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    • 9. 发明申请
    • SELECTIVE DIMETHYLETHER RECOVERY AND RECYCLE IN A METHANOL-TO-OLEFIN PROCESS
    • 甲醇到烯烃选择性二甲基醚的回收和再循环
    • WO2004094355A2
    • 2004-11-04
    • PCT/US2004/012415
    • 2004-04-22
    • UOP LLCSENETAR, John, J.
    • SENETAR, John, J.
    • C07C41/00
    • C07C41/34Y02P30/42C07C43/043
    • An improved methanol-to-olefin (MTO) product recovery scheme is provided which enables substantial reduction in the amount of light olefins that are undesirably captured in a dimethylether (DME) recycle stream when a portion of the methanolic feed to the MTO reaction zone is used as the scrubbing solvent in a primary DME absorption zone in order to recycle this DME oxygenate by-product to the MTO reaction zone. In accordance with the present invention, a liquid solvent stream recovered from the primary DME absorption zone is subjected in a stripping zone to light olefin stripping conditions sufficient to lift a substantial portion of the light olefins that are absorbed in the DME solvent without stripping a significant portion of this methanol solvent, thereby increasing the recovery of desired light olefins while simultaneously diminishing the amount of light olefins carried by the DME recycle stream back to MTO conversion step.
    • 提供了一种改进的甲醇 - 烯烃(MTO)产物回收方案,其能够显着减少在二甲醚(DME)再循环料流中不希望地捕获的轻质烯烃的量, 使用MTO反应区的甲醇进料作为初级DME吸收区中的洗涤溶剂,以便将该DME含氧化合物副产物再循环至MTO反应区。 根据本发明,将从初级DME吸收区回收的液体溶剂流在汽提区中进行轻质烯烃汽提条件,所述条件足以提升吸收在DME溶剂中的大部分轻质烯烃而不剥离显着 从而增加所需轻质烯烃的回收率,同时将由DME再循环料流携带的轻质烯烃的量减少回到MTO转化步骤。
    • 10. 发明申请
    • TWO-STAGE QUENCH TOWER FOR USE WITH OXYGENATE CONVERSION PROCESS
    • 两级QU CH OWER。。。。。。。。。。。。。。。。。
    • WO2003104170A1
    • 2003-12-18
    • PCT/US2002/018713
    • 2002-06-10
    • UOP LLCMILLER, Lawrence, W.SENETAR, John, J.
    • MILLER, Lawrence, W.SENETAR, John, J.
    • C07C1/20
    • C07C1/20C07C2529/85C10G3/49C10G2400/20Y02A20/402Y02P30/20C07C11/02
    • The present invention relates to a process for the recovering heat and removing impurities from a reactor effluent stream withdrawn from a fluidized exothermic reaction zone for the conversion of oxygenates into light olefins from an oxygenate feedstream. The process comprises a novel two-stage quench tower system to remove water from the reactor effluent stream in the first tower and recover heat from the reactor effluent to at least partially vaporize the feedstream by indirect heat exchange between the oxygenate feedstream and either a first stage overhead stream or a first stage pumparound stream. A drag stream withdrawn from the first tower comprises the majority of the impurities and any higher boiling oxygenates. The second stage tower further removes water from the light olefin product stream and provides a purified water stream which requires only minimal water stripping to produce a high purity water stream. The present invention concentrates the impurities into a relatively small stream and results in a significant energy and capital savings in providing a vaporized feedstream to the fluidized exothermic reaction zone.
    • 本发明涉及一种从流化的放热反应区取出的反应器流出物流中回收热量和去除杂质的方法,用于将含氧化合物从含氧化合物进料流转化成轻质烯烃。 该方法包括一种新型的两级骤冷塔系统,用于从第一塔中的反应器流出物流中除去水,并从反应器流出物回收热量,以通过在含氧化合物进料流和第一级之间的间接热交换来至少部分地蒸发进料流 塔顶流或第一级泵送流。 从第一塔排出的拖曳流包括大部分杂质和任何较高沸点的含氧化合物。 第二级塔还进一步从轻质烯烃产物流中除去水,并提供纯化水流,其仅需要极少的水汽提来产生高纯度水流。 本发明将杂质浓缩成相对较小的流,并且在向流化的放热反应区提供蒸发的进料流方面导致显着的能量和资本节省。