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    • 8. 发明申请
    • DISHWASHER DETERGENT FORMULATIONS COMPRISING A MIXTURE OF HYDROPHOBICALLY MODIFIED POLYCARBOXYLATES AND HYDROPHILICALLY MODIFIED POLYCARBOXYLATES
    • 含有疏水性改性聚碳酸酯和疏水改性聚碳酸酯的混合物的洗涤剂洗涤剂配方
    • US20100234265A1
    • 2010-09-16
    • US12682260
    • 2008-10-10
    • Heike WeberRoland EttlJuergen Tropsch
    • Heike WeberRoland EttlJuergen Tropsch
    • C11D3/37
    • C11D3/3757C11D1/72C11D3/33C11D3/3905
    • Phosphate-free detergent formulations for machine dishwashing, comprising, as components: a) from 1 to 20% by weight of a mixture of a1) from 5 to 95% by weight of hydrophobically modified polycarboxylates I formed from a11) from 20 to 80 mol % of at least one monoethylenically unsaturated C3-C10-mono- or -dicarboxylic acid or anhydrides thereof, a12) from 0 to 80 mol % of at least one monomer of the general formula (I)  in which R1, R2 and R3 are each independently H, CH3 or C2H5, and R4 is a linear, branched or cyclic radical having from 1 to 6 carbon atoms or an aromatic radical having from 6 to 12 carbon atoms, and a13) from 0 to 20 mol % of at least one further monomer selected from the group consisting of olefins having 10 or more carbon atoms or mixtures thereof and reactive polyisobutenes having an average of from 12 to 100 carbon atoms, a2) from 5 to 95% by weight of hydrophilically modified polycarboxylates II formed from a21) from 50 to 99 mol % of acrylic acid or acrylic acid salt, a22) from 0 to 50 mol % of a further acidic monomer and/or of a water-soluble salt thereof, a23) from 0.1 to 20 mol % of at least one nonionic monomer of the general formula (II), where the sum of a1) and a2) adds up to 100% by weight, b) from 0 to 50% by weight of complexing agents, c) from 0.1 to 20% by weight of low-foam nonionic surfactants, d) from 0.1 to 30% by weight of bleaches and if appropriate bleach activators, e) from 0 to 60% by weight of further builders, f) from 0 to 8% by weight of enzymes, g) from 0 to 50% by weight of one or more further additives.
    • 包含作为组分的无磷酸盐洗涤剂配方:a)1至20重量%的a1)5至95重量%的疏水改性的多羧酸盐I的混合物,由a11)20至80mol %的至少一种单烯属不饱和C 3 -C 10 - 单 - 或二羧酸或其酸酐,a 12)0至80摩尔%的至少一种通式(I)的单体,其中R 1,R 2和R 3各自为 独立地是H,CH 3或C 2 H 5,并且R 4是具有1至6个碳原子的直链,支链或环状基团或具有6至12个碳原子的芳族基团,和a 13)0至20摩尔%的至少一种 选自具有10个或更多个碳原子的烯烃或其混合物的单体和平均具有12至100个碳原子的活性聚异丁烯,a2)5至95重量%的亲水改性的聚羧酸盐II,其由 50〜99摩尔%的丙烯酸或丙烯酸 酸性盐,a22)0〜50摩尔%的其它酸性单体和/或其水溶性盐,a23)0.1〜20摩尔%的至少一种通式(II)的非离子单体,其中 a1)和a2)的总和相加至100重量%,b)0至50重量%的络合剂,c)0.1至20重量%的低泡沫非离子表面活性剂,d)0.1至 30%(重量)的漂白剂和适当的漂白活化剂,e)0-60%(重量)的另外助洗剂,f)0-8%(重量)的酶,g)0-50%重量的一种或多种 其他添加剂。