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    • 4. 发明授权
    • Polypropylene-base resin composition and products of injection molding thereof
    • 聚丙烯基树脂组合物及其注射成型品
    • US06441081B1
    • 2002-08-27
    • US09555826
    • 2000-07-11
    • Hajime SadatoshiKenichi OhkawaSusumu KanzakiHisayuki IwaiTakao NomuraShoichi Ichikawa
    • Hajime SadatoshiKenichi OhkawaSusumu KanzakiHisayuki IwaiTakao NomuraShoichi Ichikawa
    • C08K334
    • C08L23/12C08F297/083C08L23/0815C08L23/10C08L23/16C08L53/00C08L2666/04C08L2666/24C08L2666/02
    • A polypropylene resin composition which comprises: (1) 55 to 75% by weight of (A) a polypropylene resin consisting of a mixture of the following polymers (i) and (ii): (i) a propylene-ethylene block copolymer having a propylene homopolymer part which is the first segment and having a propylene-ethylene random copolymer part which is the second segment and (ii) a propylene homopolymer having an intrinsic viscosity [&eegr;]P of 0.8 to 1.8 dl/g as measured in tetralin at 135° C., (2) 21 to 30% by weight of (B) an ethylene-1-octene copolymer rubber having a melt flow rate (JIS-K-6758 at 190° C.) of 2 to 10 g/10 min and having a 1-octene component content of 20 to 25% by weight, and (3) 5 to 20% by weight of (C) talc having an average particle diameter of not more than 3 &mgr;m, wherein when the amount of the second segment contained in the propylene-ethylene block copolymer of the polypropylene resin (A) is designated as (A)′ and the ethylene-1-octene copolymer rubber content is designated as (B)′, the following expression is satisfied: 0.10≦{(A)′/[(A)′+(B)′]}≦0.30, and when the above composition is subjected to a tensile test according to ASTM D638, it exhibits, an ultimate elongation of at least 400%, and the melt flow rate (JIS-K-6758 at 230° C.) of the composition is at least 30 g/10 min, and an injection-molded article obtained by injection molding the above polypropylene resin composition.
    • 一种聚丙烯树脂组合物,其包含:(1)55至75重量%的(A)由以下聚合物(i)和(ii)的混合物组成的聚丙烯树脂:(i)丙烯 - 乙烯嵌段共聚物,其具有 丙烯均聚物部分,其是第一链段并且具有作为第二链段的丙烯 - 乙烯无规共聚物部分和(ii)在135℃下在四氢化萘中测得的特性粘度ηP为0.8至1.8dl / g的丙烯均聚物 (2)熔体流动速率(JIS-K-6758,190℃)的(B)乙烯-1-辛烯共聚物橡胶的21〜30重量%为2〜10g / 10分钟 并且具有20至25重量%的1-辛烯组分含量,和(3)5至20重量%的(C)平均粒径不大于3μm的滑石,其中当第二 包含在聚丙烯树脂(A)的丙烯 - 乙烯嵌段共聚物中的链段被称为(A)',乙烯-1-辛烯共聚物橡胶含量指定为(B)', 满足以下表达式:当根据ASTM D638对上述组合物进行拉伸试验时,其表现出至少400%的极限伸长率和熔体流动速率(JIS-K-6758在230℃) )为30g / 10分钟以上,注射成型上述聚丙烯树脂组合物得到的注射成型体。
    • 5. 发明授权
    • Polypropylene resin composition
    • 聚丙烯树脂组合物
    • US5621046A
    • 1997-04-15
    • US499908
    • 1995-07-11
    • Kunio IwanamiMasatoshi OhkuraSatoshi UekiShigeyuki TokiTakeyoshi NishioTakao Nomura
    • Kunio IwanamiMasatoshi OhkuraSatoshi UekiShigeyuki TokiTakeyoshi NishioTakao Nomura
    • C08K7/14C08L23/08C08L23/12C08L23/16C08L53/00C08L23/00
    • C08L23/12C08K7/14C08L2205/03C08L2205/035C08L23/0815C08L23/16C08L53/00
    • A polypropylene resin composition including (A) 50-90 parts by weight of a polypropylene resin including (a) 3-30 weight % of stereoblock polypropylene having a weight-average molecular weight of 5,000-1,000,000, a percentage of five continuous propylene monomer units in which all propylene bonds are meso bonds and a percentage of five continuous propylene monomer units in which all propylene bonds are racemic bonds being 70% or more and 5% or more, respectively relative to the all propylene bonds, and (b) 70-97 weight % of an ultra-high stereospecific polypropylene having a melt flow rate of 0.1-1,000 g/10 minutes, an average meso chain length Nm calculated from a triad percentage determined from .sup.13 C-NMR spectrum by the following formula of Nm=2[mm]/[mr]+1, wherein [mm] is (isotactic triad/total triad).times.100 (%) and [mr] is (heterotactic triad/total triad).times.100 (%), meeting a relation of Nm>250+29.5 log (MFR), and (B) 50-10 parts by weight of an olefinic rubber and/or a polyolefin other than (A).
    • 一种聚丙烯树脂组合物,其包含(A)50-90重量份的聚丙烯树脂,其包含(a)3-30重量%的重均分子量为5,000-1,000,000的立构嵌段聚丙烯,五个连续丙烯单体单元的百分比 其中所有丙烯键均为内消旋键,其中所有丙烯键为外消旋键的五个连续丙烯单体单元的百分比相对于全部丙烯键分别为70%以上且5%以上,(b)70〜 97重量%的熔体流动速率为0.1-1,000g / 10分钟的超高立体定向聚丙烯,由根据13 C-NMR光谱由下式Nm / 2确定的三单元组百分比计算的平均内消旋链长度Nm: mm] / [mr] +1,其中[mm]为(全同立构三单元组/总三元组)×100(%),[mr]为(异质三单元组/总三元组)×100(%),满足Nm> 29.5log(MFR)和(B)50-10重量份的烯烃橡胶和/或其它聚烯烃 比(A)。
    • 8. 发明授权
    • Polypropylene resin composition
    • 聚丙烯树脂组合物
    • US5883174A
    • 1999-03-16
    • US680971
    • 1996-07-16
    • Tomohiko AkagawaIkunori SakaiSaburo HinenoyaYasuo KitaKaoru InoueTakeyoshi NishioTakao Nomura
    • Tomohiko AkagawaIkunori SakaiSaburo HinenoyaYasuo KitaKaoru InoueTakeyoshi NishioTakao Nomura
    • C08K3/34C08L23/16C08L53/00C08J5/10C08L23/12
    • C08L53/00
    • A polypropylene resin composition having excellent rigidity, impact resistance and formability (moldability) and thus useful for the interior parts of automobile, includes (A) a crystalline E/P block copolymer containing a fraction Ac soluble in p-xylene at room temperature and having an ethylene content of 18 to 22%; (B) a crystalline E/P block copolymer containing a fraction Bc soluble in p-xylene at room temperature and having an ethylene content of 27 to 40% and (C) talc particles having an average size of 3 to 5 .mu.m and largest size less than 20 .mu.m, in which composition, (a) the p-xylene-soluble fractions Ac and Bc are in contents As and Bs based on the total weight of the copolymers (A) and (B) and satisfying As+Bs=7 to 17% by weight and As/(A +Bs)=0.1 to 0.6; (b) an isotactic pentad fraction of propylene in each of copolymers (A) and (B) is 96% or more, and the mixture of the copolymers (A) and (B) has a MFR of 20 to 35 g/10 min at 230.degree. C. under 2160 g load; and (c) the copolymers (A) and (B) are in a total weight content of 50 to 95% and talc (C) is in a weight content of 5 to 50%.
    • 具有优异的刚性,耐冲击性和成型性(成型性),因此可用于汽车内部的聚丙烯树脂组合物包括(A)在室温下含有可溶于对二甲苯的馏分Ac的结晶E / P嵌段共聚物,并具有 乙烯含量为18〜22%; (B)在室温下含有可溶于对二甲苯的馏分Bc,乙烯含量为27〜40%的结晶性E / P嵌段共聚物,(C)平均粒径为3〜5μm的滑石粉末和最大 (a)对二甲苯可溶级分Ac和Bc的含量为A,Bs为基于共聚物(A)和(B)的总重量,满足As + Bs = 7〜17重量%,As /(A + Bs)= 0.1〜0.6; (b)共聚物(A)和(B)中的丙烯的全同立构五单元组分率为96%以上,共聚物(A)和(B)的混合物的MFR为20〜35g / 10分钟 在230℃,2160g负荷下; 和(c)共聚物(A)和(B)的总重量含量为50-95%,滑石(C)的重量含量为5-50%。