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    • 2. 发明申请
    • Combined copper plating method to improve gap fill
    • 组合镀铜方法提高间隙填充
    • US20070293039A1
    • 2007-12-20
    • US11454397
    • 2006-06-16
    • Xiaomei BuAlex SeeFan ZhangJane HuiTae Jong LeeLiang Choo Hsia
    • Xiaomei BuAlex SeeFan ZhangJane HuiTae Jong LeeLiang Choo Hsia
    • H01L21/4763H01L21/44
    • H01L21/288H01L21/2885H01L21/76873H01L21/76877
    • A method of filling gaps in dielectric layers is disclosed. A wafer is provided having a dielectric layer containing gaps to be filled with copper, some of the gaps, denoted deeper gaps, having aspect ratios so large that filling these gaps with copper using ECP could result in pinhole like voids. A blanket conformal metal barrier layer is formed and the wafer is then submerged in a solution to electroless plate a blanket conformal copper seed layer. A partial filling of deeper gaps with copper reduces the effective aspect ratios of the deeper gaps to the extent that ECP could be used to complete the copper filling of the gaps without forming pinhole like voids. ECP is then used to complete the copper filling of the gaps. The wafer is annealed and CMP performed to planarize the surface, giving rise to a structure in which the gaps are filled with copper and are separated by the dielectric layer.
    • 公开了一种在电介质层中填充间隙的方法。 提供具有包含要填充铜的间隙的电介质层的晶片,其中一些间隙表示为更深的间隙,其纵横比大到使用ECP填充这些间隙的铜可导致针孔状空隙。 形成覆盖的共形金属阻挡层,然后将晶片浸没在无电镀平板上的覆盖层保形铜种子层的溶液中。 用铜部分填充更深的间隙可以减少较深间隙的有效纵横比,使得ECP可以用于完成间隙的铜填充而不形成针孔如空隙的程度。 然后使用ECP来完成间隙的铜填充。 对晶片进行退火并进行CMP以平坦化表面,产生其中间隙被铜填充并由介电层分离的结构。
    • 4. 发明授权
    • Combined copper plating method to improve gap fill
    • 组合镀铜方法提高间隙填充
    • US07585768B2
    • 2009-09-08
    • US11454397
    • 2006-06-16
    • Xiaomei BuAlex SeeFan ZhangJane HuiTae Jong LeeLiang Choo Hsia
    • Xiaomei BuAlex SeeFan ZhangJane HuiTae Jong LeeLiang Choo Hsia
    • H01L21/44
    • H01L21/288H01L21/2885H01L21/76873H01L21/76877
    • A method of filling gaps in dielectric layers is disclosed. A wafer is provided having a dielectric layer containing gaps to be filled with copper, some of the gaps, denoted deeper gaps, having aspect ratios so large that filling these gaps with copper using ECP could result in pinhole like voids. A blanket conformal metal barrier layer is formed and the wafer is then submerged in a solution to electroless plate a blanket conformal copper seed layer. A partial filling of deeper gaps with copper reduces the effective aspect ratios of the deeper gaps to the extent that ECP could be used to complete the copper filling of the gaps without forming pinhole like voids. ECP is then used to complete the copper filling of the gaps. The wafer is annealed and CMP performed to planarize the surface, giving rise to a structure in which the gaps are filled with copper and are separated by the dielectric layer.
    • 公开了一种在电介质层中填充间隙的方法。 提供具有包含要填充铜的间隙的电介质层的晶片,其中一些间隙表示为更深的间隙,其纵横比大到使用ECP填充这些间隙的铜可导致针孔状空隙。 形成覆盖的共形金属阻挡层,然后将晶片浸没在无电镀平板上的覆盖层保形铜种子层的溶液中。 用铜部分填充更深的间隙可以减少较深间隙的有效纵横比,使得ECP可以用于完成间隙的铜填充而不形成针孔如空隙的程度。 然后使用ECP来完成间隙的铜填充。 对晶片进行退火并进行CMP以平坦化表面,产生其中间隙被铜填充并由介电层分离的结构。
    • 9. 发明授权
    • Method to eliminate top metal corner shaping during bottom metal patterning for MIM capacitors via plasma ashing and hard masking technique
    • 用于通过等离子体灰化和硬掩蔽技术消除MIM电容器底金属图案化期间的顶部金属角成形的方法
    • US06319767B1
    • 2001-11-20
    • US09798639
    • 2001-03-05
    • Randall Cher Liang ChaTae Jong LeeAlex SeeLap ChanYeow Kheng Lim
    • Randall Cher Liang ChaTae Jong LeeAlex SeeLap ChanYeow Kheng Lim
    • H01L218242
    • H01L28/60H01L21/31122H01L21/31144H01L21/32136H01L21/32139
    • A method for fabricating a metal-insulator-metal capacitor wherein top metal corner shaping during patterning is eliminated is described. An insulating layer is provided overlying a semiconductor substrate. A composite metal stack is formed comprising a first metal layer overlying the insulating layer, a capacitor dielectric layer overlying the first metal layer, a second metal layer overlying the capacitor dielectric layer, and a hard mask layer overlying the second metal layer. A first photoresist mask is formed overlying the hard mask layer. The composite metal stack is patterned using the first photoresist mask as an etching mask whereby the patterned first metal layer forms a bottom electrode of the capacitor. A portion of the first photoresist mask is removed by plasma ashing to form a second photoresist mask narrower than the first photoresist mask. The hard mask layer is patterned using the second photoresist mask as an etching mask. The second metal layer is patterned using the hard mask layer as an etching mask whereby the second metal layer forms a top electrode of the capacitor to complete fabrication of a metal-insulator-metal capacitor.
    • 描述了一种用于制造金属 - 绝缘体 - 金属电容器的方法,其中消除了图案化期间的顶部金属角成形。 绝缘层设置在半导体衬底上。 形成复合金属堆叠,其包括覆盖绝缘层的第一金属层,覆盖第一金属层的电容器电介质层,覆盖电容器电介质层的第二金属层和覆盖第二金属层的硬掩模层。 第一光致抗蚀剂掩模形成在硬掩模层上。 使用第一光致抗蚀剂掩模将复合金属堆叠图案化为蚀刻掩模,由此图案化的第一金属层形成电容器的底部电极。 通过等离子体灰化除去第一光致抗蚀剂掩模的一部分,以形成比第一光致抗蚀剂掩模窄的第二光刻胶掩模。 使用第二光致抗蚀剂掩模将硬掩模层图案化为蚀刻掩模。 使用硬掩模层作为蚀刻掩模对第二金属层进行构图,由此第二金属层形成电容器的顶部电极,以完成金属 - 绝缘体 - 金属电容器的制造。