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1. 发明授权

US4263423A Process for the preparation of polyurethane casting elastomers 失效
标题翻译：制备聚氨酯浇铸弹性体的方法
公开(公告)号：US4263423A
公开(公告)日：1981-04-21
申请号：US057936
申请日：1979-07-16
申请人： Jurgen Schwindt , Holger Meyborg , Gerhard Grogler , Klaus Recker
发明人： Jurgen Schwindt , Holger Meyborg , Gerhard Grogler , Klaus Recker
IPC分类号： C08G18/00 , C08G18/22 , C08G18/72 , C08G18/73 , C08G18/16 , C08G18/24 , C08G18/26
CPC分类号： C08G18/72 , C08G18/22
摘要： The instant invention is directed to a process for the production of a light fast, transparent polyurethane elastomer comprising reacting:(A) from 90 to 50% by weight, based on the polyurethane solids content, of a compound having a molecular weight of from 400 to 10,000 which has at least two Zerewitinoff active hydrogen atoms;(B) from 50 to 10% by weight, based on the polyurethane solids content, of an aliphatic and/or alicyclic polyisocyanate; and(C) from 0 to 20% by weight, based on the polyurethane solids content, of a chain-lengthening agent having a molecular weight of from 60 to 400; in the presence of:(D) catalysts for the isocyanate polyaddition reaction, the improvement wherein said catalysts, component (D), is a catalyst combination of:(a) an alkali metal hydroxide and/or alkaline earth metal hydroxide; and(b) an organometallic compound selected from the group consisting of the acetyl acetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetyl acetonates of metals of the 4th main group or sulfur-containing compounds of metals of the 4th main group, in which compounds the sulfur is directly attached to the metal atom.
摘要翻译：本发明涉及一种生产轻质，透明的聚氨酯弹性体的方法，包括使（A）基于聚氨酯固体含量的90至50重量％的分子量为400的化合物至10,000具有至少两个Zerewitinoff活性氢原子; （B）基于聚氨酯固体含量为50至10重量％的脂族和/或脂环族多异氰酸酯; 和（C）基于聚氨酯固体含量为0至20重量％的分子量为60至400的链延长剂; 在（D）用于异氰酸酯加聚反应的催化剂的存在下，其中所述催化剂组分（D）是以下的催化剂组合：（a）碱金属氢氧化物和/或碱土金属氢氧化物; 和（b）选自第四主要金属的第四主要金属的第四主要金属的乙酰丙酮酸铁，C 1 -C 8醇盐，酚盐，烯醇化物和/或乙酰丙酮化物的有机金属化合物或第四主要金属的含硫化合物基团，其中化合物硫直接连接到金属原子上。

2. 发明授权

US4263408A Process for the production of molded foams 失效
标题翻译：生产模制泡沫的方法
公开(公告)号：US4263408A
公开(公告)日：1981-04-21
申请号：US57935
申请日：1979-07-16
申请人： Holger Meyborg , Werner Mormann , Gerhard Grogler , Jurgen Schwindt
发明人： Holger Meyborg , Werner Mormann , Gerhard Grogler , Jurgen Schwindt
IPC分类号： C08G18/00 , C08G18/22 , C08G18/72 , C08G18/14
CPC分类号： C08G18/22 , C08G18/72 , C08G2101/0033 , C08G2410/00 , Y10T428/249989
摘要： The instant invention is directed to a process for the production of molded foams having a compact surface and cellular core and an integral density distribution over the cross-section of the body, comprising reacting(A) polyisocyanates, and(B) relatively high molecular and/or low molecular compounds having an average of at least two isocyanate-reactive hydrogen atoms in the presence of:(C) catalysts for the isocyanate polyaddition reaction and(D) blowing agents and optionally other known additives, in a closed mold under the conditions of foaming inside molds, the improvement wherein said polyisocyanates are aliphatic and/or alicyclic polyisocyanates and said catalysts are catalyst combinations of:(i) an alkali metal and/or alkaline earth metal hydroxide and(ii) a metal compound, the metal compound being the acetylacetonate of iron, C.sub.1 -C.sub.8 alcoholates, phenolates, enolates and/or acetylacetonates of metals of the 4th Main Group or sulfur compounds of metals of the 4th Main Group of the Periodic System of Elements in which the sulfur is directly attached to the metal atom.
摘要翻译：本发明涉及一种生产具有紧凑的表面和多孔芯的模制泡沫的方法以及在主体的横截面上的整体密度分布，包括使（A）多异氰酸酯与（B）相对高分子和 /或在以下情况下平均具有至少两个异氰酸酯反应性氢原子的低分子化合物：（C）用于异氰酸酯加聚反应的催化剂和（D）发泡剂和任选的其它已知添加剂，在封闭模具中在条件在模具中发泡的改进，其中所述多异氰酸酯是脂族和/或脂环族多异氰酸酯，所述催化剂是以下催化剂组合：（i）碱金属和/或碱土金属氢氧化物和（ii）金属化合物，金属化合物为第四主要金属的金属的乙酰丙酮化物，C1-C8醇盐，酚盐，烯醇化物和/或乙酰丙酮化物或第四主族金属的硫化合物的元素周期系统，其中硫直接连接到金属原子上。

3. 发明授权

US4587275A Process for the preparation of polyurethane elastomers 失效
标题翻译：制备聚氨酯弹性体的方法
公开(公告)号：US4587275A
公开(公告)日：1986-05-06
申请号：US429707
申请日：1982-09-30
申请人： Richard Kopp , Holger Meyborg , Gerhard Grogler , Jurgen Schwindt
发明人： Richard Kopp , Holger Meyborg , Gerhard Grogler , Jurgen Schwindt
IPC分类号： C08G18/00 , C08G18/10 , C08G18/32 , C08G18/38 , C08G18/65 , C08G18/14
CPC分类号： C08G18/3861 , C08G18/10
摘要： Polyurethane urea elastomers are produced by reacting polyisocyanates with compounds containing at least two isocyanate reactive hydrogen atoms having a molecular weight of 400 to 10,000 and mononuclear or dinuclear aromatic diamines. The aromatic diamines must have at least one sulfonamide group as a substituent on at least one of their aromatic rings. Known chain lengthening agents, activators, blowing agents, auxiliary agents and additives may also be included in the reaction mixture.Polyurethane elastomers produced by this process have excellent mechanical properties. In particular, such elastomers are soft yet have high tear propagation resistance.
摘要翻译：聚氨酯脲弹性体是通过使多异氰酸酯与分子量为400至10,000的至少两个异氰酸酯反应性氢原子和单核或双核芳族二胺的化合物反应来制备的。芳族二胺必须在至少一个它们的芳环上具有至少一个磺酰胺基作为取代基。已知的增链剂，活化剂，发泡剂，辅助剂和添加剂也可以包括在反应混合物中。通过该方法生产的聚氨酯弹性体具有优异的机械性能。特别地，这种弹性体是柔软的但具有高的抗撕裂传播性。

4. 发明授权

US4348512A Polyisocyanate reaction products of diisocyanates and s-triazine derivatives containing amino groups, and polymers therefrom 失效
标题翻译：含有氨基的二异氰酸酯和s-三嗪衍生物的多异氰酸酯反应产物及其聚合物
公开(公告)号：US4348512A
公开(公告)日：1982-09-07
申请号：US206115
申请日：1980-11-12
申请人： Gerhard Grogler , Holger Meyborg
发明人： Gerhard Grogler , Holger Meyborg
IPC分类号： C07D251/18 , C07D251/50 , C07D251/52 , C07D251/70 , C08G18/80 , C08G18/77
CPC分类号： C07D251/52 , C07D251/18 , C07D251/50 , C07D251/70 , C08G18/8058
摘要： The invention relates to polyisocyanates corresponding to the following general formula: ##STR1## wherein X represents a radical of the type obtained by removing the more reactive isocyanate group from an organic diisocyanate containing isocyanate groups of different reactivity; andY represents a chlorine, bromine, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aroxy radical or a radical corresponding to the general formula: --NH--CO--NH--X.These polyisocyanates are produced by reacting polyamines corresponding toX as shown above;Y represents --NH--CO--NH--X.
摘要翻译：本发明涉及对应于以下通式的多异氰酸酯：其中X表示通过从具有不同反应性的异氰酸酯基团的有机二异氰酸酯基中除去更多的反应性异氰酸酯基而获得的类型的基团; 并且Y表示氯，溴，C1-C8烷基，C1-C8烷氧基，C6-C10芳基，C6-C10芳氧基或对应于通式-NH-CO-NH-X的基团。这些多异氰酸酯是通过使如上所示的对应于X的多胺反应来制备的; Y表示-NH-CO-NH-X。

5. 发明授权

US4189542A Process for the production of foam moldings having an impervious outer skin using semi-prepolymer prepared from isocyanates such as isophorone diisocyanate 失效
标题翻译：使用由异氰酸酯如异佛尔酮二异氰酸酯制备的半预聚物生产具有不透水外皮的泡沫塑料制品的方法
公开(公告)号：US4189542A
公开(公告)日：1980-02-19
申请号：US930303
申请日：1978-08-02
申请人： Helmut Kleimann , Holger Meyborg , Hans-Jurgen Lienert , Gerhard Grogler
发明人： Helmut Kleimann , Holger Meyborg , Hans-Jurgen Lienert , Gerhard Grogler
IPC分类号： C08J9/02 , C08G18/10 , C08G18/75 , C08G18/80 , C08G18/14
CPC分类号： C08G18/8058 , C08G18/10 , C08G18/75 , C08G18/8032
摘要： The instant invention is directed to a process for the production of weather-resistant rigid molded foams based on polyurethanes having a dimensional stability under heat according to DIN 53 432 of at least 70.degree. C. and a compact surface, a cellular core and an integral density distribution throughout the cross-section of the moldings, comprising foaming a foamable reaction mixture of polyisocyanates, polyhydroxyl compounds, blowing agents and, optionally, other isocyanate-reactive compounds, activators and other auxiliaries in a closed mold under the conditions of in-mold foaming, the improvement wherein the polyisocyanates used are reaction products containing isocyanate groups and urethane groups, said reaction products formed by reacting diisocyanates containing at least one cycloaliphatically bound isocyanate group and no more than one aliphatically bound isocyanate group with sub-stoichiometric quantities of organic polyhydroxyl compounds.
摘要翻译：本发明涉及一种用于生产基于聚氨酯的耐候刚性模塑泡沫的方法，所述聚氨酯在根据DIN 53 432的加热条件下具有至少70℃的尺寸稳定性，以及紧凑的表面，多孔芯和积分包括在模制品的整个横截面处的密度分布，包括在模内的条件下，在封闭模具中发泡多异氰酸酯，多羟基化合物，发泡剂和任选的其它异氰酸酯反应性化合物，活化剂和其它助剂的可发泡反应混合物发泡，其中使用的多异氰酸酯是含有异氰酸酯基团和氨基甲酸酯基团的反应产物的改进，所述反应产物是通过使含有至少一个环脂族连接的异氰酸酯基团的二异氰酸酯和不超过一个脂族结合的异氰酸酯基团与亚化学计量的有机多羟基化合物。

6. 发明授权

US4255570A Polyisocyanate reaction products of diisocyanates and s-triazine derivatives containing amino groups 失效
标题翻译：含有氨基的二异氰酸酯和s-三嗪衍生物的多异氰酸酯反应产物
公开(公告)号：US4255570A
公开(公告)日：1981-03-10
申请号：US930611
申请日：1978-08-03
申请人： Gerhard Grogler , Holger Meyborg
发明人： Gerhard Grogler , Holger Meyborg
IPC分类号： C07D251/18 , C07D251/50 , C07D251/52 , C07D251/70 , C08G18/80 , C07D251/54 , C07D251/46 , C07D251/48
CPC分类号： C07D251/52 , C07D251/18 , C07D251/50 , C07D251/70 , C08G18/8058
摘要： The invention relates to polyisocyanates corresponding to the following general formula: ##STR1## wherein X represents a radical of the type obtained by removing the more reactive isocyanate group from an organic diisocyanate containing isocyanate groups of different reactivity; andY represents a chlorine, bromine, C.sub.1 -C.sub.8 alkyl, C.sub.1 -C.sub.8 alkoxy, C.sub.6 -C.sub.10 aryl, C.sub.6 -C.sub.10 aroxy radical or a radical corresponding to the general formula: --NH--CO--NH--X.
摘要翻译：本发明涉及对应于以下通式的多异氰酸酯：其中X表示通过从具有不同反应性的异氰酸酯基团的有机二异氰酸酯基中除去更多的反应性异氰酸酯基而获得的类型的基团; 并且Y表示氯，溴，C1-C8烷基，C1-C8烷氧基，C6-C10芳基，C6-C10芳氧基或对应于通式-NH-CO-NH-X的基团。

7. 发明授权

US4350781A Process for the preparation of polymer precursors containing oxazolin-2-one rings 失效
标题翻译：制备含恶唑啉-2-酮环的聚合物前体的方法
公开(公告)号：US4350781A
公开(公告)日：1982-09-21
申请号：US286419
申请日：1981-07-24
申请人： Werner Rasshofer , Gerhard Grogler , Holger Meyborg
发明人： Werner Rasshofer , Gerhard Grogler , Holger Meyborg
IPC分类号： C07D263/62 , C08G18/10 , C08G18/38 , C08G18/80 , C08G18/32
CPC分类号： C07D263/62 , C08G18/10 , C08G18/3844 , C08G18/80
摘要： A polymer precursor containing an oxazolin-2-one ring is made by reacting (a) an amino-reactive group containing compound having at least two groups capable of entering into an addition or condensation reaction with primary or secondary aromatically-bound amino groups with (b) an aromatic amine having at least one primary or secondary aromatically-bound amino group and at least one condensed oxazolin-2-one ring. The reactants are used in quantities such that for each aromatically bound primary or secondary amino group there are from 0.95 to 5 groups present in the amino-reactive group containing compound which are capable of reacting with the amino group. These polymer precursors may be used to produce high molecular weight polymers useful in the production of solid molded products, adhesives, foam plastics and coatings.
摘要翻译：含有恶唑啉-2-酮环的聚合物前体是通过使（a）具有至少两个能够与伯或仲芳族结合的氨基进行加成或缩合反应的基团的含氨基反应性基团的化合物与（ b）具有至少一个伯或仲芳族结合的氨基和至少一个稠合的恶唑啉-2-酮的芳族胺。反应物的用量使得对于每个芳香结合的伯或仲氨基，在含有氨基反应性基团的化合物中存在0.95至5个能够与氨基反应的基团。这些聚合物前体可用于生产用于生产固体模制产品，粘合剂，泡沫塑料和涂料的高分子量聚合物。

8. 发明授权

US4146688A Process for making polyurethane resins via thio-group containing diamines 失效
标题翻译：通过含有二氨基的组合制备聚氨酯树脂的方法
公开(公告)号：US4146688A
公开(公告)日：1979-03-27
申请号：US826496
申请日：1977-08-22
申请人： Jurgen Schwindt , Gerhard Grogler , Paul Uhrhan
发明人： Jurgen Schwindt , Gerhard Grogler , Paul Uhrhan
IPC分类号： C08G18/00 , C08G18/10 , C08G18/38 , C08G18/65 , C08G18/14
CPC分类号： C08G18/3868 , C08G18/10
摘要： This invention relates to new polyurethane resins produced by a process in which aromatic diamines containing thio-groups are used as chain-lengthening agents.

9. 发明授权

US4276386A Diisocyanates having urea groups, a process for their preparation and their use in the production of polyurethanes 失效
标题翻译：具有尿素基团的二异氰酸酯，其制备方法及其在生产聚氨酯中的应用
公开(公告)号：US4276386A
公开(公告)日：1981-06-30
申请号：US152285
申请日：1980-05-22
申请人： Jurgen Schwindt , Gerhard Grogler
发明人： Jurgen Schwindt , Gerhard Grogler
IPC分类号： C07C323/44 , C08G18/10 , C08G18/77 , C08G18/78 , C08G18/80 , C08G18/14
CPC分类号： C08G18/8045 , C07C323/44 , C08G18/10 , C08G18/775 , C08G18/7825
摘要： This invention relates to new diisocyanates containing urea groups which are liquid at room temperature or can be liquefied by heating to a temperature of up to 80.degree. C. These novel diisocyanates may be in the form of solutions in isocyanate prepolymers. The invention also is directed to a process for preparation of these new diisocyanates by the reaction of special diisocyanate starting materials and water and to their use as components for the production of polyurethanes.
摘要翻译：本发明涉及含有尿素基团的新型二异氰酸酯，其在室温下为液体，或通过加热至高达80℃的温度而液化。这些新型二异氰酸酯可以是异氰酸酯预聚物中的溶液形式。本发明还涉及通过特殊的二异氰酸酯原料与水的反应制备这些新的二异氰酸酯的方法，以及它们作为生产聚氨酯的组分的用途。

10. 发明授权

US4254229A Polyurethane plastics containing thio groups 失效
标题翻译：含硫基的聚氨酯塑料
公开(公告)号：US4254229A
公开(公告)日：1981-03-03
申请号：US106976
申请日：1979-12-26
申请人： Jurgen Schwindt , Gerhard Grogler , Paul Uhrhan
发明人： Jurgen Schwindt , Gerhard Grogler , Paul Uhrhan
IPC分类号： C08G18/10 , C08G18/38 , C08J5/18 , C08G18/14 , C07C149/40 , C08G18/32
CPC分类号： C08J5/18 , C08G18/10 , C08G18/3868 , C08J2367/02
摘要： The instant invention is directed to polyurethane plastics which may be cellular, produced by reaction of polyisocyanates with relatively high molecular weight polyhydroxyl compounds and, optionally, low molecular weight polyhydroxyl compounds, and diamines, said polyurethane plastic containing structural units corresponding to the general formula ##STR1## in which R' represents a straight or branched divalent aliphatic, cycloaliphatic or aromatic radicals containing from 2 to 20 carbon atoms andR" represents hydrogen, a straight or branched alkyl radical containing from 1 to 6 carbon atoms, an aryl radical containing from 6 to 15 carbon atoms, a cycloalkyl radical containing from 4 to 12 carbon atoms, halogen, --NO.sub.2, --CN, --OR'" or a radical ##STR2## where R"' represents a straight or branched alkyl radical containing from 1 to 6 carbon atoms.
摘要翻译：本发明涉及可通过多异氰酸酯与相对高分子量多羟基化合物和任选的低分子量多羟基化合物和二胺的反应制备的聚氨酯塑料，所述聚氨酯塑料含有对应于通式 IMAGE>其中R'表示含有2至20个碳原子的直链或支链二价脂族，脂环族或芳族基团，R“表示氢，含有1至6个碳原子的直链或支链烷基，含有 6至15个碳原子的环烷基，含有4至12个碳原子的环烷基，卤素，-NO 2，-CN，-OR“或其中R”'表示含有直链或支链烷基的基团 1至6个碳原子。

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