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1. 发明申请

US20100148109A1 XEROGELS MADE FROM AROMATIC POLYUREAS 审中-公开
标题翻译：来自芳族聚酯的XEROGELS
公开(公告)号：US20100148109A1
公开(公告)日：2010-06-17
申请号：US12600350
申请日：2008-05-16
申请人： Volker Schädler , Marc Fricke , Werner Wiegmann , Andreas Emge , Vijay Immanuel Raman , Antonio Sanchez-Ferrer
发明人： Volker Schädler , Marc Fricke , Werner Wiegmann , Andreas Emge , Vijay Immanuel Raman , Antonio Sanchez-Ferrer
IPC分类号： E04B1/74
CPC分类号： C08J9/28 , C08G18/3243 , C08G18/7664 , C08G2101/0091 , C08G2330/50 , C08J2201/0502 , C08J2205/028 , C08J2375/02 , E06B3/6612 , E06B3/6775
摘要： The invention relates to a xerogel comprising from 30 to 90% by weight of a monomer component (a1) composed of at least one polyfunctional isocyanate and from 10 to 70% by weight of a monomer component (a2) composed of at least one polyfunctional aromatic amine, at least one of which is selected from 4,4′-diaminodiphenylmethane, 2,4′-diaminodiphenylmethane, 2,2′-diaminodiphenylmethane and oligomeric diaminodiphenylmethane, where the sum of the % by weight of monomer components (a1) and (a2) adds up to 100% by weight and where the monomer components are present in polymeric form in the xerogel and the volume-weighted mean pore diameter of the xerogel is at most 5 μm, The invention further relates to a process for preparing xerogels, to the xerogels thus obtainable and to the use of the xerogels as an insulating material and in vacuum insulation panels.
摘要翻译：本发明涉及一种干凝胶，其包含30至90重量％的由至少一种多官能异氰酸酯组成的单体组分（a1）和10至70重量％的由至少一种多官能芳族化合物组成的单体组分（a2）胺，其中至少一种选自4,4'-二氨基二苯基甲烷，2,4'-二氨基二苯基甲烷，2,2'-二氨基二苯基甲烷和低聚二氨基二苯基甲烷，其中单体成分（a1）和（a1） a2）加入高达100重量％，其中单体组分以干凝胶形式存在于聚合物形式中，并且干凝胶的体积加权平均孔径至多为5μm。本发明还涉及一种制备干凝胶的方法，涉及这样获得的干凝胶，以及使用干凝胶作为绝缘材料和真空绝热面板。

2. 发明授权

US09505900B2 Method for producing xerogel composites 有权
标题翻译：干凝胶复合材料的制备方法
公开(公告)号：US09505900B2
公开(公告)日：2016-11-29
申请号：US13256905
申请日：2010-03-12
申请人： Marc Fricke , Volker Schädler , Thomas Breiner , Antoni Sánchez-Ferrer , Francois-Xavier Simon , Daniel Schmidt
发明人： Marc Fricke , Volker Schädler , Thomas Breiner , Antoni Sánchez-Ferrer , Francois-Xavier Simon , Daniel Schmidt
IPC分类号： C08J9/40 , C08G18/32 , C08L75/04 , C08G101/00
CPC分类号： C08J9/405 , C08G18/3243 , C08G2101/0091 , C08G2330/50 , C08J2205/02 , C08J2361/28 , C08J2475/00 , C08L75/04
摘要： The invention relates to a process for producing xerogel composites, which comprises: (a) provision of a composition comprising an organic gel precursor (A) comprising a monomer component (A1) composed of at least one polyfunctional isocyanate and a monomer component (A2) composed of at least one compound selected from among polyfunctional amines and polyfunctional hydroxy compounds; (b) reaction of the gel precursor (A) in the presence of an open-celled macroporous foam (B) and a solvent (C) to form a xerogel composite; (c) drying of the xerogel composite by conversion of the solvent (C) into the gaseous state at a temperature and a pressure below the critical temperature and the critical pressure of the solvent (C). The invention further relates to the xerogel composites which can be obtained in this way and their use as insulating material, for thermal insulation, vacuum insulation panels, in refrigeration units or in buildings.
摘要翻译：本发明涉及一种生产干凝胶复合材料的方法，其包括：（a）提供包含由至少一种多官能异氰酸酯和单体组分（A2）组成的单体组分（A1）的有机凝胶前体（A）由至少一种选自多官能胺和多官能羟基化合物的化合物组成; （b）凝胶前体（A）在开孔大孔泡沫（B）和溶剂（C）的存在下的反应以形成干凝胶复合材料; （c）通过在低于临界温度和溶剂（C）的临界压力的温度和压力下将溶剂（C）转化为气态来干燥干凝胶复合材料。本发明还涉及可以以这种方式获得的干凝胶复合材料及其作为绝热材料，隔热材料，真空隔热板，制冷装置或建筑物中的用途。

3. 发明申请

US20120007012A1 METHOD FOR PRODUCING XEROGEL COMPOSITES 有权
标题翻译：生产XEROGEL复合材料的方法
公开(公告)号：US20120007012A1
公开(公告)日：2012-01-12
申请号：US13256905
申请日：2010-03-12
申请人： Marc Fricke , Volker Schädler , Thomas Breiner , Antoni Sánchez-Ferrer , Francois-Xavier Simon , Daniel Schmidt
发明人： Marc Fricke , Volker Schädler , Thomas Breiner , Antoni Sánchez-Ferrer , Francois-Xavier Simon , Daniel Schmidt
IPC分类号： E04B1/78 , C08J9/42
CPC分类号： C08J9/405 , C08G18/3243 , C08G2101/0091 , C08G2330/50 , C08J2205/02 , C08J2361/28 , C08J2475/00 , C08L75/04
摘要： The invention relates to a process for producing xerogel composites, which comprises: (a) provision of a composition comprising an organic gel precursor (A) comprising a monomer component (A1) composed of at least one polyfunctional isocyanate and a monomer component (A2) composed of at least one compound selected from among polyfunctional amines and polyfunctional hydroxy compounds; (b) reaction of the gel precursor (A) in the presence of an open-celled macroporous foam (B) and a solvent (C) to form a xerogel composite; (c) drying of the xerogel composite by conversion of the solvent (C) into the gaseous state at a temperature and a pressure below the critical temperature and the critical pressure of the solvent (C). The invention further relates to the xerogel composites which can be obtained in this way and their use as insulating material, for thermal insulation, vacuum insulation panels, in refrigeration units or in buildings.
摘要翻译：本发明涉及一种生产干凝胶复合材料的方法，其包括：（a）提供包含由至少一种多官能异氰酸酯和单体组分（A2）组成的单体组分（A1）的有机凝胶前体（A）由至少一种选自多官能胺和多官能羟基化合物的化合物组成; （b）凝胶前体（A）在开孔大孔泡沫（B）和溶剂（C）的存在下的反应以形成干凝胶复合材料; （c）通过在低于临界温度和溶剂（C）的临界压力的温度和压力下将溶剂（C）转化为气态来干燥干凝胶复合材料。本发明还涉及可以以这种方式获得的干凝胶复合材料及其作为绝热材料，隔热材料，真空隔热板，制冷装置或建筑物中的用途。

4. 发明授权

US06852423B2 Paper coating slips containing binding agents with macromonomers 失效
标题翻译：含有大分子单体的粘合剂的纸涂布纸
公开(公告)号：US06852423B2
公开(公告)日：2005-02-08
申请号：US10240267
申请日：2001-03-27
申请人： Volker Schädler , David Christie , Roland Ettl
发明人： Volker Schädler , David Christie , Roland Ettl
IPC分类号： D21H19/58 , D21H19/56
CPC分类号： D21H19/58 , Y10T428/24802 , Y10T428/31899 , Y10T428/31902 , Y10T428/31906
摘要： In paper coating slips containing, as a binder, a copolymer which is obtainable by free radical polymerization of ethylenically unsaturated compounds, at least one of the ethylenically unsaturated compounds is a polymer having at least one copolymerizable ethylenically unsaturated group, a number average molecular weight of from 500 to 50000 g/mol and at least one carboxyl group (referred to below as ethylenically unsaturated polymer for short).
摘要翻译：在含有可通过烯键式不饱和化合物的自由基聚合获得的共聚物作为粘合剂的纸涂布纸中，至少一种烯属不饱和化合物是具有至少一个可共聚的烯属不饱和基团的聚合物，数均分子量 500〜50000g / mol和至少一个羧基（以下简称为烯属不饱和聚合物）。

5. 发明授权

US06696518B1 Method of selectively hydrogenating ethylenically unsaturated double bonds in polymers 失效
标题翻译：在聚合物中选择性氢化烯属不饱和双键的方法
公开(公告)号：US06696518B1
公开(公告)日：2004-02-24
申请号：US09926625
申请日：2001-11-27
申请人： Rolf Dersch , Heiko Maas , Volker Schädler
发明人： Rolf Dersch , Heiko Maas , Volker Schädler
IPC分类号： C08L3310
CPC分类号： C08C19/02 , C08F8/04 , C09D1/04
摘要： The present invention relates to a process for hydrogenating ethylenically unsaturated double bonds in polymers P by reacting an aqueous dispersion of at least one polymer P with hydrogen in the presence of at least one hydrogenation catalyst comprising at least one transition metal selected from rhodium and/or ruthenium and at least one nonionic phosphorus compound capable of forming a coordinative compound with the transition metal, which comprises incorporating the hydrogenation catalyst into the aqueous dispersion of the polymer P without adding a solvent. The present invention also relates to the aqueous dispersions of the hydrogenated polymers P obtainable by this process and to coating compositions comprising such dispersions.
摘要翻译：本发明涉及通过使至少一种聚合物P的水性分散体与氢在至少一种包含至少一种选自铑和/或其中的过渡金属的氢化催化剂的存在下，使聚合物P中的烯属不饱和双键氢化的方法，钌和能够与过渡金属形成配位化合物的至少一种非离子型磷化合物，其包括在不添加溶剂的情况下将氢化催化剂并入聚合物P的水性分散体。本发明还涉及通过该方法获得的氢化聚合物P的水分散体和包含这种分散体的涂料组合物。

6. 发明授权

US08206626B2 Method for producing nanoporous molded parts 有权
标题翻译：生产纳米多孔成型件的方法
公开(公告)号：US08206626B2
公开(公告)日：2012-06-26
申请号：US12307179
申请日：2007-06-27
申请人： Andre Guerin Moreira , Marc Bothe , Volker Schädler , Markus Allmendinger , Pedro Manuel Sampaio Lopes , Bernd Sowart , Timothy Francis , Erik Waβner , Christian Schade , Daniela Longo , Siljana Lietz , Volker Alstädt , Jan Sandler
发明人： Andre Guerin Moreira , Marc Bothe , Volker Schädler , Markus Allmendinger , Pedro Manuel Sampaio Lopes , Bernd Sowart , Timothy Francis , Erik Waβner , Christian Schade , Daniela Longo , Siljana Lietz , Volker Alstädt , Jan Sandler
IPC分类号： C08J9/00 , B29C44/34
CPC分类号： C08J9/0061 , B29C44/04 , B29C44/0484 , C08J9/14 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2203/142 , C08J2325/06 , C08J2425/00 , C08J2451/00 , C08J2453/00
摘要： Process for the production of moldings from nanoporous polymer materials, comprising the stages of a) preparation of a multiphase polymer mixture with domains in the range from 5 to 200 nm, b) impregnation of the polymer mixture with a blowing agent, where the solubility of the blowing agent in the phase forming the domains is at least twice as high as in the adjacent phases, c) expansion of the multiphase polymer mixture comprising blowing agent, by introducing the polymer mixture into a cavity and expanding it therein, thus obtaining the molding.
摘要翻译：包括以下步骤：a）制备具有5至200nm范围内的结构域的多相聚合物混合物的步骤，b）用发泡剂浸渍聚合物混合物，其中溶解度形成区域的相中的发泡剂是相邻相中的至少两倍，c）通过将聚合物混合物引入空腔并在其中膨胀从而使包含发泡剂的多相聚合物混合物膨胀，从而获得模塑。

7. 发明申请

US20100025877A1 METHOD FOR PRODUCING NANOPOROUS MOLDED PARTS 有权
标题翻译：生产纳米成型件的方法
公开(公告)号：US20100025877A1
公开(公告)日：2010-02-04
申请号：US12307179
申请日：2007-06-27
申请人： Andre Guerin Moreira , Marc Bothe , Volker Schädler , Markus Allmendinger , Pedro Manuel Sampaio Lopes , Bernd Sowart , Timothy Francis , Erik Wassner , Christian Schade , Daniela Longo , Siljana Lietz , Volker Alstädt , Jan Sandler
发明人： Andre Guerin Moreira , Marc Bothe , Volker Schädler , Markus Allmendinger , Pedro Manuel Sampaio Lopes , Bernd Sowart , Timothy Francis , Erik Wassner , Christian Schade , Daniela Longo , Siljana Lietz , Volker Alstädt , Jan Sandler
IPC分类号： C08J9/06
CPC分类号： C08J9/0061 , B29C44/04 , B29C44/0484 , C08J9/14 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2203/142 , C08J2325/06 , C08J2425/00 , C08J2451/00 , C08J2453/00
摘要： Process for the production of moldings from nanoporous polymer materials, comprising the stages of a) preparation of a multiphase polymer mixture with domains in the range from 5 to 200 nm, b) impregnation of the polymer mixture with a blowing agent, where the solubility of the blowing agent in the phase forming the domains is at least twice as high as in the adjacent phases, c) expansion of the multiphase polymer mixture comprising blowing agent, by introducing the polymer mixture into a cavity and expanding it therein, thus obtaining the molding.
摘要翻译：包括以下步骤：a）制备具有5至200nm范围内的结构域的多相聚合物混合物的步骤，b）用发泡剂浸渍聚合物混合物，其中溶解度形成区域的相中的发泡剂是相邻相中的至少两倍，c）通过将聚合物混合物引入空腔并在其中膨胀从而使包含发泡剂的多相聚合物混合物膨胀，从而获得模塑。

8. 发明授权

US06566457B2 Impact modifiers prepared from (partially) hydrogenated butadiene-containing dispersions 失效
标题翻译：由（部分）含氢化丁二烯的分散体制备的抗冲改性剂
公开(公告)号：US06566457B2
公开(公告)日：2003-05-20
申请号：US09825957
申请日：2001-04-05
申请人： Peter Barghoorn , Volker Schädler , Heiko Maas , Norbert Niessner
发明人： Peter Barghoorn , Volker Schädler , Heiko Maas , Norbert Niessner
IPC分类号： C08F804
CPC分类号： C08F279/02 , C08F212/06
摘要： The invention relates to a process for preparing graft rubbers built up from at least one graft core and from at least one graft shell, comprising a) preparing an aqueous dispersion of at least one elastomeric polymer, b) then, to obtain the at least one graft core, selectively hydrogenating ethylenically unsaturated double bonds in the elastomeric polymer, using hydrogen, in the presence of at least one hydrogenation catalyst, where the aqueous dispersion of the elastomeric polymer comprises not more than 20% by volume of an organic solvent, and c) grafting onto the graft core at least one graft shell, and also to the corresponding graft rubbers. The invention further relates to blends comprising a) from 2 to 70% by weight of a graft rubber according to the invention, as component A, b) from 30 to 98% by weight of a thermoplastic polymer or of a mixture of various thermoplastic polymers, as component B, and c) from 0 to 50% by weight of other additives, as component C, where the entirety of components A to C is 100% by weight, based on the blend.
摘要翻译：本发明涉及一种用于制备由至少一个接枝芯和至少一个接枝壳构成的接枝橡胶的方法，该方法包括：a）制备至少一种弹性体聚合物的水性分散体，b）然后b）得到至少一个接枝在至少一种氢化催化剂的存在下，使用氢气在弹性体聚合物中选择性氢化烯键式不饱和双键，其中弹性体聚合物的水分散体包含不超过20体积％的有机溶剂，和c）接枝在接枝芯上至少一个接枝壳，以及相应的接枝橡胶。本发明还涉及包含a）2-70重量％的根据本发明的接枝橡胶作为组分A，b）从30 至98重量％的热塑性聚合物或作为组分B的各种热塑性聚合物的混合物，和c）0至50重量％的其它添加剂作为组分C，其中全部Co 基于混合物，组分A至C为100重量％。

9. 发明授权

US09623540B2 Flexible, flat substrates having an abrasive surface 有权
公开(公告)号：US09623540B2
公开(公告)日：2017-04-18
申请号：US12524184
申请日：2008-01-22
申请人： Maxim Peretolchin , Günter Scherr , Roland Ettl , Volker Schädler
发明人： Maxim Peretolchin , Günter Scherr , Roland Ettl , Volker Schädler
IPC分类号： B24D3/28 , D21H19/16 , D21H19/26
CPC分类号： B24D3/28 , D21H19/16 , D21H19/26 , Y10T428/24355
摘要： Flexible, sheet-like substrates having an abrasive surface, which are obtainable by applying an aqueous solution or dispersion of at least one precondensate of a heat-curable resin to the top and/or bottom of a flexible, sheet-like substrate in an amount of at least 5 to 90% by weight, based on the uncoated, dry substrate, crosslinking the precondensate and drying the treated substrate.

10. 发明授权

US08067480B2 Porous polyisocyanate polyaddition products 有权
标题翻译：多孔多异氰酸酯加成产物
公开(公告)号：US08067480B2
公开(公告)日：2011-11-29
申请号：US11916069
申请日：2006-05-30
申请人： Daniel Schmidt , Volker Schädler
发明人： Daniel Schmidt , Volker Schädler
IPC分类号： C08G18/28
CPC分类号： C08G18/4236 , C08G2101/0066 , C08G2101/0091
摘要： Process for producing porous polyisocyanate polyaddition products by reacting (a) isocyanates with (b) compounds which are reactive toward isocyanates in the presence of (f) solvent, wherein compounds having a functionality toward isocyanates of at least 6 and a molecular weight of at least 1000 g/mol are used as (b) compounds which are reactive toward isocyanates.
摘要翻译：通过使（a）异氰酸酯与（b）在（f）溶剂存在下对异氰酸酯具有反应性的化合物反应制备多孔多异氰酸酯加聚产物的方法，其中具有至少6的异氰酸酯官能度至少为6，分子量至少为使用1000g / mol作为（b）对异氰酸酯具有反应性的化合物。

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