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1. 发明授权

US5035934A Adhesive sheet for preventing icing 失效
标题翻译：用于防止结冰的粘合片
公开(公告)号：US5035934A
公开(公告)日：1991-07-30
申请号：US436997
申请日：1989-11-15
申请人： Takeshi Tomiyama , Sadaaki Hashimoto , Heihachi Murase
发明人： Takeshi Tomiyama , Sadaaki Hashimoto , Heihachi Murase
IPC分类号： B32B27/08 , C07C265/00 , C08G18/28 , C08G18/61 , C08G18/62 , C08G18/71 , C08G18/77 , C08L27/12 , C08L87/00 , C09J7/02 , C09K3/18
CPC分类号： C08G18/289 , C08G18/6279 , C08G18/718 , C08G18/778 , C09J7/025 , C09J2205/114 , C09J2427/006 , C09J2451/006 , C09J2475/006 , C09J2483/006 , Y10T428/1429 , Y10T428/3154 , Y10T428/31544
摘要： Disclosed is an adhesive sheet for preventing icing, the sheet being characterized in that the sheet comprises a release sheet (1), a pressure-sensitive adhesive layer (2) formed on the sheet (1), a base sheet (3) adhered to the layer (2) and an anti-icing layer (4) formed on the base sheet (3) and that the anti-icing layer (4) is formed from a composition (A) or a composition (B), the composition (A) consisting essentially of:(a) a copolymer having hydroxyl, or hydroxyl and other reactive group and comprising an essential monomer components a fluoroolefin and a vinyl monomer having hydroxyl and copolymerizable with the fluoroolefin,(b) a silicone compound represented by the formula ##STR1## wherein n is an integer of 6 to 300, k is an integer of 0 to 6, h is 0 or 1, m is an integer of 0 to 6, j is 1 or 2, and Y is hydroxyl, carboxyl, epoxy, or a monovalent or bivalent groups containing one or two free isocyanate groups, and(c) a polyisocyanate compound, and the composition (B) consisting essentially of:(d) a graft copolymer prepared by reacting the component (a) and the component (b), and(c) the polyisocyanate compound.
摘要翻译：公开了一种用于防止结冰的粘合片，其特征在于，片材包括剥离片（1），形成在片材（1）上的压敏粘合剂层（2），粘合到片材所述层（2）和形成在所述基片（3）上的防冰层（4）和所述防结冰层（4）由组合物（A）或组合物（B）形成，所述组合物（ A）基本上由以下组成：（a）具有羟基或羟基和其它反应性基团并且包含必需单体组分的共聚物，其中氟烯烃和具有羟基的乙烯基单体和可与氟烯烃共聚的乙烯基单体，（b）由式（I）其中n为6〜300的整数，k为0〜6的整数，h为0或1，m为0〜6的整数，j为1或2，Y为羟基，羧基，环氧基或含有一个或两个游离异氰酸酯基团的一价或二价基团，和（c）多异氰酸酯化合物，组合物（B）c 主要包括：（d）通过使组分（a）和组分（b）反应制备的接枝共聚物，和（c）多异氰酸酯化合物。

2. 发明授权

US5445871A Surface-modified plastic plate 失效
标题翻译：表面改性塑料板
公开(公告)号：US5445871A
公开(公告)日：1995-08-29
申请号：US279066
申请日：1994-07-22
申请人： Heihachi Murase , Tsutomu Norimatsu , Masao Ogawa , Naoya Haruta
发明人： Heihachi Murase , Tsutomu Norimatsu , Masao Ogawa , Naoya Haruta
IPC分类号： C08J7/04 , B32B7/02
CPC分类号： C08J7/045 , C08J7/047 , C08J2483/00 , Y10T428/2495 , Y10T428/24967 , Y10T428/265 , Y10T428/31504 , Y10T428/31507 , Y10T428/31612 , Y10T428/31663 , Y10T428/31667
摘要： A surface-modified plastic plate for use in optical disc bases, windows of aircrafts, automobiles or of architectural structures, solar cell receptors, liquid crystal display panels and protective sheet of computer touch panels, which comprises a laminate consisting of a plastic substrate; a cured film of an actinic ray-curable primer composition, said cured film formed onto a surface of the plastic substrate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.1 .mu.m or more but less than 1.0 .mu.m; and a surface-modified plastic plate for use in windows, preferably windows of aircrafts, automobiles and architectural structures, which comprises a laminate consisting of a plastic plate, preferably comprising a plastic selected from polymethyl methacrylate polymer and polycarbonate in the case of the window of the aircraft; a cured film of a heat-curable primer composition, said cured film being formed on a surface of the plastic plate in a film thickness of 0.1 to 10 .mu.m; and an inorganic material layer formed onto the cured film by a physical deposition process and having a thickness of 0.25 .mu.m or more but less than 1.0 .mu.m.
摘要翻译：用于光盘基座，飞机窗口，汽车或建筑结构的表面改性塑料板，太阳能电池接收器，液晶显示面板和计算机触摸面板的保护片，其包括由塑料基板组成的层压板; 光固化性底漆组合物的固化膜，所述固化膜形成在塑料基板的表面上，膜厚为0.1〜10μm; 以及通过物理沉积工艺形成在固化膜上并具有0.1μm以上且小于1.0μm的厚度的无机材料层; 以及用于窗户，优选飞机，汽车和建筑结构的窗户的表面改性塑料板，其包括由塑料板组成的层压板，该塑料板优选地包括选自聚甲基丙烯酸甲酯聚合物和聚碳酸酯的塑料，在窗口飞机; 热固性底漆组合物的固化膜，所述固化膜形成在所述塑料板的表面上，膜厚度为0.1-10μm; 以及通过物理沉积工艺在固化膜上形成的厚度为0.25μm以上且小于1.0μm的无机材料层。

3. 发明授权

US4246368A Powder coating compositions for forming multi layer coatings 失效
标题翻译：用于形成多层涂层的粉末涂料组合物
公开(公告)号：US4246368A
公开(公告)日：1981-01-20
申请号：US903260
申请日：1978-05-05
申请人： Heihachi Murase
发明人： Heihachi Murase
IPC分类号： C09D5/46 , C09D157/00 , C08L63/00 , C08L33/06 , C08L33/14 , C08L67/00
CPC分类号： C09D157/00 , Y10S524/904 , Y10S525/934
摘要： A powder coating composition for forming multi layer coatings comprising:(1) at least one of finely divided thermosetting addition copolymers having a glass transition temperature of 35.degree. to 75.degree. C. and comprising as comonomers a wt. % of a hardness imparting monomer and b wt. % of a softness imparting monomer based on the copolymer wherein a+b.ltoreq.60, b.ltoreq.a and b.ltoreq.20, and(2) at least one of finely divided thermosetting resinous materials having incompatibility or low compatibility with the copolymer and a substantially greater surface tension than the copolymer when melted at the same temperature and substantially differing from the copolymer in composite parameter.
摘要翻译：一种用于形成多层涂层的粉末涂料组合物，包括：（1）至少一种细分热固性加成共聚物，其玻璃化转变温度为35-75℃，并且包含共聚单体wt％％的硬度赋予单体和bwt。％的基于共聚物的柔软性赋予单体，其中a +b≤60，b≤a和b≤20，和（2）至少一种细分散的热固性树脂材料，其具有不相容性或与该共聚物和当在相同温度下熔融并且与复合参数中的共聚物基本不同时，共聚物具有显着更大的表面张力。

4. 发明授权

US5196487A Corrosion preventive resin and photopolymerizable composition incorporating same 失效
标题翻译：腐蚀预防性树脂和合成化合物的光热可塑组合物
公开(公告)号：US5196487A
公开(公告)日：1993-03-23
申请号：US712279
申请日：1991-06-10
申请人： Hideo Kogure , Heihachi Murase , Naozumi Iwasawa
发明人： Hideo Kogure , Heihachi Murase , Naozumi Iwasawa
IPC分类号： C07F7/18 , C08F2/46 , C08F299/00 , C09D5/08 , C09D183/07 , C09D183/08
CPC分类号： C07F7/1836 , C08F299/00 , C09D183/08 , C09D5/08
摘要： A corrosion preventive resin having in the molecule at least one chelate forming group selected from among groups represented by the formula ##STR1## wherein R.sup.1 and R.sup.2 are the same or different and are each a hydrogen atom or alkyl having 1 to 8 carbon atoms, and groups represented by teh general formula ##STR2## wherein R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are the same or different and are each a hydrogen atom, alkyl having 1 to 8 carbon atoms or a group forming a bivalent o-phenylene group along with two carbon atoms attached thereto. A photopolymerizable composition which includes (a) a resin having in the molecule at least one mole of polymerizable double bond per 1000 g of the resin and having per molecule at least one chelate forming group selected from among the groups represented by formula (II) and formula (III), and (b) a photopolymerization initiator is also disclosed.
摘要翻译：一种防腐树脂，其在分子中具有至少一种螯合形成基团，其选自由式（I）表示的基团，其中R 1和R 2相同或不同，各自为氢原子或具有1至8个碳原子的烷基原子和由通式（II）表示的基团，其中R 3，R 4，R 5和R 6相同或不同，各自为氢原子，具有1至8个碳原子的烷基或形成二价o- 亚苯基以及与其连接的两个碳原子。一种可光聚合组合物，其包含（a）分子中每1000克所述树脂具有至少1摩尔可聚合双键并且每分子具有选自式（II）表示的基团中的至少一种螯合形成基团和式（III）和（b）光聚合引发剂也被公开。

5. 发明授权

US4636324A Anti-icing compositions 失效
标题翻译：防冰组合物
公开(公告)号：US4636324A
公开(公告)日：1987-01-13
申请号：US712724
申请日：1985-03-18
申请人： Heihachi Murase , Kiyoshi Nanishi
发明人： Heihachi Murase , Kiyoshi Nanishi
IPC分类号： C09D183/04 , C09K3/18 , C09D5/20
CPC分类号： C09D183/04 , C08K3/0075 , C08K5/01 , C08K5/09
摘要： The present invention provides: a composition for use in preventing the formation of ice comprising (A) organopolysiloxane, (B) alkali metal compound and (C) liquid or solid paraffin; a method for preventing the formation of ice by applying the composition to the surface of an object; and another method for preventing the formation of ice by applying a primer containing a silane coupling agent to the surface of an object and applying the composition to the primer coat formed.
摘要翻译：本发明提供：用于防止形成冰的组合物，其包含（A）有机聚硅氧烷，（B）碱金属化合物和（C）液体或固体石蜡; 一种通过将组合物施用到物体的表面来防止形成冰的方法; 以及另一种通过将含有硅烷偶联剂的底漆施用到物体表面并将组合物施加到所形成的底漆涂层来防止形成冰的方法。

6. 发明授权

US4305994A Process for forming multilayer coating 失效
标题翻译：多层涂层成型工艺
公开(公告)号：US4305994A
公开(公告)日：1981-12-15
申请号：US177509
申请日：1980-08-12
申请人： Heihachi Murase
发明人： Heihachi Murase
IPC分类号： B05D3/10 , C09D5/46 , B05D1/36
CPC分类号： B05D3/102 , B05D3/10 , B05D7/54 , B05D2202/00 , B05D2451/00 , Y10T428/31529 , Y10T428/31678 , Y10T428/31681
摘要： In a process for forming a multilayer coated film which comprises coating a multilayer coat-forming paint on the surface of a substrate to form a multilayer coated film thereon, the improvement wherein prior to the coating, the surface of the substrate is treated with a solution containing at least one onium compound selected from compounds of formulae (I) and (II) below ##STR1## wherein Y represents a nitrogen, phosphorus or arsenic atom, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are identical or different and each represents a hydrogen atom or an organic group having not more than 8 carbon atoms, and X.sub..crclbar. represents an anion.
摘要翻译：在形成多层涂膜的方法中，其包括在基材表面上涂覆多层涂层涂料以在其上形成多层涂膜，其改进在于，在涂布之前，用溶液处理基材表面含有至少一种选自下述式（I）和（II）的化合物的鎓化合物，其中Y表示氮，磷或砷原子，R 1，R 2，R 3和R 4相同或不同，各自表示氢原子或不大于8个碳原子的有机基团，X（ - ）表示阴离子。

7. 发明授权

US6114446A Polymer composition capable of forming surface slidable on water 失效
标题翻译：能够形成表面在水上滑动的聚合物组合物
公开(公告)号：US6114446A
公开(公告)日：2000-09-05
申请号：US331760
申请日：1999-06-25
申请人： Ikuo Narisawa , Makoto Takeishi , Heihachi Murase
发明人： Ikuo Narisawa , Makoto Takeishi , Heihachi Murase
IPC分类号： C08F8/30 , C08F8/42 , C08F14/18 , C08G77/14 , C08G77/442 , C08L27/12 , C08L83/08 , C09D127/12 , C09D183/10
CPC分类号： C09D183/10 , C08F8/30 , C08F8/42 , C08G77/442 , C08L27/12 , C09D127/12 , C08L83/08
摘要： The present invention relates to a polymer composition capable of forming a super-hydrophobic surface which is difficult to be wetted with water and from which an adhered waterdrop can easily slide down comprising(A) a reaction product formed by a reaction of(a) a hydroxyl group-containing fluoropolymer obtained by copolymerizing a fluoroolefin, a hydroxyl group-containing vinyl monomer and another unsaturated monomer capable of coploymerizing with them,(b) an epoxy-terminated siloxane polymer represented by the formula ##STR1## wherein m is a number of 6-300 and n is a number of 0-6, at the equivalent ratio of the hydroxyl groups of the fluoropolymer (a) to the epoxy groups of the siloxane polymer (b) of 1/0.05 to 1/0.8, in the presence of(c) a sulphonic acid compound, and(B) a polyisocyanate compound, which may be blocked, or a melamine type crosslinking agent.
摘要翻译： PCT No.PCT / JP97 / 04739 Sec。 371日期1999年6月25日第 102（e）1999年6月25日PCT 1997年12月22日PCT PCT。第WO98 / 29505号公报日期：1998年7月9日本发明涉及一种能够形成疏水性表面的聚合物组合物，其难以用水润湿，并且粘附的水滴容易从其中滑落，包括（A）通过反应形成的反应产物（a）通过使氟代烯烃，含羟基的乙烯基单体和能够与其共聚合的另一种不饱和单体共聚获得的含羟基的含氟聚合物，（b）由下式表示的环氧基封端的硅氧烷聚合物，其中m是数量为6-300，n为0-6，以含氟聚合物（a）的羟基与硅氧烷聚合物（b）的环氧基的当量比为1 / 0.05〜1 / 0.8，在（c）磺酸化合物的存在，和（B）可被封闭的多异氰酸酯化合物或三聚氰胺型交联剂。

8. 发明授权

US5443900A Electromagnetic wave absorber 失效
标题翻译：电磁波吸收器
公开(公告)号：US5443900A
公开(公告)日：1995-08-22
申请号：US115252
申请日：1993-09-01
申请人： Toshiaki Nagano , Heihachi Murase , Hideo Kogure
发明人： Toshiaki Nagano , Heihachi Murase , Hideo Kogure
IPC分类号： H01Q17/00 , H05K9/00 , B32B5/16
CPC分类号： H05K9/0088 , H01Q17/00 , Y10T428/12535 , Y10T428/12556 , Y10T428/12562 , Y10T428/12569 , Y10T428/26 , Y10T428/265 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699
摘要： An electromagnetic wave absorber comprising at least one of a unit film as a multilayered film comprising a resin layer (A) optionally containing a pigment and a layer (B) applied onto the resin layer (A), selected from a group consisting of a metal layer, an alloy layer and a partly oxidized layer of the metal layer or the alloy layer, and having a film thickness of 1 nm to 50 nm.
摘要翻译：一种电磁波吸收体，包括作为多层膜的单位膜中的至少一种，其包含任选地含有颜料的树脂层（A）和施加到树脂层（A）上的层（B），所述层（B）选自金属层，合金层和金属层或合金层的部分氧化层，并且具有1nm至50nm的膜厚度。

9. 发明授权

US5281449A Method of forming pattern coatings based on a radiation curable composition which contains a resin having both thioether and carboxyl groups 失效
标题翻译：基于含有具有硫醚和羧基的树脂的可辐射固化组合物形成图案涂层的方法
公开(公告)号：US5281449A
公开(公告)日：1994-01-25
申请号：US742232
申请日：1991-08-08
申请人： Naozumi Iwasawa , Hideo Kogure , Heihachi Murase
发明人： Naozumi Iwasawa , Hideo Kogure , Heihachi Murase
IPC分类号： G03F7/027 , G03F7/028 , G03F7/031 , G03F7/038 , G03F7/075 , H01L21/027 , H05K3/00 , B05D3/06 , G03C1/705
CPC分类号： G03F7/038 , H05K3/0076
摘要： The invention provides a method for forming a pattern coating, the method including the steps of:applying to a substrate a radiation curable composition containing a resin (a) which contains, per kilogram of said resin (a) about 1.5 to about 4.5 moles of a polyermizable unsaturated group, about 0.4 to about 2.5 moles of a carboxyl group and 0.2 to about 3.5 moles of a thioether group, the resin having a number average molecular weight of about 500 to about 50,000; selectively irradiating a portion of the applied coating with actinic rays; and subjecting the coating to development with an alkali aqueous solution.
摘要翻译：本发明提供一种形成图案涂层的方法，该方法包括以下步骤：向基材施加含有树脂（a）的可辐射固化组合物，该树脂（a）每千克所述树脂（a）含有约1.5至约4.5摩尔约0.4至约2.5摩尔的羧基和0.2至约3.5摩尔的硫醚基团，所述树脂的数均分子量为约500至约50,000; 用光化射线选择性地照射所涂敷的涂层的一部分; 并用碱性水溶液对涂层进行显影。

10. 发明授权

US06403225B1 Article superior in slipping waterdrops down surface thereof 失效
标题翻译：文章在其水滴下滑的表面优越
公开(公告)号：US06403225B1
公开(公告)日：2002-06-11
申请号：US09438146
申请日：1999-11-10
申请人： Ikuo Narisawa , Makoto Takeishi , Heihachi Murase , Toshihiro Takekawa , Yasuaki Kai , Tetsuro Tayu
发明人： Ikuo Narisawa , Makoto Takeishi , Heihachi Murase , Toshihiro Takekawa , Yasuaki Kai , Tetsuro Tayu
IPC分类号： B32B1706
CPC分类号： C03C17/009 , B32B17/10018 , B32B17/10165 , B32B17/10688 , Y10T428/31612 , Y10T428/31663
摘要： The invention relates to an article superior in slipping a waterdrop down a surface of the article. The article has a substrate; and a functional layer formed on a surface of the substrate. The functional layer is chemically bonded to the surface of the substrate through siloxane-bonding. The article is prepared by a method including: (a) dissolving in a solvent (1) a silicone that is one of a first silicone having at an end a hydrolyzable functional group and a second silicone having at an end a hydrolyzable functional group and at the other end a fluoroalkyl group, (2) an acid, and (3) water, thereby to prepare a mixed liquid; (b) applying the mixed liquid to the surface of the substrate, thereby to form thereon a precursory layer; and (c) drying the precursory layer into the functional layer. In the preparation of the article, a silica precursor sol is optionally added to the mixed liquid. Alternatively, a combination of a silica precursor sol and a fluoroalkylsilane having at its end a hydrolyzable functional group is optionally added to the mixed liquid. Furthermore, an underlayer made from a hydrolyzable silicon compound may be provided between the substrate and the functional layer.
摘要翻译：本发明涉及一种将水滴从制品的表面滑下来的优点。该物品具有底物; 以及形成在所述基板的表面上的功能层。功能层通过硅氧烷键化学键合到基板的表面。该制品通过以下方法制备：（a）将溶剂（1）溶解在作为末端具有可水解官能团的第一硅酮中的硅酮和末端具有可水解官能团的第二硅酮，另一端为氟烷基，（2）酸和（3）水，由此制备混合液; （b）将混合液体施加到基板的表面，由此在其上形成前兆层; 和（c）将前体层干燥成功能层。在制品中，任选地将二氧化硅前体溶胶加入到混合液中。或者，任选地将二氧化硅前体溶胶和其末端具有可水解官能团的氟代烷基硅烷的组合加入到混合液中。此外，可以在基板和功能层之间设置由可水解硅化合物制成的底层。

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