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    • 2. 发明申请
    • Spherical Active Carbon And Process For Producing The Same
    • 球形活性炭及其生产方法
    • US20080063592A1
    • 2008-03-13
    • US11597265
    • 2005-05-16
    • Fumio NakaharaKuroo KizakiAkira Miyake
    • Fumio NakaharaKuroo KizakiAkira Miyake
    • C01B31/08
    • B01J20/28019B01J20/20C01B32/336C01B32/384
    • An active carbon produced from an infusible carbonaceous material as a raw material, which active carbon when used for prevention of automobile fuel evaporation, etc., would not cause any trouble attributed to dust generation, exhibiting reduced pressure loss; and a process for producing the same. There is provided a spherical active carbon produced from an infusible solid carbon material as a raw material, wherein providing that x represents an average particle diameter (mm) and y an MS hardness (%), when x is in the range of 0.5 to 20, y is ≧100×(1-0.8×1.45(0.3-x)). This spherical active carbon can be produced by a process comprising mixing a carbon material with a carbonizable binder; extruding the mixture into a strand form; carrying out rolling granulation so as to obtain a spherical form; rendering the same infusible under appropriate conditions corresponding to the particle size; and performing carbonization and thereafter activation under conditions appropriately restricting the contact with activation gas.
    • 从作为原料的不可渗入的碳质材料生成的活性碳,当用于防止汽车燃料蒸发等时使用的活性炭不会引起由于粉尘产生而引起的任何故障,表现出减小的压力损失; 及其制造方法。 提供由作为原料的不溶性固体碳材料制成的球状活性炭,其中x表示平均粒径(mm),y表示MS硬度(%),当x在0.5〜20的范围内时 ,y => 100×(1-0.8×1.4×(0.3-x))。 该球形活性炭可以通过包括将碳材料与可碳化粘合剂混合的方法来制备; 将混合物挤出成锭状; 进行轧制造粒,得到球形; 在与粒度对应的适当条件下使相同的不可渗透性; 进行碳酸化,然后在适当限制与活化气体接触的条件下进行活化。
    • 5. 发明授权
    • Metal tube oxidation treatment apparatus
    • 金属管氧化处理装置
    • US5295668A
    • 1994-03-22
    • US842361
    • 1992-04-13
    • Tadahiro OhmiYoshiyuki NakaharaShigeki HayashiTakashi SakanakaEiji OhtaFumio Nakahara
    • Tadahiro OhmiYoshiyuki NakaharaShigeki HayashiTakashi SakanakaEiji OhtaFumio Nakahara
    • C21D9/08C23C8/10C23C8/18
    • C21D9/08C23C8/10C23C8/18
    • It is a metal oxidation treatment apparatus for carrying out the inactivation treatment of metal tubes used especially in a super high purity gas piping system and an apparatus of super high vacuum.The support part of a support member is made as a tubular form member, and a tapered part is provided on the outer periphery thereof, and further, since a spring is mounted to be displaceable, even if fluctuation is present in the internal diameter of stainless steel tubes, it is possible to let the stainless tubes easily be supported on the support part. Also, even fluctuation of the length is present in the stainless steel tubes, the support member is always pushed to the stainless steel tubes. Oxidative gas diffusing out of the tube to be treated to the outside thereof can be released to the outside of the oxidation treatment furnace without letting it contact to the tube to be treated.
    • PCT No.PCT / JP90 / 01230 Sec。 371日期:1992年4月13日 102(e)日期1992年4月13日PCT 1990年9月25日PCT PCT。 公开号WO91 / 05071 日期为1991年04月18日。它是一种金属氧化处理装置,用于特别在超高纯度气体管道系统和超高真空装置中使用的金属管的灭活处理。 支撑构件的支撑部分被制成管状构件,并且在其外周上设置有锥形部分,此外,由于弹簧安装成可移动,即使在不锈钢的内径中存在波动 钢管,可以使不锈钢管容易地支撑在支撑部分上。 此外,不锈钢管中存在长度均匀的波动,总是将支撑构件推到不锈钢管上。 从待处理的管扩散到其外部的氧化气体可以释放到氧化处理炉的外部,而不会使其与待处理的管接触。
    • 7. 发明授权
    • Process gas supplying apparatus
    • 工艺气体供应装置
    • US5241987A
    • 1993-09-07
    • US773893
    • 1991-12-02
    • Tadahiro OhmiKazuhiko SugiyamaFumio Nakahara
    • Tadahiro OhmiKazuhiko SugiyamaFumio Nakahara
    • B01F15/04B01F3/02B01F3/04C23C16/44C23C16/448C23F4/00H01L21/205H01L21/302H01L21/3065
    • B01F3/04985B01F3/026Y10T137/87249
    • When a process gas obtained by mixing a source gas with a diluting gas is supplied to a predetermined process apparatus, by supplying the process gas to the predetermined process apparatus through a gas contacting part connecting at least one source gas supplying pipe with at least one diluting gas supplying pipe, no chance that the source gas is exposed to air contamination is provided. Moreover, in particular, by forming the gas contacting part which is to be in contact with the above source gas, diluting gas and the like using such a material as metal, ceramic or the like, emission of materials having bad influences on the process gas, such as organic materials in particular, is eliminated. Furthermore, by providing a branching pipe or exhausting pipe, the degree of diluting the source gas can be varied stepwise, and by further combining with a flow rate adjuster, it can be varied continuously.
    • PCT No.PCT / JP89 / 01014 Sec。 371 1991年12月2日第 102(e)日期1991年12月2日PCT提交1989年10月4日PCT公布。 出版物WO90 / 12641 1990年11月1日,当通过将源气体与稀释气体混合而获得的处理气体被供给到预定的处理装置时,通过将至少一个源气体 向管道供给至少一个稀释气体供给管,并且不存在源气体暴露于空气污染的可能性。 此外,特别地,通过使用诸如金属,陶瓷等的材料形成与上述源气体接触的气体接触部分,稀释气体等,对处理气体的影响的材料的排放 ,特别是有机材料被消除。 此外,通过设置分支管或排气管,可以逐渐改变源气体的稀释度,并且通过与流量调节器进一步组合,可以连续变化。
    • 10. 发明授权
    • Method of producing carboxylic acid and alcohol
    • 制备羧酸和醇的方法
    • US06462231B1
    • 2002-10-08
    • US09594767
    • 2000-06-16
    • Masatoshi YanagawaKazunori WatanabeFumio Nakahara
    • Masatoshi YanagawaKazunori WatanabeFumio Nakahara
    • C07C5300
    • C07C51/09C07C53/08
    • A method of producing carboxylic acid and alcohol, that includes: supplying a liquid to a first distillation tower, said liquid including a carboxylic acid ester, and said first distillation tower being operated in a total reflux condition, to obtain a side stream; supplying said side stream to a hydrolysis reactor that includes an acid catalyst to obtain a reaction product liquid that includes a carboxylic acid, an alcohol, water and a carboxylic acid ester; supplying said reaction product liquid to said first distillation tower and removing a first bottom liquid therefrom, said first bottom liquid including a carboxylic acid, an alcohol and water; supplying said first bottom liquid to a second distillation tower and separating said first bottom liquid into a first top distillate that includes an alcohol, and a second bottom liquid that includes a carboxylic acid and water; supplying said second bottom liquid to a third distillation tower and separating said second bottom liquid into a second top distillate that includes a carboxylic acid and water, and a third bottom liquid that includes a carboxylic acid; circulating said second top distillate back to a tower top of said first distillation tower, and adding water to said tower top.
    • 一种制备羧酸和醇的方法,包括:向第一蒸馏塔供应液体,所述液体包括羧酸酯,所述第一蒸馏塔在完全回流条件下操作,得到侧流; 将所述侧流供应到包括酸催化剂的水解反应器,以获得包含羧酸,醇,水和羧酸酯的反应产物液体; 将所述反应产物液体供应到所述第一蒸馏塔并从其中除去第一底部液体,所述第一底部液体包括羧酸,醇和水; 将所述第一底部液体供应到第二蒸馏塔并将所述第一底部液体分离成包括醇的第一顶部馏出物和包含羧酸和水的第二底部液体; 将所述第二底部液体供应到第三蒸馏塔并将所述第二底部液体分离成包含羧酸和水的第二顶部馏出物和包含羧酸的第三底部液体; 将所述第二顶部馏出物循环回所述第一蒸馏塔的塔顶,并将水加入所述塔顶。