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    • 4. 发明申请
    • METHOD FOR PRODUCING SILICON WAFER AND SILICON WAFER
    • 生产硅波和硅波的方法
    • US20130093060A1
    • 2013-04-18
    • US13704905
    • 2011-06-07
    • Tetsuya OkaKoji EbaraShuji Takahashi
    • Tetsuya OkaKoji EbaraShuji Takahashi
    • H01L21/26H01L29/06
    • H01L21/26C30B15/00C30B29/06C30B33/02H01L21/3225H01L29/0684
    • A silicon wafer and method for producing a silicon wafer, including at least: a first heat treatment process in which rapid heat treatment is performed on the wafer by using a rapid heating/cooling apparatus in an atmosphere containing at least one of nitride film formation atmospheric gas, rare gas, and oxidizing gas at a temperature higher than 1300° C. and lower than or equal to a silicon melting point for 1 to 60 seconds; and a second heat treatment process in which temperature and atmosphere are controlled to suppress generation of a defect caused by a vacancy in the wafer and rapid heat treatment is performed on the wafer. Therefore, RIE defects such as oxide precipitates, COPs, and OSFs are not present at a depth of at least 1 μm from the surface, which becomes a device fabrication region, and the lifetime is 500 μsec or longer.
    • 一种硅晶片和硅晶片的制造方法,其至少包括:第一热处理工序,其中在包含氮化膜形成大气中的至少一种的气氛中使用快速加热/冷却装置在晶片上进行快速热处理 气体,稀有气体和氧化气体,温度高于1300℃,低于或等于硅熔点1〜60秒; 以及第二热处理工艺,其中控制温度和气氛以抑制由晶片空位引起的缺陷的产生,并且对晶片进行快速热处理。 因此,RIE缺陷如氧化物沉淀物,COP和OSF在距离表面至少1um的深度处不存在,其成为器件制造区域,并且寿命为500μs或更长。
    • 6. 发明授权
    • Production method for silicon epitaxial wafer and silicon epitaxial wafer
    • 硅外延晶片和硅外延晶片的生产方法
    • US06589336B1
    • 2003-07-08
    • US09889020
    • 2001-07-10
    • Koji EbaraHiroki OseYasuo Kasahara
    • Koji EbaraHiroki OseYasuo Kasahara
    • C30B2522
    • H01L21/26513H01L21/324H01L21/3247H01L21/743H01L29/0821H01L29/66272H01L29/66712H01L29/732H01L29/7809
    • Performing the post-implantation annealing for recovering crystallinity in a hydrogen atmosphere can successfully suppress the surface roughening on the ion-implanted layers without pre-implantation oxidation. This allows omission of the pre-implantation oxidation and allows ion implantation using only a photoresist film as a mask in a method for producing an epitaxial wafer having buried ion-implanted layers. Since an intentional formation of an oxide film, including such pre-implantation oxidation, on an epitaxial layer is omitted, the number of repetition of the thermal history exerted to the buried ion-implanted layers can be reduced, which effectively suppresses lateral diffusion of implanted ions. Since the formation and removal of the oxide film is thus no more necessary, the number of process steps in the production of the epitaxial wafer can dramatically be reduced.
    • 在氢气氛中进行回收结晶度的注入后退火可以成功地抑制离子注入层上的表面粗糙化而无需预植入氧化。 这允许省略预植入氧化,并且允许在用于制造具有埋入的离子注入层的外延晶片的方法中仅使用光致抗蚀剂膜作为掩模的离子注入。 由于省略了在外延层上有意形成包括这种预植入氧化的氧化膜,所以能够减少施加到掩埋离子注入层的热历程重复次数,这有效地抑制了植入物的横向扩散 离子。 由于不需要氧化膜的形成和去除,因此可以显着地减少外延晶片生产中的工艺步骤数量。
    • 7. 发明授权
    • Method for manufacturing silicon wafer and silicon wafer manufactured by this method
    • 通过该方法制造硅晶片和硅晶片的方法
    • US08377202B2
    • 2013-02-19
    • US12227907
    • 2007-05-17
    • Koji Ebara
    • Koji Ebara
    • C30B15/14
    • H01L21/3225C30B29/06C30B33/02H01L21/268H01L21/76229
    • A method for manufacturing a silicon wafer having a defect-free region in a surface layer, in which at least only a surface layer region to a predetermined depth from a front surface of a silicon wafer to be processed is subjected to heat treatment at a temperature of not less than 1100 degrees C. for not less than 0.01 msec to not more than 1 sec, to thereby make the surface layer defect-free. As a result of this, there is provided a method for manufacturing a silicon wafer, in which a DZ layer without generation of crystal defects from the front surface to a constant depth can be uniformly formed, and oxide precipitates having a steep profile inside the wafer can be secured and controlled with a high degree of accuracy.
    • 一种用于制造具有表层的无缺陷区域的硅晶片的方法,其中至少只有从待处理的硅晶片的前表面到预定深度的表面层区域在温度 不低于1100℃,不小于0.01毫秒至不超过1秒,从而使表面层无缺陷。 作为其结果,提供了一种制造硅晶片的方法,其中可以均匀地形成从前表面到恒定深度而不产生晶体缺陷的DZ层,并且在晶片内部具有陡峭轮廓的氧化物沉淀 可以高精度地固定和控制。
    • 10. 发明申请
    • Method For Manufacturing Silicon Single Crystal Wafer
    • 制造硅单晶硅片的方法
    • US20090000535A1
    • 2009-01-01
    • US12087742
    • 2006-12-21
    • Koji Ebara
    • Koji Ebara
    • C30B15/14
    • H01L21/3225C30B15/04C30B15/203C30B29/06C30B33/02
    • The present invention provides a method for manufacturing a silicon single crystal wafer by which a silicon single crystal ingot is pulled based on a Czochralski method and a rapid thermal annealing is performed with respect to a wafer that is sliced out from the silicon single crystal ingot and has a whole area in a radial direction formed of N region, wherein a heat treatment at 800 to 1100° C. as a heat treatment temperature for two hours or below as a hear treatment time is carried out after the rapid thermal annealing while adjusting the heat treatment temperature and the heat treatment time so that at least diffusion distances of vacancies as point defects injected by the rapid thermal annealing become longer than diffusion distances of the vacancies by a heat treatment performed at 800° C. for 30 minutes, thereby annihilating a vacancy type defect. As a result, there is provided the manufacturing method capable of inexpensively manufacturing a silicon wafer that can assure a DZ layer with a sufficient thickness in a wafer front surface layer region and can also assure a sufficient quantity of oxide precipitates functioning as gettering sites in a bulk region on an earlier stage of a heat treatment in a device process.
    • 本发明提供一种用于制造硅单晶晶片的方法,其中基于切克劳斯基法(Czochralski method)拉制硅单晶锭,并且相对于从硅单晶锭切片的晶片进行快速热退火,以及 具有由N区形成的沿径向的整个面积,其中在快速热退火之后进行800℃至1100℃作为处理时间的2小时以上的热处理温度的热处理,同时调整 热处理温度和热处理时间,使得至少通过快速热退火注入的点缺陷的空位的扩散距离比通过在800℃进行30分钟的热处理的空位的扩散距离变得更长,从而湮灭 空缺型缺陷。 结果,提供了能够廉价地制造硅晶片的制造方法,该硅晶片可以确保在晶片前表面层区域中具有足够厚度的DZ层,并且还可以确保足够量的作为吸收位置的氧化物沉淀物在 在装置过程中的热处理的早期阶段的大块区域。