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1. 发明授权

US4495271A Radiation polymerizable mixture and copying material produced therefrom 失效
标题翻译：由其制造的可辐照聚合混合物和复印材料
公开(公告)号：US4495271A
公开(公告)日：1985-01-22
申请号：US379865
申请日：1982-05-19
申请人： Ulrich Geissler , Walter Herwig , Elisabeth Fetsch
发明人： Ulrich Geissler , Walter Herwig , Elisabeth Fetsch
IPC分类号： G03F7/004 , C08F2/48 , C08F299/02 , G03F7/00 , G03F7/027 , G03F7/033 , G03C1/94 , G03C1/70
CPC分类号： C08F299/024 , C08F2/48 , G03F7/027 , Y10S430/111 , Y10S430/117
摘要： A radiation-polymerizable mixture comprising a binder which is insoluble in water, but soluble or at least swellable in aqueous alkaline solutions; a radiation-activatable polymerization initiator; and a polymerizable polypropylene glycol diester with acrylic or methacrylic acid corresponding to the formula: ##STR1## wherein R represents a hydrogen atom or a methyl group and n represents a number from 2 to 13; and a light-sensitive copying material comprising a support and a light-sensitive layer comprising a mixture of the foregoing type. The radiation-polymerizable mixture of the invention produces non-tacky layers which exhibit a low sensitivity to atmospheric oxygen and are useful as dry or liquid photoresists.
摘要翻译：一种可辐射聚合的混合物，其包含不溶于水但在碱性水溶液中可溶或至少可溶胀的粘合剂; 辐射可激活的聚合引发剂; 和具有对应于下式的丙烯酸或甲基丙烯酸的可聚合的聚丙二醇二酯：其中R表示氢原子或甲基，n表示2至13的数; 以及包含载体和包含前述类型的混合物的感光层的感光复印材料。本发明的可辐射聚合的混合物产生对气氛氧的低敏感性的非粘性层，并且可用作干或液体光致抗蚀剂。

2. 发明授权

US4438189A Radiation-polymerizable mixture and photopolymerizable copying material prepared therefrom 失效
标题翻译：由其制备的可辐射聚合混合物和可光聚合的复印材料
公开(公告)号：US4438189A
公开(公告)日：1984-03-20
申请号：US407488
申请日：1982-08-12
申请人： Ulrich Geissler , Walter Herwig
发明人： Ulrich Geissler , Walter Herwig
IPC分类号： G03F7/038 , B23K35/22 , C08G59/40 , G03F7/004 , G03F7/027 , G03F7/032 , G03C1/68
CPC分类号： B23K35/224 , G03F7/027 , G03F7/032 , Y10S430/106 , Y10S430/114
摘要： A radiation-polymerizable mixture is described comprising (a) a compound which has at least two terminal ethylenically unsaturated groups and which can form a crosslinked polymer by means of free radical initiated chain addition polymerization, (b) a polymeric binder, (c) a radiation-activatable polymerization initiator which can be activated by radiation, and (d) a compound which is thermally crosslinkable with the polymeric binder (b), with the polymerization product of compound (a) and/or with itself and which, if its crosslinking groups are epoxy groups, has at least three epoxy groups. A photopolymerizable copying material is also disclosed having a flexible transparent temporary support and a transferable thermoplastic photopolymerizable layer comprising the foregoing radiation-polymerizable mixture. The photopolymerizable layer, after photocrosslinking, can be additionally cured by thermal crosslinking and is therefore suitable for the manufacture of solder resists and high performance printing plates.
摘要翻译：描述了可辐射聚合的混合物，其包含（a）具有至少两个末端烯属不饱和基团并且可以通过自由基引发的链加成聚合形成交联聚合物的化合物，（b）聚合物粘合剂，（c）可以通过辐射活化的可辐射活化的聚合引发剂，和（d）与聚合物粘合剂（b）可热交联的化合物与化合物（a）和/或其自身的聚合产物，并且如果其交联基团是环氧基团，具有至少三个环氧基团。还公开了一种可光聚合的复印材料，其具有柔性透明临时支撑体和包含上述可辐射聚合混合物的可转移热塑性可光聚合层。光致可聚合层在光致交联之后可以通过热交联进一步固化，因此适用于制造阻焊剂和高性能印刷版。

3. 发明授权

US4559292A Photosensitive transfer material having a support of defined roughness 失效
标题翻译：感光转印材料具有规定的粗糙度的支撑
公开(公告)号：US4559292A
公开(公告)日：1985-12-17
申请号：US537000
申请日：1983-09-29
申请人： Ulrich Geissler , Walter Herwig , Helga Sikora
发明人： Ulrich Geissler , Walter Herwig , Helga Sikora
IPC分类号： G03F7/004 , G03C1/76 , G03C1/805 , G03F7/09 , G03F7/115 , G03F7/34 , G03C3/00
CPC分类号： G03F7/115 , G03F7/346
摘要： The present invention relates to a photosensitive transfer material, which comprises a flexible temporary support film which is preferably transparent, a thermoplastic photosensitive layer, optionally a flexible cover film on the free side of the photosensitive layer and, optionally, an intermediate layer between the support film and the photosensitive layer. The photosensitive transfer material is suitable for manufacturing photoresist stencils and solder masks. The temporary support film has a rough surface which exerts an embossing effect on the surface of the photosensitive layer and the intermediate layer, respectively. The mat-finish of the intermediate layer prevents an irregular deformation of this layer in moist air, while the mat-finish of the photosensitive layer precludes unwanted reflections.
摘要翻译：本发明涉及一种感光转印材料，其包括优选透明的柔性临时支撑膜，热敏感光层，可选地在感光层的自由侧上的柔性覆盖膜，以及可选地，在支撑体胶片和感光层。感光转印材料适用于制造光刻胶模板和焊接掩模。临时支撑膜具有分别在感光层和中间层的表面上施加压花效果的粗糙表面。中间层的表面处理防止了该层在潮湿空气中的不规则变形，而感光层的光洁度则排除了不希望的反射。

4. 发明授权

US4956264A Radiation-polymerizable mixture 失效
标题翻译：可辐射聚合的混合物
公开(公告)号：US4956264A
公开(公告)日：1990-09-11
申请号：US820782
申请日：1986-01-22
申请人： Ulrich Geissler , Hartmut Steppan , Walter Herwig
发明人： Ulrich Geissler , Hartmut Steppan , Walter Herwig
IPC分类号： C08F2/50 , C08F2/46 , C08F2/48 , C08F2/54 , C08F20/28 , C08F20/34 , C08F290/00 , C08F299/02 , G03C1/00 , G03F7/004 , G03F7/027 , G03F7/028 , G03F7/032 , H01L21/027
CPC分类号： G03F7/027 , Y10S430/111
摘要： A radiation-polymerizable mixture, recording material and process for using the recording material in relief recordings. The radiation-polymerizable mixture contains:(a) a polymeric binder,(b) a compound of the formula: ##STR1## `in which A is O, NH or N-alkyl,Q is --CO--C.sub.p H.sub.2p -Z-- or --C.sub.k H.sub.2k O--,Z is O or NH,R.sup.1 is H or alkyl,R.sup.2 is alkyl, alkenyl, cycloalkyl, aryl, aralkyl or SO.sub.2 R.sup.3,R.sup.3 is alkyl, alkenyl, cycloalkyl, aryl, aralkyl or aryloxy,k is a number from 3 to 20,l is a number from 0 to 20,m is a number from 2 to 20,n is a number from 1 to 20 andp is a number from 2 to 10, and(c) a compound or a combination of compounds, which is capable of initiating the polymerization of the compound (b) under the action of actinic radiation.The mixture is especially suitable for the preparation of dry photoresist materials and is distinguished by good flexibility and adhesion to copper and by easy strippability in the light-cured state.
摘要翻译：辐射聚合性混合物，记录材料以及在凸版记录中使用记录材料的方法。可辐射聚合的混合物包含：（a）聚合物粘合剂，（b）下式化合物：其中A是O，NH或N-烷基，Q是-CO-CpH2p-Z-或 - CkH2kO-，Z是O或NH，R1是H或烷基，R2是烷基，烯基，环烷基，芳基，芳烷基或SO2R3，R3是烷基，烯基，环烷基，芳基，芳烷基或芳氧基，k是3〜 20，l为0〜20的数，m为2〜20的数，n为1至20的数，p为2至10的数，以及（c）化合物或化合物的组合，其能够在光化辐射的作用下引发化合物（b）的聚合。该混合物特别适用于干燥光致抗蚀剂材料的制备，并且具有良好的柔韧性和对铜的粘合性，并且在光固化状态下易于剥离。

5. 发明授权

US4458007A Radiation polymerizable mixture containing reaction products of glycerol acrylates and polyisocyanates 失效
标题翻译：含有甘油丙烯酸酯和多异氰酸酯的反应产物的可辐射聚合混合物
公开(公告)号：US4458007A
公开(公告)日：1984-07-03
申请号：US330888
申请日：1981-12-15
申请人： Ulrich Geissler , Heide Sprengel , Walter Herwig , Manfred Hasenjaeger
发明人： Ulrich Geissler , Heide Sprengel , Walter Herwig , Manfred Hasenjaeger
IPC分类号： C08F2/00 , C08F2/46 , C08F2/48 , C08F2/50 , C08F220/36 , C08F290/00 , C08F299/00 , C08F299/06 , C08G18/67 , C08L75/06 , G03F7/004 , G03F7/027 , G03F7/26 , G03C1/68
CPC分类号： C08G18/675 , G03F7/027 , Y10S430/106 , Y10S430/107
摘要： A radiation-polymerizable mixture comprising a polymeric binder, a radiation-activatable polymerization initiator and a polymerizable acrylate or methacrylate ester having at least two urethane groups in the molecule, said ester being a reaction product of glycerol dimethacrylate or glycerol diacrylate and a polyisocyanate obtained by reacting a polyhydroxy compound having from two to six hydroxyl groups with a diisocyanate or a reaction product of glycerol dimethacrylate or glycerol diacrylate and a diisocyanate. The new polymerizable urethanes provide the mixture with a high light-sensitivity, good reciprocity and a low tendency to crystallize.
摘要翻译：一种可辐射聚合的混合物，其包含聚合物粘合剂，可辐射激活的聚合引发剂和在分子中具有至少两个氨基甲酸酯基团的可聚合丙烯酸酯或甲基丙烯酸酯酯，所述酯是甘油二甲基丙烯酸酯或甘油二丙烯酸酯与多异氰酸酯的反应产物，使具有2至6个羟基的多羟基化合物与二异氰酸酯或二甲基丙烯酸甘油酯或二丙烯酸甘油酯和二异氰酸酯的反应产物反应。新的可聚合聚氨酯为混合物提供高的光敏性，良好的互惠性和低结晶倾向。

6. 发明授权

US4387139A Elastomeric, ethylenically unsaturated polyurethanes and radiation polymerizable mixtures containing such polyurethanes 失效
标题翻译：弹性体，烯属不饱和聚氨酯和含有这种聚氨酯的可辐射聚合的混合物
公开(公告)号：US4387139A
公开(公告)日：1983-06-07
申请号：US302687
申请日：1981-09-15
申请人： Walter Herwig , Kurt Erbes , Rudolf Decker , Helga Sikora
发明人： Walter Herwig , Kurt Erbes , Rudolf Decker , Helga Sikora
IPC分类号： C08F2/00 , C08F2/48 , C08F2/50 , C08F290/00 , C08F299/00 , C08F299/06 , C08G18/00 , C08G18/67 , G03F7/032 , C08G18/32 , C08G69/00 , C08L29/04
CPC分类号： G03F7/032 , C08F299/065 , C08G18/6705 , C08G18/675 , Y10T428/31605 , Y10T428/31786
摘要： A polyurethane corresponding to the formula: ##STR1## wherein Q is a divalent, mononuclear or dinuclear aromatic radial which is unsubstituted or is substituted by lower alkyl groups and which can contain, as a linking member, a lower alkylene group,X is one of the groups --O--Ph--Z--Ph--O-- and --OOC--(CH.sub.2).sub.y --COO--,Ph being an optionally substituted phenylene group,Z being an alkylene group having 1-4 carbon atoms and y being a number from 2 to 12,R is a hydrogen atom or a methyl group,Y is an alkylene radical having 2-6 carbon atoms,m is an integer from 4 to 50n is an integer from 1 to 6 ando is an integer from 4 to 20having the properties of thermoplasts and being hardenable to give elastic products. It is suitable for use as a hardenable constituent of photopolymerizable materials.
摘要翻译：对应于下式的聚氨酯：其中Q是未取代的或被低级烷基取代的二价，单核或双核芳族离子，其可以含有作为连接成员的低级亚烷基基团，X是-O-Ph-Z-Ph-O-和-OOC-（CH 2）y -COO-基团之一，Ph是任选取代的亚苯基，Z是具有1-4个碳原子的亚烷基 y为2〜12的数，R为氢原子或甲基，Y为碳原子数2〜6的亚烷基，m为4〜50的整数，n为1〜6的整数，o 是4〜20的整数，具有热塑性的特性，并且可硬化以产生弹性产品。适用于光聚合材料的可硬化组分。

7. 发明授权

US4014957A Thermoplastic polyamide moulding compositions 失效
标题翻译：热塑性聚酰胺模塑组合物
公开(公告)号：US4014957A
公开(公告)日：1977-03-29
申请号：US609674
申请日：1975-09-02
申请人： Gunther Kirsch , Harald Cherdron , Walter Herwig
发明人： Gunther Kirsch , Harald Cherdron , Walter Herwig
IPC分类号： C08L67/00 , C08L77/00
CPC分类号： C08L77/00
摘要： The present invention relates to thermoplastic moulding compositions of (A) 99.5 to 80% by weight, of at least one amorphous linear polyamide and (B) 0.5 to 20% by weight of at least one segmented thermoplastic elastomeric copolyester. These novel moulding compositions combine good toughness and hardness with good elongation and stiffness properties as well as good flowing properties of the molten material.
摘要翻译：本发明涉及（A）99.5至80重量％的至少一种非晶形线性聚酰胺和（B）0.5至20重量％的至少一个分段的热塑性弹性体共聚酯的热塑性模塑组合物。这些新型成型组合物具有良好的韧性和硬度，具有良好的伸长率和刚度特性以及熔融材料的良好流动性能。

8. 发明授权

US3980614A Flame retarding plastic materials 失效
标题翻译：阻燃塑胶材料
公开(公告)号：US3980614A
公开(公告)日：1976-09-14
申请号：US620247
申请日：1975-10-06
申请人： Siegfried Noetzel , Walter Herwig , Rudolf Kern , Werner Lotz
发明人： Siegfried Noetzel , Walter Herwig , Rudolf Kern , Werner Lotz
IPC分类号： C08L23/00 , C07F9/30 , C08K5/49 , C08K5/53 , C08L67/00 , C08L77/00 , C08L101/00 , C09K21/12 , C08J3/20
CPC分类号： C08K5/53
摘要： The specification discloses flame retarding plastic materials which contain, as the flame retarding agent, a phosphinic, diphosphinic or tri-phosphinic acid derived from 2-alkyl-2,5-dioxo-1,2-oxaphospholane and an organic monoamine or diamine or triamine, respectively.
摘要翻译：该说明书公开了阻燃塑料材料，其含有由2-烷基-2,5-二氧代-1,2-氧代磷杂环戊酸和有机单胺或二胺或三胺衍生的次膦酸，二次膦酸或三次膦酸作为阻燃剂，分别。

9. 发明授权

US5387486A Radiation-polymerizable mixture and process for producing a solder resist mask 失效
标题翻译：可辐射聚合的混合物和制造阻焊掩模的方法
公开(公告)号：US5387486A
公开(公告)日：1995-02-07
申请号：US144115
申请日：1993-10-27
申请人： Michael Emmelius , Walter Herwig , Kurt Erbes , Rudolf Decker
发明人： Michael Emmelius , Walter Herwig , Kurt Erbes , Rudolf Decker
IPC分类号： G03F7/033 , C08F257/02 , C08F283/10 , C08G59/00 , C08G59/18 , C08G59/40 , C08K3/36 , G03F1/08 , G03F7/004 , G03F7/031 , G03F7/032 , G03F7/038 , H05K3/06 , H05K3/28 , G03C3/00
CPC分类号： H05K3/287 , C08F257/02 , C08F283/10 , G03F7/004 , G03F7/032 , H05K2203/0793 , Y10S430/136
摘要： The present invention relates to a radiation-polymerizable mixture which includes a polymerizable compound, a polymeric binder which has units of methacrylic acid, a methacrylic acid ester and a styrene, the latter in a proportion of 40 to 65% by weight, a finely divided mineral pigment on a silicic acid or silicate basis, a photopolymerization initiator, a compound having at least two epoxy groups in its molecule and a thermal hardener for epoxy groups. The mixture is advantageous, in particular, for producing solder masks and can be cured after exposure to an image and development by heating to about 80.degree. to 150.degree. C. to form a stencil which is resistant under soldering conditions.
摘要翻译：本发明涉及一种可辐射聚合的混合物，其包括可聚合化合物，具有甲基丙烯酸单元，甲基丙烯酸酯和苯乙烯的聚合物粘合剂，后者的比例为40至65重量％，细分在硅酸或硅酸盐基础上的矿物颜料，光聚合引发剂，在其分子中具有至少两个环氧基的化合物和用于环氧基的热硬化剂。该混合物特别有利于制备焊料掩模，并且可以在暴露于图像之后进行固化，并通过加热至约80-150℃进行显影，以形成在焊接条件下具有耐受性的模版。

10. 发明授权

US4399239A Elastomeric, ethylenically unsaturated polyurethanes and radiation polymerizable mixtures containing such polyurethanes 失效
标题翻译：弹性体，烯属不饱和聚氨酯和含有这种聚氨酯的可辐射聚合的混合物
公开(公告)号：US4399239A
公开(公告)日：1983-08-16
申请号：US400351
申请日：1982-07-21
申请人： Walter Herwig , Kurt Erbes , Rudolf Decker , Helga Sikora
发明人： Walter Herwig , Kurt Erbes , Rudolf Decker , Helga Sikora
IPC分类号： C08F2/00 , C08F2/48 , C08F2/50 , C08F290/00 , C08F299/00 , C08F299/06 , C08G18/00 , C08G18/67 , G03F7/032 , C08G18/14 , C08G18/32 , C08L29/04
CPC分类号： G03F7/032 , C08F299/065 , C08G18/6705 , C08G18/675 , Y10T428/31605 , Y10T428/31786
摘要： A polyurethane corresponding to the formula: ##STR1## wherein Q is a divalent, mononuclear or dinuclear aromatic radial which is unsubstituted or is substituted by lower alkyl groups and which can contain, as a linking member, a lower alkylene group,X is one of the groups --O--Ph--Z--Ph--O-- and --OOC--(CH.sub.2).sub.y --COO--,Ph being an optionally substituted phenylene group,Z being an alkylene group having 1--4 carbon atoms andy being a number from 2 to 12,R is a hydrogen atom or a methyl group,Y is an alkylene radical having 2-6 carbon atoms,m is an integer from 4 to 50n is an integer from 1 to 6 ando is an integer from 4 to 20having the properties of thermolasts and being hardenable to give elastic products. It is suitable for use as a hardenable constituent of photopolymerizable materials.
摘要翻译：对应于下式的聚氨酯：其中Q是未取代的或被低级烷基取代的二价，单核或双核芳族离子，其可以含有作为连接成员的低级亚烷基基团，X是-O-Ph-Z-Ph-O-和-OOC-（CH 2）y -COO-基团之一，Ph是任选取代的亚苯基，Z是具有1-4个碳原子的亚烷基 y为2〜12的数，R为氢原子或甲基，Y为碳原子数2〜6的亚烷基，m为4〜50的整数，n为1〜6的整数，o 是4〜20的整数，具有热熔胶的性质，并且可硬化以产生弹性产品。适用于光聚合材料的可硬化组分。

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