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    • 1. 发明授权
    • Method of producing thick-film gas sensor element having improved
stability
    • 具有提高稳定性的厚膜气体传感器元件的制造方法
    • US5202154A
    • 1993-04-13
    • US565994
    • 1990-08-13
    • Toshitaka MatsuuraKeizo FurusakiMineji NasuAkio Takami
    • Toshitaka MatsuuraKeizo FurusakiMineji NasuAkio Takami
    • G01N27/12
    • G01N27/12
    • The invention relates to a method of producing a gas sensor element having a porous film formed by a thick-film technique on a ceramic substrate surface so as to cover selected portions of electrode films precedingly formed on the substrate surface. The electrode material is a noble metal such as platinum. Both the electrode films and the gas sensitive porous thick-film are formed by known methods. To improve the contact between the gas sensitive porous thick-film and the electrode films both mechanically and electrically and stabilize the internal resistance of the sensor element by depositing a noble metal such as platinum at the interface between the porous thick-film and each electrode film, the porous thick-film is impregnated with a solution of a noble metal compound such as chloroplatinic acid and thereafter maintained in a reducing gas atmosphere having a controlled humidity in the range from 5 to 90% (relative humidity) at a temperature in the range from 10.degree. C. to 135.degree. C.
    • 本发明涉及一种制造气体传感器元件的方法,该气体传感器元件具有通过厚膜技术在陶瓷基板表面上形成的多孔膜,以覆盖在基板表面上形成的电极膜的选定部分。 电极材料是贵金属如铂。 通过已知的方法形成电极膜和气敏多孔厚膜。 为了通过机械和电气来改善气体敏感性多孔厚膜和电极膜之间的接触,并且通过在多孔厚膜和每个电极膜之间的界面上沉积贵金属如铂来稳定传感器元件的内阻 多孔厚膜用氯铂酸等贵金属化合物的溶液浸渍,然后保持在5〜90%(相对湿度)范围内的受控湿度的还原气体气氛中,温度范围 从10℃到135℃
    • 6. 发明授权
    • Gas sensing element
    • 气体传感元件
    • US4958514A
    • 1990-09-25
    • US273621
    • 1988-11-17
    • Akio TakamiToshitaka MatsuuraKeizo Furusaki
    • Akio TakamiToshitaka MatsuuraKeizo Furusaki
    • G01N27/12
    • G01N27/12
    • A gas sensing element, such as may be used to sense the presence of oxygen contained in the exhaust from a burner or internal combustion engine, whereby, by preventing the re-sintering of functional layers of the sensing element, a deterioration of the performance of the element under high-temperature operating conditions is prevented. The inventive sensing element includes a ceramic susbtrate, an electrode layer formed on the ceramic substrate, a first functional layer overlying the ceramic susbtrate and the electrode layer and which contains a transition metal oxide as a main component, and a second functional layer that cover the first functional layer and which contains 1 to 30 wt % of an anti-sintering agent and has a transition metal oxide as a main component.
    • 诸如可以用于感测来自燃烧器或内燃机的废气中所含的氧的存在的气体感测元件,由此通过防止感测元件的功能层的再烧结,性能的恶化 在高温运行条件下防止了元件。 本发明的传感元件包括陶瓷芯片,形成在陶瓷基片上的电极层,覆盖陶瓷电极和电极层的第一功能层,其中含有过渡金属氧化物作为主要成分,第二功能层覆盖 第一功能层,含有1〜30重量%的耐烧结剂,并具有过渡金属氧化物作为主要成分。