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    • 3. 发明授权
    • Method of manufacturing semiconductor device
    • 制造半导体器件的方法
    • US06908857B2
    • 2005-06-21
    • US10657081
    • 2003-09-09
    • Kazuo AkamatsuYoshihiko IsobeHiroyuki Yamane
    • Kazuo AkamatsuYoshihiko IsobeHiroyuki Yamane
    • H01L23/52H01L21/28H01L21/285H01L21/3205H01L21/768H01L23/485H01L23/522H01L23/532H01L21/44H01L21/4763
    • H01L21/7685H01L21/28518H01L21/2855H01L21/32051H01L21/76886H01L23/485H01L23/5226H01L23/53223H01L2924/0002H01L2924/00
    • A method for manufacturing a semiconductor device having on a silicon substrate semiconductor elements and aluminum (Al) alloy wiring leads as electrically connected thereto is disclosed. The method includes the steps of forming on the silicon substrate an Al alloy layer containing therein copper (Cu), and forming on the Al alloy layer a titanium nitride (TiN) film with enhanced chemical reactivity by using sputtering techniques while applying thereto a DC power of 5.5 W/cm2 or less. Fabrication of such reactivity-rich TiN film on the Al alloy layer results in a reaction layer of Al and Ti being subdivided into several spaced-apart segments. In this case, the reaction layer hardly serves as any diffusion path; thus, it becomes possible to prevent Cu as contained in the Al alloy layer from attempting to outdiffuse with the reaction layer being as its diffusion path. This makes it possible to suppress or minimize unwanted fabrication of AlN on or above the surface of an Al containing lead pattern, thereby enabling increase in electromigration (EM) lifetime of electrical interconnect leads used.
    • 公开了一种制造半导体器件的方法,该半导体器件具有硅衬底半导体元件和与其电连接的铝(Al)合金布线引线。 该方法包括以下步骤:在硅衬底上形成含有铜(Cu)的Al合金层,并且通过使用溅射技术在Al合金层上形成具有增强的化学反应性的氮化钛(TiN)膜,同时施加直流电力 为5.5W / cm 2以下。 在Al合金层上制备这种富含反应性的TiN膜导致Al和Ti的反应层被细分成几个间隔开的段。 在这种情况下,反应层几乎不作为任何扩散路径; 因此,可以防止Al合金层中所含的Cu作为其扩散路径而反向扩散。 这使得可以抑制或最小化在含铝的引线图案的表面上或上方的AlN的不希望的制造,从而能够增加使用的电互连引线的电迁移(EM)寿命。
    • 4. 发明授权
    • Electrical wiring of semiconductor device enabling increase in electromigration (EM) lifetime
    • 半导体器件的电气布线能够增加电迁移(EM)寿命
    • US06650017B1
    • 2003-11-18
    • US09637066
    • 2000-08-11
    • Kazuo AkamatsuYoshihiko IsobeHiroyuki Yamane
    • Kazuo AkamatsuYoshihiko IsobeHiroyuki Yamane
    • H01L2348
    • H01L21/7685H01L21/28518H01L21/2855H01L21/32051H01L21/76886H01L23/485H01L23/5226H01L23/53223H01L2924/0002H01L2924/00
    • A method for manufacturing a semiconductor device having on a silicon substrate semiconductor elements and aluminum (Al) alloy wiring leads as electrically connected thereto is disclosed. The method includes the steps of forming on the silicon substrate an Al alloy layer containing therein copper (Cu), and forming on the Al alloy layer a titanium nitride (TiN) film with enhanced chemical reactivity by using sputtering techniques while applying thereto a DC power of 5.5 W/cm2 or less. Fabrication of such reactivity-rich TiN film on the Al alloy layer results in a reaction layer of Al and Ti being subdivided into several spaced-apart segments. In this case, the reaction layer hardly serves as any diffusion path; thus, it becomes possible to prevent Cu as contained in the Al alloy layer from attempting to outdiffuse with the reaction layer being as its diffusion path. This makes it possible to suppress or minimize unwanted fabrication of AlN on or above the surface of an Al containing lead pattern, thereby enabling increase in electromigration (EM) lifetime of electrical interconnect leads used.
    • 公开了一种制造半导体器件的方法,该半导体器件具有硅衬底半导体元件和与其电连接的铝(Al)合金布线引线。 该方法包括以下步骤:在硅衬底上形成含有铜(Cu)的Al合金层,并且通过使用溅射技术在Al合金层上形成具有增强的化学反应性的氮化钛(TiN)膜,同时施加直流电力 为5.5W / cm 2以下。 在Al合金层上制备这种富含反应性的TiN膜导致Al和Ti的反应层被细分成几个间隔开的段。 在这种情况下,反应层几乎不作为任何扩散路径; 因此,可以防止Al合金层中所含的Cu作为其扩散路径而反向扩散。 这使得可以抑制或最小化在含铝的引线图案的表面上或上方的AlN的不希望的制造,从而能够增加使用的电互连引线的电迁移(EM)寿命。
    • 9. 发明授权
    • Method of manufacturing a semiconductor device having a plurality of
elements
    • 制造具有多个元件的半导体器件的方法
    • US5019526A
    • 1991-05-28
    • US249514
    • 1988-09-26
    • Hiroyuki YamaneYasushi HiguchiTetsuo Fujii
    • Hiroyuki YamaneYasushi HiguchiTetsuo Fujii
    • H01L21/311H01L21/762
    • H01L21/76213H01L21/31111H01L21/76216Y10S148/117Y10S438/911
    • A method of manufacturing a semiconductor apparatus having a plurality of elements formed on a substrate comprises forming a pad oxidized film on the surface of the semiconductor substrate, forming a pattern of silicon nitride film to coat device areas on the pad oxidized film, and injecting boron ions into that surface of the pad oxidized film where no silicon nitride film is present, thereby to form a channel stopper region. Using the pattern of the silicon nitride film as a mask, a heat oxidized film is then formed on an elements separating region by heat oxidization, and ions of Si, N, C, or the like are injected into the surface of the heat oxidized film with such an acceleration energy that the ions are not injected into the silicon nitride film thereby to change the quality of the heat oxidized film. The silicon nitride film is removed by etching and the heat oxidized film is etching-treated by a solution of the hydrofluoric acid group to etching-remove particularly the bird's beak portions each of which is present along and under the peripheral rim of an element area of the silicon nitride film.
    • 一种制造具有形成在基板上的多个元件的半导体装置的方法包括在半导体基板的表面上形成焊盘氧化膜,形成氮化硅膜的图案以涂覆焊盘氧化膜上的器件区域,并注入硼 离子进入焊盘氧化膜的不存在氮化硅膜的表面,从而形成通道停止区域。 使用氮化硅膜的图案作为掩模,然后通过热氧化在元件分离区域上形成热氧化膜,并且将Si,N,C等的离子注入到热氧化膜的表面 具有这样的加速能量,使得离子不被注入到氮化硅膜中,从而改变热氧化膜的质量。 通过蚀刻去除氮化硅膜,并且通过氢氟酸基团的溶液对热氧化膜进行蚀刻处理,特别是沿着元件区域的外围边缘沿着和/或 氮化硅膜。