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    • 1. 发明授权
    • Polypropylene resin composition
    • 聚丙烯树脂组合物
    • US5621046A
    • 1997-04-15
    • US499908
    • 1995-07-11
    • Kunio IwanamiMasatoshi OhkuraSatoshi UekiShigeyuki TokiTakeyoshi NishioTakao Nomura
    • Kunio IwanamiMasatoshi OhkuraSatoshi UekiShigeyuki TokiTakeyoshi NishioTakao Nomura
    • C08K7/14C08L23/08C08L23/12C08L23/16C08L53/00C08L23/00
    • C08L23/12C08K7/14C08L2205/03C08L2205/035C08L23/0815C08L23/16C08L53/00
    • A polypropylene resin composition including (A) 50-90 parts by weight of a polypropylene resin including (a) 3-30 weight % of stereoblock polypropylene having a weight-average molecular weight of 5,000-1,000,000, a percentage of five continuous propylene monomer units in which all propylene bonds are meso bonds and a percentage of five continuous propylene monomer units in which all propylene bonds are racemic bonds being 70% or more and 5% or more, respectively relative to the all propylene bonds, and (b) 70-97 weight % of an ultra-high stereospecific polypropylene having a melt flow rate of 0.1-1,000 g/10 minutes, an average meso chain length Nm calculated from a triad percentage determined from .sup.13 C-NMR spectrum by the following formula of Nm=2[mm]/[mr]+1, wherein [mm] is (isotactic triad/total triad).times.100 (%) and [mr] is (heterotactic triad/total triad).times.100 (%), meeting a relation of Nm>250+29.5 log (MFR), and (B) 50-10 parts by weight of an olefinic rubber and/or a polyolefin other than (A).
    • 一种聚丙烯树脂组合物,其包含(A)50-90重量份的聚丙烯树脂,其包含(a)3-30重量%的重均分子量为5,000-1,000,000的立构嵌段聚丙烯,五个连续丙烯单体单元的百分比 其中所有丙烯键均为内消旋键,其中所有丙烯键为外消旋键的五个连续丙烯单体单元的百分比相对于全部丙烯键分别为70%以上且5%以上,(b)70〜 97重量%的熔体流动速率为0.1-1,000g / 10分钟的超高立体定向聚丙烯,由根据13 C-NMR光谱由下式Nm / 2确定的三单元组百分比计算的平均内消旋链长度Nm: mm] / [mr] +1,其中[mm]为(全同立构三单元组/总三元组)×100(%),[mr]为(异质三单元组/总三元组)×100(%),满足Nm> 29.5log(MFR)和(B)50-10重量份的烯烃橡胶和/或其它聚烯烃 比(A)。
    • 3. 发明授权
    • Olefin polymerization catalyst
    • OLEFIN聚合催化剂
    • US5223465A
    • 1993-06-29
    • US776350
    • 1991-11-18
    • Satoshi UekiHiroyuki FuruhashiMasahide MurataShigeyuki Toki
    • Satoshi UekiHiroyuki FuruhashiMasahide MurataShigeyuki Toki
    • C08F4/64C08F4/642C08F10/00C08F12/04
    • C08F10/00C08F12/04
    • The present invention aims at providing an olefin polymerization catalyst comprising, as a component, a transition metal compound having two ligands such as .beta.-diketone, etc. coordinated, and having excellent properties as a polymerization catalyst in the polymerization of olefins including styrene compounds. This olefin polymerization catalyst comprises:(a) a transition metal compound represented by the general formula, ##STR1## wherein M represents titanium, zirconium, hafnium or vanadium, Y.sup.1 and Y.sup.2 each represent, same or different, halogen atoms or alkyl groups containing 1 to 10 carbon atoms and R.sup.1, R.sup.2 and R.sup.3 each represent hydrogen atoms or hydrocarbon groups containing 1 to 10 carbon atoms, at least one of which is a hydrogen atom but all of which must not be hydrogen atoms, and(b) an organoaluminum compound, in particular, aluminoxane.
    • PCT No.PCT / JP91 / 00345 Sec。 371日期1991年11月18日 102(e)1991年11月18日日期PCT 1991年3月13日PCT PCT。 出版物WO91 / 日本1991年9月19日。本发明旨在提供一种烯烃聚合催化剂,其包含作为组分的具有两个配位体如β-二酮等的配位的过渡金属化合物,并且具有优异的作为聚合催化剂的性能 烯烃聚合包括苯乙烯化合物。 该烯烃聚合催化剂包括:(a)由通式表示的过渡金属化合物,其中M表示钛,锆,铪或钒,Y1和Y2各自表示相同或不同的卤原子或含1个 至10个碳原子,R 1,R 2和R 3各自表示氢原子或含有1至10个碳原子的烃基,其中至少一个为氢原子,但全部不能为氢原子,(b)有机铝化合物 ,特别是铝氧烷。