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    • 4. 发明授权
    • Multi-layer ceramic capacitor
    • 多层陶瓷电容
    • US4752858A
    • 1988-06-21
    • US24778
    • 1987-03-11
    • Yoichiro YokotaniJunichi KatoToshihiro Mihara
    • Yoichiro YokotaniJunichi KatoToshihiro Mihara
    • H01G4/30C04B35/499H01G4/12H01B3/12H01G4/10
    • C04B35/499H01G4/1209
    • Material forming dielectric ceramics includes an oxide containing a component A and a component B. The component A is selected from a group I of lead, calcium, strontium, and barium. The component B is selected from a group II of magnesium, nickel, titanium, zinc, niobium, and tungsten. The component A includes lead and at least one of the other substances in the group I. The component B includes at least two of the substances in the group II. A ratio between values a and b is chosen so that a/b>1.00, where the value a denotes a total mol value of the substances in the component A and the value b denotes a total mol value of the substances in the component B. Electrode layers are made of copper or an alloy principally containing copper. Since the firing temperature of the dielectric ceramics is low, excellent characteristics of a capacitor are enabled in spite of the fact that electrodes contain copper.
    • 材料形成介电陶瓷包括含有组分A和组分B的氧化物。组分A选自铅,钙,锶和钡的组I。 组分B选自镁,镍,钛,锌,铌和钨的组II。 组分A包括铅和组I中的至少一种其它物质。组分B包括组II中的至少两种物质。 选择值a和b之间的比率使得a / b> 1.00,其中a表示组分A中物质的总摩尔值,值b表示组分B中物质的总摩尔值。 电极层由铜或主要含有铜的合金制成。 由于电介质陶瓷的烧制温度低,所以尽管电极含有铜,但电容器的特性也是优异的。
    • 6. 发明授权
    • Dielectric ceramic and dielectric device
    • 介质陶瓷和电介质器件
    • US06762142B2
    • 2004-07-13
    • US10251585
    • 2002-09-19
    • Kojiro OkuyamaJunichi KatoHiroshi KagataKenji Iijima
    • Kojiro OkuyamaJunichi KatoHiroshi KagataKenji Iijima
    • C04B35465
    • C04B35/49C04B35/6262C04B2235/3206C04B2235/3249C04B2235/3251C04B2235/3262C04B2235/3275C04B2235/3284C04B2235/604C04B2235/786C04B2235/94C04B2235/96H01P7/10
    • A dielectric ceramic is made of a sintered body of a complex oxide including at least one element selected from the group consisting of Zr, Ti and Mn, at least one element selected from the group consisting of Mg, Zn and Co, and at least one element selected from the group consisting of Nb and Ta, wherein, the complex oxide is represented by a formula xZrO2-yTiO2-zA(1+w)/3B(2−w)/3O2 where ‘A’ in the formula denotes at least one element selected from the group (A) consisting of Mg, Zn and Co, ‘B’ denotes at one element selected from the group (B) consisting of Nb and Ta; x, y, z and w denote values in the respective ranges of 0.20≦x≦0.55, 0.40≦y≦0.55, 0.05≦z≦0.25, and 0≦w≦0.30, and x, y and z have a relationship represented as x+y+z=1; MnO is present in a range of 0.1 mol % to 1.0 mol % to the complex oxide; and an average grain size of the dielectric ceramic is from 10 &mgr;m to 70 &mgr;m, thereby providing a dielectric ceramic that has a high dielectric constant (&egr;r) and an unloaded (Qu) value even in a comparatively low frequency region as a microwave region i.e., in a range of 0.4 GHz to 2.4 GHz and that realizes a desired temperature coefficient (&tgr;f) of a resonant frequency with a high mechanical strength, and thus a dielectric device using the dielectric ceramic is provided.
    • 电介质陶瓷由包含选自Zr,Ti和Mn中的至少一种元素的复合氧化物的烧结体,选自Mg,Zn和Co中的至少一种元素和至少一种 元素选自Nb和Ta,其中复合氧化物由式xZrO2-yTiO2-zA(1 + w)/ 3B(2-w)/ 3O2表示,其中式中的“A”至少表示 选自由Mg,Zn和Co组成的组(A)中的一种元素,'B'表示选自Nb和Ta组成的组(B)中的一种元素; x,y,z和w分别表示0.20 <= x <= 0.55,0.40 <= y <= 0.55,0.05 <= z <= 0.25,0 <= w <0.30的各个范围内的值,x, y和z具有表示为x + y + z = 1的关系; MnO以0.1mol%至1.0mol%的范围存在于复合氧化物中; 并且电介质陶瓷的平均晶粒尺寸为10μm至70μm,从而提供即使在作为微波区域的较低频率区域中也具有高介电常数(ε)和无载(Qu)值的电介质陶瓷,即 ,在0.4GHz至2.4GHz的范围内,并且实现具有高机械强度的谐振频率的期望温度系数(tauf),因此提供了使用电介质陶瓷的电介质器件。