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    • 2. 发明申请
    • PROCESS FOR AIR ENRICHMENT IN PRODUCING HYDROGEN FOR USE WITH FUEL CELLS
    • 用于生产用于燃料电池的氢气的空气加工方法
    • WO0247191A2
    • 2002-06-13
    • PCT/US0147996
    • 2001-12-05
    • UOP LLCTOWLER GAVIN PDOSHI KISHORE J
    • TOWLER GAVIN PDOSHI KISHORE J
    • H01M8/04H01M8/06
    • H01M8/0662C01B3/382C01B2203/0233C01B2203/0261C01B2203/0288C01B2203/043C01B2203/044C01B2203/047C01B2203/066C01B2203/127C01B2203/143H01M8/04022H01M8/0612
    • Hydrogen generation and fuel cell operation are integrated through the use of a fuel processor (104) or hydrogen generation zone which comprises a pre-reforming zone, a partial oxidation zone, a reforming zone, a water gas shift zone and a preferential oxidation zone. According to the present invention, an oxygen-enriched stream (14, 16) is provided to the fuel processor (104) and to the fuel cell (106) from the adsorption effluent (12) withdrawn from an adsorption zone (101). The oxygen-enriched stream is depleted in nitrogen which improved the efficiency of the fuel processor and the fuel cell by reducing nitrogen dilution. A further advantage resulted in fuel processor/fuel cell systems which burn the anode waste gas (20) in a combustion zone (108) to provide heat to the fuel processor zone. By diluting the anode waste gas with an oxygen-reduced gas (24), it is possible to maintain the combustion temperature in the convection range and reduce or eliminate the amount of excess air employed in the combustion zone.
    • 通过使用包括预重整区,部分氧化区,重整区,水煤气换挡区和优先氧化区的燃料处理器(104)或氢生成区来集成氢发生和燃料电池操作。 根据本发明,从吸附区(101)排出的吸附流出物(12)向燃料处理器(104)和燃料电池(106)提供富氧流(14,16)。 富氧流在氮中耗尽,通过减少氮稀释来提高燃料处理器和燃料电池的效率。 另一个优点是燃料处理器/燃料电池系统将燃烧区(108)中的阳极废气(20)燃烧以向燃料处理器区域提供热量。 通过用氧还原气体(24)稀释阳极废气,可以将燃烧温度保持在对流范围内并减少或消除在燃烧区中使用的过量空气的量。
    • 10. 发明申请
    • PROCESS FOR AIR ENRICHMENT IN PRODUCING HYDROGEN FOR USE WITH FUEL CELLS
    • 用于生产用于燃料电池的氢气的空气加工方法
    • WO0247191A9
    • 2003-09-18
    • PCT/US0147996
    • 2001-12-05
    • UOP LLCTOWLER GAVIN PDOSHI KISHORE J
    • TOWLER GAVIN PDOSHI KISHORE J
    • H01M8/04H01M8/06
    • H01M8/0662C01B3/382C01B2203/0233C01B2203/0261C01B2203/0288C01B2203/043C01B2203/044C01B2203/047C01B2203/066C01B2203/127C01B2203/143H01M8/04022H01M8/0612
    • Hydrogen generation and fuel cell operation are integrated through the use of a fuel processor (104) or hydrogen generation zone which comprises a pre-reforming zone, a partial oxidation zone, a reforming zone, a water gas shift zone and a preferential oxidation zone. According to the present invention, an oxygen-enriched stream (14, 16) is provided to the fuel processor (104) and to the fuel cell (106) from the adsorption effluent (12) withdrawn from an adsorption zone (101). The oxygen-enriched stream is depleted in nitrogen which improved the efficiency of the fuel processor and the fuel cell by reducing nitrogen dilution. A further advantage resulted in fuel processor/fuel cell systems which burn the anode waste gas (20) in a combustion zone (108) to provide heat to the fuel processor zone. By diluting the anode waste gas with an oxygen-reduced gas (24), it is possible to maintain the combustion temperature in the convection range and reduce or eliminate the amount of excess air employed in the combustion zone.
    • 通过使用包括预重整区,部分氧化区,重整区,水煤气换挡区和优先氧化区的燃料处理器(104)或氢生成区来集成氢发生和燃料电池操作。 根据本发明,从吸附区(101)排出的吸附流出物(12)向燃料处理器(104)和燃料电池(106)提供富氧流(14,16)。 富氧流在氮中耗尽,通过减少氮稀释来提高燃料处理器和燃料电池的效率。 另一个优点是燃料处理器/燃料电池系统将燃烧区(108)中的阳极废气(20)燃烧以向燃料处理器区域提供热量。 通过用氧还原气体(24)稀释阳极废气,可以将燃烧温度保持在对流范围内并减少或消除在燃烧区中使用的过量空气的量。