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1. 发明专利

AU5828473A FLAME RESISTANT THERMOPLASTIC POLYESTERS 未知
公开(公告)号：AU5828473A
公开(公告)日：1975-01-23
申请号：AU5828473
申请日：1973-07-19
申请人： HANS JERG KLEINER , WALTER HERWIG
发明人： KLEINER HANS-JERG , HERWIG WALTER
IPC分类号： C08G79/00 , C07F9/32 , C07F9/38 , C07F9/40 , C08G63/00 , C08G63/692 , C08G79/02 , D01F6/84 , C08G17/04 , C08G39/02

2. 发明专利

AU5828373A DIPHOSPHINIC ACID ESTERS 未知
公开(公告)号：AU5828373A
公开(公告)日：1975-01-23
申请号：AU5828373
申请日：1973-07-19
申请人： WALTER HERWIG , HANS JERG KLEINER
发明人： HERWIG WALTER , KLEINER HANS-JERG
IPC分类号： C08L67/00 , B01J31/00 , C07B61/00 , C07F9/32 , C08G63/692 , C08G79/00 , C08G79/02 , C08G79/04 , C08K5/00 , C08K5/53 , C08G39/00
摘要： Di-phosphinic acid esters of the formula WHEREIN R represents saturated, open-chain alkylene having from 1 to 15 carbon atoms, phenylene, biphenylene or phenylalkylene, R1 and R2 represent alkyl or cycloalkyl groups, as well as phenyl or benzyl and R3 represents saturated, open-chain alkylene and n is from 1 to 30, are described as well as suitable processes for the preparation of the di-phosphinic acid ester named and their use for flame-proofing polyesters.

3. 发明专利

AU5828273A FLAME RESISTANT FILAMENTS AND FIBERS FROM POLYESTERS 未知
公开(公告)号：AU5828273A
公开(公告)日：1975-01-23
申请号：AU5828273
申请日：1973-07-19
申请人： WALTER HERWIG , ULRICH BOLLERT , HANS JERG KLEINER
发明人： HERWIG WALTER , BOLLERT ULRICH , KLEINER HANS-JERG
IPC分类号： C08G63/00 , C07F9/30 , C07F9/32 , C08G63/692 , D01F6/84 , C09K3/28 , D01F7/04
摘要： 1435162 Flame resistant polyester fibres HOECHST AG 20 July 1973 [22 July 1972] 34663/73 Heading C3R [Also in Division C2] Fibres or filaments are made from a polyester comprising dicarboxylic acid units, diol units and units of the formula in which R is an alkylene, cycloalkylene, arylene or aralkylene radical and R 1 and R 2 are C 1-6 alkyl or an aryl or aralkyl group, and R, R 1 and R 2 may carry substituents or contain hetero atoms. The examples describe fibres of polyesters prepared from dimethyl terephthalate, optionally with dimethyl isophthalate, ethylene glycol or 1,4-butanediol and methylene- or ethylene-di(methylphosphinic acids), phenylene - 1,4 - di(methylphosphinic acid), pxylylene - di(methyl - phosphinic acid), ethylene - 1,2 - di(phenylphosphinic acid)

4. 发明授权

US5387486A Radiation-polymerizable mixture and process for producing a solder resist mask 失效
标题翻译：可辐射聚合的混合物和制造阻焊掩模的方法
公开(公告)号：US5387486A
公开(公告)日：1995-02-07
申请号：US144115
申请日：1993-10-27
申请人： Michael Emmelius , Walter Herwig , Kurt Erbes , Rudolf Decker
发明人： Michael Emmelius , Walter Herwig , Kurt Erbes , Rudolf Decker
IPC分类号： G03F7/033 , C08F257/02 , C08F283/10 , C08G59/00 , C08G59/18 , C08G59/40 , C08K3/36 , G03F1/08 , G03F7/004 , G03F7/031 , G03F7/032 , G03F7/038 , H05K3/06 , H05K3/28 , G03C3/00
CPC分类号： H05K3/287 , C08F257/02 , C08F283/10 , G03F7/004 , G03F7/032 , H05K2203/0793 , Y10S430/136
摘要： The present invention relates to a radiation-polymerizable mixture which includes a polymerizable compound, a polymeric binder which has units of methacrylic acid, a methacrylic acid ester and a styrene, the latter in a proportion of 40 to 65% by weight, a finely divided mineral pigment on a silicic acid or silicate basis, a photopolymerization initiator, a compound having at least two epoxy groups in its molecule and a thermal hardener for epoxy groups. The mixture is advantageous, in particular, for producing solder masks and can be cured after exposure to an image and development by heating to about 80.degree. to 150.degree. C. to form a stencil which is resistant under soldering conditions.
摘要翻译：本发明涉及一种可辐射聚合的混合物，其包括可聚合化合物，具有甲基丙烯酸单元，甲基丙烯酸酯和苯乙烯的聚合物粘合剂，后者的比例为40至65重量％，细分在硅酸或硅酸盐基础上的矿物颜料，光聚合引发剂，在其分子中具有至少两个环氧基的化合物和用于环氧基的热硬化剂。该混合物特别有利于制备焊料掩模，并且可以在暴露于图像之后进行固化，并通过加热至约80-150℃进行显影，以形成在焊接条件下具有耐受性的模版。

5. 发明授权

US4438189A Radiation-polymerizable mixture and photopolymerizable copying material prepared therefrom 失效
标题翻译：由其制备的可辐射聚合混合物和可光聚合的复印材料
公开(公告)号：US4438189A
公开(公告)日：1984-03-20
申请号：US407488
申请日：1982-08-12
申请人： Ulrich Geissler , Walter Herwig
发明人： Ulrich Geissler , Walter Herwig
IPC分类号： G03F7/038 , B23K35/22 , C08G59/40 , G03F7/004 , G03F7/027 , G03F7/032 , G03C1/68
CPC分类号： B23K35/224 , G03F7/027 , G03F7/032 , Y10S430/106 , Y10S430/114
摘要： A radiation-polymerizable mixture is described comprising (a) a compound which has at least two terminal ethylenically unsaturated groups and which can form a crosslinked polymer by means of free radical initiated chain addition polymerization, (b) a polymeric binder, (c) a radiation-activatable polymerization initiator which can be activated by radiation, and (d) a compound which is thermally crosslinkable with the polymeric binder (b), with the polymerization product of compound (a) and/or with itself and which, if its crosslinking groups are epoxy groups, has at least three epoxy groups. A photopolymerizable copying material is also disclosed having a flexible transparent temporary support and a transferable thermoplastic photopolymerizable layer comprising the foregoing radiation-polymerizable mixture. The photopolymerizable layer, after photocrosslinking, can be additionally cured by thermal crosslinking and is therefore suitable for the manufacture of solder resists and high performance printing plates.
摘要翻译：描述了可辐射聚合的混合物，其包含（a）具有至少两个末端烯属不饱和基团并且可以通过自由基引发的链加成聚合形成交联聚合物的化合物，（b）聚合物粘合剂，（c）可以通过辐射活化的可辐射活化的聚合引发剂，和（d）与聚合物粘合剂（b）可热交联的化合物与化合物（a）和/或其自身的聚合产物，并且如果其交联基团是环氧基团，具有至少三个环氧基团。还公开了一种可光聚合的复印材料，其具有柔性透明临时支撑体和包含上述可辐射聚合混合物的可转移热塑性可光聚合层。光致可聚合层在光致交联之后可以通过热交联进一步固化，因此适用于制造阻焊剂和高性能印刷版。

6. 发明授权

US4399239A Elastomeric, ethylenically unsaturated polyurethanes and radiation polymerizable mixtures containing such polyurethanes 失效
标题翻译：弹性体，烯属不饱和聚氨酯和含有这种聚氨酯的可辐射聚合的混合物
公开(公告)号：US4399239A
公开(公告)日：1983-08-16
申请号：US400351
申请日：1982-07-21
申请人： Walter Herwig , Kurt Erbes , Rudolf Decker , Helga Sikora
发明人： Walter Herwig , Kurt Erbes , Rudolf Decker , Helga Sikora
IPC分类号： C08F2/00 , C08F2/48 , C08F2/50 , C08F290/00 , C08F299/00 , C08F299/06 , C08G18/00 , C08G18/67 , G03F7/032 , C08G18/14 , C08G18/32 , C08L29/04
CPC分类号： G03F7/032 , C08F299/065 , C08G18/6705 , C08G18/675 , Y10T428/31605 , Y10T428/31786
摘要： A polyurethane corresponding to the formula: ##STR1## wherein Q is a divalent, mononuclear or dinuclear aromatic radial which is unsubstituted or is substituted by lower alkyl groups and which can contain, as a linking member, a lower alkylene group,X is one of the groups --O--Ph--Z--Ph--O-- and --OOC--(CH.sub.2).sub.y --COO--,Ph being an optionally substituted phenylene group,Z being an alkylene group having 1--4 carbon atoms andy being a number from 2 to 12,R is a hydrogen atom or a methyl group,Y is an alkylene radical having 2-6 carbon atoms,m is an integer from 4 to 50n is an integer from 1 to 6 ando is an integer from 4 to 20having the properties of thermolasts and being hardenable to give elastic products. It is suitable for use as a hardenable constituent of photopolymerizable materials.
摘要翻译：对应于下式的聚氨酯：其中Q是未取代的或被低级烷基取代的二价，单核或双核芳族离子，其可以含有作为连接成员的低级亚烷基基团，X是-O-Ph-Z-Ph-O-和-OOC-（CH 2）y -COO-基团之一，Ph是任选取代的亚苯基，Z是具有1-4个碳原子的亚烷基 y为2〜12的数，R为氢原子或甲基，Y为碳原子数2〜6的亚烷基，m为4〜50的整数，n为1〜6的整数，o 是4〜20的整数，具有热熔胶的性质，并且可硬化以产生弹性产品。适用于光聚合材料的可硬化组分。

7. 发明授权

US4062828A Flame resistant polyamide moulding compositions 失效
标题翻译：耐火聚酰胺成型组合物
公开(公告)号：US4062828A
公开(公告)日：1977-12-13
申请号：US688895
申请日：1976-05-21
申请人： Walter Herwig , Hans-Jerg Kleiner
发明人： Walter Herwig , Hans-Jerg Kleiner
IPC分类号： C08L77/00 , C07F9/53 , C08K5/5397 , C08K5/04
CPC分类号： C07F9/5312 , C08K5/53 , C08K5/5397
摘要： The present invention relates to novel agents for the flame-proofing of polymers, especially transparent polyamides. These agents, phosphinylphosphinic acids, are used in quantities of 3 to 40 weight percent calculated on the weight of the polymer. These flame-proofing agents can easily be prepared and render the polymers flame-proof to a high degree without deteriorating the mechanical and physical properties.
摘要翻译：本发明涉及用于聚合物，特别是透明聚酰胺阻燃的新型试剂。这些试剂，次膦基次膦酸的用量为聚合物重量计算的3至40重量％。这些阻燃剂可以容易地制备并使聚合物具有高度的阻燃性，而不会降低机械和物理性能。

8. 发明授权

US3962194A Polyesters containing structural units derived from phosphonic acids or estere 失效
标题翻译：含有从PHOSPHONIC ACIDS或ESTERE衍生的结构单元的聚酯
公开(公告)号：US3962194A
公开(公告)日：1976-06-08
申请号：US548828
申请日：1975-02-10
申请人： Ulrich Bollert , Hans-Jerg Kleiner , Walter Herwig
发明人： Ulrich Bollert , Hans-Jerg Kleiner , Walter Herwig
IPC分类号： C08G63/00 , C07F9/30 , C07F9/32 , C08G63/692 , D01F6/84 , C08G63/16 , C08G63/18 , C08G63/66 , C08G63/68
CPC分类号： C08G63/6926 , C07F9/305 , C07F9/3241 , D01F6/84 , Y10S260/24
摘要： Permanently flame resistant filaments and fibers are produced from synthetic linear polyesters in which about 5 to 15 mol% of the acid component of the polyester consist of phosphinic acid structural units of the formula ##EQU1## in which R, R.sub.1 and R.sub.2 stand for organic radicals which may contain hetero atoms, preferably halogen, oxygen or sulfur. The filaments and fibers can be well dyed deep shades and are suitable in all fields of application where textiles which are hard to inflame are desired.

9. 发明授权

US3941752A Flame retarding linear polyesters and shaped articles thereof 失效
标题翻译：阻燃线性聚酯及其成型制品
公开(公告)号：US3941752A
公开(公告)日：1976-03-02
申请号：US505686
申请日：1974-09-13
申请人： Hans-Jerg Kleiner , Manfred Finke , Ulrich Bollert , Walter Herwig
发明人： Hans-Jerg Kleiner , Manfred Finke , Ulrich Bollert , Walter Herwig
IPC分类号： C08G63/00 , C07F9/6571 , C08G63/20 , C08G63/692 , C08G79/04 , D01F6/84 , C08G63/18
CPC分类号： D01F6/84 , C07F9/657172 , C08G63/6926 , Y10S260/24 , Y10S57/904
摘要： Flame-repellant linear polyesters are obtained by incorporating by condensation phosphorus-compounds having the formula ##EQU1## wherein R and R.sub.1 are organic radicals which may also contain hereto atoms into the linear polyesters, preferably those from terephthalic acid and ethylene glycol. These polyesters are materials of which flame-repellent filaments, fibers, sheets, press-moulded and injection-moulded articles may be made. Products of the invention can be used whereever especially acute risks of ignition and fire exist.
摘要翻译：阻燃线性聚酯通过掺入具有式O＆amp; amp; HO-PR-COOH，| R1的缩合磷化合物而获得，其中R和R 1是也可以含有原子的有机基团，优选来自对苯二甲酸和乙二醇。这些聚酯是可以制造阻燃长丝，纤维，片材，压制成型和注射成型制品的材料。本发明的产品可以在特别急剧的点火和火灾风险存在的情况下使用。

10. 发明授权

US4956264A Radiation-polymerizable mixture 失效
标题翻译：可辐射聚合的混合物
公开(公告)号：US4956264A
公开(公告)日：1990-09-11
申请号：US820782
申请日：1986-01-22
申请人： Ulrich Geissler , Hartmut Steppan , Walter Herwig
发明人： Ulrich Geissler , Hartmut Steppan , Walter Herwig
IPC分类号： C08F2/50 , C08F2/46 , C08F2/48 , C08F2/54 , C08F20/28 , C08F20/34 , C08F290/00 , C08F299/02 , G03C1/00 , G03F7/004 , G03F7/027 , G03F7/028 , G03F7/032 , H01L21/027
CPC分类号： G03F7/027 , Y10S430/111
摘要： A radiation-polymerizable mixture, recording material and process for using the recording material in relief recordings. The radiation-polymerizable mixture contains:(a) a polymeric binder,(b) a compound of the formula: ##STR1## `in which A is O, NH or N-alkyl,Q is --CO--C.sub.p H.sub.2p -Z-- or --C.sub.k H.sub.2k O--,Z is O or NH,R.sup.1 is H or alkyl,R.sup.2 is alkyl, alkenyl, cycloalkyl, aryl, aralkyl or SO.sub.2 R.sup.3,R.sup.3 is alkyl, alkenyl, cycloalkyl, aryl, aralkyl or aryloxy,k is a number from 3 to 20,l is a number from 0 to 20,m is a number from 2 to 20,n is a number from 1 to 20 andp is a number from 2 to 10, and(c) a compound or a combination of compounds, which is capable of initiating the polymerization of the compound (b) under the action of actinic radiation.The mixture is especially suitable for the preparation of dry photoresist materials and is distinguished by good flexibility and adhesion to copper and by easy strippability in the light-cured state.
摘要翻译：辐射聚合性混合物，记录材料以及在凸版记录中使用记录材料的方法。可辐射聚合的混合物包含：（a）聚合物粘合剂，（b）下式化合物：其中A是O，NH或N-烷基，Q是-CO-CpH2p-Z-或 - CkH2kO-，Z是O或NH，R1是H或烷基，R2是烷基，烯基，环烷基，芳基，芳烷基或SO2R3，R3是烷基，烯基，环烷基，芳基，芳烷基或芳氧基，k是3〜 20，l为0〜20的数，m为2〜20的数，n为1至20的数，p为2至10的数，以及（c）化合物或化合物的组合，其能够在光化辐射的作用下引发化合物（b）的聚合。该混合物特别适用于干燥光致抗蚀剂材料的制备，并且具有良好的柔韧性和对铜的粘合性，并且在光固化状态下易于剥离。

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