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    • 1. 发明申请
    • METHOD FOR SYNTHESIZING HOMOPOLYMER N-VINYL BUTYROLACTAM WITH SUPER-LOW MOLECULAR WEIGHT AND SUPER-LOW RESIDUAL MONOMER
    • 用于合成具有超低分子量和超低残留单体的均聚物N-乙烯基丁二酰胺的方法
    • US20150141600A1
    • 2015-05-21
    • US14401743
    • 2012-07-23
    • Yu WangWei LiuZhan Chen
    • Yu WangWei LiuZhan Chen
    • C08F24/00
    • C08F24/00C08F4/38C08F6/003C08F126/06C08L39/04
    • The present invention relates to a synthesis method of ultra low molecular weight homopolymerized N-vinyl butyrolactam with ultra low residual monomer content, which comprises: using N-vinyl butyrolactam monomers and water with the mass ratio of 3:17˜8:12, then based on the N-vinyl butyrolactam monomers, using 0.5%˜5.0% by weight of initiators, 0.1%˜5.0% by weight of a catalyst, and 0.1%˜10% by weight of a molecular weight regulator; in the presence of an inert gas, adding the above mentioned raw materials in batches, adjusting the pH of the reaction system to 7.0-8.0 with an activator, reacting at the polymerization temperature of 60-85° C.; finally adding a peroxide and keeping the temperature for 2 hours, to obtain an aqueous solution of ultra low molecular weight homopolymerized N-vinyl butyrolactam, drying the aqueous solution to obtain a powdery ultra low molecular weight homopolymerized N-vinyl butyrolactam with ultra low residual monomer content, whose K value is 12-17, whose molecular weight is 2000-15000, and whose residual monomer content is less than 10 ppm, so the present invention is designed skillfully and simple in preparation, the residual monomer content of the ultra low molecular weight homopolymerized N-vinyl butyrolactam with ultra low residual monomer content prepared is less than 10 ppm, and the K value is 12-17, therefore the present invention is suitable for large-scale popularization.
    • 本发明涉及具有超低残留单体含量的超低分子量均聚N-乙烯基丁内酰胺的合成方法,其包括:使用N-乙烯基丁内酰胺单体和质量比为3:17〜8:12的水,然后 基于N-乙烯基丁内酰胺单体,使用0.5重量%〜5.0重量%的引发剂,0.1重量%〜5.0重量%的催化剂和0.1重量%〜10重量%的分子量调节剂; 在惰性气体的存在下,分批加入上述原料,用活化剂将反应体系的pH调节至7.0-8.0,在聚合温度为60-85℃下反应; 最后加入过氧化物并保持温度2小时,得到超低分子量均聚N-乙烯基丁内酰胺水溶液,干燥该水溶液,得到具有超低残留单体的粉状超低分子量均聚N-乙烯基丁内酰胺 其K值为12-17,分子量为2000-15000,残留单体含量小于10ppm,本发明设计巧妙简单,超低分子量的残留单体含量 制备的超低残留单体含量的均聚的N-乙烯基丁内酰胺重量小于10ppm,K值为12-17,因此本发明适用于大规模普及。
    • 2. 发明授权
    • Method for synthesizing homopolymer N-vinyl butyrolactam with super-low molecular weight and super-low residual monomer
    • 用超低分子量和超低残留单体合成均聚物N-乙烯基丁内酰胺的方法
    • US09453087B2
    • 2016-09-27
    • US14401743
    • 2012-07-23
    • Yu WangWei LiuZhan Chen
    • Yu WangWei LiuZhan Chen
    • C08F24/00C08F126/06C08F4/38C08F6/00
    • C08F24/00C08F4/38C08F6/003C08F126/06C08L39/04
    • A synthesis method of ultra low molecular weight homopolymerized N-vinyl butyrolactam with ultra low residual monomer content is provided N-vinyl butyrolactam monomers and water are provided with the mass ratio of 3:17˜8:12 0.5%˜5.0% by weight of initiators, 0.1%˜5.0% by weight of a catalyst, and 0.1%˜10% by weight of a molecular weight regulator are provided in the presence of an inert gas, adding the above mentioned raw materials in batches, adjusting the pH of the reaction system to 7.0-8.0 with an activator, reacting at the polymerization temperature of 60-85° C. A peroxide is added and maintaining the temperature for 2 hours, to obtain an aqueous solution of ultra low molecular weight homopolymerized N-vinyl butyrolactam. The aqueous solution is dried to obtain a powdery ultra low molecular weight homopolymerized N-vinyl butyrolactam with ultra low residual monomer content.
    • 提供了具有超低残留单体含量的超低分子量均聚的N-乙烯基丁内酰胺的合成方法,提供了N-乙烯基丁内酰胺单体和水,其质量比为3:17〜8:12 0.5%〜5.0% 引发剂,0.1重量%〜5.0重量%的催化剂和0.1重量%〜10重量%的分子量调节剂,在惰性气体存在下,分批加入上述原料,调节pH值 反应体系为7.0-8.0,用活化剂,在聚合温度为60-85℃下反应。加入过氧化物并保持温度2小时,得到超低分子量均聚N-乙烯基丁内酰胺水溶液。 将水溶液干燥,得到具有超低残留单体含量的粉末状超低分子量均聚N-乙烯基丁内酰胺。