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1. 发明授权

US5672704A 2-Hydroxyphenyl-s-Triazines substituted with ethylenically unsaturated moieties 失效
标题翻译：用烯属不饱和部分取代的2-羟基苯基-s-三嗪
公开(公告)号：US5672704A
公开(公告)日：1997-09-30
申请号：US535406
申请日：1995-09-28
申请人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
发明人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
IPC分类号： C07D251/24 , C08F12/00 , C08F12/26 , C08F16/14 , C08F16/28 , C08F16/32 , C08F18/00 , C08F18/24 , C08F20/36 , C08F20/52 , C08F26/02 , C08F212/14 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/42 , C08F220/56 , C08F226/06 , C08K5/3492 , C09D7/12 , C09K3/00 , C09K15/30 , G03C1/815
CPC分类号： G03C1/8155 , C07D251/24 , C08F12/26 , C08F20/36 , C08K5/3492 , C09D7/1241 , C08K5/34926
摘要： s-Triazine UV absorbers of formula I ##STR1## where R.sub.1 is ##STR2## --CH.sub.2 --C(.dbd.CH.sub.2)--R.sub.10, --(CH.sub.2).sub.p --SiR.sub.11 R.sub.11 '--CH.dbd.CH.sub.2, --C(.dbd.O)--(CH.sub.2).sub.q --CH.dbd.CH.sub.2 or --C(.dbd.O)--O--CH.sub.2 --C(.dbd.CH.sub.2)--R.sub.10 ; and E.sub.1 and E.sub.2 are phenyl groups which may be unsubstituted or substituted with a variety of substituents including inter alia alkyl, OH and R.sub.1 ; are polymerizable and are effective stabilizers for a variety of polymeric and other organic substrates.
摘要翻译：（I）其中R1是图像，-CH2-C（= CH2）-R10， - （CH2）p-SiR11R11'-CH = CH2，-C（ = O） - （CH 2）q -CH = CH 2或-C（= O）-O-CH 2 -C（= CH 2）-R 10; E1和E2是可以是未取代的或被各种取代基取代的苯基，所述取代基尤其包括烷基，OH和R 1; 是可聚合的，并且是各种聚合物和其它有机基材的有效的稳定剂。

2. 发明授权

US5869588A Polymeric compounds derived from 2-hydroxy-phenyl-s-triazines substituted with ethylenically unsaturated moieties 失效
标题翻译：衍生自被烯属不饱和部分取代的2-羟基 - 苯基-s-三嗪的聚合物
公开(公告)号：US5869588A
公开(公告)日：1999-02-09
申请号：US865148
申请日：1997-05-29
申请人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
发明人： Vien Van Toan , David George Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
IPC分类号： C07D251/24 , C08F12/00 , C08F12/26 , C08F16/14 , C08F16/28 , C08F16/32 , C08F18/00 , C08F18/24 , C08F20/36 , C08F20/52 , C08F26/02 , C08F212/14 , C08F220/04 , C08F220/06 , C08F220/10 , C08F220/42 , C08F220/56 , C08F226/06 , C08K5/3492 , C09D7/12 , C09K3/00 , C09K15/30 , G03C1/815 , C08F26/06 , C08F26/08 , C08K5/34
CPC分类号： G03C1/8155 , C07D251/24 , C08F12/26 , C08F20/36 , C08K5/3492 , C09D7/1241 , C08K5/34926
摘要： The invention relates to novel 2-hydroxyphenyltriazines and to homopolymers and copolymers obtainable therefrom, as described in greater detail in claims 1 and 5; the novel compounds can be used as UV absorbers in or for organic materials.
摘要翻译：本发明涉及新的2-羟基苯基三嗪及其可从其获得的均聚物和共聚物，如权利要求1和5中更详细描述的; 新型化合物可用作有机材料中的UV吸收剂或用于有机材料。

3. 发明授权

US5538840A Photographic recording material containing a UV absorber 失效
标题翻译：含有紫外线吸收剂的摄影记录材料
公开(公告)号：US5538840A
公开(公告)日：1996-07-23
申请号：US538090
申请日：1995-10-02
申请人： Vien Van Toan , David G. Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
发明人： Vien Van Toan , David G. Leppard , Gerhard Rytz , Norbert Wurms , Pascal Hayoz
IPC分类号： C07D251/24 , C08F12/26 , C08F20/34 , C08F20/36 , C08F20/38 , C08F30/08 , C08K3/16 , C08K5/3492 , C08L87/00 , C09D7/12 , C09K3/00 , G03C1/815
CPC分类号： G03C1/8155 , C07D251/24 , C08F12/26 , C08F20/36 , C08K5/3492 , C09D7/1241 , C08K5/34926
摘要： The invention relates to a photographic recording material comprising, on a base, at least one silver-halide emulsion layer and, if desired, at least one interlayer and/or a protection layer, where at least one of said layers contains a UV absorber of the 2-hydroxyphenyltriazine type, as described in greater detail in claim 1; this UV absorber can also be in the form of a homopolymer or copolymer.
摘要翻译：本发明涉及一种照相记录材料，其在基体上包含至少一种卤化银乳剂层，如果需要，其包含至少一层中间层和/或保护层，其中至少一层所述层含有紫外线吸收剂如在权利要求1中更详细描述的2-羟基苯基三嗪类型; 该UV吸收剂也可以是均聚物或共聚物的形式。

4. 发明授权

US5597854A Latent light stabilizers 失效
标题翻译：潜光稳定剂
公开(公告)号：US5597854A
公开(公告)日：1997-01-28
申请号：US556159
申请日：1995-11-09
申请人： Jean-Luc Birbaum , Gerhard Rytz , Vien Van Toan , Andreas Valet , Norbert W urms
发明人： Jean-Luc Birbaum , Gerhard Rytz , Vien Van Toan , Andreas Valet , Norbert W urms
IPC分类号： C07D251/24 , C07D401/12 , C07D405/12 , C07F7/18 , C08K5/3442 , C08K5/3462 , C08K5/3477 , C08K5/3492 , C08L101/00 , G03C1/815 , G03C7/392 , C07D251/00 , C07D251/02 , C07D403/00 , G03C1/46 , C07D234/02
CPC分类号： C08K5/3462 , C08K5/3492 , G03C1/8155 , G03C7/39244 , G03C7/39252 , G03C7/39256 , Y10S430/132
摘要： The invention relates to compounds of the formula I ##STR1## in which n is 1 or 2, A is CH or a nitrogen atom, and the other radicals R.sup.1 to R.sup.25 are as defined in claim 1.The compounds of the formula I can advantageously be employed for stabilizing organic material against the harmful effect of light, oxygen and/or heat.
摘要翻译：本发明涉及式Ⅰ化合物（Ⅰ），其中n为1或2，A为CH或氮原子，其余基团R 1至R 25如权利要求1所定义。式我可以有利地用于稳定有机材料以抵抗光，氧和/或热的有害影响。

5. 发明授权

US06284821B1 Hydroxyphenyltriazines 有权
标题翻译：羟基苯基三嗪
公开(公告)号：US06284821B1
公开(公告)日：2001-09-04
申请号：US09715799
申请日：2000-11-17
申请人： Dietmar Hüglin , Vien Van Toan , Helmut Luther , Christophe Bulliard , Gerhard Rytz
发明人： Dietmar Hüglin , Vien Van Toan , Helmut Luther , Christophe Bulliard , Gerhard Rytz
IPC分类号： C08K534
CPC分类号： A61Q17/04 , A61K8/4966 , C07D251/24 , C09K15/30 , G03C1/8155
摘要： A description is given of compounds of the formula I in which R1 is C1-C18alkyl; C5-C12cycloalkyl; C3-C6alkenyl; phenyl; C1-C18alkyl which is substituted by phenyl, OH, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C18alkenyloxy, halogen, —COOH, —COOR4, —O—CO—R5, —O—CO—O—R6, —CO—NH2, —CO—NHR7, —CO—N(R7)(R8), CN, NH2, NHR7, —N(R7)(R8), —NH—CO—R5, phenoxy, C1-C18alkyl-substituted phenoxy, phenyl-C1-C4alkoxy, C6-C15bicycloalkoxy, C6-C15bicycloalkylalkoxy, C6-C15bicycloalkenylalkoxy, or C6-C15tricycloalkoxy; C5-C12cycloalkyl which is substituted by OH, C1-C4alkyl, C2-C6alkenyl or —O—CO—R5; glycidyl; —CO—R9 or —SO2—R10; or R1 is C3-C50alkyl which is interrupted by one or more oxygen atoms and/or substituted by OH, phenoxy or C7-C18alkylphenoxy; or R1 denotes the specific polymerizable radicals indicated in claim 1; R2 is C6-C18alky1; C2-C6alkenyl; phenyl; C7-C11phenylalkyl; COOR4; CN; NH—CO—R5; halogen; trifluoromethyl; —O—R3; R3 embraces the definitions given for R1; the radicals R11 independently of one another are H; C1-C18alkyl; C3-C6alkenyl; phenyl; C7-C11phenylalkyl; halogen or C1-C18alkoxy, and the remaining radicals embrace the definitions given in claim 1, at least one of the radicals R1, R2 and R11 containing 4 or more carbon atoms. The novel compounds are effective as stabilizers for organic material against the damaging effect of light, oxygen and heat; they are also suitable for use in skin or hair protection preparations.
摘要翻译：给出式Iin化合物的描述，其中R 1是C 1 -C 18烷基; C5-C12环烷基; C 3 -C 6烯基; 苯基; 被苯基，OH，C1-C18烷氧基，C5-C12环烷氧基，C3-C18链烯氧基，卤素，-COOH，-COOR4，-O-CO-R5，-O-CO-O-R6，-CO- NH，-CO-NHR7，-CO-N（R7）（R8），CN，NH2，NHR7，-N（R7）（R8），-NH-CO-R5，苯氧基，C1-C18烷基取代的苯氧基，苯基 C 1 -C 4烷氧基，C 6 -C 15双环烷氧基，C 6 -C 15双环烷基烷氧基或C 6 -C 15三环烷氧基; 被OH，C 1 -C 4烷基，C 2 -C 6烯基或-O-CO-R 5取代的C 5 -C 12环烷基; 缩水甘油基 -CO-R 9或-SO 2 -R 10; 或R1是被一个或多个氧原子中断和/或被OH，苯氧基或C 7 -C 18烷基苯氧基取代的C 3 -C 50烷基;或R 1表示权利要求1所示的特异性可聚合基团; R 2是C 6 -C 18烷基; C 2 -C 6烯基; 苯基; C7-C11苯基烷基; COOR4; CN; NH-CO-R5; 卤素; 三氟甲基 -O-R3; R3包含给定的R 1的定义;基团R 11彼此独立地是H; C1-C18烷基; C 3 -C 6烯基; 苯基; C7-C11苯基烷基; 卤素或C 1 -C 18烷氧基，其余基团包括权利要求1中给出的定义，含有4个或更多个碳原子的基团R 1，R 2和R 11中的至少一个。新型化合物有效地作为有机材料的稳定剂，防止光，氧和热的破坏作用; 它们也适用于皮肤或护发制剂。

6. 发明授权

US06184375B2 Hydroxyphenyl triazines 失效
标题翻译：羟基苯基三嗪
公开(公告)号：US06184375B2
公开(公告)日：2001-02-06
申请号：US08974263
申请日：1997-11-19
申请人： Dietmar Hüglin , Vien Van Toan , Helmut Luther , Christophe Bulliard , Gerhard Rytz
发明人： Dietmar Hüglin , Vien Van Toan , Helmut Luther , Christophe Bulliard , Gerhard Rytz
IPC分类号： C07D41300
CPC分类号： A61Q17/04 , A61K8/4966 , C07D251/24 , C09K15/30 , G03C1/8155
摘要： A description is given of compounds of the formula I in which R1 is C1-C18alkyl; C5-C12cycloalkyl; C3-C6alkenyl; phenyl; C1-C18alkyl which is substituted by phenyl, OH, C1-C18alkoxy, C5-C12cycloalkoxy, C3-C18alkenyloxy, halogen, —COOH, —COOR4, —O—CO—R5, —O—CO—O—R6, —CO—NH2, —CO—NHR7, —CO—N(R7)(R8), CN, NH2, NHR7, —N(R7)(R8), —NH—CO—R5, phenoxy, C1-C18alkyl-substituted phenoxy, phenyl-C1-C4alkoxy, C6-C15bicycloalkoxy, C6-C15bicycloalkylalkoxy, C6-C15bicycloalkenylalkoxy, or C6-C15tricycloalkoxy; C5-C12cycloalkyl which is substituted by OH, C1-C4alkyl, C2-C6alkenyl or —O—CO—R5; glycidyl; —CO—R9 or —SO2—R10; or R1 is C3-C50alkyl which is interrupted by one or more oxygen atoms and/or substituted by OH, phenoxy or C7-C18alkylphenoxy; or R1 denotes the specific polymerizable radicals indicated in claim 1; R2 is C6-C18alkyl; C2-C6alkenyl; phenyl; C7-C11phenylalkyl; COOR4; CN; NH—CO—R5; halogen; trifluoromethyl; —O—R3; R3 embraces the definitions given for R1; the radicals R11 independently of one another are H; C1-C18alkyl; C3-C6alkenyl; phenyl; C7-C11phenylalkyl; halogen or C1-C18alkoxy, and the remaining radicals embrace the definitions given in claim 1, at least one of the radicals R1, R2 and R11 containing 4 or more carbon atoms. The novel compounds are effective as stabilizers for organic material against the damaging effect of light, oxygen and heat; they are also suitable for use in skin or hair protection preparations.
摘要翻译：给出式Iin化合物的描述，其中R 1是C 1 -C 18烷基; C5-C12环烷基; C 3 -C 6烯基; 苯基; 被苯基，OH，C1-C18烷氧基，C5-C12环烷氧基，C3-C18链烯氧基，卤素，-COOH，-COOR4，-O-CO-R5，-O-CO-O-R6，-CO- NH，-CO-NHR7，-CO-N（R7）（R8），CN，NH2，NHR7，-N（R7）（R8），-NH-CO-R5，苯氧基，C1-C18烷基取代的苯氧基，苯基 C 1 -C 4烷氧基，C 6 -C 15双环烷氧基，C 6 -C 15双环烷基烷氧基或C 6 -C 15三环烷氧基; 被OH，C 1 -C 4烷基，C 2 -C 6烯基或-O-CO-R 5取代的C 5 -C 12环烷基; 缩水甘油基 -CO-R 9或-SO 2 -R 10; 或R1是被一个或多个氧原子中断和/或被OH，苯氧基或C 7 -C 18烷基苯氧基取代的C 3 -C 50烷基;或R 1表示权利要求1中所示的特定可聚合基团; R 2是C 6 -C 18烷基; C 2 -C 6烯基; 苯基; C7-C11苯基烷基; COOR4; CN; NH-CO-R5; 卤素; 三氟甲基 -O-R3; R3包含给定的R 1的定义;基团R 11彼此独立地是H; C1-C18烷基; C 3 -C 6烯基; 苯基; C7-C11苯基烷基; 卤素或C 1 -C 18烷氧基，其余基团包括权利要求1中给出的定义，含有4个或更多个碳原子的基团R 1，R 2和R 11中的至少一个。新型化合物有效地作为有机材料的稳定剂，防止光，氧和热的破坏作用; 它们也适用于皮肤或护发制剂。

7. 发明授权

US5753729A Coating compositions stabilized against damage by light, heat, and oxygen 失效
标题翻译：涂料组合物稳定，防止光，热和氧气的损伤
公开(公告)号：US5753729A
公开(公告)日：1998-05-19
申请号：US665041
申请日：1996-06-07
申请人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wurms
发明人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wurms
IPC分类号： C07D239/26 , C07D401/12 , C08K5/3442 , C08K5/3462 , C08K5/3472 , C08K5/3475 , C08K5/3477 , C08K5/3492 , C09D7/12 , C09K3/00 , C08K5/3495
CPC分类号： C07D239/26 , C07D401/12 , C08K5/3462 , C09D7/1241
摘要： Coatings comprising A) a binder based on an organic polymer and B) as stabilizer against damage by light, heat and oxygen, a 2-(2'-hydroxyphenyl)-1,3-pyrimidine of the formula I ##STR1## in which the radicals R.sub.1 to R.sup.6 are as defined in claim 1 have an outstanding resistance to the damaging effects of light, oxygen and heat. Compounds of the formula Ib defined in claim 18 are suitable in general for the stabilization of organic material.
摘要翻译：包含A）基于有机聚合物的粘合剂和B）作为防止光，热和氧损伤的稳定剂的式I（I）的2-（2'-羟基苯基）-1,3-嘧啶，其中基团R 1至R 6如权利要求1中所定义，具有突出的抗光，氧和热的破坏作用的抗性。权利要求18中定义的式Ib化合物通常适用于有机材料的稳定化。

8. 发明授权

US5668200A Stabilizer combination 失效
标题翻译：稳定剂组合
公开(公告)号：US5668200A
公开(公告)日：1997-09-16
申请号：US586267
申请日：1996-01-16
申请人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
发明人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
IPC分类号： G03C7/392 , C07D251/14 , C08K5/3477 , C08K5/3492 , C08L101/00 , C09D7/12
CPC分类号： C08K5/3492
摘要： A mixture comprising a compound of the formula I and a compound of the formula II ##STR1## in which n is 1 or 2; R.sub.1, R'.sub.1, R.sub.2, R'.sub.2, R.sub.3 and R.sub.4, independently of one another, are H, C.sub.1 -C.sub.12 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.1 -C.sub.12 alkoxy; C.sub.2 -C.sub.18 alkenoxy; halogen; trifluoromethyl; C.sub.7 -C.sub.11 phenylalkyl; phenyl; phenyl which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; phenoxy; or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen;R.sub.6 is hydrogen, C.sub.1 -C.sub.24 alkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.7 -C.sub.15 phenylalkyl;R.sub.7, in the case where n=1, and R'.sub.7, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl; or are C.sub.1 -C.sub.12 alkyl which is substituted by OH, C.sub.1 -C.sub.18 alkoxy, allyloxy, halogen, --COOH, --COOR.sub.8, --CONH.sub.2, --CONHR.sub.9, --CON(R.sub.9)(R.sub.10), --NH.sub.2, --NHR.sub.9, --N(R.sub.9)(R.sub.10), --NHCOR.sub.11, --CN, --OCOR.sub.11, phenoxy and/or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; or R.sub.7 is C.sub.3 -C.sub.50 alkyl which is interrupted by --O-- and may be substituted by OH; or R.sub.7 is C.sub.3 -C.sub.6 alkenyl; glycidyl; C.sub.5 -C.sub.12 cycloalkyl; cyclohexyl which is substituted by OH, C.sub.1 -C.sub.4 alkyl or --OCOR.sub.11 ; C.sub.7 -C.sub.11 phenylalkyl which is unsubstituted or substituted by OH, Cl or CH.sub.3 ; --CO--R.sub.12 or --SO.sub.2 --R.sub.13 ;and R.sub.7, in the case where n=2, and R.sub.8 to R.sub.23 are as defined in claim 1, is highly suitable for stabilizing organic material.
摘要翻译：包含式I化合物和其中n为1或2的式II化合物（I）其中n为1或2的混合物; R 1，R'1，R 2，R'2，R 3和R 4彼此独立地是H，C 1 -C 12烷基; C 2 -C 6烯基; C1-C12烷氧基; C2-C18链烯氧基; 卤素; 三氟甲基 C7-C11苯基烷基; 苯基; 被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯基; 苯氧基或被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基; R6是氢，C1-C24烷基，C5-C12环烷基或C7-C15苯基烷基; 在n = 1的情况下，R 7，R 7彼此独立地为氢或C 1 -C 18烷基; 或被C 1 -C 18烷氧基，烯丙氧基，卤素，-COOH，-COOR 8，-CONH 2，-CONHR 9，-CON（R 9）（R 10），-NH 2，-NHR 9，-N（R 9）取代的C 1 -C 12烷基）（R 10），-NHCOR 11，-CN，-OCOR 11，被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基和/或苯氧基; 或R 7为被-O-间隔并可被OH取代的C 3 -C 50烷基; 或R 7为C 3 -C 6烯基; 缩水甘油基 C5-C12环烷基; 被OH，C1-C4烷基或-OCOR11取代的环己基; 未被取代或被OH，Cl或CH3取代的C7-C11苯基烷基; -CO-R12或-SO2-R13; 和R 7，在n = 2的情况下，R 8至R 23如权利要求1中所定义，非常适用于稳定有机材料。

9. 发明授权

US06455442B1 Process for the preparation of UV protective coatings by plasma-enhanced deposition 失效
标题翻译：通过等离子体增强沉积制备UV保护涂层的方法
公开(公告)号：US06455442B1
公开(公告)日：2002-09-24
申请号：US09674332
申请日：2001-01-02
申请人： Michael Bauer , Werner Kaufmann , Gerhard Rytz
发明人： Michael Bauer , Werner Kaufmann , Gerhard Rytz
IPC分类号： H01L2131
CPC分类号： B05D1/62 , Y10S977/89
摘要： This invention relates to a process for the preparation of UV protective coatings by plasma-enhanced vacuum deposition, using hydroxyphenyl-s-triazines as UV absorbers. This invention also relates to the use of hydroxyphenyl-s-triazines in plasma-enhanced vacuum depositions and to the substrates coated by this process.
摘要翻译：本发明涉及使用羟基苯基-s-三嗪作为UV吸收剂，通过等离子体增强真空沉积制备UV保护涂层的方法。本发明还涉及羟基苯基-s-三嗪在等离子体增强真空沉积中的用途以及通过该方法涂覆的基材。

10. 发明授权

US5288777A Process for the preparation of stabilized styrene copolymers containing elastomer particles 失效
标题翻译：制备含有弹性体颗粒的稳定的苯乙烯共聚物的方法
公开(公告)号：US5288777A
公开(公告)日：1994-02-22
申请号：US973478
申请日：1992-11-09
申请人： Bernard Gilg , Gerhard Rytz , Werner Stauffer , Margot Clauss
发明人： Bernard Gilg , Gerhard Rytz , Werner Stauffer , Margot Clauss
IPC分类号： C08F279/00 , C08F279/02 , C08F285/00 , C08K5/34 , C08K5/3435 , C08L51/04 , C08K5/3432 , C08G63/91 , C08K5/3415 , C08L39/04
CPC分类号： C08F279/02 , C08F285/00
摘要： ABS copolymers and similar styrene or .alpha.-methylstyrene copolymers which contain an elastomer phase are stabilized against light-induced degradation by a) incorporation of a copolymerizable sterically hindered amine in, and b) addition of a non-copolymerizable sterically hindered amine to, the copolymer. Preferred sterically hindered amines are polyalkylpiperidines.
摘要翻译：包含弹性体相的ABS共聚物和类似的苯乙烯或α-甲基苯乙烯共聚物通过以下方式稳定，以防由光诱导的降解：a）在可共聚的空间位阻胺中引入并且b）向共聚物中加入不可共聚的空间位阻胺。优选的空间位阻胺是聚烷基哌啶。

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