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1. 发明授权

US08778080B2 Apparatus for double-plasma graft polymerization at atmospheric pressure 失效
标题翻译：用于在大气压下进行双等离子体接枝聚合的装置
公开(公告)号：US08778080B2
公开(公告)日：2014-07-15
申请号：US12124685
申请日：2008-05-21
申请人： Mien-Win Wu , Tien-Hsiang Hsueh , Cheng-Chang Hsieh , Chi-fong Ai
发明人： Mien-Win Wu , Tien-Hsiang Hsueh , Cheng-Chang Hsieh , Chi-fong Ai
IPC分类号： C08F2/46 , C23C16/513 , B05D3/04 , C08F2/52 , B05D7/04 , B05D3/14 , B05D1/18
CPC分类号： C08F2/52 , B05D1/18 , B05D3/0446 , B05D3/144 , B05D3/147 , B05D7/04 , B05D2252/02
摘要： Disclosed is an atmospheric-pressure double-plasma graft polymerization apparatus. The apparatus includes a workbench, an initial roller of a roll-to-roll device, an atmospheric-pressure plasma activation device, a peroxide formation device, a coating and grafting device, a drying device, a graft polymerization and curing device, a curing device and a final roller of a roll-to-roll device. The devices are sequentially provided on the workbench.
摘要翻译：公开了一种大气压双等离子体接枝聚合装置。该装置包括工作台，卷对卷装置的初始辊，大气压等离子体激活装置，过氧化物形成装置，涂覆和接枝装置，干燥装置，接枝聚合和固化装置，固化装置和卷对卷装置的最终辊。设备依次设置在工作台上。

2. 发明申请

US20110045200A1 Structure and its Method for Hydrophobic and Oleophobic Modification of Polymeric Materials with Atmospheric Plasmas 失效
标题翻译：具有大气等离子体的聚合材料的疏水性和疏水性改性的结构及其方法
公开(公告)号：US20110045200A1
公开(公告)日：2011-02-24
申请号：US12545664
申请日：2009-08-21
申请人： Tien-Hsiang Hsueh , Mien-Win Wu , Chi-Fong Ai
发明人： Tien-Hsiang Hsueh , Mien-Win Wu , Chi-Fong Ai
IPC分类号： C08J7/18
CPC分类号： B05D3/142 , C08J7/18 , C08J2427/12 , D06M10/025 , D06M14/18 , D06M14/22 , D06M14/26 , D06M14/28 , D06M14/32 , D06M14/34 , D06M2200/11 , D06M2200/12
摘要： The present invention fabricates a hydrophobic and oleophobic polymer fabric through two stages of modification using atmospheric plasmas. The modified fabric has a rough surface and a fluorocarbon functional group having the lowest surface free energy. The fabric has a grafted fluorocarbon monomer layer to enhance the graft efficiency of the fluorocarbon functional groups and its wash fastness. The atmospheric plasmas can be mass produced and less expensively. Hence, the present invention can rapidly modify surfaces of polymeric materials with low cost and good environment protection.
摘要翻译：本发明通过使用大气等离子体的两个修改阶段制造疏水和疏油聚合物织物。改性织物具有粗糙表面和具有最低表面自由能的氟碳官能团。织物具有接枝的氟碳单体层，以提高碳氟化合物官能团的接枝效率及其耐洗牢度。大气等离子体可以批量生产，而且成本较低。因此，本发明可以以低成本和良好的环境保护快速地改变聚合物材料的表面。

3. 发明授权

US08414980B2 Method for hydrophobic and oleophobic modification of polymeric materials with atmospheric plasmas 失效
标题翻译：具有大气等离子体的聚合材料疏水和疏油改性的方法
公开(公告)号：US08414980B2
公开(公告)日：2013-04-09
申请号：US12545664
申请日：2009-08-21
申请人： Tien-Hsiang Hsueh , Mien-Win Wu , Chi-Fong Ai
发明人： Tien-Hsiang Hsueh , Mien-Win Wu , Chi-Fong Ai
IPC分类号： C08J7/18
CPC分类号： B05D3/142 , C08J7/18 , C08J2427/12 , D06M10/025 , D06M14/18 , D06M14/22 , D06M14/26 , D06M14/28 , D06M14/32 , D06M14/34 , D06M2200/11 , D06M2200/12
摘要： A method of fabricating hydrophobic and oleophobic polymer fabric through two stages of modification using atmospheric plasmas including (a) moving a substrate into an atmospheric plasma area, generating an atmospheric filamentary discharge plasma with a first plasma working gas to obtain a first rough surface of said substrate, (b) exposing plasma treated substrate to air to obtain highly active peroxide on said first rough surface of said substrate, (c) immersing said substrate in a solution of fluorocarbon compound and processing a first stage of graft of a fluorocarbon monomer or oligomer on said substrate to obtain a grafted fluorocarbon monomer or oligomer layer on said first rough surface of said substrate, (d) processing a second stage of graft a fluorocarbon functional group to said grafted fluorocarbon monomer or oligomer layer by generating a carbon tetrafluoride plasma from a second plasma working gas and irradiating said carbon tetrafluoride plasma on said grafted fluorocarbon monomer or oligomer layer; and (e) curing and drying said substrate.
摘要翻译：一种通过使用大气等离子体的两个阶段的修饰制造疏水和疏油聚合物织物的方法，包括：（a）将基底移动到大气等离子体区域，用第一等离子体工作气体产生大气丝状放电等离子体，以获得所述（b）将等离子体处理的基板暴露于空气中以在所述基板的所述第一粗糙表面上获得高活性过氧化物，（c）将所述基材浸入氟碳化合物溶液中，并处理氟碳单体或低聚物的第一接枝段在所述基板上在所述基板的所述第一粗糙表面上获得接枝的碳氟单体或低聚物层，（d）通过从所述基板上生成碳氟化合物单体或低聚物层，第二等离子体工作气体，并且在所述接枝的氟碳上照射所述四氟化碳等离子体单体或低聚物层; 和（e）固化和干燥所述基材。

4. 发明申请

US20090291226A1 Apparatus and Method for Double-Plasma Graft Polymerization at Atmospheric Pressure 失效
标题翻译：在大气压下双等离子体接枝聚合的装置和方法
公开(公告)号：US20090291226A1
公开(公告)日：2009-11-26
申请号：US12124685
申请日：2008-05-21
申请人： Mien-Win WU , Tien-Hsiang Hsueh , Cheng-Chang Hsieh , Chi-fong Ai
发明人： Mien-Win WU , Tien-Hsiang Hsueh , Cheng-Chang Hsieh , Chi-fong Ai
IPC分类号： C08F2/46 , C23C16/513
CPC分类号： C08F2/52 , B05D1/18 , B05D3/0446 , B05D3/144 , B05D3/147 , B05D7/04 , B05D2252/02
摘要： Disclosed is a n atmospheric-pressure double-plasma graft polymerization apparatus. The apparatus includes a workbench, an initial roller of a roll-to-roll device, an atmospheric-pressure plasma activation device, a peroxide formation device, a coating and grafting device, a drying device, a graft polymerization and curing device, a curing device and a final roller of a roll-to-roll device. The devices are sequentially provided on the workbench.
摘要翻译：公开了一种n大气压双等离子体接枝聚合装置。该装置包括工作台，卷对卷装置的初始辊，大气压等离子体激活装置，过氧化物形成装置，涂覆和接枝装置，干燥装置，接枝聚合和固化装置，固化装置和卷对卷装置的最终辊。设备依次设置在工作台上。

5. 发明申请

US20100225234A1 Hollow-cathode plasma generator 审中-公开
标题翻译：空心阴极等离子体发生器
公开(公告)号：US20100225234A1
公开(公告)日：2010-09-09
申请号：US11896620
申请日：2007-09-04
申请人： Ching-Pei Tseng , Cheng-Chang Hsieh , Chi-Fong Ai , Chia-Cheng Lee , Tien-Hsiang Hsueh , Chun-Han Wang
发明人： Ching-Pei Tseng , Cheng-Chang Hsieh , Chi-Fong Ai , Chia-Cheng Lee , Tien-Hsiang Hsueh , Chun-Han Wang
IPC分类号： H05H1/24
CPC分类号： H05H1/46 , H01J37/32596 , H01J37/32724
摘要： A hollow-cathode plasma generator includes a plurality of hollow cathodes joined together and connected to a power supply for generating plasma in vacuum. Each of the hollow cathodes includes at least one fillister defined therein, a fin formed on a side of the fillister, an air-circulating tunnel in communication with the fillister and a coolant-circulating tunnel defined therein. The fillister is used to contain working gas. The fin receives negative voltage from the power supply for ionizing the working gas to generate the plasma and spread the plasma in a single direction. The working gas travels into the fillister from the air-circulating tunnel. The coolant-circulating tunnel is used to circulate coolant for cooling the hollow cathode.
摘要翻译：中空阴极等离子体发生器包括多个连接在一起的中空阴极，并连接到用于在真空中产生等离子体的电源。每个中空阴极包括限定在其中的至少一个填充器，形成在填充器一侧的翅片，与填充器连通的空气循环隧道和限定在其中的冷却剂循环通道。灌装机用于容纳工作气体。翅片从电源接收负电压，用于电离工作气体以产生等离子体并且在单个方向上扩散等离子体。工作气体从空气循环通道进入灌装机。冷却剂循环隧道用于循环冷却剂以冷却空心阴极。

6. 发明授权

US07416761B2 Composite membrane and method for forming the same 有权
标题翻译：复合膜及其形成方法
公开(公告)号：US07416761B2
公开(公告)日：2008-08-26
申请号：US11435718
申请日：2006-05-18
申请人： Da-Ming Wang , Kueir-Rarn Lee , Juin-Yih Lai , Tien-Hsiang Hsueh , Yung-Hsin Lee , Chia-Hao Lo
发明人： Da-Ming Wang , Kueir-Rarn Lee , Juin-Yih Lai , Tien-Hsiang Hsueh , Yung-Hsin Lee , Chia-Hao Lo
IPC分类号： B05D3/02
CPC分类号： B01D71/36 , B01D67/0004 , B01D67/0025 , B01D69/12 , B01D2323/08 , B01D2323/28 , B01D2323/283 , B32B5/16 , B32B5/18 , B32B5/30 , B32B27/14 , B32B27/18 , B32B27/30 , B32B27/322 , B32B2264/0257 , B32B2266/025 , B32B2307/206 , B32B2307/31 , B32B2307/554 , B32B2307/714 , B32B2457/00 , Y10T428/249978 , Y10T428/249979 , Y10T428/24998 , Y10T428/249981
摘要： The present invention discloses discloses a composite PTFE membrane comprising an expanded PTFE membrane as substrate and a sintered porous PTFE membrane on top of it. The porous PTFE membrane on top has porous structure with interconnected channels formed with a sintering process that fuses the PTFE fine powders coated on the ePTFE membrane. Furthermore, the present invention discloses a method for forming the composite PTFE membrane.
摘要翻译：本发明公开了一种复合PTFE膜，其包括作为基底的膨体PTFE膜和其顶部的烧结多孔PTFE膜。顶部的多孔PTFE膜具有多孔结构，其互连通道形成有烧结方法，熔化PTFE涂层在ePTFE膜上的细粉末。此外，本发明公开了一种形成复合PTFE膜的方法。

7. 发明申请

US20060269735A1 Composite membrane and method for forming the same 有权
标题翻译：复合膜及其形成方法
公开(公告)号：US20060269735A1
公开(公告)日：2006-11-30
申请号：US11435718
申请日：2006-05-18
申请人： Da-Ming Wang , Kueir-Rarn Lee , Juin-Yih Lai , Tien-Hsiang Hsueh , Yung-Hsin Lee , Chia-Hao Lo
发明人： Da-Ming Wang , Kueir-Rarn Lee , Juin-Yih Lai , Tien-Hsiang Hsueh , Yung-Hsin Lee , Chia-Hao Lo
IPC分类号： B32B3/00
CPC分类号： B01D71/36 , B01D67/0004 , B01D67/0025 , B01D69/12 , B01D2323/08 , B01D2323/28 , B01D2323/283 , B32B5/16 , B32B5/18 , B32B5/30 , B32B27/14 , B32B27/18 , B32B27/30 , B32B27/322 , B32B2264/0257 , B32B2266/025 , B32B2307/206 , B32B2307/31 , B32B2307/554 , B32B2307/714 , B32B2457/00 , Y10T428/249978 , Y10T428/249979 , Y10T428/24998 , Y10T428/249981
摘要： The present invention discloses discloses a composite PTFE membrane comprising an expanded PTFE membrane as substrate and a sintered porous PTFE membrane on top of it. The porous PTFE membrane on top has porous structure with interconnected channels formed with a sintering process that fuses the PTFE fine powders coated on the ePTFE membrane. Furthermore, the present invention discloses a method for forming the composite PTFE membrane.
摘要翻译：本发明公开了一种复合PTFE膜，其包括作为基底的膨体PTFE膜和其顶部的烧结多孔PTFE膜。顶部的多孔PTFE膜具有多孔结构，其互连通道形成有烧结方法，熔化PTFE涂层在ePTFE膜上的细粉末。此外，本发明公开了一种形成复合PTFE膜的方法。

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