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1. 发明授权

US06787769B2 Conductive probe for scanning microscope and machining method using the same 失效
标题翻译：用于扫描显微镜的导电探针及使用其的加工方法
公开(公告)号：US06787769B2
公开(公告)日：2004-09-07
申请号：US10182331
申请日：2002-07-26
申请人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa , Yuichi Takano , Masatoshi Yasutake , Yoshiharu Shirakawabe
发明人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa , Yuichi Takano , Masatoshi Yasutake , Yoshiharu Shirakawabe
IPC分类号： G01N2300
CPC分类号： G01Q60/16 , G01Q60/38 , G01Q60/54 , G01Q70/12
摘要： A conductive probe for a scanning type microscope that captures the substance information of the surface of a specimen by the tip end of a conductive nanotube probe needle fastened to a cantilever, in which the conductive probe is constructed from a conductive film formed on the surface of the cantilever, a conductive nonatube with its base end portion being fixed in contact which the surface of a predetermined of the cantilever, and a conductive deposit which fastens the conductive nanotube by covering from the base end portion of the nonatube to a part of the conductive film. The conductive nonatube and the conductive film are electrically connected to each other by the conductive deposit.
摘要翻译：一种用于扫描型显微镜的导电探针，其通过固定到悬臂的导电纳米管探针的尖端捕获试样表面的物质信息，其中导电探针由形成在表面上的导电膜构成悬臂，其基端部固定为导电的非导管，其中预定的悬臂的表面是接触的，以及导电沉积物，其通过从非管形管的基端部分覆盖到导电的一部分来紧固导电纳米管电影。导电非导体和导电膜通过导电沉积物彼此电连接。

2. 发明授权

US06759653B2 Probe for scanning microscope produced by focused ion beam machining 失效
标题翻译：通过聚焦离子束加工扫描显微镜的探头
公开(公告)号：US06759653B2
公开(公告)日：2004-07-06
申请号：US10182330
申请日：2002-07-26
申请人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa , Yuichi Takano , Masatoshi Yasutake , Yoshiharu Shirakawabe
发明人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa , Yuichi Takano , Masatoshi Yasutake , Yoshiharu Shirakawabe
IPC分类号： G21K700
CPC分类号： G01Q60/38 , G01Q70/12
摘要： A scanning type microscope that captures substance information of the surface of a specimen by the tip end of a nanotube probe needle fastened to a cantilever, in which an organic gas is decomposed by a focused ion beam in a focused ion beam apparatus, and the nanotube is bonded to the cantilever with a deposit of the decomposed component thus produced. With this probe, the quality of the nanotube probe needle can be improved by removing an unnecessary deposit adhering to the nanotube tip end portion using a ion beam, by cutting an unnecessary part of the nanotube in order to control length of the probe needle and by injecting ions into the tip end portion of the nanotube.
摘要翻译：一种扫描型显微镜，其通过紧固在悬臂上的纳米管探针的前端捕获试样表面的物质信息，其中有机气体在聚焦离子束装置中被聚焦离子束分解，并且纳米管与由此产生的分解成分的沉积物粘合到悬臂上。利用该探针，可以通过使用离子束除去附着在纳米管末端部分的不必要的沉积物，通过切割不需要的纳米管部分来控制探针的长度，并且通过将离子注入纳米管的前端部。

3. 发明授权

US06705154B2 Cantilever for vertical scanning microscope and probe for vertical scan microscope 失效
标题翻译：垂直扫描显微镜悬臂，垂直扫描显微镜探针
公开(公告)号：US06705154B2
公开(公告)日：2004-03-16
申请号：US10182363
申请日：2002-07-26
申请人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa , Yuichi Takano , Masatoshi Yasutake , Yoshiharu Shirakawabe
发明人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa , Yuichi Takano , Masatoshi Yasutake , Yoshiharu Shirakawabe
IPC分类号： G01N2100
CPC分类号： G01Q70/10 , G01Q70/12
摘要： A cantilever for a vertical scanning type microscope that obtains substance information of a surface of a specimen by a tip end of a nanotube probe needle fastened to the cantilever, in which the cantilever has a fixing region to which a base end portion of a nanotube serving as a probe needle is fastened, and a height direction of the fixing region is set to be substantially perpendicular to a mean surface of the specimen when the cantilever is disposed in a measuring state with respect to the mean surface of the specimen; and the base end portion of the nanotube is bonded in the height direction of the fixing region.
摘要翻译：一种用于垂直扫描型显微镜的悬臂，其通过固定到悬臂的纳米管探针的尖端获得试样表面的物质信息，其中悬臂具有固定区域，其中纳米管的基端部分当所述探针针被固定时，并且当所述悬臂相对于所述试样的平均表面设置在测量状态时，所述固定区域的高度方向被设定为基本上垂直于所述试样的平均表面; 并且纳米管的基端部在固定区域的高度方向上接合。

4. 发明授权

US06805390B2 Nanotweezers and nanomanipulator 失效
标题翻译：纳米技术人员和纳米机器人
公开(公告)号：US06805390B2
公开(公告)日：2004-10-19
申请号：US10406844
申请日：2003-04-04
申请人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa
发明人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa
IPC分类号： B25J1512
CPC分类号： B25J7/00 , B81B2201/032 , B81B2201/12 , B81B2203/0118 , B81C99/002 , B82B3/00 , G01Q80/00 , Y10S977/732 , Y10S977/734 , Y10S977/742 , Y10S977/778 , Y10S977/78 , Y10S977/837 , Y10S977/842 , Y10S977/858 , Y10S977/863 , Y10S977/875 , Y10S977/876 , Y10S977/89 , Y10S977/901 , Y10S977/962
摘要： To provide nanotweezers and a nanomanipulator which allow great miniaturization of the component and are capable of gripping various types of nano-substances such as insulators, semiconductors and conductors and of gripping nano-substances of various shapes. Electrostatic nanotweezers 2 are characterized in that the nanotweezers 2 are comprised of a plurality of nanotubes whose base end portions are fastened to a holder 6 so that the nanotubes protrude from the holder 6, coating films which insulate and cover the surfaces of the nanotubes, and lead wires 10, 10 which are connected to two of the nanotubes 8, 9; and the tip ends of the two nanotubes are freely opened and closed by means of an electrostatic attractive force generated by applying a voltage across these lead wires. Furthermore, by way of forming a piezo-electric film 32 on the surface of the nanotube 9, and the tip ends of the nanotubes are freely opened and closed by expanding and contracting the piezo-electric film, thus allowing any desired nano-substances to be handled regardless of whether the nano-substances are insulators, semiconductors or conductors. Furthermore, if by way of designing three nanotubes so as to be freely opened and closed by an electrostatic system, nano-substances of various shapes such as spherical, rod-form, etc. can be handled. Moreover, a nanomanipulator that is constructed by combining the nanotweezers with a three-dimensional driving mechanism facilitates the gripping, moving and releasing of nano-substances.
摘要翻译：提供纳米扫描器和纳米管操纵器，其允许部件的极小化，并且能够夹持各种类型的纳米物质，例如绝缘体，半导体和导体，并且夹持各种形状的纳米物质。静电纳米尺寸器2的特征在于纳米晶体管 2由多个纳米管构成，其基端部固定在支架6上，使得纳米管从支架6突出，绝缘并覆盖纳米管的表面的涂膜和与导线10,10连接的导线10,10 两个纳米管8,9; 并且通过在这些引线上施加电压而产生的静电吸引力自由地打开和闭合两个纳米管的末端。此外，通过在纳米管9的表面上形成压电膜32，通过使压电膜膨胀收缩来使纳米管的前端自由地开闭，从而使任何所需的纳米物质无论纳米物质是绝缘体，半导体还是导体，都要进行处理。此外，如果通过设计三个纳米管以通过静电系统自由地打开和关闭，则可以处理诸如球形，棒状等各种形状的纳米物质。此外，通过将纳米技术人员与三维驱动机构组合而构成的纳米机械手有利于纳米物质的夹持，移动和释放。

5. 发明授权

US06802549B2 Nanotweezers and nanomanipulator 失效
公开(公告)号：US06802549B2
公开(公告)日：2004-10-12
申请号：US10406845
申请日：2003-04-04
申请人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa
发明人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa
IPC分类号： B25J1512
CPC分类号： B25J7/00 , B81B2201/032 , B81B2201/12 , B81B2203/0118 , B81C99/002 , B82B3/00 , G01Q80/00 , Y10S977/732 , Y10S977/734 , Y10S977/742 , Y10S977/778 , Y10S977/78 , Y10S977/837 , Y10S977/842 , Y10S977/858 , Y10S977/863 , Y10S977/875 , Y10S977/876 , Y10S977/89 , Y10S977/901 , Y10S977/962
摘要： To provide nanotweezers and a nanomanipulator which allow great miniaturization of the component and are capable of gripping various types of nano-substances such as insulators, semiconductors and conductors and of gripping nano-substances of various shapes. Electrostatic nanotweezers 2 are characterized in that the nanotweezers 2 are comprised of a plurality of nanotubes whose base end portions are fastened to a holder 6 so that the nanotubes protrude from the holder 6, coating films which insulate and cover the surfaces of the nanotubes, and lead wires 10, 10 which are connected to two of the nanotubes 8, 9; and the tip ends of the two nanotubes are freely opened and closed by means of an electrostatic attractive force generated by applying a voltage across these lead wires. Furthermore, by way of forming a piezo-electric film 32 on the surface of the nanotube 9, and the tip ends of the nanotubes are freely opened and closed by expanding and contracting the piezo-electric film, thus allowing any desired nano-substances to be handled regardless of whether the nano-substances are insulators, semiconductors or conductors. Furthermore, if by way of designing three nanotubes so as to be freely opened and closed by an electrostatic system, nano-substances of various shapes such as spherical, rod-form, etc. can be handled. Moreover, a nanomanipulator that is constructed by combining the nanotweezers with a three-dimensional driving mechanism facilitates the gripping, moving and releasing of nano-substances.

6. 发明授权

US06669256B2 Nanotweezers and nanomanipulator 失效
公开(公告)号：US06669256B2
公开(公告)日：2003-12-30
申请号：US10009471
申请日：2001-11-07
申请人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa
发明人： Yoshikazu Nakayama , Seiji Akita , Akio Harada , Takashi Okawa
IPC分类号： B25J1512
CPC分类号： B25J7/00 , B81B2201/032 , B81B2201/12 , B81B2203/0118 , B81C99/002 , B82B3/00 , G01Q80/00 , Y10S977/732 , Y10S977/734 , Y10S977/742 , Y10S977/778 , Y10S977/78 , Y10S977/837 , Y10S977/842 , Y10S977/858 , Y10S977/863 , Y10S977/875 , Y10S977/876 , Y10S977/89 , Y10S977/901 , Y10S977/962
摘要： To provide nanotweezers and a nanomanipulator which allow great miniaturization of the component and are capable of gripping various types of nano-substances such as insulators, semiconductors and conductors and of gripping nano-substances of various shapes. Electrostatic nanotweezers 2 are characterized in that the nanotweezers 2 are comprised of a plurality of nanotubes whose base end portions are fastened to a holder 6 so that the nanotubes protrude from the holder 6, coating films which insulate and cover the surfaces of the nanotubes, and lead wires 10, 10 which are connected to two of the nanotubes 8, 9; and the tip ends of the two nanotubes are freely opened and closed by means of an electrostatic attractive force generated by applying a voltage across these lead wires. Furthermore, by way of forming a piezo-electric film 32 on the surface of the nanotube 9, and the tip ends of the nanotubes are freely opened and closed by expanding and contracting the piezo-electric film, thus allowing any desired nano-substances to be handled regardless of whether the nano-substances are insulators, semiconductors or conductors. Furthermore, if by way of designing three nanotubes so as to be freely opened and closed by an electrostatic system, nano-substances of various shapes such as spherical, rod-form, etc. can be handled. Moreover, a nanomanipulator that is constructed by combining the nanotweezers with a three-dimensional driving mechanism facilitates the gripping, moving and releasing of nano-substances.

7. 发明授权

US07398678B2 Probe for a scanning microscope 失效
标题翻译：探针扫描显微镜
公开(公告)号：US07398678B2
公开(公告)日：2008-07-15
申请号：US11145869
申请日：2005-06-06
申请人： Yoshikazu Nakayama , Takashi Okawa , Shigenobu Yamanaka , Akio Harada , Masatoshi Yasutake , Yoshiharu Shirakawabe
发明人： Yoshikazu Nakayama , Takashi Okawa , Shigenobu Yamanaka , Akio Harada , Masatoshi Yasutake , Yoshiharu Shirakawabe
IPC分类号： G01B5/28
CPC分类号： G01Q60/04 , G01Q60/08 , G01Q60/16 , G01Q60/38 , G01Q60/54 , G01Q60/56 , G01Q70/12
摘要： A scanning microscope probe in which a palladium covering film is formed on the surface of the protruding portion of a cantilever, and the base end portion of a nanotube is disposed in contact with the palladium covering film with the tip end portion of the nanotube protruding to the outside, thus allowing the tip end to be used as a probe needle end for detecting signals. A coating film is formed to cover all or part of the surface of this base end portion, and the nanotube is thus firmly fastened to the cantilever. Since the base end portion adheres tightly to the palladium covering film, both of them are electrically continuous. This palladium covering film allows, as an electrode film, the application of a voltage to the nanotube or the passage of an electric current through the nanotube, showing also good adhesion to the nanotube and cantilever.
摘要翻译：扫描显微镜探针，其中在悬臂的突出部分的表面上形成钯覆盖膜，并且纳米管的基端部设置成与钯覆盖膜接触，其中纳米管的末端部突出到从而允许尖端用作检测信号的探针针端。形成涂膜以覆盖该基端部的全部或部分表面，并且因此将纳米管牢固地固定在悬臂上。由于基端部紧密地附着在钯覆盖膜上，所以两者都是电连续的。这种钯覆膜可以作为电极膜，对纳米管施加电压或使电流通过纳米管，对纳米管和悬臂也表现出良好的粘附性。

8. 发明申请

US20060150720A1 Probe for a scanning microscope 失效
标题翻译：探针扫描显微镜
公开(公告)号：US20060150720A1
公开(公告)日：2006-07-13
申请号：US11145869
申请日：2005-06-06
申请人： Yoshikazu Nakayama , Takashi Okawa , Shigenobu Yamanaka , Akio Harada , Masatoshi Yasutake , Yoshiharu Shirakawabe
发明人： Yoshikazu Nakayama , Takashi Okawa , Shigenobu Yamanaka , Akio Harada , Masatoshi Yasutake , Yoshiharu Shirakawabe
IPC分类号： G01B5/28
CPC分类号： G01Q60/04 , G01Q60/08 , G01Q60/16 , G01Q60/38 , G01Q60/54 , G01Q60/56 , G01Q70/12
摘要： A scanning microscope probe in which a palladium covering film is formed on the surface of the protruding portion of a cantilever, and the base end portion of a nanotube is disposed in contact with the palladium covering film with the tip end portion of the nanotube protruding to the outside, thus allowing the tip end to be used as a probe needle end for detecting signals. A coating film is formed to cover all or part of the surface of this base end portion, and the nanotube is thus firmly fastened to the cantilever. Since the base end portion adheres tightly to the palladium covering film, both of them are electrically continuous. This palladium covering film allows, as an electrode film, the application of a voltage to the nanotube or the passage of an electric current through the nanotube, showing also good adhesion to the nanotube and cantilever.
摘要翻译：扫描显微镜探针，其中在悬臂的突出部分的表面上形成钯覆盖膜，并且纳米管的基端部设置成与钯覆盖膜接触，其中纳米管的末端部突出到从而允许尖端用作检测信号的探针针端。形成涂膜以覆盖该基端部的全部或部分表面，并且因此将纳米管牢固地固定在悬臂上。由于基端部紧密地附着在钯覆盖膜上，所以两者都是电连续的。这种钯覆膜可以作为电极膜，对纳米管施加电压或使电流通过纳米管，对纳米管和悬臂也表现出良好的粘附性。

9. 发明授权

US07405178B2 Catalysts for manufacturing carbon substances 失效
标题翻译：用于制造碳物质的催化剂
公开(公告)号：US07405178B2
公开(公告)日：2008-07-29
申请号：US10328105
申请日：2002-12-23
申请人： Xu Li , Youchang Wang , Takashi Okawa , Akio Harada , Yoshikazu Nakayama
发明人： Xu Li , Youchang Wang , Takashi Okawa , Akio Harada , Yoshikazu Nakayama
IPC分类号： B01J23/58
CPC分类号： B82Y40/00 , B01J23/825 , B01J23/835 , B01J37/0219 , B01J37/082 , B82Y30/00 , C01B32/162 , C01B32/18 , C01B2202/36
摘要： A catalyst for manufacturing carbon substances, such as carbon nanotube that has a diameter of 1000 nm or less, the catalyst containing at least iron, cobalt or nickel of a first element group and tin or indium of a second element group. The catalyst can be formed by at least tin and indium in addition to cobalt or nickel. The former catalyst provides a 2-component type catalyst and a multi-component type catalyst that is composed on the basis of the 2-component type catalyst, and the later catalyst provides a 3-component type catalyst and a multi-component type catalyst that is composed on the basis of the 3-component type catalyst.
摘要翻译：用于制造直径为1000nm以下的碳纳米管等碳材料的催化剂，所述催化剂至少含有第一元素基团的铁，钴或镍，以及第二元素基团的锡或铟。除了钴或镍之外，催化剂可以至少由锡和铟形成。前一种催化剂提供基于2-组分型催化剂组成的2-组分型催化剂和多组分型催化剂，后催化剂提供一种3-组分型催化剂和多组分型催化剂，是基于3组分型催化剂组成的。

10. 发明申请

US20070111885A1 Method for manufacturing nano-carbon substances 审中-公开
标题翻译：制造纳米碳物质的方法
公开(公告)号：US20070111885A1
公开(公告)日：2007-05-17
申请号：US11376856
申请日：2006-03-16
申请人： Xu Li , Youchang Wang , Takashi Okawa , Akio Harada , Yoshikazu Nakayama
发明人： Xu Li , Youchang Wang , Takashi Okawa , Akio Harada , Yoshikazu Nakayama
IPC分类号： B01J23/00 , B01J23/56 , B01J23/74 , B01J23/70
CPC分类号： B82Y40/00 , B01J23/825 , B01J23/835 , B01J37/0219 , B01J37/082 , B82Y30/00 , C01B32/162 , C01B32/18 , C01B2202/36
摘要： A catalyst for manufacturing carbon substances, such as carbon nanotube that has a diameter of 1000 nm or less, the catalyst containing at least iron, cobalt or nickel of a first element group and tin or indium of a second element group. The catalyst can be formed by at least tin and indium in addition to cobalt or nickel. The former catalyst provides a 2-component type catalyst and a multi-component type catalyst that is composed on the basis of the 2-component type catalyst, and the later catalyst provides a 3-component type catalyst and a multi-component type catalyst that is composed on the basis of the 3-component type catalyst.
摘要翻译：一种用于制造直径为1000nm以下的碳纳米管的碳物质的催化剂，至少含有第一元素基团的铁，钴或镍的催化剂以及第二元素基团的锡或铟。除了钴或镍之外，催化剂可以至少由锡和铟形成。前一种催化剂提供基于2-组分型催化剂组成的2-组分型催化剂和多组分型催化剂，后催化剂提供一种3-组分型催化剂和多组分型催化剂，是基于3组分型催化剂组成的。

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