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1. 发明授权

US09073009B2 Air purification system 有权
标题翻译：空气净化系统
公开(公告)号：US09073009B2
公开(公告)日：2015-07-07
申请号：US12302615
申请日：2007-05-31
申请人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
发明人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
IPC分类号： A62B7/08 , B01D53/88 , B01J23/38 , B01J35/00
CPC分类号： B01D53/885 , B01D2255/802 , B01D2259/804 , B01J23/38 , B01J35/0013 , B01J35/004
摘要： An air purification system that comprises a substrate, and at least one layer of photocatalysts. The at least one layer of photocatalysts further comprise a plurality of metal clusters.
摘要翻译：一种空气净化系统，其包括基底和至少一层光催化剂层。至少一层光催化剂还包括多个金属簇。

2. 发明申请

US20090246091A1 AIR PURIFICATION SYSTEM 有权
标题翻译：空气净化系统
公开(公告)号：US20090246091A1
公开(公告)日：2009-10-01
申请号：US12302615
申请日：2007-05-31
申请人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
发明人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
IPC分类号： A62B7/08
CPC分类号： B01D53/885 , B01D2255/802 , B01D2259/804 , B01J23/38 , B01J35/0013 , B01J35/004
摘要： An air purification system that comprises a substrate, and at least one layer of photocatalysts. The at least one layer of photocatalysts further comprise a plurality of metal clusters.
摘要翻译：一种空气净化系统，其包括基底和至少一层光催化剂层。至少一层光催化剂还包括多个金属簇。

3. 发明申请

US20090110623A1 Siloxane Resistant Ultra Violet Photocatalysts 有权
标题翻译：硅氧烷耐紫外光催化剂
公开(公告)号：US20090110623A1
公开(公告)日：2009-04-30
申请号：US12227420
申请日：2006-05-15
申请人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes
发明人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes
IPC分类号： B01D53/72 , B01D53/34
CPC分类号： B01D53/885 , B01D2255/20707 , B01D2255/802 , B01D2257/708 , B01D2259/4508 , B01J35/004
摘要： Deactivation resistant photocatalysts can be formulated by coating one or more photocatalyst crystals onto a suitable substrate. The photocatalyst crystals are doped with a dopant M. The dopant could be used to repel the silicon-based compound or be used to attract the silicon-based compound. In one embodiment, the dopant can uniformly be distributed in the photocatalyst crystals. In another embodiment, the dopant can be introduced only to photocatalyst crystals between about 0.1 to about 2 nanomenters below the surface of the structure. In another embodiment, the doped photocatalyst crystals can be interdispersed with non-doped photocatalyst crystals.
摘要翻译：可以通过将一种或多种光催化剂晶体涂覆到合适的基底上来配制灭活性光催化剂。光催化剂晶体掺杂有掺杂剂M.掺杂剂可用于排斥硅基化合物或用于吸引硅基化合物。在一个实施方案中，掺杂剂可以均匀地分布在光催化剂晶体中。在另一个实施方案中，掺杂剂可以仅引入结构表面下约0.1至约2纳姆的光催化剂晶体。在另一个实施方案中，掺杂的光催化剂晶体可以与非掺杂的光催化剂晶体分散。

4. 发明授权

US08123837B2 Siloxane resistant ultra violet photocatalysts 有权
标题翻译：硅氧烷耐紫外线光催化剂
公开(公告)号：US08123837B2
公开(公告)日：2012-02-28
申请号：US12227420
申请日：2006-05-15
申请人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes , Leland G. Brandes, legal representative
发明人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes
IPC分类号： B01D46/00 , A62B7/08 , B01D50/00
CPC分类号： B01D53/885 , B01D2255/20707 , B01D2255/802 , B01D2257/708 , B01D2259/4508 , B01J35/004
摘要： Deactivation resistant photocatalysts can be formulated by coating one or more photocatalyst crystals onto a suitable substrate. The photocatalyst crystals are doped with a dopant M. The dopant can be used to repel the silicon-based compound or be used to attract the silicon-based compound. The dopant can uniformly be distributed in the photocatalyst crystals. The dopant can be introduced only to photocatalyst crystals between about 0.1 to about 2 nanometers below the surface of the structure. The doped photocatalyst crystals can be interdispersed with non-doped photocatalyst crystals.
摘要翻译：可以通过将一种或多种光催化剂晶体涂覆到合适的基底上来配制灭活性光催化剂。光催化剂晶体掺杂有掺杂剂M.掺杂剂可用于排斥硅基化合物或用于吸引硅基化合物。掺杂剂可以均匀地分布在光催化剂晶体中。掺杂剂可以仅引入结构表面下约0.1至约2纳米之间的光催化剂晶体。掺杂的光催化剂晶体可以与非掺杂光催化剂晶体分散。

5. 发明授权

US07655183B2 Durable pd-based alloy and hydrogen generation membrane thereof 有权
标题翻译：耐用pd基合金及其氢生成膜
公开(公告)号：US07655183B2
公开(公告)日：2010-02-02
申请号：US11712200
申请日：2007-02-28
申请人： Raymond C. Benn , Susanne M. Opalka , Thomas Henry Vanderspurt
发明人： Raymond C. Benn , Susanne M. Opalka , Thomas Henry Vanderspurt
IPC分类号： C22C5/04 , C22C5/00 , C22C30/00 , B01J20/28 , B01J35/00
CPC分类号： C01B3/505 , B01D71/022 , B01D2325/22 , C01B2203/041 , C01B2203/047 , C01B2203/0475 , H01M8/0687
摘要： A durable Pd-based alloy is used for a H2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes “X”, where “X” comprises at least one metal from group “M” that is BCC and acts to stabilize the β BCC phase for stability during operating temperatures. The metal from group “M” is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. “X” may further comprise at least one metal from a group “N” that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group “N” is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd—Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of “X” in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.
摘要翻译：耐用的Pd基合金用于氢发生器中的H 2选择性膜，如在燃料电池厂的燃料处理器中。 Pd基合金包括Cu作为二元元素，并且还包括“X”，其中“X”包括至少一种B族的“M”族金属，并且用于稳定βBCC相以保持工作温度。来自组“M”的金属选自Fe，Cr，Nb，Ta，V，Mo和W，Nb和Ta是最优选的。 “X”可以进一步包含至少一种金属，其来自非BCC（优选FCC）的组“N”，其提高膜的其它性质，例如延展性。来自组“N”的金属选自Ag，Au，Re，Ru，Rh，Y，Ce，Ni，Ir，Pt，Co，La和In。在。二元Pd-Cu合金中Pd的％为约35at。％至55华氏度。％，和at。基于所述二元合金的高阶合金中的“X”的％在约1at的范围内。％至约15英寸％。根据新颖的方法选择金属。

6. 发明授权

US07612011B2 Ceria-based mixed-metal oxide structure, including method of making and use 有权
标题翻译：二氧化铈基混合金属氧化物结构，包括制造和使用的方法
公开(公告)号：US07612011B2
公开(公告)日：2009-11-03
申请号：US11605515
申请日：2006-11-28
申请人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
发明人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
IPC分类号： C01F17/00
CPC分类号： C01G27/006 , B01J23/002 , B01J23/10 , B01J23/63 , B01J23/6567 , B01J35/10 , B01J35/1019 , B01J35/1061 , B01J37/0036 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01B3/16 , C01B2203/0283 , C01B2203/044 , C01B2203/066 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01F17/0043 , C01G25/00 , C01G25/006 , C01P2002/50 , C01P2002/52 , C01P2002/60 , C01P2002/72 , C01P2002/82 , C01P2006/12 , C01P2006/14 , C01P2006/16 , Y02P20/52 , Y10T436/12 , B01J2523/3712 , B01J2523/48 , B01J2523/3706 , B01J2523/3718 , B01J2523/49 , B01J2523/375 , B01J2523/32 , B01J2523/74 , B01J2523/828 , B01J2523/56 , B01J2523/824 , B01J2523/68 , B01J2523/821 , B01J2523/3737 , B01J2523/827 , B01J2523/822
摘要： A homogeneous ceria-based mixed-metal oxide, useful as a catalyst support, a co-catalyst and/or a getter has a relatively large surface area per weight, typically exceeding 150 m2/g, a structure of nanocrystallites having diameters of less than 4 nm, and including pores larger than the nanocrystallites and having diameters in the range of 4 to about 9 nm. The ratio of pore volumes, VP, to skeletal structure volumes, VS, is typically less than about 2.5, and the surface area per unit volume of the oxide material is greater than 320 m2/cm3, for low internal mass transfer resistance and large effective surface area for reaction activity. The mixed metal oxide is ceria-based, includes Zr and or Hf, and is made by a novel co-precipitation process. A highly dispersed catalyst metal, typically a noble metal such as Pt, may be loaded on to the mixed metal oxide support from a catalyst metal-containing solution following a selected acid surface treatment of the oxide support. Appropriate ratioing of the Ce and other metal constituents of the oxide support contribute to it retaining in a cubic phase and enhancing catalytic performance. Rhenium is preferably further loaded on to the mixed-metal oxide support and passivated, to increase the activity of the catalyst. The metal-loaded mixed-metal oxide catalyst is applied particularly in water gas shift reactions as associated with fuel processing systems, as for fuel cells.
摘要翻译：可用作催化剂载体，助催化剂和/或吸气剂的均匀二氧化铈基混合金属氧化物具有相对较大的每重量的表面积，通常超过150m 2 / g，直径小于 4nm，并且包括大于纳米晶体的孔，并且具有在4至约9nm范围内的直径。孔体积VP与骨架结构体积的比率VS通常小于约2.5，并且氧化物材料的每单位体积的表面积大于320m 2 / cm 3，对于低内部传质阻力和大的有效反应活性的表面积。复合金属氧化物是二氧化铈基，包括Zr和Hf，并且通过新的共沉淀法制备。通过选择的氧化物载体的酸表面处理，可以将高度分散的催化剂金属（通常为贵金属如Pt）负载到来自含催化剂金属的溶液的混合金属氧化物载体上。 Ce和其他金属成分对氧化物载体的适当比例有助于其保持立方相并提高催化性能。优选将铼进一步负载在混合金属氧化物载体上并钝化，以提高催化剂的活性。负载金属的混合金属氧化物催化剂特别适用于燃料处理系统与燃料电池相关的水煤气变换反应。

7. 发明授权

US07166263B2 Ceria-based mixed-metal oxide structure, including method of making and use 有权
标题翻译：二氧化铈基混合金属氧化物结构，包括制造和使用的方法
公开(公告)号：US07166263B2
公开(公告)日：2007-01-23
申请号：US10402808
申请日：2003-03-28
申请人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
发明人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
IPC分类号： C01F17/00
CPC分类号： C01G27/006 , B01J23/002 , B01J23/10 , B01J23/63 , B01J23/6567 , B01J35/10 , B01J35/1019 , B01J35/1061 , B01J37/0036 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01B3/16 , C01B2203/0283 , C01B2203/044 , C01B2203/066 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01F17/0043 , C01G25/00 , C01G25/006 , C01P2002/50 , C01P2002/52 , C01P2002/60 , C01P2002/72 , C01P2002/82 , C01P2006/12 , C01P2006/14 , C01P2006/16 , Y02P20/52 , Y10T436/12 , B01J2523/3712 , B01J2523/48 , B01J2523/3706 , B01J2523/3718 , B01J2523/49 , B01J2523/375 , B01J2523/32 , B01J2523/74 , B01J2523/828 , B01J2523/56 , B01J2523/824 , B01J2523/68 , B01J2523/821 , B01J2523/3737 , B01J2523/827 , B01J2523/822
摘要： A homogeneous ceria-based mixed-metal oxide, useful as a catalyst support, a co-catalyst and/or a getter has a relatively large surface area per weight, typically exceeding 150 m2/g, a structure of nanocrystallites having diameters of less than 4 nm, and including pores larger than the nanocrystallites and having diameters in the range of 4 to about 9 nm. The ratio of pore volumes, VP, to skeletal structure volumes, VS, is typically less than about 2.5, and the surface area per unit volume of the oxide material is greater than 320 m2/cm3, for low internal mass transfer resistance and large effective surface area for reaction activity. The mixed metal oxide is ceria-based, includes Zr and or Hf, and is made by a novel co-precipitation process. A highly dispersed catalyst metal, typically a noble metal such as Pt, may be loaded on to the mixed metal oxide support from a catalyst metal-containing solution following a selected acid surface treatment of the oxide support. Appropriate ratioing of the Ce and other metal constituents of the oxide support contribute to it retaining in a cubic phase and enhancing catalytic performance. Rhenium is preferably further loaded on to the mixed-metal oxide support and passivated, to increase the activity of the catalyst. The metal-loaded mixed-metal oxide catalyst is applied particularly in water gas shift reactions as associated with fuel processing systems, as for fuel cells.
摘要翻译：可用作催化剂载体，助催化剂和/或吸气剂的均匀的二氧化铈基混合金属氧化物具有相对较大的每重量的表面积，通常超过150m 2 / g，具有直径小于4nm的纳米晶体的结构，并且包括大于纳米微晶并且直径在4至约9nm范围内的孔。孔体积V V P与骨架结构体积V S S的比例通常小于约2.5，并且氧化物材料的每单位体积的表面积为大于320m 2 / cm 3，因为低的内部传质阻力和反应活性的大的有效表面积。复合金属氧化物是二氧化铈基，包括Zr和Hf，并且通过新的共沉淀法制备。通过选择的氧化物载体的酸表面处理，可以将高度分散的催化剂金属（通常为贵金属如Pt）负载到来自含催化剂金属的溶液的混合金属氧化物载体上。 Ce和其他金属成分对氧化物载体的适当比例有助于其保持立方相并提高催化性能。优选将铼进一步负载在混合金属氧化物载体上并钝化，以提高催化剂的活性。负载金属的混合金属氧化物催化剂特别适用于燃料处理系统与燃料电池相关的水煤气变换反应。

8. 发明授权

US06881491B2 Protective fluoride coatings for aluminum alloy articles 失效
标题翻译：铝合金制品防护氟化物涂层
公开(公告)号：US06881491B2
公开(公告)日：2005-04-19
申请号：US10439988
申请日：2003-05-16
申请人： Sally A. Jankosky , Susanne M. Opalka , Paula L. Kolek , Joseph P. Harenski , Roger W. Kaufold , Larry F. Wieserman
发明人： Sally A. Jankosky , Susanne M. Opalka , Paula L. Kolek , Joseph P. Harenski , Roger W. Kaufold , Larry F. Wieserman
IPC分类号： B21D39/00 , B32B15/04 , B32B15/20 , C22F1/04 , C23C22/56 , C23C22/73 , C23C22/78
CPC分类号： C22F1/04 , Y10T428/12535 , Y10T428/12556 , Y10T428/12569
摘要： An aluminum alloy article is cleaned to remove oxides and organic matter from a coatable surface, coated with a composition comprising an organic resin and a fluorine compound, and then heated to an elevated temperature to decompose the organic resin and at least a portion of the fluorine compound. After heating the coated surface is left with a protective oxyfluoride film that prevents blistering and hydrogen pickup and promotes hydrogen degassing from the article.
摘要翻译：清洁铝合金制品以从可涂覆表面除去氧化物和有机物质，涂覆有包含有机树脂和氟化合物的组合物，然后加热到升高的温度以分解有机树脂和至少一部分氟复合。加热涂覆表面之后留下保护性氟氧化物膜，防止起泡和吸氢，并促进制品的氢气脱气。

9. 发明授权

US06440279B1 Chemical milling process for inert anodes 失效
标题翻译：惰性阳极的化学研磨工艺
公开(公告)号：US06440279B1
公开(公告)日：2002-08-27
申请号：US09750392
申请日：2000-12-28
申请人： Dennis R. De Capite , Gary P. Tarcy , Susanne M. Opalka , Don R. Careatti
发明人： Dennis R. De Capite , Gary P. Tarcy , Susanne M. Opalka , Don R. Careatti
IPC分类号： B01D5950
CPC分类号： C25C3/12 , C25C3/06 , C25C7/025
摘要： A cermet inert anode having a reduced level of contaminating surface metal is disclosed. Methods for preparing cermet inert anodes and methods for treating cermet inert anodes are also disclosed. The methods generally use an oxidizing agent to convert metals on the surface of the anode to inert oxides and/or to otherwise remove the metal contaminants. The inert anodes of the present invention may be used in electrolytic reduction cells for the production of commercial purity aluminum, as well as other metals.
摘要翻译：公开了具有降低的污染表面金属含量的金属陶瓷惰性阳极。还公开了制备金属陶瓷惰性阳极的方法和用于处理金属陶瓷惰性阳极的方法。所述方法通常使用氧化剂将阳极表面上的金属转化为惰性氧化物和/或以其它方式除去金属污染物。本发明的惰性阳极可以用于生产商业纯度的铝以及其它金属的电解还原电池中。

10. 发明授权

US6120618A Hydrocarbon phosphonic acid surface treatment that eliminates hydrogen absorption and enhances hydrogen degassing of aluminum at elevated temperatures 失效
标题翻译：烃膦酸表面处理，消除氢吸收，并在升高的温度下增强铝的脱氢
公开(公告)号：US6120618A
公开(公告)日：2000-09-19
申请号：US349665
申请日：1999-07-08
申请人： Susanne M. Opalka
发明人： Susanne M. Opalka
IPC分类号： C23C22/56 , C23C22/00
CPC分类号： C23C22/56
摘要： A method of controlling bulk absorption of atomic hydrogen and facilitating degassing of hydrogen from aluminum alloy workpieces during heat treatments in furnaces with ambient and/or moisture-laden atmospheres by exposing the surface of the workpieces to a low molecular weight solution or dispersion of an alkyl phosphonic acid, an olefinic phosphonic acid or an aryl phosphonic acid before subjecting the workpieces to heat treatments. The workpieces exposed to the phosphonic acid solution or dispersion are subjected to heat treatment in furnaces having ambient or moisture-laden atmospheres. The solution or dispersion involves chemical species that are deposited onto the aluminum surface from the phosphonic acid solution or dispersion which substantially decrease the amount of atomic hydrogen entering the bulk of the workpieces from their surfaces during heat treatment and, in addition, facilitate removal of atomic and molecular hydrogen from the bulk of the workpieces during heat treatment.
摘要翻译：通过将工件的表面暴露于低分子量溶液或烷基分散体中，控制原子氢的大量吸收并促进在具有环境和/或含水量的气氛的炉中的热处理期间从铝合金工件脱氢的方法膦酸，烯属膦酸或芳基膦酸，然后对工件进行热处理。暴露于膦酸溶液或分散体的工件在具有环境或含水量的气氛的炉中进行热处理。溶液或分散体包括从膦酸溶液或分散体沉积到铝表面上的化学物质，其在热处理期间从其表面大大减少进入大部分工件的原子氢的量，并且另外还有助于除去原子和热处理期间大部分工件的分子氢。

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