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    • 1. 发明授权
    • Propylene-ethylene copolymer composition and process for producing the
same
    • 丙烯 - 乙烯共聚物组合物及其制备方法
    • US6005034A
    • 1999-12-21
    • US817850
    • 1997-04-30
    • Teruaki HayashidaShinei GimaKouichi HatadaOsamu KojimaKen ShimizuHirokazu NakajimaTakao NomuraYoshihiro KanomeTakeyoshi Nishio
    • Teruaki HayashidaShinei GimaKouichi HatadaOsamu KojimaKen ShimizuHirokazu NakajimaTakao NomuraYoshihiro KanomeTakeyoshi Nishio
    • C08F4/60C08F4/64C08F4/658C08F210/16C08F297/08C08L23/12C08F10/06C08F210/06
    • C08F297/083C08F210/16
    • A propylene-ethylene copolymer composition is obtained which has good moldability and an excellent balance of rigidity, toughness, and impact-strength. The composition has a melt flow rate of 10 to 300 g/10 minutes and is obtained by producing 60 to 95% by weight, based on the weight of whole polymer, of a propylene polymer having a melt flow rate (ASTM D1238) in the range of 100 to 1,000 g/10 minutes and having a ratio (Cf) of integrated values of the propylene polymer dissolved in o-dichlorobenzene at a temperature of lower than 112.degree. C., and a temperature of 112.degree. C. or higher, respectively, of 0.5 or less, by carrying out polymerization of propylene in the presence of a highly stereoregular catalyst and hydrogen in a polymerization step (I), and then producing 5 to 40% by weight, based on the weight of whole polymer, of an ethylene-propylene copolymer by feeding ethylene and propylene to the propylene polymer to react so that the content of ethylene becomes 30 to 80% by weight. Also provided is a propylene-ethylene copolymer composition comprising the composition mentioned above and a .alpha.-crystal and/or .beta.-crystal nucleator added therewith.
    • PCT No.PCT / JP96 / 02449 Sec。 371日期1997年04月30日 102(e)1997年4月30日PCT PCT 1996年8月30日PCT公布。 公开号WO97 / 08218 PCT 日期1997年3月6日获得了具有良好的成型性和刚性,韧性和冲击强度优异平衡的丙烯 - 乙烯共聚物组合物。 该组合物的熔体流动速率为10-300g / 10分钟,并且通过以全聚合物的重量计60至95重量%的丙烯聚合物的熔体流动速率(ASTM D1238)在 范围为100〜1000g / 10分钟,并且在低于112℃的温度和112℃或更高的温度下,溶解在邻二氯苯中的丙烯聚合物的积分值的比率(Cf) 分别为0.5以下,通过在聚合工序(I)中,在高度立体规则的催化剂和氢的存在下进行丙烯的聚合,然后以全聚合物的重量为基准计5〜40重量% 通过将乙烯和丙烯进料至丙烯聚合物进行反应以使乙烯含量为30至80重量%的乙烯 - 丙烯共聚物。 还提供了包含上述组合物和加入其中的α-结晶和/或β-晶核成核剂的丙烯 - 乙烯共聚物组合物。
    • 5. 发明授权
    • Polypropylene resin composition
    • 聚丙烯树脂组合物
    • US5621046A
    • 1997-04-15
    • US499908
    • 1995-07-11
    • Kunio IwanamiMasatoshi OhkuraSatoshi UekiShigeyuki TokiTakeyoshi NishioTakao Nomura
    • Kunio IwanamiMasatoshi OhkuraSatoshi UekiShigeyuki TokiTakeyoshi NishioTakao Nomura
    • C08K7/14C08L23/08C08L23/12C08L23/16C08L53/00C08L23/00
    • C08L23/12C08K7/14C08L2205/03C08L2205/035C08L23/0815C08L23/16C08L53/00
    • A polypropylene resin composition including (A) 50-90 parts by weight of a polypropylene resin including (a) 3-30 weight % of stereoblock polypropylene having a weight-average molecular weight of 5,000-1,000,000, a percentage of five continuous propylene monomer units in which all propylene bonds are meso bonds and a percentage of five continuous propylene monomer units in which all propylene bonds are racemic bonds being 70% or more and 5% or more, respectively relative to the all propylene bonds, and (b) 70-97 weight % of an ultra-high stereospecific polypropylene having a melt flow rate of 0.1-1,000 g/10 minutes, an average meso chain length Nm calculated from a triad percentage determined from .sup.13 C-NMR spectrum by the following formula of Nm=2[mm]/[mr]+1, wherein [mm] is (isotactic triad/total triad).times.100 (%) and [mr] is (heterotactic triad/total triad).times.100 (%), meeting a relation of Nm>250+29.5 log (MFR), and (B) 50-10 parts by weight of an olefinic rubber and/or a polyolefin other than (A).
    • 一种聚丙烯树脂组合物,其包含(A)50-90重量份的聚丙烯树脂,其包含(a)3-30重量%的重均分子量为5,000-1,000,000的立构嵌段聚丙烯,五个连续丙烯单体单元的百分比 其中所有丙烯键均为内消旋键,其中所有丙烯键为外消旋键的五个连续丙烯单体单元的百分比相对于全部丙烯键分别为70%以上且5%以上,(b)70〜 97重量%的熔体流动速率为0.1-1,000g / 10分钟的超高立体定向聚丙烯,由根据13 C-NMR光谱由下式Nm / 2确定的三单元组百分比计算的平均内消旋链长度Nm: mm] / [mr] +1,其中[mm]为(全同立构三单元组/总三元组)×100(%),[mr]为(异质三单元组/总三元组)×100(%),满足Nm> 29.5log(MFR)和(B)50-10重量份的烯烃橡胶和/或其它聚烯烃 比(A)。