereto directly or indirectly; M.sup.1 and M.sup.2 independently represent a hydrogen atom, an alkali metal, a quaternary ammonium group, or a quaternary phosphonium group; and R.sup.1 and R.sup.2 independently represent a hydrogen atom, or a substituted or unsubstituted alkyl group. The material has a high sensitivity and has excellent graininess, pressure resistance, color reproducibility and sharpness.
    • 公开了一种卤化银彩色照相材料,其在载体上具有至少一个感光乳剂层,其中至少一个感光乳剂层中所有卤化银颗粒的总投影面积的至少50%为 平均纵横比为2以上的片状颗粒和至少一层构成材料的层包含下式(I)的成色剂和/或下式(II)的成色剂:(*化学结构*)(I )(*化学结构*)(II)其中X1和X2各自表示烷基,芳基或杂环基; X3表示式中含有氮原子的有机残基以及> N - Y表示芳基或杂环基; Z表示当式的成色剂与显影剂的氧化产物反应时能够从式中释放的基团。 该材料优选含有式(A)的化合物:Q-SM1(A)其中Q表示具有至少一个选自-SO 3 M 2,-COOM 2,-OH和-NR 1 R 2的取代基的杂环残基直接键合到其上, 间接地 M1和M2独立地表示氢原子,碱金属,季铵基或季鏻基; 并且R 1和R 2独立地表示氢原子或取代或未取代的烷基。 该材料具有高灵敏度,具有优异的颗粒度,耐压性,色彩再现性和清晰度。