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1. 发明授权

US06365689B1 Propylene/ethylene random copolymer, molding material, and molded article 有权
标题翻译：丙烯/乙烯无规共聚物，成型材料和模制品
公开(公告)号：US06365689B1
公开(公告)日：2002-04-02
申请号：US09485618
申请日：2000-02-15
申请人： Tsutomu Ushioda , Jun Saito , Mototake Tsutsui , Yoshitoyo Yasuda , Hiroyuki Fujita , Yoshiyuki Oogi , Minoru Adachi , Yoshitaka Morimoto , Taketo Hirose , Youichi Kugimiya , Yasuhiro Shiraishi
发明人： Tsutomu Ushioda , Jun Saito , Mototake Tsutsui , Yoshitoyo Yasuda , Hiroyuki Fujita , Yoshiyuki Oogi , Minoru Adachi , Yoshitaka Morimoto , Taketo Hirose , Youichi Kugimiya , Yasuhiro Shiraishi
IPC分类号： C08F442
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F210/06 , Y10S526/943 , C08F4/65916 , C08F2500/03 , C08F210/08 , C08F2500/12
摘要： The present invention provides propylene/ethylene random copolymers characterized in that: an ethylene content (Ew) is 0.1-10 wt %, a relationship between an isolated ethylene content (E1) and the ethylene content (Ew) is represented by the following equation E1>0.85−0.01 Ew 2,1- and 1,3-propylene units present in a polymer chain are 0-1 mol %, a weight average molecular weight (Mw) is in the range of 40,000-1,000,000, and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight(Mn) is in the range of 1.5-3.8. The copolymers are suitable for a base resin for a molding material for the production of a wide variety of molded articles which are high in randomness and excellent in stiffness, heat resistance and transparency.
摘要翻译：本发明提供丙烯/乙烯无规共聚物，其特征在于：乙烯含量（Ew）为0.1-10重量％，分离的乙烯含量（E1）和乙烯含量（Ew）之间的关系由下列等式2表示：存在于聚合物链中的1-和1,3-丙烯单元为0-1mol％，重均分子量（Mw）为40,000-1,000,000，重均分子量（Mw / Mn）重量（Mw）与数均分子量（Mn）的比值在1.5-3.8的范围内。该共聚物适用于用于生产各种随机性高的成型制品的成型材料的基础树脂，刚性，耐热性和透明度优异。

2. 发明授权

US06410662B1 Process for the preparation of olefin (co) polymers, olefin copolymers, and application thereof 有权
标题翻译：烯烃（共）聚合物，烯烃共聚物的制备方法及其应用
公开(公告)号：US06410662B1
公开(公告)日：2002-06-25
申请号：US09485492
申请日：2000-02-11
申请人： Tsutomu Ushioda , Jun Saito , Mototake Tsutsui , Yoshitoyo Yasuda , Hiroyuki Fujita , Toshihiro Uwai , Yoshiyuki Ohgi , Minoru Adachi , Yoshitaka Morimoto , Taketo Hirose , Youichi Kugimiya , Masahiko Taniguchi , Hitoshi Kuramochi
发明人： Tsutomu Ushioda , Jun Saito , Mototake Tsutsui , Yoshitoyo Yasuda , Hiroyuki Fujita , Toshihiro Uwai , Yoshiyuki Ohgi , Minoru Adachi , Yoshitaka Morimoto , Taketo Hirose , Youichi Kugimiya , Masahiko Taniguchi , Hitoshi Kuramochi
IPC分类号： C08F444
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65927 , C08F10/00 , C08F110/06 , Y10S526/943 , C08F4/65916 , C08F2500/03 , C08F2500/15 , C08F2500/01 , C08F2500/12 , C08F2500/26
摘要： Disclosed is a process for producing olefin polymers or copolymers which can freely regulates the molecular weight of the polymers or copolymers as well as novel olefin polymers or copolymers excellent in rigidity, heat-resisting property and transparency, moldings and compositions thereof which find a wide variety of applications in versatile industrial parts including containers, films, sheets, filaments or fibers, featured by (1) a process for producing olefin polymers or copolymers by the aid of a catalyst comprised predominantly of the compounds: (A) a transition metal compound of the formula: Q(C5H4−mR1m)(C5H4−nR2n)MXY, (B) an aluminoxane, (C) a fine particulate carrier, and (D) an organoaluminum compound; (2) olefin polymers or copolymers characterized by (a) a specific ratio of isotactic pentad, (b) 2,1- and 1.3-propylene units contents in the polymer chain, (c) a specific Mw, (d) a specific Mw/Mn, and (e) in case of elevating temperature of o-dichlorobenzene continuously or stepwise up to given temperatures to measure the amount of eluated polyolefin at each temperature, the position of a main elution peak and the amount of components existing in the range of ±10° C. of the main elution peak; (3) injection moldings, films, filaments or fibers, and non-woven fabric of the polypropylene obtained; and (4) a composition comprising the polypropylene obtained and an &agr;-nucleating agent or a composition comprising the polypropylene and a radical generator and having been produced by subjecting to the mixture to melt-kneading.
摘要翻译：公开了可以自由调节聚合物或共聚物的分子量的烯烃聚合物或共聚物的方法，以及刚性，耐热性能和透明性，模制品和组合物的新型烯烃聚合物或共聚物，其具有广泛的种类在包括容器，膜，片，长丝或纤维在内的通用工业部件中的应用，其特征在于（1）主要由以下化合物构成的催化剂生产烯烃聚合物或共聚物的方法：（A）过渡金属化合物式（QH（C5H4-mR1m）（C5H4-nR2n））MXY，（B）铝氧烷，（C）微粒载体和（D）有机铝化合物; （2）烯烃聚合物或共聚物，其特征在于（a）聚合物链中全同立构五单体，（b）2,1-和1.3-丙烯单元含量的比例，（c）特定Mw，（d）特定Mw / Mn，（e）在邻二氯苯连续或逐步升高至给定温度的情况下，在每个温度下测量洗脱聚烯烃的量，主洗脱峰的位置和存在于该范围内的组分的量 ±10℃的主洗脱峰; （3）注射成型品，薄膜，细丝或纤维，以及得到的聚丙烯的无纺布; 和（4）包含所得聚丙烯和α-成核剂或包含聚丙烯和自由基发生剂的组合物并通过使混合物进行熔融捏合而制备的组合物的组合物。

3. 发明授权

US06326432B1 Polypropylene composition 有权
标题翻译：聚丙烯组成
公开(公告)号：US06326432B1
公开(公告)日：2001-12-04
申请号：US09508799
申请日：2000-03-17
申请人： Hiroyuki Fujita , Jun Saito , Yoshitoyo Yasuda , Tsutomu Ushioda , Mototake Tsutsui , Yoshiyuki Ohgi , Minoru Adachi
发明人： Hiroyuki Fujita , Jun Saito , Yoshitoyo Yasuda , Tsutomu Ushioda , Mototake Tsutsui , Yoshiyuki Ohgi , Minoru Adachi
IPC分类号： C08F800
CPC分类号： C08L23/12 , C08F110/06 , C08L23/16 , C08L2666/04 , C08F2500/03 , C08F2500/15
摘要： Disclosed is a polypropylene composition excellent in balance of low temperature impact-strength, rigidity, heat resistance and transparency, which is featured by comprising 20-95% by weight of a polypropylene defined in the following [I] and 5-80% by weight of a propylene-&agr;-olefin copolymer defined in the following [II]: [I] a polypropylene featured by having: (1) a ratio of isotactic pentad (mmmm) of 0.900-0.949, (2) the 2,1- and 1,3-propylene units in the polymer chain in the amount of 0-1 mole %, (3) a weight average molecular weight (Mw) of 40,000-1,000,000, (4) a ratio of a weight average molecular weight (Mw) to a number average molecular weight (Mn), i.e. (Mw)/(Mn) of 1.5-3.8, and (5) in case of elevating the temperature of o-dichlorobenzene continuously or stepwise up to given temperatures to measure the amount of eluted polypropylene at each temperature, the position of a main elution peak is 95-110° C. and the amount of components existing in the range of ±10° C. of the main elution peak is at least 90% of the total amounts of components eluted at a temperature higher than 0° C. and [II] a propylene-&agr;-olefin copolymer containing 10-90% by weight of a constituent derived from propylene and 10-90% by weight of a constituent derived from &agr;-olefin other than propylene.
摘要翻译：公开了低温冲击强度，刚性，耐热性和透明性的平衡优异的聚丙烯组合物，其特征在于包含20-95重量％的以下[I]中定义的聚丙烯和5-80重量％的以下[II]中定义的丙烯-α-烯烃共聚物：[I]聚丙烯，其特征在于具有：（1）全同立构五单元组比（mmmm）为0.900-0.949，（2）2,1-和聚合物链中的1,3-丙烯单元的量为0-1摩尔％，（3）重均分子量（Mw）为40,000-1,000,000，（4）重均分子量（Mw）达到数均分子量（Mn），即（Mw）/（Mn）为1.5-3.8，和（5）在连续或逐步升高到给定温度的邻二氯苯温度下测量洗脱量聚丙烯在每个温度下，主洗脱峰的位置为95-110℃，组分的存在量在±10℃的范围内 n洗脱峰为在高于0℃的温度下洗脱的组分的总量的至少90％，[II]含有10-90重量％的衍生自丙烯的组分和10重量％的丙烯-α-烯烃共聚物 -90重量％的除丙烯以外的α-烯烃的成分。

4. 发明授权

US06441111B1 Polydisperse propylene polymer and process for producing the same 失效
标题翻译：多分散丙烯聚合物及其制备方法
公开(公告)号：US06441111B1
公开(公告)日：2002-08-27
申请号：US09485617
申请日：2000-02-14
申请人： Tsutomu Ushioda , Jun Saito , Mototake Tsutsui , Yoshitoyo Yasuda , Hiroyuki Fujita , Minoru Adachi
发明人： Tsutomu Ushioda , Jun Saito , Mototake Tsutsui , Yoshitoyo Yasuda , Hiroyuki Fujita , Minoru Adachi
IPC分类号： C08F1008
CPC分类号： C08F10/06 , C08F4/65912 , C08F4/65916 , C08F110/06 , Y10S526/943 , C08F2/001 , C08F4/65927 , C08F2500/05 , C08F2500/12
摘要： A polydisperse propylene polymer characterized by being produced by polymerizing a propylene monomer or a mixed monomer of propylene and other olefin(s) by a multistage polymerization wherein the polymerization conditions are stepwise changed in the presence of a supported metallocene catalyst having a transition metal compound and an aluminoxane or a reaction product thereof supported on a finely particulate support, and an organoaluminum compound as a scavenger, and by having a ratio of a weight-average molecular weight to a number-average molecular weight (Mw/Mn) of 4.0 or higher, a melting point (Tm) of 165° C. or lower and a difference between the melting point (Tm) and a heat distortion temperature (HDT) of 30° C. or less.
摘要翻译：一种多分散丙烯聚合物，其特征在于通过多级聚合使丙烯单体或丙烯与其它烯烃的混合单体聚合而制备，其中聚合条件在具有过渡金属化合物的负载金属茂催化剂存在下逐步改变，负载在细颗粒载体上的铝氧烷或其反应产物和作为清除剂的有机铝化合物，并且通过使重均分子量与数均分子量（Mw / Mn）之比为4.0以上，熔点（Tm）为165℃以下，熔点（Tm）与热变形温度（HDT）的差为30℃以下。

5. 发明授权

US07001560B2 Molding resin composition and method of molding 失效
公开(公告)号：US07001560B2
公开(公告)日：2006-02-21
申请号：US10332027
申请日：2001-07-02
申请人： Minoru Adachi , Shoji Uesugi
发明人： Minoru Adachi , Shoji Uesugi
IPC分类号： B28B5/00 , C08L61/26 , C08L63/04
CPC分类号： B41J2/1637 , B29C45/0013 , B29C45/2628 , B41J2/16 , B41J2/1634 , B41J2002/14387 , C08L63/00 , C08L101/00 , C08L61/20 , C08L2666/14
摘要： The present invention provides a resin composition suitable for molding a microscopic structure that has small cure shrinkage, good mold transfer properties and excellent properties for post-processing such as polishing processing and laser processing. Such a resin is a thermosetting resin composition comprising 95 to 35 wt % of a thermosetting resin and 5 to 65 wt % of organic filler having a particle size of 10 μm or less. From such a resin, an ink ejecting apparatus having a microscopic structure, for example, a nozzle of a diameter of 30 μm, is integrally molded.

6. 发明授权

US4886377A Rotary body of hard material with plastic supporter 失效
标题翻译：旋转体硬质材料与塑料支架
公开(公告)号：US4886377A
公开(公告)日：1989-12-12
申请号：US134129
申请日：1987-12-17
申请人： Minoru Adachi , Takashi Kizawa
发明人： Minoru Adachi , Takashi Kizawa
IPC分类号： F16C33/44 , B29C45/36 , B29D33/00 , B29L31/04 , B32B1/00 , B60B33/08 , B65G39/00 , B65G39/02 , F16C11/06 , F16C17/10 , F16C19/00 , F16C29/00 , F16C29/04 , F16C33/32 , F16C33/34 , F16C33/38 , F16C43/06 , F16G13/00 , F16G13/10 , F16H55/17 , F16H55/36
CPC分类号： F16C29/046 , B60B33/08 , B65G39/02 , F16C11/0619 , F16C17/10 , F16C19/00 , F16C29/04 , F16C33/32 , F16C33/34 , F16C33/3812 , F16C43/06 , F16G13/00 , F16G13/10 , Y10T29/49686 , Y10T29/49694
摘要： A rotary body of hard material with a plastic supporter and a method of manufacturing therefor, which essentially comprises a coating film coated with the rotary body and removed after molding so as to make a clearance between the rotary body and the supporter, so that rotation of the rotary body may be allowed smoothly. The method of this invention defines steps of molding, coating of film and removing of the film so as to obtain rotation of rotary body relative to the plastic supporter.
摘要翻译：具有塑料支撑体的硬质材料的旋转体及其制造方法，其基本上包括涂覆有旋转体的涂膜，并且在模制之后移除以在旋转体和支撑体之间形成间隙，使得旋转体可以顺利地允许旋转体。本发明的方法确定了成型，涂膜和除去膜以便获得旋转体相对于塑料支撑件的旋转的步骤。

7. 发明授权

US4698774A Method of and apparatus for controlling automatic soldering system 失效
标题翻译：控制自动焊接系统的方法和设备
公开(公告)号：US4698774A
公开(公告)日：1987-10-06
申请号：US781351
申请日：1985-09-27
申请人： Nobuhide Abe , Minoru Adachi , Makoto Ito , Toshiya Uchida
发明人： Nobuhide Abe , Minoru Adachi , Makoto Ito , Toshiya Uchida
IPC分类号： H05K3/34 , B23K1/08 , B23K3/00 , G05D23/22 , G06F15/46 , B23K31/02
CPC分类号： B23K3/00 , B23K1/085 , G05D23/1917 , G05D23/22
摘要： A method of and apparatus for controlling automatic soldering system in which respective units of the automatic soldering system are controlled preparatorily to reduce the waiting time until main driving to zero. In the soldering driving time, the temperature of the work itself is precisely controlled to the predetermined value by means of directly measuring the temperature of the work and controlling the preheater to bring the soldering characteristic in the next soldering step into the most optimal value in compliance with the size and the like of the work to be soldered.
摘要翻译：一种用于控制自动焊接系统的方法和装置，其中自动焊接系统的各个单元被预先控制，以减少直到主驱动到零的等待时间。在焊接驱动时间中，通过直接测量工件的温度并控制预热器将工件本身的温度精确地控制在预定值，使焊接步骤中的焊接特性达到最合适的最佳值与要焊接的工作的大小等。

8. 发明授权

US06441075B2 Polyolefin-based resin composition and automotive molded plastic made from same 失效
标题翻译：聚烯烃基树脂组合物和由其制成的汽车模制塑料
公开(公告)号：US06441075B2
公开(公告)日：2002-08-27
申请号：US08837874
申请日：1997-04-25
申请人： Tomio Hirata , Kazuo Matsuyama , Kazuyuki Yamamoto , Kazushige Ohnishi , Minoru Adachi , Tamihiro Ohashi , Motoru Komatsu , Satoru Ichikawa , Masahiro Terada , Hirosuke Kamae , Akira Kawai
发明人： Tomio Hirata , Kazuo Matsuyama , Kazuyuki Yamamoto , Kazushige Ohnishi , Minoru Adachi , Tamihiro Ohashi , Motoru Komatsu , Satoru Ichikawa , Masahiro Terada , Hirosuke Kamae , Akira Kawai
IPC分类号： C08K300
CPC分类号： C08L53/00 , C08L2666/04
摘要： The invention relates to a polyolefin-based resin composition that is in an amount of 100 wt % in total. This composition includes (a) 60-66 wt % of a crystalline propylene-ethylene block copolymer, (b) 12-20 wt % of an ethylene-propylene copolymer rubber, and (c) 18-25 wt % of an inorganic filler. The block copolymer contains a first segment of a homopolymer of propylene and a second segment of a copolymer of propylene and ethylene, and has an isotactic pentad tacticity of at least 0.96. The ratio of the weight average molecular weight of the block copolymer to the number average molecular weight thereof is not greater than 6. The copolymer rubber contains therein 50-60 wt % of ethylene, and has a Mooney viscosity of from 45 to 55 at 125° C. The inorganic filler is one selected from the group consisting of a talc, a first combination of the talc and a glass fiber, and a second combination of the talc and a whisker. The talc has an average particle diameter of not greater than 2 &mgr;m. The glass fiber has an average fiber length of from 5 to 10 mm and an average diameter of from 15 to 20 &mgr;m. The whisker has an average fiber length of from 15 to 25 &mgr;m and an average diameter of from 0.5 to 1 &mgr;m. A molded plastic article made from the resin composition is substantially improved in scratch resistance.
摘要翻译：本发明涉及总量为100重量％的聚烯烃基树脂组合物。该组合物包括（a）60-66重量％的结晶丙烯 - 乙烯嵌段共聚物，（b）12-20重量％的乙烯 - 丙烯共聚物橡胶，和（c）18-25重量％的无机填料。嵌段共聚物含有丙烯均聚物的第一段和丙烯与乙烯的共聚物的第二段，并且具有至少0.96的全同立构五单元组立构规整度。嵌段共聚物的重均分子量与其数均分子量的比例不大于6.共聚物橡胶中含有50-60重量％的乙烯，并且在125℃时门尼粘度为45至55 无机填料是选自滑石，滑石和玻璃纤维的第一组合以及滑石和晶须的第二组合的组。滑石的平均粒径不大于2μm。玻璃纤维的平均纤维长度为5〜10mm，平均直径为15〜20μm。晶须的平均纤维长度为15至25μm，平均直径为0.5至1μm。由树脂组合物制成的模制塑料制品的耐刮擦性大大提高。

9. 发明授权

US4753969A Diaphragm for electroacoustic transducer 失效
标题翻译：电声换能器隔膜
公开(公告)号：US4753969A
公开(公告)日：1988-06-28
申请号：US756290
申请日：1985-07-18
申请人： Shinya Mizone , Tamotsu Abe , Minoru Adachi , Takashi Kizawa
发明人： Shinya Mizone , Tamotsu Abe , Minoru Adachi , Takashi Kizawa
IPC分类号： C08K3/34 , C08K7/06 , H04R7/02 , H04R7/12 , C08K9/10
CPC分类号： H04R7/12 , C08K3/346 , C08K7/06 , H04R7/02 , H04R2307/029 , Y10T428/2978
摘要： A diaphragm for an electroacoustic transducer comprising stratiform mineral of layers into which a hardener or an agent for facilitating hardening is adsorbed between the layers, thermosetting resin monomer, and carbonfibers which constitute a composite material which is formed under heat and pressure. The diaphragm is increased in rigidity which is required as physical properties therefor and is easy in forming.
摘要翻译：一种用于电声转换器的隔膜，包括层之间的层状矿物，其中硬化剂或用于促进硬化的试剂被吸附在层之间，热固性树脂单体和碳纤维构成在热和压力下形成的复合材料。隔膜的刚度增加，作为其物理性能所需要的并且易于成型。

10. 发明申请

US20090326136A1 PROPYLENE-BASED BLOCK COPOLYMER COMPOSITION AND EXTERIOR MEMBER FOR AUTOMOBILE 审中-公开
标题翻译：丙烯基嵌段共聚物组合物和汽车外部成员
公开(公告)号：US20090326136A1
公开(公告)日：2009-12-31
申请号：US12304584
申请日：2007-06-15
申请人： Kenji Masuda , Ken Shimizu , Minoru Adachi , Hiroshi Inanami , Kaoru Inoue
发明人： Kenji Masuda , Ken Shimizu , Minoru Adachi , Hiroshi Inanami , Kaoru Inoue
IPC分类号： C08K3/34
CPC分类号： C08L53/00 , C08K3/34 , C08K9/04 , C08L23/0815 , C08L2666/06 , C08L2666/08 , C08L2666/04
摘要： A polypropylene resin composition for molding material, which is excellent in an appearance of weld line and an appearance of tiger stripe and is used for automobile exterior parts and an automobile exterior part comprising the same, are provided. A propylene-based block copolymer composition, comprising 100 parts by weight of a propylene-based block copolymer having an MFR of 50 to 100 g/10 minutes and an Mw/Mn of 7 or less, wherein the propylene-based block copolymer comprises 75 to 95% by weight of a crystalline polypropylene portion and 5 to 25% by weight of an ethylene-propylene copolymer portion, where the ethylene content of the ethylene-propylene copolymer portion is 35 to 45% by weight and the ratio of the weight-average molecular weight of the ethylene-propylene copolymer portion to the weight-average molecular weight of the crystalline polypropylene portion is 3 to 5; 25 to 45 parts by weight of an ethylene-α-olefin copolymer elastomer having an MFR of 1 to 9 g/10 minutes; and 30 to 45 parts by weight of talc having an average particle diameter of 1.5 to 15 μm.
摘要翻译：提供了一种用于成型材料的聚丙烯树脂组合物，其外观为焊接线的外观和虎纹的外观，并且用于汽车外部部件和包括该材料的汽车外部部件。一种基于丙烯的嵌段共聚物组合物，其包含100重量份MFR为50至100g / 10分钟和Mw / Mn为7或更小的丙烯基嵌段共聚物，其中所述丙烯类嵌段共聚物包含75 至95重量％的结晶聚丙烯部分和5至25重量％的乙烯 - 丙烯共聚物部分，其中乙烯 - 丙烯共聚物部分的乙烯含量为35-45重量％，并且重量 - 乙烯 - 丙烯共聚物部分的平均分子量与结晶聚丙烯部分的重均分子量为3〜5; 25〜45重量份MFR为1〜9g / 10分钟的乙烯-α-烯烃共聚物弹性体; 和30〜45重量份的平均粒径为1.5〜15μm的滑石。

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