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    • 6. 发明授权
    • Sanitary earthen products
    • 卫生陶土制品
    • US06514622B1
    • 2003-02-04
    • US09762144
    • 2001-06-04
    • Makoto HayakawaKoichi HayashiMasami AndoMasaaki ItoTomoyasu IchikiHirotaka IshibashiMitsuyoshi Machida
    • Makoto HayakawaKoichi HayashiMasami AndoMasaaki ItoTomoyasu IchikiHirotaka IshibashiMitsuyoshi Machida
    • B32B1504
    • C04B41/009C04B41/52C04B41/89C04B2111/2069C04B41/4543C04B41/5022C04B41/5116C04B41/5075C04B33/00
    • Disclosed is a sanitary ware which has a self-cleaning function for releasing carboxyl-containing greasy stains or soils, such as fatty acids, fatty esters, metallic soaps (scum of soaps), proteins, amino acids, bacteria, and fungi, and deposited stains or soils, such as water scale and urinary calculi. This sanitary ware comprises at least a sanitary ware body and a glaze layer as an outermost layer of the sanitary ware, a monovalent metal component and/or a metal component having a measure of the electronegativity based on Pouling's rule of not more than 1 being provided so as to be releasable evenly and continuously, over the whole surface of the glaze layer as the outermost layer, in such an amount large enough to impart a self-cleaning function for releasing stains or soils to the surface of the glaze layer as the outermost layer, the metal component being suppliable from the glaze layer as the outermost layer and/or the sanitary ware body to the whole surface of the outermost layer. The sanitary ware is advantageous in that stains or soils on the sanitary ware can be simply removed, for example, by running water without using any surfactant and without strongly scrubbing the surface of the sanitary ware by a scrubbing brush or a cleaning brush.
    • 公开了一种卫生洁具,其具有用于释放含羧基的油脂污渍或污垢如脂肪酸,脂肪酸酯,金属皂(肥皂),蛋白质,氨基酸,细菌和真菌的自清洁功能,并沉积 污渍或污垢,如水垢和尿结石。 这种卫生洁具至少包括作为卫生洁具的最外层的卫生洁具主体和釉层,具有基于Pouling规则的不超过1的电负性量度的一价金属成分和/或金属成分 以均匀且连续的方式在作为最外层的釉层的整个表面上以足够大的量赋予自清洁功能,以将污渍或污垢释放到釉层的表面作为最外层 层,作为最外层的釉层提供的金属成分和/或卫生洁具主体到最外层的整个表面。 卫生洁具的优点在于,可以简单地除去卫生洁具上的污渍或污垢,例如通过流水而不使用任何表面活性剂,并且不用擦洗刷或清洁刷强力洗涤卫生洁具的表面。
    • 9. 发明授权
    • Antifouling member and antifouling coating composition
    • US06337129B1
    • 2002-01-08
    • US09201499
    • 1998-11-30
    • Toshiya WatanabeMakoto HayakawaMitsuyoshi Machida
    • Toshiya WatanabeMakoto HayakawaMitsuyoshi Machida
    • B32B516
    • F28F19/04B01J35/002B01J35/004B01J37/0215C08K3/22C09D7/00C09D7/61C09D183/04F28F2245/02F28F2245/04Y10T428/256Y10T428/259Y10T428/3154Y10T428/31551Y10T428/31663Y10T428/31786Y10T428/31935C08L2666/04C08L2666/54
    • Disclosed is a member having an antifouling surface on which the so-called “stains,” such as deposits and contaminants, are less likely to be deposited. The surface of the member has both a hydrophobic portion, and a hydrophilic portion induced by a photocatalyst, the hydrophobic portion and the hydrophilic portion being present in a microscopically dispersed and exposed state on the surface. More specifically, according to a first aspect of the present invention, there is provided a member comprising: a substrate; and a surface layer provided on the substrate, the surface layer comprising a photocatalytic oxide, a silicone resin or silica, and a water-repellent fluororesin, the silicone or silica and the water-repellent fluororesin being present in a microscopically dispersed and exposed state on the outermost surface of the surface layer. According to a second aspect of the present invention, there is provided a member comprising: a substrate; and a surface layer provided on the substrate, the surface layer comprising a hydrophobic resin and a photocatalytic oxide, the hydrophobic resin and the photocatalytic oxide being present in a microscopically dispersed and exposed state on the outermost surface of the surface layer, the photocatalytic oxide being self-hydrophilified or functioning to hydrophilify the photocatalytic oxide still remaining unhydrophilified present around the photocatalytic oxide by photocatalytic action created in response to photoexcitation. In this surface where the hydrophobic portion and the hydrophilic portion are present adjacent to each other, a hydrophilic deposit having affinity for the hydrophilic portion does not have affinity for the adjacent water-repellent portion. On the other hand, a hydrophobic deposit having affinity for the hydrophobic portion does not have affinity for the adjacent hydrophilic portion. Therefore, both the hydrophilic deposit and the hydrophobic deposit cannot be deposited on the surface of the member, and, even when deposited on the surface of the member, are unstable and hence are easily removed, permitting the surface of the member to be kept clean.