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1. 发明授权

US4386218A Polyamines and processes for the production of such polyamines and of polyurethane plastics therefrom 失效
标题翻译：用于生产这种多胺和聚氨酯塑料的多胺和方法
公开(公告)号：US4386218A
公开(公告)日：1983-05-31
申请号：US308326
申请日：1981-10-05
申请人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
发明人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
IPC分类号： C07C275/62 , B01J23/02 , B01J31/08 , C07B61/00 , C07C271/20 , C07C271/26 , C07C273/18 , C07C275/00 , C07C275/14 , C08G18/00 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/65 , C08G18/83 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C07C273/1809 , C08G18/10 , C08G18/5048
摘要： A compound having a terminal isocyanate group is hydrolyzed to produce a polyamine having a urethane and/or a urea and/or a biuret group. More particularly, a carbamate is made by mixing an isocyanate prepolymer having urethane and/or urea and/or biuret groups present with aqueous base solutions at a temperature of from 0.degree. to 0.degree. C. and in quantities such that the equivalent ratio of hydroxyl to isocyanate groups is between from 0.3:1 to .gtoreq.1.01 to 1. The carbamate is then treated with an acid ion exchanger to form an amine. The amine is then removed from any other material which may be present. A preferred polyamine thus-produced corresponds to the general formula: ##STR1## in which each R radical may represent a divalent straight or branched-chain aliphatic radical; a divalent cycloaliphatic radical; a 4,4'- and/or a 2,4'-dicyclohexylmethane radical; or a 2,4- and/or 2,6-methyl cyclohexane radical. Such an amine may be reacted with a polyisocyanate and optionally with other known additives to form a polyurethane plastic or foam.
摘要翻译：将具有末端异氰酸酯基的化合物水解以制备具有氨基甲酸酯和/或脲和/或缩二脲基的多胺。更具体地，氨基甲酸酯是通过在0℃至0℃的温度下混合存在有氨基甲酸酯和/或脲和/或缩二脲基的异氰酸酯预聚物和/或缩二脲基与碱水溶液形成的，其量使得羟基的当量比到异氰酸酯基团之间的比例为0.3:1至> / = 1.01:1。然后用酸式离子交换剂处理氨基甲酸酯以形成胺。然后将胺从可能存在的任何其它材料中除去。如此制备的优选的多胺对应于通式：其中每个R基团可以表示二价直链或支链脂族基团; 二价脂环族基团; 4,4'-和/或2,4'-二环己基甲基基团; 或2,4-和/或2,6-甲基环己烷基。这样的胺可以与多异氰酸酯和任选地与其它已知的添加剂反应以形成聚氨酯塑料或泡沫。

2. 发明授权

US4532266A Polymer-containing polyether polyamines and a process for the production of these polyamines 失效
标题翻译：含聚合物的聚醚多胺和这些多胺的制备方法
公开(公告)号：US4532266A
公开(公告)日：1985-07-30
申请号：US360037
申请日：1982-03-19
申请人： Werner Rasshofer , Gerhard Balle , Dieter Dieterich , Holger Meyborg
发明人： Werner Rasshofer , Gerhard Balle , Dieter Dieterich , Holger Meyborg
IPC分类号： C08G18/10 , C08G18/12 , C08G18/50 , C08G18/63 , C07C127/15 , C07C127/24
CPC分类号： C08G18/632 , C08G18/10 , C08G18/12 , C08G18/5048
摘要： Polyether-based urethane-group-containing polyamines containing polymers and/or copolymers of unsaturated monomers and, optionally, urea and/or biuret and/or allophanate groups are produced by (a) reacting an NCO-prepolymer in aqueous alkaline solution at 0.degree. to 40.degree. C. to form a carbamate; (b) converting this carbamate to an amine by adding an ion exchanger to the reaction mixture; and (c) separating the polyamine from the reaction mixture. The NCO-prepolymers used as starting materials are prepolymers of (i) polyalkylene ether polyols having a molecular weight of from 1,000 to 10,000 containing from 1 to 60 wt. % of graft (co)polymers of unsaturated monomers; and (ii) excess molar quantities of organic polyisocyanate; and optionally, (iii) a low molecular weight chain-extending agent. The product polyamines have a molecular weight of from 1,000 to 10,000 and contain from 0.65 to 59.3 wt. % graft (co)polymer and from 0.11 to 2.9 wt. % terminal NH.sub.2 groups attached to the ethers by urethane groups in the polyisocyanate. The product polyamines are particularly useful in the production of polyurethanes.
摘要翻译：通过（a）使NCO预聚物在0℃的碱性水溶液中反应，制备含有聚氨酯基的聚胺和/或不饱和单体和任选的脲和/或缩二脲和/或脲基甲酸酯基团的聚合物和/ 至40℃以形成氨基甲酸酯; （b）通过向反应混合物中加入离子交换剂将该氨基甲酸酯转化为胺; 和（c）从反应混合物中分离多胺。用作原料的NCO-预聚物是（i）分子量为1,000至10,000的聚亚烷基醚多元醇的预聚物，其含有1至60wt。％的不饱和单体的接枝（共）聚合物; 和（ii）有机多异氰酸酯的过量摩尔数; 和（iii）低分子量链增长剂。产物多胺的分子量为1,000至10,000，含有0.65至59.3重量％％的接枝（共）聚合物和0.11-2.9重量％通过多异氰酸酯中的氨基甲酸酯连接到醚上的末端NH 2基团。产物多胺在聚氨酯的生产中特别有用。

3. 发明授权

US4418160A Polyamines and processes for the production of such polyamines and of polyurethane plastics therefrom 失效
标题翻译：用于生产这种多胺和聚氨酯塑料的多胺和方法
公开(公告)号：US4418160A
公开(公告)日：1983-11-29
申请号：US412614
申请日：1982-08-30
申请人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
发明人： Werner Rasshofer , Dieter Dieterich , Holger Meyborg
IPC分类号： C07C275/62 , B01J23/02 , B01J31/08 , C07B61/00 , C07C271/20 , C07C271/26 , C07C273/18 , C07C275/00 , C07C275/14 , C08G18/00 , C08G18/10 , C08G18/32 , C08G18/50 , C08G18/65 , C08G18/83 , C08G18/14
CPC分类号： C08G18/83 , C07C273/1809 , C08G18/10 , C08G18/5048
摘要： A compound having a terminal isocyanate group is hydrolyzed to produce a polyamine having a urethane and/or a urea and/or a biuret group. More particularly, a carbamate is made by mixing an isocyanate prepolymer having urethane and/or urea and/or biuret groups present with aqueous base solutions at a temperature of from 0.degree. to 0.degree. C. and in quantities such that the equivalent ratio of hydroxyl to isocyanate groups is between from 0,3:1 to .gtoreq.1,01 to 1. The carbamate is then treated with an acid ion exchanger to form an amine. The amine is then removed from any other material which may be present. A preferred polyamine thus-produced corresponds to the general formula: ##STR1## in which each R radical may represent a divalent straight or branched- chain aliphatic radical; a divalent cycloaliphatic radical; a 4,4'- and/or a 2,4'-dicyclohexylmethane radical; or a 2,4- and/or 2,6-methyl cyclohexane radical. Such an amine may be reacted with a polyisocyanate and optionally with other known additives to form a polyurethane plastic or foam.
摘要翻译：将具有末端异氰酸酯基的化合物水解以制备具有氨基甲酸酯和/或脲和/或缩二脲基的多胺。更具体地，氨基甲酸酯是通过在0℃至0℃的温度下混合存在有氨基甲酸酯和/或脲和/或缩二脲基的异氰酸酯预聚物和/或缩二脲基与碱水溶液形成的，其量使得羟基的当量比到异氰酸酯基团之间的比例为0.3:1至> / = 1,01:1。然后用酸性离子交换剂处理氨基甲酸酯以形成胺。然后将胺从可能存在的任何其它材料中除去。如此制备的优选的多胺对应于通式：其中每个R基团可以表示二价直链或支链脂族基团; 二价脂环族基团; 4,4'-和/或2,4'-二环己基甲基基团; 或2,4-和/或2,6-甲基环己烷基。这样的胺可以与多异氰酸酯和任选地与其它已知的添加剂反应以形成聚氨酯塑料或泡沫。

4. 发明授权

US4525590A Simplified process for the production of polyamines by the alkaline hydrolysis of compounds containing NCO-groups 失效
标题翻译：通过碱性水解含有NCO基团的化合物制备多胺的简化方法
公开(公告)号：US4525590A
公开(公告)日：1985-06-25
申请号：US398493
申请日：1982-07-15
申请人： Werner Rasshofer , Klaus Konig , Holger Meyborg , Walter Meckel , Armin Zenner
发明人： Werner Rasshofer , Klaus Konig , Holger Meyborg , Walter Meckel , Armin Zenner
IPC分类号： C07D251/34 , C07B61/00 , C07C67/00 , C07C213/02 , C07C239/00 , C07C265/02 , C07C265/12 , C07C269/02 , C07C271/20 , C07C271/46 , C07C273/18 , C07C275/00 , C07C275/30 , C07C275/40 , C07C275/62 , C08G18/00 , C08G18/10 , C08G18/50 , C08G18/64 , C08G18/83 , C07C125/06 , C07C127/15 , C07C127/24
CPC分类号： C08G18/83 , C08G18/10 , C08G18/5048 , C08G18/6415
摘要： The invention relates to an improved process for the production of polyamines containing urethane and/or urea and/or biuret and/or isocyanurate groups and, preferably, also alkylene ether, carbonate and/or acetal groups by the alkaline hydrolysis of corresponding compounds containing terminal aliphatic and/or aromatic isocyanate groups.To this end, the compounds containing terminal NCO-groups, preferably NCO-preadducts, are converted by means of selected bases into the carbamates and neutralized by introduction into equivalent quantities of acid or by the simultaneous introduction of the components in equivalent quantities into a reaction vessel, after which the polyamines are directly isolated by methods known per se.The invention also relates to the use of the polyamines obtained by the process for the production of polyurethanes.
摘要翻译：本发明涉及一种用于生产含氨基甲酸酯和/或脲和/或缩二脲和/或异氰脲酸酯基团的多胺的改进方法，并且优选还通过碱性水解含有末端的相应化合物的亚烷基醚，碳酸酯和/或缩醛基团脂族和/或芳族异氰酸酯基团。为此，含有末端NCO基团，优选NCO-前加合物的化合物通过选定的碱被转化成氨基甲酸酯并通过引入等量的酸中和或通过同时引入相当量的组分进入反应然后通过本身已知的方法直接分离多胺。本发明还涉及通过该方法生产聚氨酯得到的多胺的用途。

5. 发明授权

US4515923A Polyamines and a process for their production 失效
标题翻译：多胺及其生产工艺
公开(公告)号：US4515923A
公开(公告)日：1985-05-07
申请号：US506471
申请日：1983-06-21
申请人： Rudolf Fauss , Hans J. Meiners , Werner Rasshofer , Holger Meyborg
发明人： Rudolf Fauss , Hans J. Meiners , Werner Rasshofer , Holger Meyborg
IPC分类号： C08G18/00 , B01J31/02 , C07B61/00 , C07C67/00 , C07C209/00 , C07C209/62 , C07C211/48 , C07C211/51 , C07C211/53 , C08G18/10 , C08G18/30 , C08G18/50 , C08G18/83 , C08G73/00 , C08G73/02 , C08G18/18 , C09K3/00
CPC分类号： C08G18/5048 , C08G18/10
摘要： Polyamines containing aromatically bound primary amino groups having an NH.sub.2 -content of from 0.19 to 20.3 wt % are produced by a single stage process. A compound containing aromatically bound NCO-groups and having an isocyanate content of from 0.5 to 40 wt % is hydrolyzed with an excess of water in the presence of a water-miscible polar solvent and optionally a catalyst. The hydrolysis is carried out at a temperature of from -10.degree. to 150.degree. C. in a manner such that the reaction mixture is substantially homogeneous. The water-miscible polar solvent generally has a boiling point of from 56.degree. to 250.degree. C. and a dielectric constant of at least 10. This polar solvent is used in a quantity of at least 5 parts solvent for every 100 parts of isocyanate. Tertiary amines are the preferred catalysts. These polyamines are particularly useful in the production of polyurethanes.
摘要翻译：含有0.19〜20.3重量％NH 2含量的芳香结合的伯氨基的多胺通过单阶段方法制备。含有芳香结合的NCO-基团并且异氰酸酯含量为0.5〜40重量％的化合物在水混溶性极性溶剂和任选的催化剂的存在下，用过量的水分水解。水解是在-10至150℃的温度下进行的，使得反应混合物基本上是均匀的。水混溶性极性溶剂的沸点通常为56-250℃，介电常数至少为10.该极性溶剂的用量为每100份异氰酸酯至少为5份溶剂。叔胺是优选的催化剂。这些多胺在聚氨酯的生产中特别有用。

6. 发明授权

US4970342A Polyamines and a process for the production thereof 失效
标题翻译：多胺及其制备方法
公开(公告)号：US4970342A
公开(公告)日：1990-11-13
申请号：US309468
申请日：1989-02-10
申请人： Rudolf Fauss , Hans J. Meiners , Werner Rasshofer , Holger Meyborg
发明人： Rudolf Fauss , Hans J. Meiners , Werner Rasshofer , Holger Meyborg
IPC分类号： C08G18/10 , C08G18/50
CPC分类号： C08G18/5048 , C08G18/10
摘要： Polyamines containing from 0.19 to 20.3 wt. % aromatically bound primary amino groups are produced by hydrolyzing an isocyanate group containing compound in the presence of excess water, a tertiary amine and, optionally an ether solvent. The hydrolysis is carried out at a temperature of from -10.degree. to 150.degree. C. in a manner such that the reaction mixture remains substantially homogeneous. The isocyanate starting material contains aromatically bound isocyanate groups and has an NCO-content of from 0.5 to 40 wt. %. The ether solvent must be water soluble and inert with respect to isocyanates. Co-solvents and catalysts may also be included in the reaction mixture. The product polyamines are particularly useful in the production of polyurethanes.
摘要翻译：含有0.19〜20.3重量％通过在过量水，叔胺和任选的醚溶剂的存在下水解含异氰酸酯基团的化合物来制备％芳族结合的伯氨基。水解在-10℃至150℃的温度下进行，使得反应混合物保持基本上均匀。异氰酸酯原料含有芳香结合的异氰酸酯基团，其NCO含量为0.5〜40wt。％。醚溶剂必须是水溶性的，相对于异氰酸酯是惰性的。共溶剂和催化剂也可以包括在反应混合物中。产物多胺在聚氨酯的生产中特别有用。

7. 发明授权

US4350781A Process for the preparation of polymer precursors containing oxazolin-2-one rings 失效
标题翻译：制备含恶唑啉-2-酮环的聚合物前体的方法
公开(公告)号：US4350781A
公开(公告)日：1982-09-21
申请号：US286419
申请日：1981-07-24
申请人： Werner Rasshofer , Gerhard Grogler , Holger Meyborg
发明人： Werner Rasshofer , Gerhard Grogler , Holger Meyborg
IPC分类号： C07D263/62 , C08G18/10 , C08G18/38 , C08G18/80 , C08G18/32
CPC分类号： C07D263/62 , C08G18/10 , C08G18/3844 , C08G18/80
摘要： A polymer precursor containing an oxazolin-2-one ring is made by reacting (a) an amino-reactive group containing compound having at least two groups capable of entering into an addition or condensation reaction with primary or secondary aromatically-bound amino groups with (b) an aromatic amine having at least one primary or secondary aromatically-bound amino group and at least one condensed oxazolin-2-one ring. The reactants are used in quantities such that for each aromatically bound primary or secondary amino group there are from 0.95 to 5 groups present in the amino-reactive group containing compound which are capable of reacting with the amino group. These polymer precursors may be used to produce high molecular weight polymers useful in the production of solid molded products, adhesives, foam plastics and coatings.
摘要翻译：含有恶唑啉-2-酮环的聚合物前体是通过使（a）具有至少两个能够与伯或仲芳族结合的氨基进行加成或缩合反应的基团的含氨基反应性基团的化合物与（ b）具有至少一个伯或仲芳族结合的氨基和至少一个稠合的恶唑啉-2-酮的芳族胺。反应物的用量使得对于每个芳香结合的伯或仲氨基，在含有氨基反应性基团的化合物中存在0.95至5个能够与氨基反应的基团。这些聚合物前体可用于生产用于生产固体模制产品，粘合剂，泡沫塑料和涂料的高分子量聚合物。

8. 发明授权

US4263423A Process for the preparation of polyurethane casting elastomers 失效
标题翻译：制备聚氨酯浇铸弹性体的方法
公开(公告)号：US4263423A
公开(公告)日：1981-04-21
申请号：US057936
申请日：1979-07-16
申请人： Jurgen Schwindt , Holger Meyborg , Gerhard Grogler , Klaus Recker
发明人： Jurgen Schwindt , Holger Meyborg , Gerhard Grogler , Klaus Recker
IPC分类号： C08G18/00 , C08G18/22 , C08G18/72 , C08G18/73 , C08G18/16 , C08G18/24 , C08G18/26
CPC分类号： C08G18/72 , C08G18/22
摘要： The instant invention is directed to a process for the production of a light fast, transparent polyurethane elastomer comprising reacting:(A) from 90 to 50% by weight, based on the polyurethane solids content, of a compound having a molecular weight of from 400 to 10,000 which has at least two Zerewitinoff active hydrogen atoms;(B) from 50 to 10% by weight, based on the polyurethane solids content, of an aliphatic and/or alicyclic polyisocyanate; and(C) from 0 to 20% by weight, based on the polyurethane solids content, of a chain-lengthening agent having a molecular weight of from 60 to 400; in the presence of:(D) catalysts for the isocyanate polyaddition reaction, the improvement wherein said catalysts, component (D), is a catalyst combination of:(a) an alkali metal hydroxide and/or alkaline earth metal hydroxide; and(b) an organometallic compound selected from the group consisting of the acetyl acetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetyl acetonates of metals of the 4th main group or sulfur-containing compounds of metals of the 4th main group, in which compounds the sulfur is directly attached to the metal atom.
摘要翻译：本发明涉及一种生产轻质，透明的聚氨酯弹性体的方法，包括使（A）基于聚氨酯固体含量的90至50重量％的分子量为400的化合物至10,000具有至少两个Zerewitinoff活性氢原子; （B）基于聚氨酯固体含量为50至10重量％的脂族和/或脂环族多异氰酸酯; 和（C）基于聚氨酯固体含量为0至20重量％的分子量为60至400的链延长剂; 在（D）用于异氰酸酯加聚反应的催化剂的存在下，其中所述催化剂组分（D）是以下的催化剂组合：（a）碱金属氢氧化物和/或碱土金属氢氧化物; 和（b）选自第四主要金属的第四主要金属的第四主要金属的乙酰丙酮酸铁，C 1 -C 8醇盐，酚盐，烯醇化物和/或乙酰丙酮化物的有机金属化合物或第四主要金属的含硫化合物基团，其中化合物硫直接连接到金属原子上。

9. 发明授权

US4255570A Polyisocyanate reaction products of diisocyanates and s-triazine derivatives containing amino groups 失效
标题翻译：含有氨基的二异氰酸酯和s-三嗪衍生物的多异氰酸酯反应产物
公开(公告)号：US4255570A
公开(公告)日：1981-03-10
申请号：US930611
申请日：1978-08-03
申请人： Gerhard Grogler , Holger Meyborg
发明人： Gerhard Grogler , Holger Meyborg
IPC分类号： C07D251/18 , C07D251/50 , C07D251/52 , C07D251/70 , C08G18/80 , C07D251/54 , C07D251/46 , C07D251/48
CPC分类号： C07D251/52 , C07D251/18 , C07D251/50 , C07D251/70 , C08G18/8058
摘要： The invention relates to polyisocyanates corresponding to the following general formula: ##STR1## wherein X represents a radical of the type obtained by removing the more reactive isocyanate group from an organic diisocyanate containing isocyanate groups of different reactivity; andY represents a chlorine, bromine, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aroxy radical or a radical corresponding to the general formula: --NH--CO--NH--X.
摘要翻译：本发明涉及对应于以下通式的多异氰酸酯：其中X表示通过从具有不同反应性的异氰酸酯基团的有机二异氰酸酯基中除去更多的反应性异氰酸酯基而获得的类型的基团; 并且Y表示氯，溴，C1-C8烷基，C1-C8烷氧基，C6-C10芳基，C6-C10芳氧基或对应于通式-NH-CO-NH-X的基团。

10. 发明授权

US4352896A Polyol mixtures containing reactive blowing agents and use thereof for the production of foamed polyurethanes 失效
标题翻译：含有反应性发泡剂的多元醇混合物及其用于生产发泡聚氨酯的用途
公开(公告)号：US4352896A
公开(公告)日：1982-10-05
申请号：US309636
申请日：1981-10-08
申请人： Richard Kopp , Holger Meyborg , Jurgen Schwindt
发明人： Richard Kopp , Holger Meyborg , Jurgen Schwindt
IPC分类号： C08G18/38 , C08J9/02 , C08G18/14 , C08G18/32
CPC分类号： C08J9/02 , C08G18/3819 , C08J2375/04
摘要： This invention relates to mixtures of polyols which are liquid at room temperature with functional aldoximes as blowing agents, wherein the aldoxime groups react with polyisocyanates to liberate carbon dioxide and are simultaneously incorporated by means of the functional group thereof into the polyurethane formed. The present invention also relates to a process for the production of polyurethane foams using these incorporated reactive blowing agents as the primary blowing agent in combination with blowing agents known in polyurethane chemistry. The process according to the invention described herein is suitable for the production of various polyurethane foams or cellular polyurethane elastomers, particularly including the production of semi-rigid and rigid polyurethane integral skin foams which are obtained by foaming the reaction mixture in closed molds.
摘要翻译：本发明涉及在室温下为功能性醛肟作为发泡剂的多元醇混合物，其中醛肟基与多异氰酸酯反应以释放二氧化碳，并通过其功能基团同时引入所形成的聚氨酯中。本发明还涉及使用这些掺入的反应性发泡剂作为主要发泡剂与聚氨酯化学中已知的发泡剂组合来生产聚氨酯泡沫体的方法。根据本文所述的本发明的方法适用于生产各种聚氨酯泡沫或多孔聚氨酯弹性体，特别是包括通过在闭合模具中使反应混合物发泡获得的半刚性和硬质聚氨酯整体表皮泡沫的生产。

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