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1. 发明授权

US5354828A Higher .alpha.-olefin copolymer, process for preparing same, and vulcanizable rubber composition 失效
标题翻译：高级α-烯烃共聚物，其制备方法和可硫化橡胶组合物
公开(公告)号：US5354828A
公开(公告)日：1994-10-11
申请号：US79845
申请日：1993-06-22
申请人： Masaaki Kawasaki , Syuji Minami , Tetsuo Tojo , Keiji Okada
发明人： Masaaki Kawasaki , Syuji Minami , Tetsuo Tojo , Keiji Okada
IPC分类号： C08F4/658 , C08F210/14 , C08L23/16 , C08F236/20 , C08L19/00
CPC分类号： C08L23/16 , C08F210/14 , C08L23/10 , C08L23/20 , C08L2312/00
摘要： The higher .alpha.-olefin copolymers obtained in accordance with the present invention are copolymers derived from higher .alpha.-olefin and non-conjugated diene represented by the following general formula [I], and (a) the non-conjugated diene content thereof is from 0.01 to 30 mol %, and (b) the intrinsic viscosity [.eta.], as measured in decahydronaphthalene at 135.degree. C., of said copolymer is from 1.0 to 10.0 dl/g. ##STR1## The invention also provides a process for preparing such higher .alpha.-olefin copolymers as illustrated above, and vulcanization products obtained from said copolymers.Furthermore, the invention provides vulcanizable compositions containing rubber comprising of the above-mentioned higher .alpha.-olefin copolymers and a specific diene rubber or a specific ethylene/.alpha.-olefin copolymer rubber.
摘要翻译： PCT No.PCT / JP90 / 00527 Sec。 371 1990年12月13日第 102（e）1990年12月13日的PCT PCT 1990年4月24日提交PCT公布。 WO90 / 12818 PCT公开号 1990年1月11日。根据本发明获得的高级α-烯烃共聚物是由以下通式[I]表示的高级α-烯烃和非共轭二烯衍生的共聚物，（a）共轭二烯含量为0.01〜30摩尔％，（b）在135℃的十氢化萘中测定的特性粘度η为1.0〜10.0dl / g。本发明还提供了制备如上所述的这种高级α-烯烃共聚物的方法和由所述共聚物获得的硫化产物。此外，本发明提供含有上述高级α-烯烃共聚物和特定二烯橡胶或特定乙烯/α-烯烃共聚物橡胶的橡胶的可硫化组合物。

2. 发明授权

US06723794B2 Olefin thermoplastic elastomer composition comprising crystalline polyolefin resin and ethylene/&agr;-olefin/nonconjugated polyene copolymer rubber 有权
标题翻译：包含结晶聚烯烃树脂和乙烯/α-烯烃/非共轭多烯共聚物橡胶的烯烃热塑性弹性体组合物
公开(公告)号：US06723794B2
公开(公告)日：2004-04-20
申请号：US10066575
申请日：2002-02-06
申请人： Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Kyoko Kobayashi , Yuichi Itoh , Akira Uchiyama , Toshiyuki Tsutsui , Toshihiro Sagane
发明人： Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Kyoko Kobayashi , Yuichi Itoh , Akira Uchiyama , Toshiyuki Tsutsui , Toshihiro Sagane
IPC分类号： C08L2302
CPC分类号： C08L23/02 , A61J1/03 , B65D23/003 , B65D51/28 , C08K5/14 , C08L23/0815 , C08L23/10 , C08L23/142 , C08L23/16 , C08L23/22 , C08L91/00 , C08L2205/03 , C08L2207/04 , C08L2312/00 , C08L2666/04
摘要： An olefin thermoplastic elastomer composition comprises a crystalline polyolefin resin (A) and an ethylene/&agr;-olefin/nonconjugated polyene copolymer rubber (B), and optionally a softener (C) and/or an inorganic filler (D), in a specific ratio. The copolymer rubber (B) is prepared by the use of a metallocene catalyst and comprises ethylene, an &agr;-olefin of 3 to 20 carbon atoms and a nonconjugated polyene. This composition ca provide molded products of more excellent tensile strength, elongation at break, elastomeric properties (elongation set, permanent compression set, etc.), heat resistance and low-temperature properties than the conventional non-crosslinked olefin thermoplastic elastomers, even if the composition is in the non-crosslinked form. The composition in the partially or completely crosslinked form can provided molded products of more excellent low-temperature properties, tensile strength, elongation at break and elastomeric properties than the conventional vulcanized rubbers.
摘要翻译：烯烃热塑性弹性体组合物包含结晶聚烯烃树脂（A）和乙烯/α-烯烃/非共轭多烯共聚物橡胶（B）和任选的软化剂（C）和/或无机填料（D）。共聚物橡胶（B）通过使用茂金属催化剂制备，包括乙烯，3-20个碳原子的α-烯烃和非共轭多烯。该组合物提供比常规非交联烯烃热塑性弹性体更优异的拉伸强度，断裂伸长率，弹性体性能（伸长率设定，永久压缩变形等），耐热性和低温性能的成型产品，即使组合物为非交联形式。部分或完全交联形式的组合物可以提供比常规硫化橡胶更优异的低温性能，拉伸强度，断裂伸长率和弹性体性能的成型产品。

3. 发明授权

US5349020A Vulcanizable rubber composition 失效
标题翻译：可硫化橡胶组合物
公开(公告)号：US5349020A
公开(公告)日：1994-09-20
申请号：US026783
申请日：1993-03-05
申请人： Keiji Okada , Kazuhiko Murata , Tetsuo Tojo , Masaaki Kawasaki , Toshimasa Takata
发明人： Keiji Okada , Kazuhiko Murata , Tetsuo Tojo , Masaaki Kawasaki , Toshimasa Takata
IPC分类号： C08L21/00 , C08L23/18 , C08L7/00 , C08L9/00 , C08L23/16
CPC分类号： C08L21/00 , C08L23/18
摘要： There is provided a composition comprising a higher a-olefin copolymer (1) obtained by copolymerization in the presence of a specific olefin polymerization catalyst of a specific higher .alpha.-olefin, a specific .alpha., .omega.-diene of the formula (I) and a specific non-conjugated diene of the formula (II), and a rubber (2) selected from the group consisting of a diene rubber, an ethylene/a-olefin copolymer, a nitrile rubber and a hydrogenated nitrile rubber. The composition is excellent in workability strength characteristics, weatherability, ozone resistance and dynamic fatigue resistance, as well as excellent in adhesive properties to fiber and in vibration-insulating properties and damping properties.
摘要翻译：提供一种组合物，其包含在特定的较高级α-烯烃的特定烯烃聚合催化剂，式（I）的特定α，ω-二烯和式（I）的特定烯烃聚合催化剂的存在下共聚获得的较高级α-烯烃共聚物（1）式（II）的非特异性非共轭二烯和选自二烯橡胶，乙烯/α-烯烃共聚物，丁腈橡胶和氢化丁腈橡胶的橡胶（2）。该组合物的加工性强度特性，耐候性，耐臭氧性和动态抗疲劳性优异，并且对纤维的粘合性能以及隔振性能和阻尼性能优异。

4. 发明授权

US5807948A Vulcanizable rubber composition containing ehtylene-.alpha.-olefin-nonconjugated polyene random copolymer 失效
标题翻译：含有乙烯-α-烯烃 - 非共轭多烯无规共聚物的可硫化橡胶组合物
公开(公告)号：US5807948A
公开(公告)日：1998-09-15
申请号：US783238
申请日：1997-01-14
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
摘要翻译：公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法，包括（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯在含有特定茂金属化合物的茂金属催化剂。通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性：（i）共聚物含有衍生自乙烯（a）的单元和衍生自3个或更多个碳原子的（b）的α-烯烃的单元摩尔比为40/60〜95/5 [（a）/（b）]，（ii）碘值为1〜50，（iii）特性粘度（η）大于0.1dl / g以下（iv）13 C-NMR光谱中的Tαβ与Tαα的强度比D（Tαβ/Tαα）不大于0.5，（v）B值为 1.00至1.50，（vi）玻璃化转变温度Tg不高于-50℃，（vii）上述定义的共聚物的特性粘度（η）与特性粘度（η）的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔％（eta）/（η）空白的直链乙烯 - 丙烯共聚物大于0.9。还公开了含有无规共聚物的可硫化橡胶组合物。乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度，耐候性，耐臭氧性，加工性，低温柔韧性和耐热性都优异。

5. 发明授权

US5696214A Process for preparing ethylene-.alpha.-olefin-nonconjugated polyene random copolymer 失效
标题翻译：制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法
公开(公告)号：US5696214A
公开(公告)日：1997-12-09
申请号：US575678
申请日：1995-12-19
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Hidenari Nakahama , Tetsuo Tojo
IPC分类号： C08F4/64 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is a process for preparing an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer comprising random copolymerizing (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene in the presence of a metallocene catalyst containing a specific metallocene compound. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer prepared by the process has such properties that (i) the copolymer contains units derived from ethylene (a) and units derived from the .alpha.-olefin of 3 or more carbon atoms (b) in a molar ratio of 40/60 to 95/5 �(a)/(b)!, (ii) the iodine value is 1 to 50, (iii) the intrinsic viscosity (.eta.) is more than 0.1 dl/g and less than 8.0 10 dl/g, (iv) the intensity ratio D of T.alpha..beta. to T.alpha..alpha. in the .sup.13 C-NMR spectrum, T.alpha..beta./T.alpha..alpha., is not more than 0.5, (v) the B value is 1.00 to 1.50, (vi) the glass transition temperature Tg is not higher than -50.degree. C., and (vii) the ratio g.eta.* of the intrinsic viscosity (.eta.) of this copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a straight-chain ethylene-propylene copolymer having the same weight-average molecular weight as this random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is more than 0.9. Also disclosed is a vulcanizable rubber composition containing the random copolymer. The ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and the rubber composition are excellent in mechanical strength, weathering resistance, ozone resistance, processability, low-temperature flexibility and heat resistance.
摘要翻译：公开了一种制备乙烯-α-烯烃 - 非共轭多烯无规共聚物的方法，包括（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯在含有特定茂金属化合物的茂金属催化剂。通过该方法制备的乙烯-α-烯烃 - 非共轭多烯无规共聚物具有以下特性：（i）共聚物含有衍生自乙烯（a）的单元和衍生自3个或更多个碳原子的（b）的α-烯烃的单元摩尔比为40/60〜95/5 [（a）/（b）]，（ii）碘值为1〜50，（iii）特性粘度（η）大于0.1dl / g以下（iv）13 C-NMR光谱中的Tαβ与Tαα的强度比D（Tαβ/Tαα）不大于0.5，（v）B值为 1.00至1.50，（vi）玻璃化转变温度Tg不高于-50℃，（vii）上述定义的共聚物的特性粘度（η）与特性粘度（η）的比值g eta * 空白的具有与该无规共聚物相同的重均分子量且乙烯含量为70摩尔％（eta）/（η）空白的直链乙烯 - 丙烯共聚物大于0.9。还公开了含有无规共聚物的可硫化橡胶组合物。乙烯-α-烯烃 - 非共轭多烯无规共聚物和橡胶组合物的机械强度，耐候性，耐臭氧性，加工性，低温柔韧性和耐热性都优异。

6. 发明授权

US5610254A Ethylene-.alpha.-olefin-nonconjugated polyene random copolymer, rubber composition, and process for preparing the random copolymer 失效
标题翻译：乙烯-α-烯烃 - 非共轭多烯无规共聚物，橡胶组合物和制备无规共聚物的方法
公开(公告)号：US5610254A
公开(公告)日：1997-03-11
申请号：US574684
申请日：1995-12-19
申请人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Tatsuya Tanizaki
发明人： Toshihiro Sagane , Toshiyuki Tsutsui , Masaaki Kawasaki , Keiji Okada , Tetsuo Tojo , Tatsuya Tanizaki
IPC分类号： C08F4/64 , C08F4/642 , C08F4/659 , C08F4/6592 , C08F210/18 , C08L23/16 , C08F236/20 , C08F232/06
CPC分类号： C08F210/18 , C08L23/16 , C08F4/65912 , C08F4/65927 , C08L2312/00 , Y10S526/943
摘要： Disclosed is an ethylene-.alpha.-olefin-nonconjugated polyene random copolymer which is a random copolymer of (a) ethylene, (b) an .alpha.-olefin of 3 or more carbon atoms and (c) a nonconjugated polyene, and has such properties that (i) the copolymer contains (a) units derived from ethylene and (b) units derived from the .alpha.-olefin of 3 or more carbon atoms in a molar ratio of 40/60 to 95/5 ((a)/(b)), (ii) the iodine value is in the range of 1 to 50, (iii) the intrinsic viscosity (.eta.), as measured in decahydronaphthalene at 135.degree. C., is in the range of 0.1 to 8.0 dl/g, and (iv) the ratio g.eta.* of the intrinsic viscosity (.eta.) of the copolymer defined above to the intrinsic viscosity (.eta.).sub.blank of a linear ethylene-propylene copolymer having the same weight-average molecular weight as the ethylene-.alpha.-olefin-nonconjugated polyene random copolymer and having an ethylene content of 70% by mol, (.eta.)/(.eta.).sub.blank, is in the range of 0.2 to 0.9 or the ratio g' of the intrinsic viscosity (.eta.) of said random copolymer defined above to the intrinsic viscosity (.eta.).sub.blank' of a linear ethylene-propylene copolymer having an ethylene content of 70% by mol which is determined by measurement of gel permeation chromatography (GPC) of ethylene-.alpha.-olefin-nonconjugated polyene random copolymer in orthodichlorobenzene at 140.degree. C., (.eta.)/(.eta.).sub.blank', is in the reange of 0.2 to 0.9.
摘要翻译：公开了一种乙烯-α-烯烃 - 非共轭多烯无规共聚物，它是（a）乙烯，（b）3个或更多个碳原子的α-烯烃和（c）非共轭多烯的无规共聚物，（i）共聚物包含（a）衍生自乙烯的单元和（b）衍生自摩尔比为40/60至95/5（（a）/（b）的3个或更多个碳原子的α-烯烃的单元）），（ii）碘值在1〜50的范围内，（iii）在135℃下在十氢化萘中测定的特性粘度（η）为0.1〜8.0dl / g，（iv）上述共聚物的特性粘度（eta）与具有与乙烯-α-烯烃相同的重均分子量的直链乙烯 - 丙烯共聚物的特性粘度（η）空白的比率g eta * 非共轭多烯无规共聚物的乙烯含量为70摩尔％（eta）/（η）空白，在0.2〜0.9的范围内或者int的比例g' 所述上述无规共聚物的特性粘度（η）为乙烯含量为70摩尔％的线性乙烯 - 丙烯共聚物的特性粘度（η）空白'，其通过乙烯的凝胶渗透色谱（GPC） α-烯烃 - 非共轭多烯无规共聚物在140℃，（η）/（η）空白'的邻二氯苯中的摩尔比为0.2-0.9。

7. 发明授权

US5387664A Higher .alpha.-olefin copolymer, vibration-insulating rubber molded product, and process for the preparaton of the rubber molded product 失效
标题翻译：高级α-烯烃共聚物，隔振橡胶模制产品和橡胶模制产品的制备方法
公开(公告)号：US5387664A
公开(公告)日：1995-02-07
申请号：US6984
申请日：1993-01-21
申请人： Masaaki Kawasaki , Toshimasa Takata , Keiji Okada , Kazuhiko Murata , Mitsuhiko Onda , Tetsuo Tojo
发明人： Masaaki Kawasaki , Toshimasa Takata , Keiji Okada , Kazuhiko Murata , Mitsuhiko Onda , Tetsuo Tojo
IPC分类号： C08F210/14 , C08L23/18 , C08F236/20
CPC分类号： C08F210/14 , C08L23/18
摘要： The higher .alpha.-olefin copolymer of the invention is a copolymer of specific higher .alpha.-olefin, specific .alpha.,.omega.-diene and specific non-conjugated diene, and this copolymer has a specific molar ratio of the higher .alpha.-olefin to the .alpha.,.omega.-diene, a specific content of the non-conjugated diene and a specific intrinsic viscosity. This higher .alpha.-olefin copolymer can be prepared using a catalyst for olefin polymerization formed from a specific solid titanium catalyst component, an organometallic compound catalyst component and an electron donor catalyst component. The vibration-insulating rubber molded product of the invention is formed from a vulcanized product of the above-mentioned copolymer. The above-mentioned copolymer is excellent not only in weathering resistance, ozone resistance, thermal aging resistance, low-temperature characteristics, vibration-damping properties and dynamic fatigue resistance but also in processability, so that an excellent vulcanized product can be obtained from the copolymer.
摘要翻译：本发明的高级α-烯烃共聚物是特定的较高级α-烯烃，特定的α，ω-二烯和特定的非共轭二烯的共聚物，该共聚物具有较高的α-烯烃与α的比摩尔比， ω-二烯，非共轭二烯的具体含量和特定的特性粘度。该高级α-烯烃共聚物可以使用由特定固体钛催化剂组分，有机金属化合物催化剂组分和电子给体催化剂组分形成的用于烯烃聚合的催化剂来制备。本发明的防振橡胶成型体由上述共聚物的硫化物形成。上述共聚物不仅耐候性，耐臭氧性，耐热老化性，低温特性，减震性和动态耐疲劳性以及加工性都优异，所以可以从共聚物获得优异的硫化产物。

8. 发明授权

US06300416B1 Rubber compositions for tires 失效
标题翻译：轮胎用橡胶组合物
公开(公告)号：US06300416B1
公开(公告)日：2001-10-09
申请号：US09142863
申请日：1998-09-17
申请人： Keiji Okada , Kenichi Morizono , Kazuyuki Takimoto , Tetsuhiro Matsumoto , Masaaki Kawasaki , Tetsuo Tojo
发明人： Keiji Okada , Kenichi Morizono , Kazuyuki Takimoto , Tetsuhiro Matsumoto , Masaaki Kawasaki , Tetsuo Tojo
IPC分类号： C08F800
CPC分类号： C08L21/00 , B60C1/0016 , B60C1/0025 , C08L23/0838 , C08L23/16 , Y02T10/862 , Y10T152/10495 , C08L2666/06 , C08L2666/04
摘要： A rubber composition useful as a tire side wall or tire tread is formed from an unsaturated olefin copolymer (A) or (A′) and diene rubber (B). Copolymers (A) and (A′) are each obtained from (i) ethylene, (ii) aromatic vinyl compound, (iii) non-conjugated polyene, and, optionally (iv) alpha-olefin having at least 3 carbon atoms. When used in forming a tire side wall, copolymer (A) has a molar ratio of (i)/(iv) from 100/0 to 40/60; molar ratio of [((i)+(iv))/(ii)] from 98/2 to 60/40; an intrinsic viscosity, measured in decalin, at 135° C., from 1.0 to 6.0 dl/g; and iodine value from 10 to 50. For use in tire tread, copolymer (A′), has a molar ratio (i)/(iv) from 100/0 to 40/60; molar ratio [((i)+(iv)):(ii)] from 99/1 to 85/15. The weight ratio (A′)/(B) is from 1/99 to 50/50. The compositions for tire side wall are characterized by excellent strength properties and bending fatigue resistance and low fuel consumption. The compositions for tire tread are characterized by superior strength properties, abrasion resistance and braking performance on wet road (wet ski resistance) and small rolling resistance.
摘要翻译：可用作轮胎侧壁或轮胎胎面的橡胶组合物由不饱和烯烃共聚物（A）或（A'）和二烯橡胶（B）形成。共聚物（A）和（A'）各自分别由（i）乙烯，（ii）芳香族乙烯基化合物，（iii）非共轭多烯，和任选地（iv）具有至少3个碳原子的α-烯烃获得。当用于形成轮胎侧壁时，共聚物（A）的摩尔比为（i）/（iv）为100/0至40/60; [（（i）+（iv））/（ii）]的摩尔比为98/2至60/40; 在135℃下，在萘烷中测定的特性粘度为1.0至6.0dl / g; 并且碘值为10至50.对于轮胎胎面使用共聚物（A'），摩尔比（i）/（iv）为100/0至40/60; 摩尔比[（（i）+（iv））:( ii）]从99/1至85/15。重量比（A'）/（B）为1/99至50/50。用于轮胎侧壁的组合物的特征在于优异的强度性能和抗弯曲疲劳性和低燃料消耗。用于轮胎胎面的组合物的特征在于在湿路面上具有优异的强度性能，耐磨性和制动性能（湿滑雪性能）和小的滚动阻力。

9. 发明授权

US5430117A Nonconjugated diene-vinyl aromatic-.alpha.-olefin interpolymers 失效
标题翻译：非共轭二烯 - 乙烯基芳族-α-烯烃互聚物
公开(公告)号：US5430117A
公开(公告)日：1995-07-04
申请号：US274284
申请日：1994-07-13
申请人： Masaaki Kawasaki , Keiji Okada , Kenzaburo Fukutani , Tetsuo Tojo , Akemi Uchimi
发明人： Masaaki Kawasaki , Keiji Okada , Kenzaburo Fukutani , Tetsuo Tojo , Akemi Uchimi
IPC分类号： B60C1/00 , C08F210/14 , C08L23/18 , C08F236/20 , C08F212/34
CPC分类号： C08F210/14 , B60C1/00 , C08L23/18
摘要： There have been provided by the present invention a higher .alpha.-olefin copolymer which has an intrinsic viscosity [.eta.], as measured in decalin at 135.degree. C., of 0.1 to 10 dl/g, and comprises polymer units derived from 95-30 parts by mol of a higher .alpha.-olefin of C.sub.6-20, 5-70 parts by mol of an aromatic ring-containing vinyl monomer represented by the formula [I] (total of the higher .alpha.-olefin and the vinyl monomer are 100 parts by mol), and 0.01 to 30% by mol of a non-conjugated diene represented by the formula [II]; ##STR1## wherein n is an integer of 0 to 5, and R.sup.1, R.sup.2 and R.sup.3 are each independently H or C.sub.1-8 alkyl; ##STR2## wherein n is an integer of 1 to 5, R.sup.4 is C.sub.1-4 alkyl, R.sup.5 and are each independently H or C.sub.1-8 alkyl but are not H simultaneously, a process for the preparation thereof, a higher .alpha.-olefin copolymer composition comprising [A] the higher .alpha.-olefin copolymer and [B] a diene rubber, and a rubber molded product comprising a vulcanized product of the higher .alpha.-olefin copolymer.
摘要翻译：本发明提供了一种较高级的α-烯烃共聚物，它在135℃萘烷中测得的特性粘度η为0.1-10dl / g，并且包含衍生自95-30的聚合物单元（摩尔）C6-20的高级α-烯烃，5-70份（摩尔）式[I]表示的含芳环的乙烯基单体（总共较高级的α-烯烃和乙烯基单体为100份和0.01〜30摩尔％的由式[II]表示的非共轭二烯; 其中n为0〜5的整数，R 1，R 2和R 3各自独立地为H或C 1-8烷基; R 4是C 1-4烷基，R 5，各自独立地为H或C 1-8烷基，但不同时为H，其制备方法为高级α-烯烃共聚物组合物，其包含[A]高级α-烯烃共聚物和[ B]二烯橡胶，以及包含较高级α-烯烃共聚物的硫化产物的橡胶模制产品。

10. 发明授权

US5076967A Semiconductive rubber foam 失效
标题翻译：半导体橡胶泡沫
公开(公告)号：US5076967A
公开(公告)日：1991-12-31
申请号：US668050
申请日：1991-03-12
申请人： Tetsuo Tojo , Yoshiharu Kikuchi , Keiji Okada
发明人： Tetsuo Tojo , Yoshiharu Kikuchi , Keiji Okada
IPC分类号： C08J9/06 , C08J9/10 , C08K3/04 , G03G15/00 , H01B1/24
CPC分类号： C08J9/10 , C08K3/04 , G03G15/65 , C08J2323/28 , G03G2215/00371 , G03G2215/00679 , G03G2215/00683
摘要： Disclosed is a semiconductive rubber foam having a volume resistivity that can be controlled to a practical level and retaining an initial softness (hardness) even after the lapse of time. This semiconductor rubber foam is composed of a molded article obtained by curing and foaming a rubber composition comprising (A) 100 parts by weight of a chlorinated ethylene/.alpha.-olefin copolymer rubber and (B) 10 to 50 parts by weight of carbon black. The volume resistivity of this semiconductive rubber foam has is in the range of from 10.sup.5 to 10.sup.11 .OMEGA.-cm.

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