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1. 发明授权

US5610254A Ethylene-.alpha.-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer 失效
标题翻译：乙烯-α-烯烃 - 非共轭多烯无规共聚物，橡胶组合物和制备无规共聚物的方法
公开(公告)号：US5610254A
公开(公告)日：1997-03-11
申请号：US574684
申请日：1995-12-19
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Tatsuya Tanizaki
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Tatsuya Tanizaki
IPC分类号： C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20 , C08F232/06
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer which is a random copolymer of (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene, and has such properties that (i) the copolymer contains (a) units derived from ethylene and (b) units derived from the .alpha.-olefin of 3 or more carbon atoms in a molar ratio of 40/60 to 95/5 ((a)/(b)), (ii) the iodine value is in the range of 1 to 50, (iii) the intrinsic viscosity (.eta.), as measured in decahydronaphthalene at 135.degree. C., is in the range of 0.1 to 8.0 dl/g, and (iv) the ratio g.eta.* of the intrinsic viscosity (.eta.) of the copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a linear ethylene-propylene copolymer having the same weight-average molecular weight as the ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is in the range of 0.2 to 0.9 or the ratio g' of the intrinsic viscosity (.eta.) of said random copolymer defined above to the intrinsic viscosity (.eta.).sub.blank' of a linear ethylene-propylene copolymer having an ethylene content of 70% by mol which is determined by measurement of gel permeation chromatography (GPC) of ethylene-.alpha.-olefin-nonconjugated polyene random copolymer in orthodichlorobenzene at 140.degree. C., (.eta.)/(.eta.).sub.blank', is in the reange of 0.2 to 0.9.
摘要翻译：公开了一种乙烯-α-烯烃 - 非共轭多烯无规共聚物，它是（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯的无规共聚物，（i）共聚物包含（a）衍生自乙烯的单元和（b）衍生自摩尔比为40/60至95/5（（a）/（b）的3个或更多个碳原子的α-烯烃的单元）），（ii）碘值在1〜50的范围内，（iii）在135℃下在十氢化萘中测定的特性粘度（η）为0.1〜8.0dl / g，（iv）上述共聚物的特性粘度（eta）与具有与乙烯-α-烯烃相同的重均分子量的直链乙烯 - 丙烯共聚物的特性粘度（η）空白的比率g eta * 非共轭多烯无规共聚物的乙烯含量为70摩尔％（eta）/（η）空白，在0.2〜0.9的范围内或者int的比例g' 所述上述无规共聚物的特性粘度（η）为乙烯含量为70摩尔％的线性乙烯 - 丙烯共聚物的特性粘度（η）空白'，其通过乙烯的凝胶渗透色谱（GPC） α-烯烃 - 非共轭多烯无规共聚物在140℃，（η）/（η）空白'的邻二氯苯中的摩尔比为0.2-0.9。

2. 发明授权

US5807948A Vulcanizable rubber composition containing ehtylene-.alpha.-olefin-nonconjugated polyene random copolymer 失效
标题翻译：含有乙烯-α-烯烃 - 非共轭多烯无规共聚物的可硫化橡胶组合物
公开(公告)号：US5807948A
公开(公告)日：1998-09-15
申请号：US783238
申请日：1997-01-14
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
摘要翻译：公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法，包括（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯在含有特定茂金属化合物的茂金属催化剂。通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性：（i）共聚物含有衍生自乙烯（a）的单元和衍生自3个或更多个碳原子的（b）的α-烯烃的单元摩尔比为40/60〜95/5 [（a）/（b）]，（ii）碘值为1〜50，（iii）特性粘度（η）大于0.1dl / g以下（iv）13 C-NMR光谱中的Tαβ与Tαα的强度比D（Tαβ/Tαα）不大于0.5，（v）B值为 1.00至1.50，（vi）玻璃化转变温度Tg不高于-50℃，（vii）上述定义的共聚物的特性粘度（η）与特性粘度（η）的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔％（eta）/（η）空白的直链乙烯 - 丙烯共聚物大于0.9。还公开了含有无规共聚物的可硫化橡胶组合物。乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度，耐候性，耐臭氧性，加工性，低温柔韧性和耐热性都优异。

3. 发明授权

US06723794B2 Olefin thermoplastic elastomer composition comprising crystalline polyolefin resin and ethylene/&agr;-olefin/nonconjugated polyene copolymer rubber 有权
标题翻译：包含结晶聚烯烃树脂和乙烯/α-烯烃/非共轭多烯共聚物橡胶的烯烃热塑性弹性体组合物
公开(公告)号：US06723794B2
公开(公告)日：2004-04-20
申请号：US10066575
申请日：2002-02-06
申请人： Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Kyoko Kobayashi , Yuichi Itoh , Akira Uchiyama , Toshiyuki Tsutsui , Toshihiro Sagane
发明人： Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Kyoko Kobayashi , Yuichi Itoh , Akira Uchiyama , Toshiyuki Tsutsui , Toshihiro Sagane
IPC分类号： C08L2302
CPC分类号： C08L23/02 , A61J1/03 , B65D23/003 , B65D51/28 , C08K5/14 , C08L23/0815 , C08L23/10 , C08L23/142 , C08L23/16 , C08L23/22 , C08L91/00 , C08L2205/03 , C08L2207/04 , C08L2312/00 , C08L2666/04
摘要： An olefin thermoplastic elastomer composition comprises a crystalline polyolefin resin (A) and an ethylene/&agr;-olefin/nonconjugated polyene copolymer rubber (B), and optionally a softener (C) and/or an inorganic filler (D), in a specific ratio. The copolymer rubber (B) is prepared by the use of a metallocene catalyst and comprises ethylene, an &agr;-olefin of 3 to 20 carbon atoms and a nonconjugated polyene. This composition ca provide molded products of more excellent tensile strength, elongation at break, elastomeric properties (elongation set, permanent compression set, etc.), heat resistance and low-temperature properties than the conventional non-crosslinked olefin thermoplastic elastomers, even if the composition is in the non-crosslinked form. The composition in the partially or completely crosslinked form can provided molded products of more excellent low-temperature properties, tensile strength, elongation at break and elastomeric properties than the conventional vulcanized rubbers.
摘要翻译：烯烃热塑性弹性体组合物包含结晶聚烯烃树脂（A）和乙烯/α-烯烃/非共轭多烯共聚物橡胶（B）和任选的软化剂（C）和/或无机填料（D）。共聚物橡胶（B）通过使用茂金属催化剂制备，包括乙烯，3-20个碳原子的α-烯烃和非共轭多烯。该组合物提供比常规非交联烯烃热塑性弹性体更优异的拉伸强度，断裂伸长率，弹性体性能（伸长率设定，永久压缩变形等），耐热性和低温性能的成型产品，即使组合物为非交联形式。部分或完全交联形式的组合物可以提供比常规硫化橡胶更优异的低温性能，拉伸强度，断裂伸长率和弹性体性能的成型产品。

4. 发明授权

US5696214A Process for preparing ethylene-.alpha.-olefin-nonconjugated polyene random copolymer 失效
标题翻译：制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法
公开(公告)号：US5696214A
公开(公告)日：1997-12-09
申请号：US575678
申请日：1995-12-19
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
摘要翻译：公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法，包括（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯在含有特定茂金属化合物的茂金属催化剂。通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性：（i）共聚物含有衍生自乙烯（a）的单元和衍生自3个或更多个碳原子的（b）的α-烯烃的单元摩尔比为40/60〜95/5 [（a）/（b）]，（ii）碘值为1〜50，（iii）特性粘度（η）大于0.1dl / g以下（iv）13 C-NMR光谱中的Tαβ与Tαα的强度比D（Tαβ/Tαα）不大于0.5，（v）B值为 1.00至1.50，（vi）玻璃化转变温度Tg不高于-50℃，（vii）上述定义的共聚物的特性粘度（η）与特性粘度（η）的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔％（eta）/（η）空白的直链乙烯 - 丙烯共聚物大于0.9。还公开了含有无规共聚物的可硫化橡胶组合物。乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度，耐候性，耐臭氧性，加工性，低温柔韧性和耐热性都优异。

5. 发明授权

US5869563A Ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition 失效
标题翻译：乙烯/α-烯烃/非共轭多烯共聚物橡胶组合物
公开(公告)号：US5869563A
公开(公告)日：1999-02-09
申请号：US661989
申请日：1996-06-12
申请人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
发明人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
IPC分类号： C08L23/02 , C08L23/16 , C08L23/26
CPC分类号： C08L23/02 , C08L23/16 , C08L2207/04
摘要： The ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition of the present invention comprises in specified proportions a crystalline polyolefin resin (A) and an ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) composed of ethylene, an .alpha.-olefin having 3 to 20 carbon atoms and a specific branched chain polyene compound. The molar ratio of ethylene units to .alpha.-olefin units, iodine value and intrinsic viscosity �.eta.! of the ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) are within respective specified ranges. This rubber composition is excellent in low temperature properties. When the above olefinic thermoplastic elastomer composition is partially or entirely crosslinked, a molding can be provided which is superior to the conventional vulcanized rubbers in low temperature properties, tensile strength, elongation at break and rubber properties.
摘要翻译：本发明的乙烯/α-烯烃/非共轭多烯共聚物橡胶组合物以特定比例包含结晶聚烯烃树脂（A）和乙烯/α-烯烃/非共轭多烯共聚物橡胶（B），乙烯，α-烯烃具有3至20个碳原子和特定的支链多烯化合物。乙烯单元与α-烯烃单元的摩尔比，乙烯/α-烯烃/非共轭多烯共聚物橡胶（B）的碘值和特性粘度η在各自的特定范围内。该橡胶组合物的低温性能优异。当上述烯烃类热塑性弹性体组合物部分或全部交联时，可以提供在低温性能，拉伸强度，断裂伸长率和橡胶性能方面优于常规硫化橡胶的成型。

6. 发明授权

US5756575A Ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition 失效
公开(公告)号：US5756575A
公开(公告)日：1998-05-26
申请号：US661989
申请日：1996-06-12
申请人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
发明人： Masaaki Kawasaki , Hidenari Nakahama , Tetsuo Tojo , Toshiyuki Tsutsui , Kyoko Kobayashi , Toshihiro Sagane
IPC分类号： C08L23/02 , C08L23/16 , C08L23/26
CPC分类号： C08L23/02 , C08L23/16 , C08L2207/04
摘要： The ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber composition of the present invention comprises in specified proportions a crystalline polyolefin resin (A) and an ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) composed of ethylene, an .alpha.-olefin having 3 to 20 carbon atoms and a specific branched chain polyene compound. The molar ratio of ethylene units to .alpha.-olefin units, iodine value and intrinsic viscosity �.eta.! of the ethylene/.alpha.-olefin/nonconjugated polyene copolymer rubber (B) are within respective specified ranges. This rubber composition is excellent in low temperature properties. When the above olefinic thermoplastic elastomer composition is partially or entirely crosslinked, a molding can be provided which is superior to the conventional vulcanized rubbers in low temperature properties, tensile strength, elongation at break and rubber properties.

7. 发明授权

US5912303A Ethylene/.alpha.-olefin/nonconjugated polyene terpolymer rubber composition and vulcanized rubber obtained therefrom 失效
标题翻译：乙烯/α-烯烃/非共轭多烯三元共聚物橡胶组合物和由其获得的硫化橡胶
公开(公告)号：US5912303A
公开(公告)日：1999-06-15
申请号：US652901
申请日：1996-05-23
申请人： Hidenari Nakahama , Masaaki Kawasaki , Tetsuo Tojo , Totshiyuki Tsutsui , Toshihiro Sagane
发明人： Hidenari Nakahama , Masaaki Kawasaki , Tetsuo Tojo , Totshiyuki Tsutsui , Toshihiro Sagane
IPC分类号： C08L9/02 , C08L23/16 , C08L9/00 , C08L47/00
CPC分类号： C08L9/02 , C08L23/16 , C08L23/083 , C08L2312/00 , C08L7/00
摘要： A terpolymer rubber prepared from ethylene, .alpha.-olefin having 3 to 20 carbon atoms and branched chain polyene of the formula ##STR1## wherein R.sup.1 represents C.sub.1 -C.sub.5 alkyl, and R.sup.2 and R.sup.3 represent hydrogen atom or C.sub.1 -C.sub.5 alkyl, such as, for example, 6,7-dimethyl-4-ethylidene-1,6-octadiene, 6,7-dimethyl-4-ethylidene-1,6-nonadiene, and 9-methyl-4-ethylidene-1,8-decadiene; when added to a rubber (diene rubber, nitrile rubber or random copolymer rubber from ethylene, C.sub.3 -C.sub.20 .alpha.-olefin, and optionally a nonconjugated diene) provides curable rubber compositions having rapid vulcanization rates, for example, as lows as about 7 to 10 seconds. The diene rubber compositions also have excellent resistances to weather,ozone and heat aging while maintaining excellent mechanical strength characteristics. The nitrile rubber compositions also have excellent oil resistance.
摘要翻译：由乙烯，具有3-20个碳原子的α-烯烃和下式的支链多烯制备的三元共聚物橡胶，其中R1代表C1-C5烷基，R2和R3代表氢原子或C1-C5烷基，例如， 6,7-二甲基-4-亚乙基-1,6-辛二烯，6,7-二甲基-4-亚乙基-1,6-辛二烯和9-甲基-4-亚乙基-1,8-癸二烯; 当加入到橡胶（二烯橡胶，丁腈橡胶或乙烯的无规共聚物橡胶，C 3 -C 20α-烯烃和任选的非共轭二烯）时，提供具有快速硫化速率的可固化橡胶组合物，例如低至约7至10 秒。二烯橡胶组合物还具有优异的耐候性，耐臭氧和热老化，同时保持优异的机械强度特性。丁腈橡胶组合物也具有优异的耐油性。

8. 发明授权

US5698651A Ethylene copolymer rubber, vulcanizable rubber composition containing the copolymer rubber, and process for preparing the copolymer rubber 失效
标题翻译：含有共聚物橡胶的乙烯共聚物橡胶，可硫化橡胶组合物，以及共聚物橡胶的制备方法
公开(公告)号：US5698651A
公开(公告)日：1997-12-16
申请号：US665342
申请日：1996-06-17
申请人： Masaaki Kawasaki , Toshiyuki Tsutsui , Tetsuo Tojo , Takashi Hakuta
发明人： Masaaki Kawasaki , Toshiyuki Tsutsui , Tetsuo Tojo , Takashi Hakuta
IPC分类号： C08F4/64 , C08F4/6592 , C08F210/18 , C08F236/20
CPC分类号： C08F210/18 , C08F4/65927 , Y10S526/943
摘要： Disclosed is an ethylene copolymer rubber which is a random copolymer rubber of (a) ethylene, (b) an .alpha.-olefin of 3 to 20 carbon atoms, (c) a nonconjugated polyene containing, in one molecule, one carbon-to-carbon double bond polymerizable by a metallocene catalyst among carbon-to-carbon double bonds, and (d) a nonconjugated polyene containing, in one molecule, two carbon-to-carbon double bonds polymerizable by the metallocene catalyst among carbon-to-carbon double bonds. The ethylene copolymer rubber has excellent moldability, high vulcanization rate, good mechanical properties such as high vulcanization strength, excellent low-temperature flexibility and thermal aging resistance. Also disclosed is a process for preparing the ethylene copolymer rubber with high activity, high conversion ratio of .alpha.-olefin and high random copolymerizability.
摘要翻译：公开了一种乙烯共聚物橡胶，它是（a）乙烯，（b）3-20个碳原子的α-烯烃的无规共聚物橡胶，（c）一个分子中含有一个碳 - 碳的非共轭多烯通过茂金属催化剂在碳 - 碳双键中可聚合的双键，和（d）在一个分子中含有由碳 - 碳双键中的茂金属催化剂可聚合的两个碳 - 碳双键的非共轭多烯。乙烯共聚物橡胶具有优异的成型性，高硫化速度，良好的机械性能，如高硫化强度，优异的低温柔韧性和耐热老化性。还公开了一种制备具有高活性，高转化率的α-烯烃和高无规共聚性的乙烯共聚物橡胶的方法。

9. 发明授权

US5354828A Higher .alpha.-olefin copolymer, process for preparing same, and vulcanizable rubber composition 失效
标题翻译：高级α-烯烃共聚物，其制备方法和可硫化橡胶组合物
公开(公告)号：US5354828A
公开(公告)日：1994-10-11
申请号：US79845
申请日：1993-06-22
申请人： Masaaki Kawasaki , Syuji Minami , Tetsuo Tojo , Keiji Okada
发明人： Masaaki Kawasaki , Syuji Minami , Tetsuo Tojo , Keiji Okada
IPC分类号： C08F4/658 , C08F210/14 , C08L23/16 , C08F236/20 , C08L19/00
CPC分类号： C08L23/16 , C08F210/14 , C08L23/10 , C08L23/20 , C08L2312/00
摘要： The higher .alpha.-olefin copolymers obtained in accordance with the present invention are copolymers derived from higher .alpha.-olefin and non-conjugated diene represented by the following general formula [I], and (a) the non-conjugated diene content thereof is from 0.01 to 30 mol %, and (b) the intrinsic viscosity [.eta.], as measured in decahydronaphthalene at 135.degree. C., of said copolymer is from 1.0 to 10.0 dl/g. ##STR1## The invention also provides a process for preparing such higher .alpha.-olefin copolymers as illustrated above, and vulcanization products obtained from said copolymers.Furthermore, the invention provides vulcanizable compositions containing rubber comprising of the above-mentioned higher .alpha.-olefin copolymers and a specific diene rubber or a specific ethylene/.alpha.-olefin copolymer rubber.
摘要翻译： PCT No.PCT / JP90 / 00527 Sec。 371 1990年12月13日第 102（e）1990年12月13日的PCT PCT 1990年4月24日提交PCT公布。 WO90 / 12818 PCT公开号 1990年1月11日。根据本发明获得的高级α-烯烃共聚物是由以下通式[I]表示的高级α-烯烃和非共轭二烯衍生的共聚物，（a）共轭二烯含量为0.01〜30摩尔％，（b）在135℃的十氢化萘中测定的特性粘度η为1.0〜10.0dl / g。本发明还提供了制备如上所述的这种高级α-烯烃共聚物的方法和由所述共聚物获得的硫化产物。此外，本发明提供含有上述高级α-烯烃共聚物和特定二烯橡胶或特定乙烯/α-烯烃共聚物橡胶的橡胶的可硫化组合物。

10. 发明授权

US5349020A Vulcanizable rubber composition 失效
标题翻译：可硫化橡胶组合物
公开(公告)号：US5349020A
公开(公告)日：1994-09-20
申请号：US026783
申请日：1993-03-05
申请人： Keiji Okada , Kazuhiko Murata , Tetsuo Tojo , Masaaki Kawasaki , Toshimasa Takata
发明人： Keiji Okada , Kazuhiko Murata , Tetsuo Tojo , Masaaki Kawasaki , Toshimasa Takata
IPC分类号： C08L21/00 , C08L23/18 , C08L7/00 , C08L9/00 , C08L23/16
CPC分类号： C08L21/00 , C08L23/18
摘要： There is provided a composition comprising a higher a-olefin copolymer (1) obtained by copolymerization in the presence of a specific olefin polymerization catalyst of a specific higher .alpha.-olefin, a specific .alpha., .omega.-diene of the formula (I) and a specific non-conjugated diene of the formula (II), and a rubber (2) selected from the group consisting of a diene rubber, an ethylene/a-olefin copolymer, a nitrile rubber and a hydrogenated nitrile rubber. The composition is excellent in workability strength characteristics, weatherability, ozone resistance and dynamic fatigue resistance, as well as excellent in adhesive properties to fiber and in vibration-insulating properties and damping properties.
摘要翻译：提供一种组合物，其包含在特定的较高级α-烯烃的特定烯烃聚合催化剂，式（I）的特定α，ω-二烯和式（I）的特定烯烃聚合催化剂的存在下共聚获得的较高级α-烯烃共聚物（1）式（II）的非特异性非共轭二烯和选自二烯橡胶，乙烯/α-烯烃共聚物，丁腈橡胶和氢化丁腈橡胶的橡胶（2）。该组合物的加工性强度特性，耐候性，耐臭氧性和动态抗疲劳性优异，并且对纤维的粘合性能以及隔振性能和阻尼性能优异。

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