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1. 发明授权

US08123837B2 Siloxane resistant ultra violet photocatalysts 有权
标题翻译：硅氧烷耐紫外线光催化剂
公开(公告)号：US08123837B2
公开(公告)日：2012-02-28
申请号：US12227420
申请日：2006-05-15
申请人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes , Leland G. Brandes, legal representative
发明人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes
IPC分类号： B01D46/00 , A62B7/08 , B01D50/00
CPC分类号： B01D53/885 , B01D2255/20707 , B01D2255/802 , B01D2257/708 , B01D2259/4508 , B01J35/004
摘要： Deactivation resistant photocatalysts can be formulated by coating one or more photocatalyst crystals onto a suitable substrate. The photocatalyst crystals are doped with a dopant M. The dopant can be used to repel the silicon-based compound or be used to attract the silicon-based compound. The dopant can uniformly be distributed in the photocatalyst crystals. The dopant can be introduced only to photocatalyst crystals between about 0.1 to about 2 nanometers below the surface of the structure. The doped photocatalyst crystals can be interdispersed with non-doped photocatalyst crystals.
摘要翻译：可以通过将一种或多种光催化剂晶体涂覆到合适的基底上来配制灭活性光催化剂。光催化剂晶体掺杂有掺杂剂M.掺杂剂可用于排斥硅基化合物或用于吸引硅基化合物。掺杂剂可以均匀地分布在光催化剂晶体中。掺杂剂可以仅引入结构表面下约0.1至约2纳米之间的光催化剂晶体。掺杂的光催化剂晶体可以与非掺杂光催化剂晶体分散。

2. 发明申请

US20090110623A1 Siloxane Resistant Ultra Violet Photocatalysts 有权
标题翻译：硅氧烷耐紫外光催化剂
公开(公告)号：US20090110623A1
公开(公告)日：2009-04-30
申请号：US12227420
申请日：2006-05-15
申请人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes
发明人： Hongmei Wen , Thomas Henry Vanderspurt , Susanne M. Opalka , Susan D. Brandes
IPC分类号： B01D53/72 , B01D53/34
CPC分类号： B01D53/885 , B01D2255/20707 , B01D2255/802 , B01D2257/708 , B01D2259/4508 , B01J35/004
摘要： Deactivation resistant photocatalysts can be formulated by coating one or more photocatalyst crystals onto a suitable substrate. The photocatalyst crystals are doped with a dopant M. The dopant could be used to repel the silicon-based compound or be used to attract the silicon-based compound. In one embodiment, the dopant can uniformly be distributed in the photocatalyst crystals. In another embodiment, the dopant can be introduced only to photocatalyst crystals between about 0.1 to about 2 nanomenters below the surface of the structure. In another embodiment, the doped photocatalyst crystals can be interdispersed with non-doped photocatalyst crystals.
摘要翻译：可以通过将一种或多种光催化剂晶体涂覆到合适的基底上来配制灭活性光催化剂。光催化剂晶体掺杂有掺杂剂M.掺杂剂可用于排斥硅基化合物或用于吸引硅基化合物。在一个实施方案中，掺杂剂可以均匀地分布在光催化剂晶体中。在另一个实施方案中，掺杂剂可以仅引入结构表面下约0.1至约2纳姆的光催化剂晶体。在另一个实施方案中，掺杂的光催化剂晶体可以与非掺杂的光催化剂晶体分散。

3. 发明申请

US20090246091A1 AIR PURIFICATION SYSTEM 有权
标题翻译：空气净化系统
公开(公告)号：US20090246091A1
公开(公告)日：2009-10-01
申请号：US12302615
申请日：2007-05-31
申请人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
发明人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
IPC分类号： A62B7/08
CPC分类号： B01D53/885 , B01D2255/802 , B01D2259/804 , B01J23/38 , B01J35/0013 , B01J35/004
摘要： An air purification system that comprises a substrate, and at least one layer of photocatalysts. The at least one layer of photocatalysts further comprise a plurality of metal clusters.
摘要翻译：一种空气净化系统，其包括基底和至少一层光催化剂层。至少一层光催化剂还包括多个金属簇。

4. 发明授权

US09073009B2 Air purification system 有权
标题翻译：空气净化系统
公开(公告)号：US09073009B2
公开(公告)日：2015-07-07
申请号：US12302615
申请日：2007-05-31
申请人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
发明人： Thomas Henry Vanderspurt , James A. Davies , Stephen O. Hay , Timothy N. Obee , Susanne M. Opalka , Di Wei
IPC分类号： A62B7/08 , B01D53/88 , B01J23/38 , B01J35/00
CPC分类号： B01D53/885 , B01D2255/802 , B01D2259/804 , B01J23/38 , B01J35/0013 , B01J35/004
摘要： An air purification system that comprises a substrate, and at least one layer of photocatalysts. The at least one layer of photocatalysts further comprise a plurality of metal clusters.
摘要翻译：一种空气净化系统，其包括基底和至少一层光催化剂层。至少一层光催化剂还包括多个金属簇。

5. 发明授权

US07655183B2 Durable pd-based alloy and hydrogen generation membrane thereof 有权
标题翻译：耐用pd基合金及其氢生成膜
公开(公告)号：US07655183B2
公开(公告)日：2010-02-02
申请号：US11712200
申请日：2007-02-28
申请人： Raymond C. Benn , Susanne M. Opalka , Thomas Henry Vanderspurt
发明人： Raymond C. Benn , Susanne M. Opalka , Thomas Henry Vanderspurt
IPC分类号： C22C5/04 , C22C5/00 , C22C30/00 , B01J20/28 , B01J35/00
CPC分类号： C01B3/505 , B01D71/022 , B01D2325/22 , C01B2203/041 , C01B2203/047 , C01B2203/0475 , H01M8/0687
摘要： A durable Pd-based alloy is used for a H2-selective membrane in a hydrogen generator, as in the fuel processor of a fuel cell plant. The Pd-based alloy includes Cu as a binary element, and further includes “X”, where “X” comprises at least one metal from group “M” that is BCC and acts to stabilize the β BCC phase for stability during operating temperatures. The metal from group “M” is selected from the group consisting of Fe, Cr, Nb, Ta, V, Mo, and W, with Nb and Ta being most preferred. “X” may further comprise at least one metal from a group “N” that is non-BCC, preferably FCC, that enhances other properties of the membrane, such as ductility. The metal from group “N” is selected from the group consisting of Ag, Au, Re, Ru, Rh, Y, Ce, Ni, Ir, Pt, Co, La and In. The at. % of Pd in the binary Pd—Cu alloy ranges from about 35 at. % to about 55 at. %, and the at. % of “X” in the higher order alloy, based on said binary alloy, is in the range of about 1 at. % to about 15 at. %. The metals are selected according to a novel process.
摘要翻译：耐用的Pd基合金用于氢发生器中的H 2选择性膜，如在燃料电池厂的燃料处理器中。 Pd基合金包括Cu作为二元元素，并且还包括“X”，其中“X”包括至少一种B族的“M”族金属，并且用于稳定βBCC相以保持工作温度。来自组“M”的金属选自Fe，Cr，Nb，Ta，V，Mo和W，Nb和Ta是最优选的。 “X”可以进一步包含至少一种金属，其来自非BCC（优选FCC）的组“N”，其提高膜的其它性质，例如延展性。来自组“N”的金属选自Ag，Au，Re，Ru，Rh，Y，Ce，Ni，Ir，Pt，Co，La和In。在。二元Pd-Cu合金中Pd的％为约35at。％至55华氏度。％，和at。基于所述二元合金的高阶合金中的“X”的％在约1at的范围内。％至约15英寸％。根据新颖的方法选择金属。

6. 发明授权

US07612011B2 Ceria-based mixed-metal oxide structure, including method of making and use 有权
标题翻译：二氧化铈基混合金属氧化物结构，包括制造和使用的方法
公开(公告)号：US07612011B2
公开(公告)日：2009-11-03
申请号：US11605515
申请日：2006-11-28
申请人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
发明人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
IPC分类号： C01F17/00
CPC分类号： C01G27/006 , B01J23/002 , B01J23/10 , B01J23/63 , B01J23/6567 , B01J35/10 , B01J35/1019 , B01J35/1061 , B01J37/0036 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01B3/16 , C01B2203/0283 , C01B2203/044 , C01B2203/066 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01F17/0043 , C01G25/00 , C01G25/006 , C01P2002/50 , C01P2002/52 , C01P2002/60 , C01P2002/72 , C01P2002/82 , C01P2006/12 , C01P2006/14 , C01P2006/16 , Y02P20/52 , Y10T436/12 , B01J2523/3712 , B01J2523/48 , B01J2523/3706 , B01J2523/3718 , B01J2523/49 , B01J2523/375 , B01J2523/32 , B01J2523/74 , B01J2523/828 , B01J2523/56 , B01J2523/824 , B01J2523/68 , B01J2523/821 , B01J2523/3737 , B01J2523/827 , B01J2523/822
摘要： A homogeneous ceria-based mixed-metal oxide, useful as a catalyst support, a co-catalyst and/or a getter has a relatively large surface area per weight, typically exceeding 150 m2/g, a structure of nanocrystallites having diameters of less than 4 nm, and including pores larger than the nanocrystallites and having diameters in the range of 4 to about 9 nm. The ratio of pore volumes, VP, to skeletal structure volumes, VS, is typically less than about 2.5, and the surface area per unit volume of the oxide material is greater than 320 m2/cm3, for low internal mass transfer resistance and large effective surface area for reaction activity. The mixed metal oxide is ceria-based, includes Zr and or Hf, and is made by a novel co-precipitation process. A highly dispersed catalyst metal, typically a noble metal such as Pt, may be loaded on to the mixed metal oxide support from a catalyst metal-containing solution following a selected acid surface treatment of the oxide support. Appropriate ratioing of the Ce and other metal constituents of the oxide support contribute to it retaining in a cubic phase and enhancing catalytic performance. Rhenium is preferably further loaded on to the mixed-metal oxide support and passivated, to increase the activity of the catalyst. The metal-loaded mixed-metal oxide catalyst is applied particularly in water gas shift reactions as associated with fuel processing systems, as for fuel cells.
摘要翻译：可用作催化剂载体，助催化剂和/或吸气剂的均匀二氧化铈基混合金属氧化物具有相对较大的每重量的表面积，通常超过150m 2 / g，直径小于 4nm，并且包括大于纳米晶体的孔，并且具有在4至约9nm范围内的直径。孔体积VP与骨架结构体积的比率VS通常小于约2.5，并且氧化物材料的每单位体积的表面积大于320m 2 / cm 3，对于低内部传质阻力和大的有效反应活性的表面积。复合金属氧化物是二氧化铈基，包括Zr和Hf，并且通过新的共沉淀法制备。通过选择的氧化物载体的酸表面处理，可以将高度分散的催化剂金属（通常为贵金属如Pt）负载到来自含催化剂金属的溶液的混合金属氧化物载体上。 Ce和其他金属成分对氧化物载体的适当比例有助于其保持立方相并提高催化性能。优选将铼进一步负载在混合金属氧化物载体上并钝化，以提高催化剂的活性。负载金属的混合金属氧化物催化剂特别适用于燃料处理系统与燃料电池相关的水煤气变换反应。

7. 发明授权

US07166263B2 Ceria-based mixed-metal oxide structure, including method of making and use 有权
标题翻译：二氧化铈基混合金属氧化物结构，包括制造和使用的方法
公开(公告)号：US07166263B2
公开(公告)日：2007-01-23
申请号：US10402808
申请日：2003-03-28
申请人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
发明人： Thomas Henry Vanderspurt , Fabienne Wijzen , Xia Tang , Miriam P. Leffler , Rhonda R. Willigan , Caroline A. Newman , Rakesh Radhakrishnan , Fangxia Feng , Bruce Leon Laube , Zissis Dardas , Susanne M. Opalka , Ying She
IPC分类号： C01F17/00
CPC分类号： C01G27/006 , B01J23/002 , B01J23/10 , B01J23/63 , B01J23/6567 , B01J35/10 , B01J35/1019 , B01J35/1061 , B01J37/0036 , B01J37/03 , B01J2523/00 , B82Y30/00 , C01B3/16 , C01B2203/0283 , C01B2203/044 , C01B2203/066 , C01B2203/1064 , C01B2203/107 , C01B2203/1082 , C01F17/0043 , C01G25/00 , C01G25/006 , C01P2002/50 , C01P2002/52 , C01P2002/60 , C01P2002/72 , C01P2002/82 , C01P2006/12 , C01P2006/14 , C01P2006/16 , Y02P20/52 , Y10T436/12 , B01J2523/3712 , B01J2523/48 , B01J2523/3706 , B01J2523/3718 , B01J2523/49 , B01J2523/375 , B01J2523/32 , B01J2523/74 , B01J2523/828 , B01J2523/56 , B01J2523/824 , B01J2523/68 , B01J2523/821 , B01J2523/3737 , B01J2523/827 , B01J2523/822
摘要： A homogeneous ceria-based mixed-metal oxide, useful as a catalyst support, a co-catalyst and/or a getter has a relatively large surface area per weight, typically exceeding 150 m2/g, a structure of nanocrystallites having diameters of less than 4 nm, and including pores larger than the nanocrystallites and having diameters in the range of 4 to about 9 nm. The ratio of pore volumes, VP, to skeletal structure volumes, VS, is typically less than about 2.5, and the surface area per unit volume of the oxide material is greater than 320 m2/cm3, for low internal mass transfer resistance and large effective surface area for reaction activity. The mixed metal oxide is ceria-based, includes Zr and or Hf, and is made by a novel co-precipitation process. A highly dispersed catalyst metal, typically a noble metal such as Pt, may be loaded on to the mixed metal oxide support from a catalyst metal-containing solution following a selected acid surface treatment of the oxide support. Appropriate ratioing of the Ce and other metal constituents of the oxide support contribute to it retaining in a cubic phase and enhancing catalytic performance. Rhenium is preferably further loaded on to the mixed-metal oxide support and passivated, to increase the activity of the catalyst. The metal-loaded mixed-metal oxide catalyst is applied particularly in water gas shift reactions as associated with fuel processing systems, as for fuel cells.
摘要翻译：可用作催化剂载体，助催化剂和/或吸气剂的均匀的二氧化铈基混合金属氧化物具有相对较大的每重量的表面积，通常超过150m 2 / g，具有直径小于4nm的纳米晶体的结构，并且包括大于纳米微晶并且直径在4至约9nm范围内的孔。孔体积V V P与骨架结构体积V S S的比例通常小于约2.5，并且氧化物材料的每单位体积的表面积为大于320m 2 / cm 3，因为低的内部传质阻力和反应活性的大的有效表面积。复合金属氧化物是二氧化铈基，包括Zr和Hf，并且通过新的共沉淀法制备。通过选择的氧化物载体的酸表面处理，可以将高度分散的催化剂金属（通常为贵金属如Pt）负载到来自含催化剂金属的溶液的混合金属氧化物载体上。 Ce和其他金属成分对氧化物载体的适当比例有助于其保持立方相并提高催化性能。优选将铼进一步负载在混合金属氧化物载体上并钝化，以提高催化剂的活性。负载金属的混合金属氧化物催化剂特别适用于燃料处理系统与燃料电池相关的水煤气变换反应。

8. 发明申请

US20100254868A1 PURIFICATION OF A FLUID USING OZONE WITH AN ADSORBENT AND/OR A PARTICLE FILTER 审中-公开
标题翻译：使用含有吸附剂和/或颗粒过滤器的臭氧的流体的纯化
公开(公告)号：US20100254868A1
公开(公告)日：2010-10-07
申请号：US12663954
申请日：2007-06-22
申请人： Timothy N. Obee , Stephen O. Hay , Susan D. Brandes , Leland G. Brandes , Thomas Henry Vanderspurt , Wayde R. Schmidt , Norberto O. Lemcoff
发明人： Timothy N. Obee , Stephen O. Hay , Susan D. Brandes , Leland G. Brandes , Thomas Henry Vanderspurt , Wayde R. Schmidt , Norberto O. Lemcoff
IPC分类号： B01D53/38 , C02F1/78 , C02F1/42 , C02F1/32 , C02F1/30 , A62B7/08
CPC分类号： C02F1/78 , A61L9/015 , A61L9/16 , A61L9/20 , A61L9/22 , B01D53/44 , B01D2251/104 , B01D2257/708 , B01D2257/91 , B01D2259/804 , C02F1/001 , C02F1/28 , C02F1/302 , C02F1/32 , C02F2101/322 , C02F2201/3222 , C02F2303/04 , C02F2303/16 , Y02A50/235 , Y02W10/37
摘要： A system and method (60) for a purifying a fluid (such as air or water) containing contaminants includes removing the contaminants from the fluid (70) using a capturing device, such as an adsorbent and/or a particle filter. The contaminants may include volatile organic compounds (VOCs) and microorganisms. The method (60) further includes generating ozone molecules using an ozone generating device (62). An ozone decomposition device is used to decompose at least a portion of the ozone molecules into oxygen and oxygen radicals (68). The captured contaminants (VOCs and microorganisms) react with the oxygen radicals and the ozone molecules to denature the contaminants (72), rendering them less harmful than the original contaminants in the fluid. In some cases, the contaminants may be reduced to carbon dioxide and water.
摘要翻译：用于净化含有污染物的流体（例如空气或水）的系统和方法（60）包括使用诸如吸附剂和/或颗粒过滤器的捕获装置从流体（70）中除去污染物。污染物可能包括挥发性有机化合物（VOC）和微生物。方法（60）还包括使用臭氧发生装置（62）产生臭氧分子。使用臭氧分解装置将至少一部分臭氧分子分解成氧和氧自由基（68）。捕获的污染物（VOC和微生物）与氧自由基和臭氧分子反应以使污染物变性（72），使其比流体中原始污染物的危害更小。在某些情况下，污染物可能被还原成二氧化碳和水。

9. 发明申请

US20110117002A1 SYSTEMS AND METHODS FOR REMOVAL OF CONTAMINANTS FROM FLUID STREAMS 有权
标题翻译：从流体流中去除污染物的系统和方法
公开(公告)号：US20110117002A1
公开(公告)日：2011-05-19
申请号：US12302651
申请日：2007-05-31
申请人： Zissis A. Dardas , Norberto O. Lemcoff , Susan D. Brandes , Leland G. Brandes , Stephen O. Hay , Timothy N. Obee , Foster P. Lamm , Albert T. Pucino , Joseph J. Sangiovanni , Thomas Henry Vanderspurt , Wayde R. Schmidt , Treese Hugener-Campbell
发明人： Zissis A. Dardas , Norberto O. Lemcoff , Susan D. Brandes , Leland G. Brandes , Stephen O. Hay , Timothy N. Obee , Foster P. Lamm , Albert T. Pucino , Joseph J. Sangiovanni , Thomas Henry Vanderspurt , Wayde R. Schmidt , Treese Hugener-Campbell
IPC分类号： B01D53/72 , B01J8/00 , B01J19/08
CPC分类号： B01D53/0423 , B01D53/885 , B01D2255/2073 , B01D2255/20761 , B01D2255/802 , B01D2257/708 , B01D2259/4146 , B01D2259/4508 , F24F2003/1628
摘要： A contaminant removal system for selectively removing contaminants from a fluid stream. The contaminant removal system has a catalytic reactor of the type that is susceptible to deactivating agents. The catalytic reactor is configured to remove contaminants from a fluid stream. The contaminant removal system has a first adsorbent device positioned upstream, with respect to the fluid stream direction, of the catalytic reactor, that is configured to remove the deactivating agents from the fluid stream. The contaminant removal system has a second adsorbent device positioned downstream, with respect to the fluid stream direction, of the catalytic reactor. The second adsorbent device is configured to remove undesirable byproducts that may be generated when the catalytic reactor removes contaminants from the fluid stream.
摘要翻译：用于从流体流中选择性去除污染物的污染物去除系统。污染物去除系统具有对钝化剂敏感的类型的催化反应器。催化反应器构造成从流体流中除去污染物。污染物去除系统具有位于催化反应器相对于流体流方向的上游的第一吸附装置，其构造成从流体流中除去去活化剂。污染物去除系统具有位于催化反应器相对于流体流方向的下游的第二吸附装置。第二吸附装置被配置为去除当催化反应器从流体流中去除污染物时可能产生的不期望的副产物。

10. 发明授权

US08070860B2 Pd menbrane having improved H2-permeance, and method of making 有权
标题翻译：具有改善的H 2渗透性的Pd menbrane和制备方法
公开(公告)号：US08070860B2
公开(公告)日：2011-12-06
申请号：US12311294
申请日：2006-09-28
申请人： Thomas Henry Vanderspurt , Ying She , Zissis Dardas , Craig Walker , James D. MacLeod
发明人： Thomas Henry Vanderspurt , Ying She , Zissis Dardas , Craig Walker , James D. MacLeod
IPC分类号： B01D53/22 , B01D71/02 , B01D67/00 , B05D5/00
CPC分类号： C01B3/503 , B01D67/0069 , B01D69/04 , B01D69/12 , B01D71/022 , B01D71/024 , B01D2256/16 , B01D2323/42 , C01B3/505 , C01B2203/00
摘要： An H2-permeable membrane system (117) comprises an electroless-deposited plating (115) of Pd or Pd alloy on a porous support (110, 110′). The Pd plating comprises face-centered cubic crystals cumulatively having a morphology of hexagonal platelets. The permeability to H2 of the membrane plating (115) on the porous support is significantly enhanced, being at least greater than about 1.3×10−8 mol·m−1·s−·Pa−0.5 at 350° C., and even greater than about 3.4×10−8 mol·m−1·s−1·Pa−0.5. The porous support (110, 110′) may be stainless steel (1100 and include a thin ceramic interlayer (110′) on which the Pd is plated. The method of providing the electroless-deposited plating includes preheating a Pd electroless plating solution to near a plating temperature substantially greater than room temperature, e.g. 60° C., prior to plating.
摘要翻译： H 2可渗透膜系统（117）包括在多孔载体（110,110'）上的Pd或Pd合金的无电沉积电镀（115）。 Pd电镀包括面心立方晶体，累积具有六角形血小板的形态。在多孔载体上的电镀（115）的H2的渗透性显着增强，在350℃下至少大于约1.3×10 -8 mol·m -1·s·Pa-0.5，甚至大于约3.4×10-8 mol·m-1·s-1·Pa-0.5。多孔载体（110,110'）可以是不锈钢（1100，并且包括在其上镀有Pd的薄陶瓷中间层（110'）。提供无电沉积电镀的方法包括将Pd化学镀溶液预热到接近在电镀之前，电镀温度显着大于室温，例如60℃。

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