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1. 发明授权

US5668200A Stabilizer combination 失效
标题翻译：稳定剂组合
公开(公告)号：US5668200A
公开(公告)日：1997-09-16
申请号：US586267
申请日：1996-01-16
申请人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
发明人： Andreas Valet , Gerhard Rytz , Pascal Hayoz
IPC分类号： G03C7/392 , C07D251/14 , C08K5/3477 , C08K5/3492 , C08L101/00 , C09D7/12
CPC分类号： C08K5/3492
摘要： A mixture comprising a compound of the formula I and a compound of the formula II ##STR1## in which n is 1 or 2; R.sub.1, R'.sub.1, R.sub.2, R'.sub.2, R.sub.3 and R.sub.4, independently of one another, are H, C.sub.1 -C.sub.12 alkyl; C.sub.2 -C.sub.6 alkenyl; C.sub.1 -C.sub.12 alkoxy; C.sub.2 -C.sub.18 alkenoxy; halogen; trifluoromethyl; C.sub.7 -C.sub.11 phenylalkyl; phenyl; phenyl which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; phenoxy; or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen;R.sub.6 is hydrogen, C.sub.1 -C.sub.24 alkyl, C.sub.5 -C.sub.12 cycloalkyl or C.sub.7 -C.sub.15 phenylalkyl;R.sub.7, in the case where n=1, and R'.sub.7, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl; or are C.sub.1 -C.sub.12 alkyl which is substituted by OH, C.sub.1 -C.sub.18 alkoxy, allyloxy, halogen, --COOH, --COOR.sub.8, --CONH.sub.2, --CONHR.sub.9, --CON(R.sub.9)(R.sub.10), --NH.sub.2, --NHR.sub.9, --N(R.sub.9)(R.sub.10), --NHCOR.sub.11, --CN, --OCOR.sub.11, phenoxy and/or phenoxy which is substituted by C.sub.1 -C.sub.18 alkyl, C.sub.1 -C.sub.18 alkoxy or halogen; or R.sub.7 is C.sub.3 -C.sub.50 alkyl which is interrupted by --O-- and may be substituted by OH; or R.sub.7 is C.sub.3 -C.sub.6 alkenyl; glycidyl; C.sub.5 -C.sub.12 cycloalkyl; cyclohexyl which is substituted by OH, C.sub.1 -C.sub.4 alkyl or --OCOR.sub.11 ; C.sub.7 -C.sub.11 phenylalkyl which is unsubstituted or substituted by OH, Cl or CH.sub.3 ; --CO--R.sub.12 or --SO.sub.2 --R.sub.13 ;and R.sub.7, in the case where n=2, and R.sub.8 to R.sub.23 are as defined in claim 1, is highly suitable for stabilizing organic material.
摘要翻译：包含式I化合物和其中n为1或2的式II化合物（I）其中n为1或2的混合物; R 1，R'1，R 2，R'2，R 3和R 4彼此独立地是H，C 1 -C 12烷基; C 2 -C 6烯基; C1-C12烷氧基; C2-C18链烯氧基; 卤素; 三氟甲基 C7-C11苯基烷基; 苯基; 被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯基; 苯氧基或被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基; R6是氢，C1-C24烷基，C5-C12环烷基或C7-C15苯基烷基; 在n = 1的情况下，R 7，R 7彼此独立地为氢或C 1 -C 18烷基; 或被C 1 -C 18烷氧基，烯丙氧基，卤素，-COOH，-COOR 8，-CONH 2，-CONHR 9，-CON（R 9）（R 10），-NH 2，-NHR 9，-N（R 9）取代的C 1 -C 12烷基）（R 10），-NHCOR 11，-CN，-OCOR 11，被C 1 -C 18烷基，C 1 -C 18烷氧基或卤素取代的苯氧基和/或苯氧基; 或R 7为被-O-间隔并可被OH取代的C 3 -C 50烷基; 或R 7为C 3 -C 6烯基; 缩水甘油基 C5-C12环烷基; 被OH，C1-C4烷基或-OCOR11取代的环己基; 未被取代或被OH，Cl或CH3取代的C7-C11苯基烷基; -CO-R12或-SO2-R13; 和R 7，在n = 2的情况下，R 8至R 23如权利要求1中所定义，非常适用于稳定有机材料。

2. 发明授权

US06369267B1 Polyoxyalkylene substituted and bridged triazine, benzotriazole and benzophenone derivatives as UV absorbers 失效
标题翻译：聚氧亚烷基取代和桥连的三嗪，苯并三唑和二苯甲酮衍生物作为UV吸收剂
公开(公告)号：US06369267B1
公开(公告)日：2002-04-09
申请号：US09679231
申请日：2000-10-04
申请人： Vien Van Toan , Andreas Valet , Pascal Hayoz
发明人： Vien Van Toan , Andreas Valet , Pascal Hayoz
IPC分类号： C07D25124
CPC分类号： A61K8/4966 , A61Q17/04 , C07C49/84 , C07C59/315 , C07D249/20 , C07D251/24 , C08K5/132 , C08K5/34 , C08K5/3475 , C08K5/3492 , Y10S430/132
摘要： Triazine, benzotriazole and benzophenone derivatives which are substituted or bridged with polyoxyalkylene groups, according to claim 1, and their use as UV absorbers, especially in photographic materials, in inks, including inkjet inks and printing inks, in transfer prints, in paints and varnishes, organic polymeric materials, plastics, rubber, glass, packaging materials, in sunscreens of cosmetic preparations and in skin protection compositions.
摘要翻译：根据权利要求1的三取代苯并三唑和二苯甲酮衍生物，它们是用聚氧亚烷基取代或桥连的，它们作为UV吸收剂，特别是在照相材料中用作墨水，包括喷墨油墨和印刷油墨，转印印刷品，油漆和清漆中的用途，有机聚合材料，塑料，橡胶，玻璃，包装材料，化妆品制剂的防晒剂和皮肤保护组合物。

3. 发明授权

US5597854A Latent light stabilizers 失效
标题翻译：潜光稳定剂
公开(公告)号：US5597854A
公开(公告)日：1997-01-28
申请号：US556159
申请日：1995-11-09
申请人： Jean-Luc Birbaum , Gerhard Rytz , Vien Van Toan , Andreas Valet , Norbert W urms
发明人： Jean-Luc Birbaum , Gerhard Rytz , Vien Van Toan , Andreas Valet , Norbert W urms
IPC分类号： C07D251/24 , C07D401/12 , C07D405/12 , C07F7/18 , C08K5/3442 , C08K5/3462 , C08K5/3477 , C08K5/3492 , C08L101/00 , G03C1/815 , G03C7/392 , C07D251/00 , C07D251/02 , C07D403/00 , G03C1/46 , C07D234/02
CPC分类号： C08K5/3462 , C08K5/3492 , G03C1/8155 , G03C7/39244 , G03C7/39252 , G03C7/39256 , Y10S430/132
摘要： The invention relates to compounds of the formula I ##STR1## in which n is 1 or 2, A is CH or a nitrogen atom, and the other radicals R.sup.1 to R.sup.25 are as defined in claim 1.The compounds of the formula I can advantageously be employed for stabilizing organic material against the harmful effect of light, oxygen and/or heat.
摘要翻译：本发明涉及式Ⅰ化合物（Ⅰ），其中n为1或2，A为CH或氮原子，其余基团R 1至R 25如权利要求1所定义。式我可以有利地用于稳定有机材料以抵抗光，氧和/或热的有害影响。

4. 发明授权

US06706215B1 Coating compositions stabilized against damage by light, heat and oxygen 失效
标题翻译：涂料组合物稳定，防止光，热和氧气的损伤
公开(公告)号：US06706215B1
公开(公告)日：2004-03-16
申请号：US08880383
申请日：1997-06-23
申请人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wüms
发明人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wüms
IPC分类号： C07D23926
CPC分类号： C07D239/26 , C07D401/12 , C08K5/3462 , C09D7/48
摘要： Coatings comprising A) a binder based on an organic polymer and B) as stabilizer against damage by light, heat and oxygen, a 2-(2′-hydroxyphenyl)-1,3-pyrimidine of the formula I in which the radicals R1 to R6 are as defined in claim 1 have an outstanding resistance to the damaging effects of light, oxygen and heat. Compounds of the formula Ib defined in claim 18 are suitable in general for the stabilization of organic material.
摘要翻译：包含A）基于有机聚合物的粘合剂和B）作为光，热和氧损伤的稳定剂，式Iin的2-（2'-羟基苯基）-1,3-嘧啶，其中R 1至 R 6如权利要求1中所定义，具有对光，氧和热的有害影响的突出的抗性。权利要求18中定义的式Ib化合物通常适用于有机材料的稳定化。

5. 发明授权

US06653484B2 Polyoxyalkylene substituted and bridged benzotriazole derivatives 失效
公开(公告)号：US06653484B2
公开(公告)日：2003-11-25
申请号：US10006634
申请日：2001-11-08
申请人： Vien Van Toan , Andreas Valet , Pascal Hayoz
发明人： Vien Van Toan , Andreas Valet , Pascal Hayoz
IPC分类号： C07D24920
CPC分类号： A61K8/4966 , A61Q17/04 , C07C49/84 , C07C59/315 , C07D249/20 , C07D251/24 , C08K5/132 , C08K5/34 , C08K5/3475 , C08K5/3492 , Y10S430/132
摘要： Triazine, benzotriazole and benzophenone derivatives which are substituted or bridged with polyoxyalkylene groups, according to claim 1, and their use as UV absorbers, especially in photographic materials, in inks, including inkjet inks and printing inks, in transfer prints, in paints and varnishes, organic polymeric materials, plastics, rubber, glass, packaging materials, in sunscreens of cosmetic preparations and in skin protection compositions.

6. 发明授权

US6013704A Hydroxyphenyltriazines 失效
标题翻译：羟基苯基三嗪
公开(公告)号：US6013704A
公开(公告)日：2000-01-11
申请号：US929147
申请日：1997-09-10
申请人： Pascal Hayoz , Andreas Valet , Vien Van Toan
发明人： Pascal Hayoz , Andreas Valet , Vien Van Toan
IPC分类号： G03C7/392 , C07D251/24 , C07D405/12 , C07D405/14 , C08K5/3435 , C08K5/3492 , C09K15/30 , C07D251/00
CPC分类号： C07D405/12 , C07D251/24 , C07D405/14 , C08K5/3435 , C08K5/3492
摘要： There are described compounds of formula A whereinr.sub.1 and r.sub.2 are each independently of the other 0 or 1;Y.sub.1 to Y.sub.9 are each independently of the others --H, --OH, C.sub.1 -C.sub.20 alkyl, C.sub.4 -C.sub.20 cycloalkyl, C.sub.2 -C.sub.20 -alkenyl, C.sub.1 -C.sub.20 alkoxy, C.sub.4 -C.sub.12 cycloalkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.7 -C.sub.20 aralkyl, halogen, --C.tbd.N, C.sub.1 -C.sub.5 haloalkyl, --SO.sub.2 R', --SO.sub.3 H, --SO.sub.3 M, wherein M is an alkali metal, --COOR', --CONHR', --CONR'R", --OCOOR', --OCOR', --OCONHR', (meth)acrylamino, (meth)-acryloxy, C.sub.6 -C.sub.12 aryl; C.sub.6 -C.sub.12 aryl substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, CN and/or by halogen; C.sub.3 -C.sub.12 heteroaryl; C.sub.3 -C.sub.12 heteroaryl substituted by C.sub.1 -C.sub.12 alkyl, C.sub.1 -C.sub.12 alkoxy, CN and/or by halogen; or Q of formula I, and at least one substituent Y.sub.1 to Y.sub.9 must be Q ##STR1## wherein q is 0 or 1,R is a cyclic radical andR.sub.1 and T are as defined in claim 1. The novel compounds are suitable, especially in combination with hindered amines, for the stabilisation of organic material against the damaging action of light, oxygen and heat.
摘要翻译：描述式A的化合物，其中r1和r2各自独立地为0或1; Y 1至Y 9各自独立地为-H，-OH，C 1 -C 20烷基，C 4 -C 20环烷基，C 2 -C 20 - 烯基，C 1 -C 20烷氧基，C 4 -C 12环烷氧基，C 2 -C 20链烯氧基，C 7 -C 20芳烷基，卤素，-C 3 N，C1-C5卤代烷基，-SO2R'，-SO3H，-SO3M，其中M是碱金属，-COOR'，-CONHR'，-CONR'R“，-OCOOR'，-OCOR'，-OCONHR' （甲基）丙烯酰氨基，（甲基）丙烯酰氧基，C6-C12芳基; 被C 1 -C 12烷基，C 1 -C 12烷氧基，CN和/或被卤素取代的C 6 -C 12芳基; C3-C12杂芳基; 被C 1 -C 12烷基，C 1 -C 12烷氧基，CN和/或被卤素取代的C 3 -C 12杂芳基; 或式I的Q，并且至少一个取代基Y1至Y9必须为Q，其中q为0或1，R为环状基团，R 1和T如权利要求1所定义。该新化合物特别适用于受阻胺，用于稳定有机材料，防止光，氧和热的破坏作用。

7. 发明授权

US5753729A Coating compositions stabilized against damage by light, heat, and oxygen 失效
标题翻译：涂料组合物稳定，防止光，热和氧气的损伤
公开(公告)号：US5753729A
公开(公告)日：1998-05-19
申请号：US665041
申请日：1996-06-07
申请人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wurms
发明人： Andreas Valet , Jean-Luc Birbaum , Gerhard Rytz , Norbert Wurms
IPC分类号： C07D239/26 , C07D401/12 , C08K5/3442 , C08K5/3462 , C08K5/3472 , C08K5/3475 , C08K5/3477 , C08K5/3492 , C09D7/12 , C09K3/00 , C08K5/3495
CPC分类号： C07D239/26 , C07D401/12 , C08K5/3462 , C09D7/1241
摘要： Coatings comprising A) a binder based on an organic polymer and B) as stabilizer against damage by light, heat and oxygen, a 2-(2'-hydroxyphenyl)-1,3-pyrimidine of the formula I ##STR1## in which the radicals R.sub.1 to R.sup.6 are as defined in claim 1 have an outstanding resistance to the damaging effects of light, oxygen and heat. Compounds of the formula Ib defined in claim 18 are suitable in general for the stabilization of organic material.
摘要翻译：包含A）基于有机聚合物的粘合剂和B）作为防止光，热和氧损伤的稳定剂的式I（I）的2-（2'-羟基苯基）-1,3-嘧啶，其中基团R 1至R 6如权利要求1中所定义，具有突出的抗光，氧和热的破坏作用的抗性。权利要求18中定义的式Ib化合物通常适用于有机材料的稳定化。

8. 发明授权

US5707690A Protective coating for wood 失效
公开(公告)号：US5707690A
公开(公告)日：1998-01-13
申请号：US384188
申请日：1995-02-06
申请人： Andreas Valet , Roger Meuwly
发明人： Andreas Valet , Roger Meuwly
IPC分类号： B27K3/34 , C07C45/46 , C07C45/69 , C07C45/71 , C07C49/83 , C07C49/84 , C07C323/22 , C07F7/08 , C09D5/00 , C09D5/32 , C09D7/12 , C09D183/04 , B05D1/36 , B05D7/00
CPC分类号： C09D7/1241 , C07C323/22 , C07C45/46 , C07C45/69 , C07C45/71 , C07C49/83 , C07C49/84 , C07F7/0818 , C07F7/0852 , C08K5/07 , C08K5/132 , Y10T428/31989 , Y10T428/662
摘要： The invention relates to a method of protecting surfaces of wood against damage by light by treatment with a coating composition comprising a benzophenone of the formula I ##STR1## in which the substituents are defined as in claim 1.

9. 发明授权

US5298067A Coating materials stabilized against light-induced degradation 失效
标题翻译：防止光诱导降解的涂料
公开(公告)号：US5298067A
公开(公告)日：1994-03-29
申请号：US835657
申请日：1992-02-13
申请人： Andreas Valet , Jean-Luc Birbaum , Mario Slongo
发明人： Andreas Valet , Jean-Luc Birbaum , Mario Slongo
IPC分类号： C07D251/24 , C08K5/34 , C08K5/3492 , C09D5/00 , C09D7/12 , C09D201/00 , C08K15/3492
CPC分类号： C09D7/1241 , C08K5/3492 , C08K5/34926
摘要： 2-(2-Hydroxyphenyl)-4,6-diphenyl- and -4,6-di-p-tolyl-1,3,5-triazines are particularly suitable stabilizers, especially against light-induced degradation, for coating materials. They are superior in this respect to the corresponding 4,6-bis(2,4 -dimethylphenyl) derivatives.
摘要翻译： 2-（2-羟基苯基）-4,6-二苯基 - 和-4,6-二对甲苯基-1,3,5-三嗪是涂料特别适合的稳定剂，特别是对光诱导的降解。它们在这方面优于相应的4,6-双（2,4-二甲基苯基）衍生物。

10. 发明授权

US5051459A N-Triazinyloxalamides 失效
标题翻译： N-三嗪嗪酰胺
公开(公告)号：US5051459A
公开(公告)日：1991-09-24
申请号：US490816
申请日：1990-03-08
申请人： Mario Slongo , Jean-Luc Birbaum , Andreas Valet
发明人： Mario Slongo , Jean-Luc Birbaum , Andreas Valet
IPC分类号： C07D251/52 , C07D251/16 , C07D251/18 , C07D251/22 , C07D251/46 , C07D251/70 , C07D401/12 , C07D401/14 , C08K5/3477 , C08K5/3492 , C09K3/00
CPC分类号： C07D401/14 , C07D251/70 , C08K5/3492
摘要： N-Triazinyloxalamides of formula I ##STR1## wherein n is 1-4 and R.sup.1, R.sup.6 and X are as defined in claim 1, are UV absorbers and are suitable as light stabilizers for organic materials.
摘要翻译：其中n为1-4并且R 1，R 6和X如权利要求1中所定义的式I的N-三嗪氧基酰胺为UV吸收剂，并且适用作有机材料的光稳定剂。

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