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1. 发明授权

US4603077A Water-absorbing laminate and production process thereof 失效
标题翻译：吸水层压板及其制造方法
公开(公告)号：US4603077A
公开(公告)日：1986-07-29
申请号：US718979
申请日：1985-04-02
申请人： Yoshimasa Fujimoto , Hirotoshi Miyazaki
发明人： Yoshimasa Fujimoto , Hirotoshi Miyazaki
IPC分类号： A01G9/14 , A01G13/02 , B32B27/12 , C08J5/12 , C08J5/18 , D04H1/407 , D21H27/30 , A01G9/24 , D04H1/64
CPC分类号： A01G13/0231 , A01G9/1438 , B32B27/12 , Y10S428/913 , Y10T428/31855 , Y10T428/3188 , Y10T428/31909 , Y10T428/31928 , Y10T442/2025 , Y10T442/2484 , Y10T442/675
摘要： A water-absorbing laminate comprising a water-absorbing film and a non-woven fabric, in which the water-absorbing film is formed by film-forming a mixture of (A) a water-soluble polymer containing, as the monomer component, at least 40 mole % of an .alpha.,.beta.-unsaturated compound containing one or two carboxyl groups or groups from which a carboxyl group can be easily derived and in which 5% to 50% of the carboxyl groups and/or groups from which a carboxyl group can be easily derived are in the form of a salt, and (B) polyvinyl alcohol in a weight ratio of (A)/(B) of not less than 1/99 to less than 1/9. This water-absorbing can be produced by laminating the water-absorbing film on the non-woven fabric under pressure either in a hydrous and heat-softened state of the film or through an adhesive and, optionally, heat-treating the resultant laminate.This water-absorbing laminate can avoid the formation of excessive moisture and prevent waterdrops from dropping while keeping the heat-retaining properties, when used as a sheet for a cover culture. As a result, the occurrence of disease in the plants under culture and any reduction in the yield and quality of the plants are effectively prevented.
摘要翻译：一种吸水性层压体，其包含吸水膜和无纺布，其中通过将（A）含有作为单体成分的水溶性聚合物的混合物成膜，形成吸水膜，至少40摩尔％的含有一个或两个羧基的α，β-不饱和化合物或其中可以容易地得到羧基的基团，其中羧基和/或羧基的基团的5％至50％可以容易地衍生为盐的形式，和（B）重量比为（A）/（B）的聚乙烯醇不小于1/99至小于1/9。该吸水可以通过在膜的水合和热软化状态下的压力下将吸水膜层叠在无纺布上，或通过粘合剂，并任选地热处理所得到的层压体来制造。当用作覆盖培养的片材时，该吸水性层压体可以避免形成过多的水分并防止水滴掉落，同时保持保温性能。结果，有效地防止了培养中的植物中的疾病的发生和植物的产量和质量的任何降低。

2. 发明授权

US6166117A Water-soluble film 失效
标题翻译：水溶性薄膜
公开(公告)号：US6166117A
公开(公告)日：2000-12-26
申请号：US94506
申请日：1998-06-10
申请人： Hirotoshi Miyazaki
发明人： Hirotoshi Miyazaki
IPC分类号： C08F8/00 , C08K5/09 , C08K5/13 , C08K5/134
CPC分类号： C08K5/13 , C08F8/00 , C08K5/09 , C08K5/1345 , C08L29/04 , C08F8/12 , C08F218/08
摘要： A water-soluble film, comprising 100 parts by weight of (A) a sulfonic acid group modified polyvinyl alcohol and 0.05-20 parts by weight of (B) gallic acid, salts thereof or a C.sub.1-5 alkyl ester thereof.
摘要翻译：包含100重量份（A）磺酸基改性聚乙烯醇和0.05-20重量份（B）没食子酸，其盐或其C 1-5烷基酯的水溶性薄膜。

3. 发明授权

US5110678A Synthetic polyvinyl alcohol fiber and process for its production 失效
标题翻译：合成聚乙烯醇纤维及其生产工艺
公开(公告)号：US5110678A
公开(公告)日：1992-05-05
申请号：US512104
申请日：1990-04-20
申请人： Hiroshi Narukawa , Akio Mizobe , Fumio Nakahara , Akira Kubotsu , Akitsugu Akiyama , Masakazu Nishiyama , Kenji Nagamatu , Hirotoshi Miyazaki
发明人： Hiroshi Narukawa , Akio Mizobe , Fumio Nakahara , Akira Kubotsu , Akitsugu Akiyama , Masakazu Nishiyama , Kenji Nagamatu , Hirotoshi Miyazaki
IPC分类号： D01F6/14
CPC分类号： D01F6/14 , Y10T428/29 , Y10T428/2904 , Y10T428/2913
摘要： Provided is a high-performance PVA fiber and its production.Each filament of the PVA fiber of the present invention having a structure comprising an aggregate of substantially innumerable fibrils, the fiber has high strength, elastic modulus, and resistances to fatigue, hot water and chemicals and can be pulpified while keeping its excellent features such as high strength. The PVA fiber of the present invention cannot, even drawn to a high ratio, be readily whitened by virtue of its fibril-aggregate structure, and can hence be made still higher in performances. The PVA fiber can be obtained by adding to a PVA solution a relatively large amount of surface active agent, and wet or dry-jet-wet spinning the thus prepared dope solution into an aqueous alkaline coagulating bath.

4. 发明授权

US5102950A Water soluble film 失效
标题翻译：水溶胶膜
公开(公告)号：US5102950A
公开(公告)日：1992-04-07
申请号：US735687
申请日：1991-07-29
申请人： Kazutoshi Terada , Hirotoshi Miyazaki , Hitoshi Maruyama
发明人： Kazutoshi Terada , Hirotoshi Miyazaki , Hitoshi Maruyama
IPC分类号： C08J5/18 , C08F8/12 , C08F16/02 , C08F216/02
CPC分类号： C08F8/12 , C08J5/18
摘要： Provided are water soluble films comprising a modified polyvinyl alcohol containing 2-pyrrolidone ring. The films have excellent water solubility, which can be maintained over a long period of time and under the condition of being contacted with an alkaline or acid substance, and at the same time have an appropriate touch and flexibility.

5. 发明授权

US5478792A Heat-sensitive recording material 失效
标题翻译：热敏记录材料
公开(公告)号：US5478792A
公开(公告)日：1995-12-26
申请号：US305448
申请日：1994-09-13
申请人： Eriko Seno , Tetsuya Katayama , Hirotoshi Miyazaki
发明人： Eriko Seno , Tetsuya Katayama , Hirotoshi Miyazaki
IPC分类号： B41M5/337 , B41M5/30
CPC分类号： B41M5/3372
摘要： A heat-sensitive recording material with a heat-sensitive recording layer comprising a modified polyvinyl alcohol containing 2.5 to 8 mole % of a carboxyl group-containing monomer units and having a degree of saponification of 40 to 65 mole % and a viscosity average degree of polymerization. of 50 to 500; a dispersing agent comprising the above modified polyvinyl alcohol for heat-sensitive dyes or color developing agents that can make the heat-sensitive dyes form color upon heating; and a process for producing aqueous dispersions which comprises dispersing a heat-sensitive dye or a color developing agent that can make the heat-sensitive dye form color upon heating, in an aqueous medium with a dispersing agent of the above modified polyvinyl alcohol. The aqueous dispersion obtained, having excellent applicability to the surface of the base paper upon preparation of heat-sensitive recording papers and containing dispersoids of a heat-sensitive dye and a color developing agent dispersed in fine particles, can produce heat-sensitive recording materials having markedly high resolution.
摘要翻译：一种具有热敏记录层的热敏记录材料，其包含含有2.5〜8摩尔％的含羧基的单体单元并且皂化度为40〜65摩尔％的改性聚乙烯醇和粘度平均度聚合。 50至500; 包含用于热敏染料的上述改性聚乙烯醇或可以在加热时使热敏染料形成颜色的彩色显影剂的分散剂; 以及一种生产含水分散体的方法，其包括在具有上述改性聚乙烯醇的分散剂的水性介质中分散可使热敏染料在加热时形成颜色的热敏染料或彩色显影剂。得到的水分散体在制备热敏记录纸并且含有分散在细颗粒中的热敏染料和显色剂的分散体的情况下对原纸的表面具有优异的适用性，可以产生具有显着高分辨率。

6. 发明授权

US5420180A Sized yarn and process therefor 失效
标题翻译：纱线及其加工方法
公开(公告)号：US5420180A
公开(公告)日：1995-05-30
申请号：US141719
申请日：1993-10-26
申请人： Tetsuya Katayama , Hirotoshi Miyazaki , Hitoshi Maruyama , Koji Onishi
发明人： Tetsuya Katayama , Hirotoshi Miyazaki , Hitoshi Maruyama , Koji Onishi
IPC分类号： D06M15/05 , D06M15/11 , D06M15/333 , D06M15/09
CPC分类号： D06M15/333 , D06M15/05 , D06M15/11 , D06M7/00 , D06M2200/40 , Y10T428/2933 , Y10T428/2938 , Y10T428/2971
摘要： A size for yarn which minimizes thread break is described. The size comprises an aqueous solution of (I) a polyvinyl alcohol resin, (II) a modified starch, and a water-soluble cellulose compound (III), wherein the components are related by the following equations:(I)/(II)+(III))=85/15 to 95/5, and(II)/(III)=20/80 to 80/20,while simultaneously satisfying the expressions0.27X-0.7.ltoreq.log.sub.10 Y.ltoreq.0.27X+0.6; and (1)20.ltoreq.Y.ltoreq.300; (2)(A)/(B).ltoreq.0.5 (3)where X is the solid concentration in % by weight, Y is viscosity in centipoise at 90.degree. C. and a shear rate of 10 sec.sup.-1, (A) is viscosity at 60.degree. C. and a shear rate of 10,000 sec.sup.-1 of an adjusted aqueous solution resulting from the adjustment of the viscosity to 100 centipoise at 60.degree. C. and a shear rate of 10 sec.sup.-1 with said compound ratio of each of the components kept constant, and (B) is viscosity of 100 centipoise at 60.degree. C. and a shear rate of 10 sec.sup.-1 of said adjusted aqueous solution. The said aqueous solution is stuck to the yarn in an amount of 3 to 12% by weight based on the bone-dry weight thereof.
摘要翻译：描述了使断线最小化的纱线的尺寸。尺寸包括（I）聚乙烯醇树脂，（II）改性淀粉和水溶性纤维素化合物（III）的水溶液，其中组分通过以下等式相关：（I）/（II） +（III））= 85/15〜95/5和（II）/（III）= 20/80〜80/20，同时满足表达式0.27X-0.7

7. 发明授权

US4418163A Water absorbing composite comprising inorganic powder encapsulated with a crosslinked carboxyl polymer 失效
标题翻译：包含用交联的羧基聚合物包封的无机粉末的吸水复合材料
公开(公告)号：US4418163A
公开(公告)日：1983-11-29
申请号：US407894
申请日：1982-08-13
申请人： Tetsuo Murakami , Hirotoshi Miyazaki , Hiroshi Harima
发明人： Tetsuo Murakami , Hirotoshi Miyazaki , Hiroshi Harima
IPC分类号： C08L33/00 , B01J20/26 , B01J20/32 , C08F8/32 , C08G81/00 , C08G81/02 , C08K3/00 , C08L23/00 , C08L33/02 , C08L35/00 , C08L101/00 , C09K17/42 , C10G33/04 , C08K3/34
CPC分类号： B01J20/3204 , B01J20/043 , B01J20/045 , B01J20/106 , B01J20/12 , B01J20/264 , B01J20/267 , B01J20/3092 , B01J20/3223 , B01J20/3276 , B01J20/3282 , C08F8/44 , C09K17/42 , C10G33/04 , B01J2220/46 , B01J2220/58 , C08F2800/10 , Y10T428/2998
摘要： A water absorbing composite comprises an inorganic powder, and a highly absorbent resin covering the whole surfaces of the individual particles of the inorganic powder. The resin is obtained by reacting with a basic substance a polymer containing as a monomeric constituent an .alpha.,.beta.-unsaturated compound having in its molecule one or two carboxyl groups, or one or two other groups convertible to a carboxyl group or groups, and by crosslinking the reaction product with a polyamine. The composite is useful as a water retaining agent for agriculture and horticulture, or as a dehydrating agent for oil.
摘要翻译：吸水复合材料包括无机粉末和覆盖无机粉末的各个颗粒的整个表面的高吸收性树脂。该树脂通过与碱性物质反应，所述聚合物含有作为单体成分的α，β-不饱和化合物，其分子具有一个或两个羧基，或一个或两个其它可转化成羧基或基团的基团，以及通过用多胺交联反应产物。该复合材料可用作农业和园艺用保水剂，或用作油的脱水剂。

8. 发明授权

US5792809A Polyvinyl alcohol shaped article 失效
标题翻译：聚乙烯醇成型制品
公开(公告)号：US5792809A
公开(公告)日：1998-08-11
申请号：US834875
申请日：1997-04-10
申请人： Masahiro Nagao , Masato Nakamae , Takeshi Kusudou , Hirotoshi Miyazaki
发明人： Masahiro Nagao , Masato Nakamae , Takeshi Kusudou , Hirotoshi Miyazaki
IPC分类号： C08L21/00 , C08L29/04 , C08L51/00
CPC分类号： C08L29/04 , C08L21/00 , C08L51/00
摘要： Disclosed herein is a polyvinyl alcohol shaped article which comprises a polyvinyl alcohol (A) and rubber particles (B), said rubber particles (B) comprising a rubber component having a glass transition temperature of 5.degree. C. or less and an average particle diameter of 5 .mu.m or less and a polyvinyl alcohol (C) being bonded to the surface of said rubber component, with the weight ratio of said rubber component on the basis of the total weight of said polyvinyl alcohols being in the range of 0.03 to 2. The polyvinyl alcohol shaped article of the present invention has a high impact strength at low temperatures and in low humidity, and also has a high strength and Young's modulus in high humidity, and has an excellent appearance.
摘要翻译：本文公开了一种聚乙烯醇成型制品，其包含聚乙烯醇（A）和橡胶颗粒（B），所述橡胶颗粒（B）包含玻璃化转变温度为5℃或更低的橡胶组分，平均粒径 5μm以下的聚乙烯醇（C）与所述橡胶成分的表面结合的聚乙烯醇（C），所述橡胶成分的重量比为所述聚乙烯醇的总重量的0.03〜2 本发明的聚乙烯醇成型体在低温，低湿度下的冲击强度高，在高湿度下也具有高强度和杨氏模量，外观美观。

9. 发明授权

US5387638A Emulsion composition 失效
标题翻译：乳液组成
公开(公告)号：US5387638A
公开(公告)日：1995-02-07
申请号：US111536
申请日：1993-08-25
申请人： Masato Nakamae , Ken Yuki , Hirotoshi Miyazaki , Hitoshi Maruyama
发明人： Masato Nakamae , Ken Yuki , Hirotoshi Miyazaki , Hitoshi Maruyama
IPC分类号： C08F2/24 , D21H19/58 , D21H19/62 , C08L29/00
CPC分类号： D21H19/62 , C08F2/24 , D21H19/58
摘要： There is disclosed an emulsion composition which comprises an aqueous emulsion (A) obtained by emulsion polymerization of 100 parts by weight of an ethylenically unsaturated monomer in the presence of 1 to 15 parts by weight of a carboxyl group-modified polyvinyl alcohol such as itaconic acid-modified polyvinyl alcohol as the dispersant and a polyamide resin (B) such as polyamide epichlorohydrin. The above emulsion composition has a long pot-life and can easily be made into a film having a high wet strength and being excellent in water resistance, hot water resistance and heat resistance. Accordingly, it can effectively be utilized in a variety of applications including paint coating, adhesive, fiber sizing agent and paper coating.
摘要翻译：公开了一种乳液组合物，其包含在1〜15重量份的羧基改性的聚乙烯醇如衣康酸的存在下，通过100重量份的烯属不饱和单体的乳液聚合获得的水性乳液（A）改性聚乙烯醇作为分散剂，聚酰胺树脂（B）如聚酰胺表氯醇。上述乳液组合物的使用寿命长，可以容易地制成具有高湿强度，耐水性，耐热水性和耐热性优异的膜。因此，它可以有效地用于各种应用，包括涂料涂料，粘合剂，纤维施胶剂和纸张涂布。

10. 发明授权

US4389513A Highly absorbent resin 失效
标题翻译：高吸水性树脂
公开(公告)号：US4389513A
公开(公告)日：1983-06-21
申请号：US309773
申请日：1981-10-08
申请人： Hirotoshi Miyazaki
发明人： Hirotoshi Miyazaki
IPC分类号： C08F8/00 , A01N25/10 , A61F13/49 , A61F13/53 , A61L9/04 , A61L15/60 , B01J20/26 , C08F8/32 , C09K3/12 , C09K17/42
CPC分类号： C09K17/42 , A01N25/10 , A61L15/60 , A61L9/048 , C09K3/12
摘要： A highly absorbent resin which is essentially a polyamine-crosslinked, partial neutralization product obtained by reaction of an alkali metal hydroxide with a carboxyl-containing polymer selected from the froup consisting of alpha-olefin-maleic anhydride copolymers, vinyl compound-maleic anhydride copolymers, polyacrylic acid, polymethacrylic acid, and mixtures thereof, the degree of neutralization of the said neutralization product being 0.4 to 0.8 equivalent of total carboxyl groups of the said carboxyl-containing polymer, the amount of polyamine as a crosslinking agent being not more than 2 parts by weight per 100 parts by weight of the neutralization product on the uncrosslinked basis, the resin being capable of absorbing at least 20 times its own weight of distilled water. The resin has good resistance to heat and good durability in the hydrous condition.
摘要翻译：一种高吸收性树脂，其基本上是通过碱金属氢氧化物与含羧基的聚合物反应获得的多胺交联的部分中和产物，所述聚合物选自由α-烯烃 - 马来酸酐共聚物，乙烯基化合物 - 马来酸酐共聚物，聚丙烯酸，聚甲基丙烯酸及其混合物，所述中和产物的中和度为所述含羧基聚合物的总羧基的0.4至0.8当量，作为交联剂的多胺的量不超过2份，相对于未交联的中和产物100重量份，树脂能够吸收其自身重量的蒸馏水的至少20倍。该树脂在含水条件下具有良好的耐热性和良好的耐久性。

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