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1. 发明授权

US06369267B1 Polyoxyalkylene substituted and bridged triazine, benzotriazole and benzophenone derivatives as UV absorbers 失效
标题翻译：聚氧亚烷基取代和桥连的三嗪，苯并三唑和二苯甲酮衍生物作为UV吸收剂
公开(公告)号：US06369267B1
公开(公告)日：2002-04-09
申请号：US09679231
申请日：2000-10-04
申请人： Vien Van Toan , Andreas Valet , Pascal Hayoz
发明人： Vien Van Toan , Andreas Valet , Pascal Hayoz
IPC分类号： C07D25124
CPC分类号： A61K8/4966 , A61Q17/04 , C07C49/84 , C07C59/315 , C07D249/20 , C07D251/24 , C08K5/132 , C08K5/34 , C08K5/3475 , C08K5/3492 , Y10S430/132
摘要： Triazine, benzotriazole and benzophenone derivatives which are substituted or bridged with polyoxyalkylene groups, according to claim 1, and their use as UV absorbers, especially in photographic materials, in inks, including inkjet inks and printing inks, in transfer prints, in paints and varnishes, organic polymeric materials, plastics, rubber, glass, packaging materials, in sunscreens of cosmetic preparations and in skin protection compositions.
摘要翻译：根据权利要求1的三取代苯并三唑和二苯甲酮衍生物，它们是用聚氧亚烷基取代或桥连的，它们作为UV吸收剂，特别是在照相材料中用作墨水，包括喷墨油墨和印刷油墨，转印印刷品，油漆和清漆中的用途，有机聚合材料，塑料，橡胶，玻璃，包装材料，化妆品制剂的防晒剂和皮肤保护组合物。

2. 发明授权

US06653484B2 Polyoxyalkylene substituted and bridged benzotriazole derivatives 失效
公开(公告)号：US06653484B2
公开(公告)日：2003-11-25
申请号：US10006634
申请日：2001-11-08
申请人： Vien Van Toan , Andreas Valet , Pascal Hayoz
发明人： Vien Van Toan , Andreas Valet , Pascal Hayoz
IPC分类号： C07D24920
CPC分类号： A61K8/4966 , A61Q17/04 , C07C49/84 , C07C59/315 , C07D249/20 , C07D251/24 , C08K5/132 , C08K5/34 , C08K5/3475 , C08K5/3492 , Y10S430/132
摘要： Triazine, benzotriazole and benzophenone derivatives which are substituted or bridged with polyoxyalkylene groups, according to claim 1, and their use as UV absorbers, especially in photographic materials, in inks, including inkjet inks and printing inks, in transfer prints, in paints and varnishes, organic polymeric materials, plastics, rubber, glass, packaging materials, in sunscreens of cosmetic preparations and in skin protection compositions.

3. 发明授权

US6013704A Hydroxyphenyltriazines 失效
标题翻译：羟基苯基三嗪
公开(公告)号：US6013704A
公开(公告)日：2000-01-11
申请号：US929147
申请日：1997-09-10
申请人： Pascal Hayoz , Andreas Valet , Vien Van Toan
发明人： Pascal Hayoz , Andreas Valet , Vien Van Toan
IPC分类号： G03C7/392 , C07D251/24 , C07D405/12 , C07D405/14 , C08K5/3435 , C08K5/3492 , C09K15/30 , C07D251/00
CPC分类号： C07D405/12 , C07D251/24 , C07D405/14 , C08K5/3435 , C08K5/3492
摘要： There are described compounds of formula A whereinr.sub.1 and r.sub.2 are each independently of the other 0 or 1;Y.sub.1 to Y.sub.9 are each independently of the others --H, --OH, C.sub.1 -C.sub.20 alkyl, C.sub.4 -C.sub.20 cycloalkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.1 -C.sub.20 alkoxy, C.sub.4 -C.sub.12 cycloalkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.7 -C.sub.20 aralkyl, halogen, --C.tbd.N, C.sub.1 -C.sub.5 haloalkyl, --SO.sub.2 R', --SO.sub.3 H, --SO.sub.3 M, wherein M is an alkali metal, --COOR', --CONHR', --CONR'R", --OCOOR', --OCOR', --OCONHR', (meth)acrylamino, (meth)-acryloxy, C.sub.6 -C.sub.12 aryl; C.sub.6 -C.sub.12 aryl substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, CN and/or by halogen; C.sub.3 -C.sub.12 heteroaryl; C.sub.3 -C.sub.12 heteroaryl substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, CN and/or by halogen; or Q of formula I, and at least one substituent Y.sub.1 to Y.sub.9 must be Q ##STR1## wherein q is 0 or 1,R is a cyclic radical andR.sub.1 and T are as defined in claim 1. The novel compounds are suitable, especially in combination with hindered amines, for the stabilisation of organic material against the damaging action of light, oxygen and heat.
摘要翻译：描述式A的化合物，其中r1和r2各自独立地为0或1; Y 1至Y 9各自独立地为-H，-OH，C 1 -C 20烷基，C 4 -C 20环烷基，C 2 -C 20 - 烯基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20链烯氧基，C 7 -C 20芳烷基，卤素，-C 3 N，C1-C5卤代烷基，-SO2R'，-SO3H，-SO3M，其中M是碱金属，-COOR'，-CONHR'，-CONR'R“，-OCOOR'，-OCOR'，-OCONHR' （甲基）丙烯酰氨基，（甲基）丙烯酰氧基，C6-C12芳基; 被C 1 -C 12烷基，C 1 -C 12烷氧基，CN和/或被卤素取代的C 6 -C 12芳基; C3-C12杂芳基; 被C 1 -C 12烷基，C 1 -C 12烷氧基，CN和/或被卤素取代的C 3 -C 12杂芳基; 或式I的Q，并且至少一个取代基Y1至Y9必须为Q，其中q为0或1，R为环状基团，R 1和T如权利要求1所定义。该新化合物特别适用于受阻胺，用于稳定有机材料，防止光，氧和热的破坏作用。

4. 发明授权

US5538840A Photographic recording material containing a UV absorber 失效
标题翻译：含有紫外线吸收剂的摄影记录材料
公开(公告)号：US5538840A
公开(公告)日：1996-07-23
申请号：US538090
申请日：1995-10-02
申请人： Vien Van Toan , David G. Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
发明人： Vien Van Toan , David G. Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
IPC分类号： C07D251/24 , C08F12/26 , C08F20/34 , C08F20/36 , C08F20/38 , C08F30/08 , C08K3/16 , C08K5/3492 , C08L87/00 , C09D7/12 , C09K3/00 , G03C1/815
CPC分类号： G03C1/8155 , C07D251/24 , C08F12/26 , C08F20/36 , C08K5/3492 , C09D7/1241 , C08K5/34926
摘要： The invention relates to a photographic recording material comprising, on a base, at least one silver-halide emulsion layer and, if desired, at least one interlayer and/or a protection layer, where at least one of said layers contains a UV absorber of the 2-hydroxyphenyltriazine type, as described in greater detail in claim 1; this UV absorber can also be in the form of a homopolymer or copolymer.
摘要翻译：本发明涉及一种照相记录材料，其在基体上包含至少一种卤化银乳剂层，如果需要，其包含至少一层中间层和/或保护层，其中至少一层所述层含有紫外线吸收剂如在权利要求1中更详细描述的2-羟基苯基三嗪类型; 该UV吸收剂也可以是均聚物或共聚物的形式。

5. 发明授权

US5672704A 2-Hydroxyphenyl-s-Triazines substituted with ethylenically unsaturated moieties 失效
标题翻译：用烯属不饱和部分取代的2-羟基苯基-s-三嗪
公开(公告)号：US5672704A
公开(公告)日：1997-09-30
申请号：US535406
申请日：1995-09-28
申请人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
发明人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
IPC分类号： C07D251/24 , C08F12/00 , C08F12/26 , C08F16/14 , C08F16/28 , C08F16/32 , C08F18/00 , C08F18/24 , C08F20/36 , C08F20/52 , C08F26/02 , C08F212/14 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/42 , C08F220/56 , C08F226/06 , C08K5/3492 , C09D7/12 , C09K3/00 , C09K15/30 , G03C1/815
CPC分类号： G03C1/8155 , C07D251/24 , C08F12/26 , C08F20/36 , C08K5/3492 , C09D7/1241 , C08K5/34926
摘要： s-Triazine UV absorbers of formula I ##STR1## where R.sub.1 is ##STR2## --CH.sub.2 --C(.dbd.CH.sub.2)--R.sub.10, --(CH.sub.2).sub.p --SiR.sub.11 R.sub.11 '--CH.dbd.CH.sub.2, --C(.dbd.O)--(CH.sub.2).sub.q --CH.dbd.CH.sub.2 or --C(.dbd.O)--O--CH.sub.2 --C(.dbd.CH.sub.2)--R.sub.10 ; and E.sub.1 and E.sub.2 are phenyl groups which may be unsubstituted or substituted with a variety of substituents including inter alia alkyl, OH and R.sub.1 ; are polymerizable and are effective stabilizers for a variety of polymeric and other organic substrates.
摘要翻译：（I）其中R1是图像，-CH2-C（= CH2）-R10， - （CH2）p-SiR11R11'-CH = CH2，-C（ = O） - （CH 2）q -CH = CH 2或-C（= O）-O-CH 2 -C（= CH 2）-R 10; E1和E2是可以是未取代的或被各种取代基取代的苯基，所述取代基尤其包括烷基，OH和R 1; 是可聚合的，并且是各种聚合物和其它有机基材的有效的稳定剂。

6. 发明授权

US5869588A Polymeric compounds derived from 2-hydroxy-phenyl-s-triazines substituted with ethylenically unsaturated moieties 失效
标题翻译：衍生自被烯属不饱和部分取代的2-羟基 - 苯基-s-三嗪的聚合物
公开(公告)号：US5869588A
公开(公告)日：1999-02-09
申请号：US865148
申请日：1997-05-29
申请人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
发明人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
IPC分类号： C07D251/24 , C08F12/00 , C08F12/26 , C08F16/14 , C08F16/28 , C08F16/32 , C08F18/00 , C08F18/24 , C08F20/36 , C08F20/52 , C08F26/02 , C08F212/14 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/42 , C08F220/56 , C08F226/06 , C08K5/3492 , C09D7/12 , C09K3/00 , C09K15/30 , G03C1/815 , C08F26/06 , C08F26/08 , C08K5/34
CPC分类号： G03C1/8155 , C07D251/24 , C08F12/26 , C08F20/36 , C08K5/3492 , C09D7/1241 , C08K5/34926
摘要： The invention relates to novel 2-hydroxyphenyltriazines and to homopolymers and copolymers obtainable therefrom, as described in greater detail in claims 1 and 5; the novel compounds can be used as UV absorbers in or for organic materials.
摘要翻译：本发明涉及新的2-羟基苯基三嗪及其可从其获得的均聚物和共聚物，如权利要求1和5中更详细描述的; 新型化合物可用作有机材料中的UV吸收剂或用于有机材料。

7. 发明授权

US5668200A Stabilizer combination 失效
标题翻译：稳定剂组合
公开(公告)号：US5668200A
公开(公告)日：1997-09-16
申请号：US586267
申请日：1996-01-16
申请人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
发明人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
IPC分类号： G03C7/392 , C07D251/14 , C08K5/3477 , C08K5/3492 , C08L101/00 , C09D7/12
CPC分类号： C08K5/3492
摘要： A mixture comprising a compound of the formula I and a compound of the formula II ##STR1## in which n is 1 or 2; R.sub.1, R'.sub.1, R.sub.2, R'.sub.2, R.sub.3 and R.sub.4, independently of one another, are H, C.sub.1 -C.sub.12 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.1 -C.sub.12 alkoxy; C.sub.2 -C.sub.18 alkenoxy; halogen; trifluoromethyl; C.sub.7 -C.sub.11 phenylalkyl; phenyl; phenyl which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; phenoxy; or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen;R.sub.6 is hydrogen, C.sub.1 -C.sub.24 alkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.7 -C.sub.15 phenylalkyl;R.sub.7, in the case where n=1, and R'.sub.7, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl; or are C.sub.1 -C.sub.12 alkyl which is substituted by OH, C.sub.1 -C.sub.18 alkoxy, allyloxy, halogen, --COOH, --COOR.sub.8, --CONH.sub.2, --CONHR.sub.9, --CON(R.sub.9)(R.sub.10), --NH.sub.2, --NHR.sub.9, --N(R.sub.9)(R.sub.10), --NHCOR.sub.11, --CN, --OCOR.sub.11, phenoxy and/or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; or R.sub.7 is C.sub.3 -C.sub.50 alkyl which is interrupted by --O-- and may be substituted by OH; or R.sub.7 is C.sub.3 -C.sub.6 alkenyl; glycidyl; C.sub.5 -C.sub.12 cycloalkyl; cyclohexyl which is substituted by OH, C.sub.1 -C.sub.4 alkyl or --OCOR.sub.11 ; C.sub.7 -C.sub.11 phenylalkyl which is unsubstituted or substituted by OH, Cl or CH.sub.3 ; --CO--R.sub.12 or --SO.sub.2 --R.sub.13 ;and R.sub.7, in the case where n=2, and R.sub.8 to R.sub.23 are as defined in claim 1, is highly suitable for stabilizing organic material.
摘要翻译：包含式I化合物和其中n为1或2的式II化合物（I）其中n为1或2的混合物; R 1，R'1，R 2，R'2，R 3和R 4彼此独立地是H，C 1 -C 12烷基; C 2 -C 6烯基; C1-C12烷氧基; C2-C18链烯氧基; 卤素; 三氟甲基 C7-C11苯基烷基; 苯基; 被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯基; 苯氧基或被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基; R6是氢，C1-C24烷基，C5-C12环烷基或C7-C15苯基烷基; 在n = 1的情况下，R 7，R 7彼此独立地为氢或C 1 -C 18烷基; 或被C 1 -C 18烷氧基，烯丙氧基，卤素，-COOH，-COOR 8，-CONH 2，-CONHR 9，-CON（R 9）（R 10），-NH 2，-NHR 9，-N（R 9）取代的C 1 -C 12烷基）（R 10），-NHCOR 11，-CN，-OCOR 11，被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基和/或苯氧基; 或R 7为被-O-间隔并可被OH取代的C 3 -C 50烷基; 或R 7为C 3 -C 6烯基; 缩水甘油基 C5-C12环烷基; 被OH，C1-C4烷基或-OCOR11取代的环己基; 未被取代或被OH，Cl或CH3取代的C7-C11苯基烷基; -CO-R12或-SO2-R13; 和R 7，在n = 2的情况下，R 8至R 23如权利要求1中所定义，非常适用于稳定有机材料。

8. 发明授权

US09362508B2 Diketopyrrolopyrrole oligomers for use in organic semiconductor devices 有权
标题翻译：用于有机半导体器件的二酮吡咯并吡咯低聚物
公开(公告)号：US09362508B2
公开(公告)日：2016-06-07
申请号：US14123975
申请日：2012-06-20
申请人： Pascal Hayoz , Natalia Chebotareva
发明人： Pascal Hayoz , Natalia Chebotareva
IPC分类号： C07D519/00 , C08G61/12 , H01L51/00 , H01B1/12 , C09B69/10 , B82Y10/00 , H01L51/42 , H01L27/30
CPC分类号： H01L51/0074 , B82Y10/00 , C07D519/00 , C08G61/12 , C08G61/124 , C08G61/125 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/226 , C08G2261/3222 , C08G2261/3223 , C08G2261/3243 , C08G2261/344 , C08G2261/364 , C08G2261/411 , C08G2261/91 , C08G2261/92 , C08G2261/94 , C08G2261/95 , C09B69/101 , C09B69/102 , C09B69/109 , H01B1/12 , H01B1/127 , H01L27/302 , H01L51/00 , H01L51/0035 , H01L51/0036 , H01L51/0047 , H01L51/0065 , H01L51/0072 , H01L51/0558 , H01L51/4253 , H01L51/5012 , Y02E10/549 , Y02P70/521
摘要： The present invention relates to oligomers of the formula (I), and their use as organic semiconductor in organic devices, especially in organic photovoltaics (solar cells) and photodiodes, or in a device containing a diode and/or an organic field effect transistor. High efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the oligomers according to the invention are used in organic field effect transistors, organic photovoltaics (solar cells) and photodiodes.
摘要翻译：本发明涉及式（I）的低聚物及其在有机器件中的有机半导体的用途，特别是在有机光伏（太阳能电池）和光电二极管中，或在含有二极管和/或有机场效应晶体管的器件中。当根据本发明的低聚物用于有机场效应晶体管，有机光伏（太阳能电池）和光电二极管时，可观察到能量转换的高效率，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性。

9. 发明授权

US08912305B2 Diketopyrrolopyrrole polymers for use in organic field effect transistors 有权
标题翻译：用于有机场效应晶体管的二酮吡咯并吡咯聚合物
公开(公告)号：US08912305B2
公开(公告)日：2014-12-16
申请号：US13126182
申请日：2009-10-21
申请人： Mathias Düggeli , Mahmoud Zaher Eteish , Pascal Hayoz , Olivier Frédéric Aebischer , Marta Fonrodona Turon , Margherita Fontana , Marian Lanz , Mathieu G. R. Turbioz , Beat Schmidhalter , Jean-Charles Flores
发明人： Mathias Düggeli , Mahmoud Zaher Eteish , Pascal Hayoz , Olivier Frédéric Aebischer , Marta Fonrodona Turon , Margherita Fontana , Marian Lanz , Mathieu G. R. Turbioz , Beat Schmidhalter , Jean-Charles Flores
IPC分类号： C08G73/06 , C08G61/12 , C08G73/00 , H01L51/00
CPC分类号： H01L51/0036 , C08G61/12 , C08G61/124 , C08G61/126 , C08G2261/124 , C08G2261/1412 , C08G2261/18 , C08G2261/228 , C08G2261/3223 , C08G2261/3229 , C08G2261/3241 , C08G2261/3243 , C08G2261/3246 , C08G2261/334 , C08G2261/364 , C08G2261/411 , C08G2261/92 , H01L27/283 , H01L51/0001 , H01L51/0007 , H01L51/0043 , H01L51/0053 , H01L51/0558
摘要： The present invention relates to polymers comprising a repeating unit of the formula I, or III and their use as organic semiconductor in organic devices, especially an organic field effect transistor (OFET), or a device containing a diode and/or an organic field effect transistor. The polymers according to the invention have excellent solubility in organic solvents and excellent film-forming properties. In addition, high efficiency of energy conversion, excellent field-effect mobility, good on/off current ratios and/or excellent stability can be observed, when the polymers according to the invention are used in organic field effect transistors.
摘要翻译：本发明涉及包含式I或III的重复单元的聚合物及其在有机器件，特别是有机场效应晶体管（OFET）中的有机半导体的用途，或包含二极管和/或有机场效应的器件晶体管。根据本发明的聚合物在有机溶剂中具有优异的溶解性和优异的成膜性能。此外，当根据本发明的聚合物用于有机场效应晶体管时，可以观察到高效率的能量转换，优异的场效应迁移率，良好的开/关电流比和/或优异的稳定性。

10. 发明授权

US08865620B2 Heat-sensitive coating compositions based on resorcinyl triazine derivatives 有权
标题翻译：基于间苯二酚三嗪衍生物的热敏涂料组合物
公开(公告)号：US08865620B2
公开(公告)日：2014-10-21
申请号：US12529718
申请日：2008-03-05
申请人： Allan Francis Cunningham , Thomas Ehlis , Jean-Luc Birbaum , Pascal Hayoz , Kamalesh Pai Fondekar
发明人： Allan Francis Cunningham , Thomas Ehlis , Jean-Luc Birbaum , Pascal Hayoz , Kamalesh Pai Fondekar
IPC分类号： B41M5/333 , C09D5/26 , C08K5/3492 , C09D7/00
CPC分类号： B41M5/3335 , B41M5/3336 , C08K5/3492 , C09D5/26 , C09D7/41 , Y10T428/24802
摘要： The present invention provides heat-sensitive coating compositions, which comprise a color developer of formula (1) or mixtures thereof wherein R1 can be hydrogen, C1-20-alkyl, C3-8-cycloalkyl, C2-10-alkenyl, aryl or SO3H, and R2 and R3 can be the same or different and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8, SR9, SO3H or COOR10 and R4 and R5 can be the same or different, and can be hydrogen, halogen, C1-20-alkyl, C3-8-cyclo-alkyl, C2-10-alkenyl, aryl, OR6, NR7R8 or SR9, R6, R7, R8, R9 and R10 can be the same or different and can be hydrogen, C1-30-alkyl, C3-8-cycloalkyl, C2-10-alkenyl or aryl, wherein C1-20-alkyl can be unsubstituted or substituted with one or more C3-8-cycloalkyl, C2-10-alkenyl, phenyl, halogen, OR11, NR12R13, SR14, SO3H or COOR15, and aryl can be unsubstituted or substituted with one or more halogen, C1-10-alkyl, halogenated C1-10-alkyl, C3-8-cycloalkyl C2-10-alkenyl, phenyl, OR11, NR12R13, SR14, SO3H or COOR15, wherein R11, R12, R13, R14 and R15 can be the same or different and can be hydrogen, C1-10-alkyl, C3-8-cycloalkyl or C2-10-alkenyl, a process for the preparation of these compositions, a process of coating substrates with these compositions, substrates coated with these compositions, a process for preparing marked substrates using these compositions, marked substrates obtainable by the latter process, and certain color developers.
摘要翻译：本发明提供热敏涂料组合物，其包含式（1）的显色剂或其混合物，其中R 1可以是氢，C 1-20烷基，C 3-8 - 环烷基，C 2-10 - 烯基，芳基或SO 3 H ，R2和R3可以相同或不同，可以是氢，卤素，C 1-20烷基，C 3-8 - 环烷基，C 2-10 - 烯基，芳基，OR 6，NR 7 R 8，SR 9，SO 3 H或COOR 10和 R4和R5可以相同或不同，可以是氢，卤素，C 1-20烷基，C 3-8 - 环烷基，C 2-10 - 烯基，芳基，OR 6，NR 7 R 8或SR 9，R 6，R 7，R 8 ，R 9和R 10可以相同或不同，并且可以是氢，C 1-30 - 烷基，C 3-8 - 环烷基，C 2-10 - 烯基或芳基，其中C 1-20 - 烷基可以是未取代的或被一个或多个 C 3-8 - 环烷基，C 2-10 - 烯基，苯基，卤素，OR 11，NR 12 R 13，SR 14，SO 3 H或COOR 15，芳基可以是未被取代的或被一个或多个卤素取代，C 1-10烷基，卤代C 1-10 - 烷基，C 3-8 - 环烷基C2-10 - 烯基，苯基，OR11，NR12R13，SR14，SO3H或COOR15，其中在R 11，R 12，R 13，R 14和R 15可以相同或不同，可以是氢，C 1-10 - 烷基，C 3-8 - 环烷基或C 2-10 - 烯基，一种制备这些组合物的方法，涂覆这些组合物的基材，用这些组合物涂布的基材，使用这些组合物制备标记的基材的方法，通过后一方法获得的标记的底物和某些显色剂。

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