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    • 4. 发明授权
    • Method of manufacturing a ceramic electronic component
    • 制造陶瓷电子部件的方法
    • US5769988A
    • 1998-06-23
    • US752837
    • 1996-11-20
    • Hiroshi KagataIchiro KameyamaTatsuya InoueJunichi Kato
    • Hiroshi KagataIchiro KameyamaTatsuya InoueJunichi Kato
    • C04B35/00C04B35/64C04B41/51C04B41/88H01G4/12H01P7/04H01P11/00C04B37/00B05D5/12
    • C04B41/009C04B41/5116C04B41/88H01P11/008C04B2111/00844
    • A method of manufacturing a ceramic electronic component having a dielectric ceramic and a conductor containing Ag as a main component, wherein a dielectric resonator with a high Q value is produced by heat treating at 400.degree. C. or more in an atmosphere containing 10% or less by volume of oxygen after sintering the dielectric ceramic. Using a BaO--TiO.sub.2 --Nd.sub.2 O.sub.3 --Bi.sub.2 O.sub.3 based composition (.epsilon..sub.r =92, Qf=5000 GHz) as a dielectric, a coaxial type dielectric ceramic is produced by granulating calcined powder of the dielectric and then compacting the powder, followed by sintering. A dielectric resonator of .lambda./4 is produced by coating the dielectric ceramic with Ag paste at a position other than either the upper or lower side and then burning the paste. Thereafter, the electrodes(1,4) are formed by burning the paste at 400.degree. C. or more in an atmosphere containing 10% or less by volume of oxygen. The coaxial type dielectric resonator accepts electromagnetic waves from the open end and obtains output by utilizing TEM mode.
    • 一种制造具有介电陶瓷和含有Ag作为主要成分的导体的陶瓷电子部件的制造方法,其特征在于,在含有10%以上的气氛中,在400℃以上的温度下进行热处理, 烧结介电陶瓷后的氧气体积小。 使用BaO-TiO2-Nd2O3-Bi2O3基组合物(ε= r = 92,Qf = 5000GHz)作为电介质,通过对电介质的煅烧粉末进行造粒,然后压实粉末,随后烧结来制造同轴型电介质陶瓷。 通过在不同于上侧或下侧的位置用Ag浆料涂覆电介质陶瓷,然后燃烧该糊料来制造λ/ 4的介质谐振器。 此后,通过在含有10体积%以下氧气的气氛中,在400℃以上的温度下将糊状物烧成而形成电极(1,4)。 同轴型介质谐振器从开口端接受电磁波,并利用TEM模式获得输出。
    • 6. 发明授权
    • Method for manufacturing a dielectric ceramic composition dielectric
ceramic and multilayer high frequency device
    • 电介质陶瓷组合物介电陶瓷和多层高频器件的制造方法
    • US5629252A
    • 1997-05-13
    • US662700
    • 1996-06-13
    • Keiji NishimotoHiroshi KagataJunichi KatoTatsuya Inoue
    • Keiji NishimotoHiroshi KagataJunichi KatoTatsuya Inoue
    • C04B35/465C04B35/495H01G4/12C04B35/46
    • H01G4/1218C04B35/465C04B35/495H01G4/1254
    • A dielectric ceramic composition that can be sintered at a low temperature of around 1000.degree. C. and also can have a high dielectric constant, a high Q value and small temperature coefficient at a resonant frequency includes a glass component that promotes sintering. The dielectric ceramics include: the main component comprising calcium oxide, magnesium oxide, niobium oxide and titanium oxide and expressed by the Formula: Ca{(Mg.sub. 1/3 Nb.sub. 2/3).sub.1-x Ti.sub.x }O.sub.3 (wherein X is more than 0 not more than 0.50) within the range of not less than 40 parts by weight nor more than 98 parts by weight; the accessory component comprising at least one selected from SiO.sub.2 and B.sub.2 O.sub.3 within the range of not less than 2 parts by weight nor more than 60 parts by weight; and at least one oxide selected from the group consisting of MgO, NiO, CuO, MNO.sub.2 and WO.sub.3 within the range of not less than 0.1 parts by weight nor more than 10 parts by weight. Consequently, the dielectric ceramic composition of the present invention can be sintered at low temperature. The dielectric ceramic composition also has a stability in composition and high Q value, which can used for the dielectric ceramic and multilayer high frequency device.
    • 可以在约1000℃的低温下烧结并且在共振频率下也可以具有高介电常数,高Q值和小的温度系数的介电陶瓷组合物包括促进烧结的玻璃成分。 电介质陶瓷包括:主要成分包括氧化钙,氧化镁,氧化铌和氧化钛,并由下式表示:Ca {(Mg + E,fra 1/3 + EE Nb + E,fra 2/3 + EE) 1-xTix} O 3(其中X大于0不大于0.50)在不小于40重量份的范围内,不大于98重量份; 所述辅助成分包含选自SiO 2和B 2 O 3中的至少一种,其含量在不小于2重量份,不大于60重量份的范围内; 以及选自MgO,NiO,CuO,MNO 2和WO 3中的至少一种氧化物,其含量在0.1重量份以上,10重量份以下。 因此,本发明的电介质陶瓷组合物可以在低温下烧结。 电介质陶瓷组合物的组成稳定性和Q值高,可用于介电陶瓷和多层高频器件。
    • 7. 发明授权
    • Dielectric ceramic compound
    • 介电陶瓷化合物
    • US5525562A
    • 1996-06-11
    • US363901
    • 1994-12-27
    • Hiroshi KagataJunichi KatoKeiji Nishimoto
    • Hiroshi KagataJunichi KatoKeiji Nishimoto
    • C04B35/465C04B35/495C04B35/497H01B3/12H01P7/10C04B35/46
    • C04B35/497C04B35/465C04B35/495H01B3/12H01P7/10
    • This invention provides a dielectric ceramic compound for microwave use which has a high dielectric constant and a high Q value, and which also has a small temperature coefficient of a resonant frequency. The dielectric ceramic compound comprising a compound represented by Formula 1 at least includes calcium oxide, magnesium oxide, zinc oxide, niobium oxide, tantalum oxide, and titanium oxide, (Formula 1)Ca[{(Mg.sub.1-x Zn.sub.x).sub.1/3 (Nb.sub.1-z Ta.sub.z).sub.2/3 }.sub.1-y Ti.sub.y ]O.sub.3wherein x and y are present within an area formed by the following apexes A, B, C, and D, excluding an area on straight line AB,A: (x, y)=(0.0, 0.0)B: (x, y)=(0.0, 0.5)C: (x, y)=(1.0, 0.55)D: (x, y)=(1.0, 0.0)and z is present in the range of 0.0.ltoreq.z.ltoreq.1.0, excluding z=1.0 when y=0.0.
    • 本发明提供一种具有高介电常数和高Q值的微波用介电陶瓷化合物,并且其谐振频率的温度系数也较小。 包含式1化合物的介电陶瓷化合物至少包括氧化钙,氧化镁,氧化锌,氧化铌,氧化钽和氧化钛,(式1)Ca [{((Mg1-xZnx))1/3(Nb1 -zTaz)2/3} 1-yTiy] O3其中x和y存在于由以下顶点A,B,C和D形成的区域中,除了直线AB上的区域,A:(x,y) =(0.0,0.0)B:(x,y)=(0.0,0.5)C:(x,y)=(1.0,0.55)D:(x,y)=(1.0,0.0) 0.0≤z≤0.0的范围,当y = 0.0时不包括z = 1.0。