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1. 发明授权

US4636324A Anti-icing compositions 失效
标题翻译：防冰组合物
公开(公告)号：US4636324A
公开(公告)日：1987-01-13
申请号：US712724
申请日：1985-03-18
申请人： Heihachi Murase , Kiyoshi Nanishi
发明人： Heihachi Murase , Kiyoshi Nanishi
IPC分类号： C09D183/04 , C09K3/18 , C09D5/20
CPC分类号： C09D183/04 , C08K3/0075 , C08K5/01 , C08K5/09
摘要： The present invention provides: a composition for use in preventing the formation of ice comprising (A) organopolysiloxane, (B) alkali metal compound and (C) liquid or solid paraffin; a method for preventing the formation of ice by applying the composition to the surface of an object; and another method for preventing the formation of ice by applying a primer containing a silane coupling agent to the surface of an object and applying the composition to the primer coat formed.
摘要翻译：本发明提供：用于防止形成冰的组合物，其包含（A）有机聚硅氧烷，（B）碱金属化合物和（C）液体或固体石蜡; 一种通过将组合物施用到物体的表面来防止形成冰的方法; 以及另一种通过将含有硅烷偶联剂的底漆施用到物体表面并将组合物施加到所形成的底漆涂层来防止形成冰的方法。

2. 发明授权

US5032641A Water-repellent film-forming composition 失效
标题翻译：防水成膜组合物
公开(公告)号：US5032641A
公开(公告)日：1991-07-16
申请号：US380595
申请日：1989-06-26
申请人： Kiyoshi Nanishi , Hideo Kogure , Heihachi Murase
发明人： Kiyoshi Nanishi , Hideo Kogure , Heihachi Murase
IPC分类号： C08L33/16 , C08L43/04 , C09D133/16 , C09D143/04
CPC分类号： C09D133/16 , C09D143/04 , C08L33/16 , C08L43/04
摘要： A water-repellant film-forming composition comprisinga mixture of(a) a (co)polymer of 5 to 100% by weight of a specific fluoroalkyl group-containing (meth)acrylic monomer and 0 to 95% by weight of an unsaturated monomer co-polymerizable with the fluoroalkyl group-containing (meth)acrylic monomer, and(b) a copolymer of 0.1 to 75% by weight of a specific silicon-containing polymerizable unsaturated monomer and 25 to 99.9% by weight of an unsaturated monomer copolymerizalbe with the silicon-containing polymerizable unsaturated monomer, andfine silica particles having an average particle diameter of not more than 5 micrometers, in specified amounts.

3. 发明授权

US4910252A Siloxane polymer antifouling paint composition containing polysiloxanes 失效
标题翻译：含硅氧烷的硅氧烷聚合物防污漆组合物
公开(公告)号：US4910252A
公开(公告)日：1990-03-20
申请号：US232537
申请日：1988-08-15
申请人： Yoiti Yonehara , Kiyoshi Nanishi
发明人： Yoiti Yonehara , Kiyoshi Nanishi
IPC分类号： C08L83/04 , C09D5/16 , C09D143/04
CPC分类号： C09D5/1668 , C09D143/04 , C08L83/04
摘要： An antifouling paint composition comprising as a film-forming component a vinyl-type copolymer obtained by copolymerization of(A) 1 to 50% by weight of a specific polymerizable unsaturated polysiloxane compound,(B) 0 to 30% by weight of a specific polymerizable unsaturated alkoxysilane compound, and(C) 20 to 99% by weight of a polymerizable unsaturated vinyl monomer other than the compounds (A) and (B) above.
摘要翻译：一种防污涂料组合物，其包含作为成膜组分的乙烯基类共聚物，其通过（A）1〜50重量％的特定的聚合性不饱和聚硅氧烷化合物，（B）0〜30重量％的特定的可聚合的不饱和烷氧基硅烷化合物，（C）20〜99重量％的上述化合物（A）和（B）以外的聚合性不饱和乙烯基单体。

4. 发明授权

US5218059A Non-toxic antifouling coating composition 失效
标题翻译：无毒防污涂料组合物
公开(公告)号：US5218059A
公开(公告)日：1993-06-08
申请号：US662821
申请日：1991-03-01
申请人： Masato Kishihara , Kiyoshi Nanishi , Yoichi Yonehara
发明人： Masato Kishihara , Kiyoshi Nanishi , Yoichi Yonehara
IPC分类号： C09D5/14 , C09D5/16 , C09D183/04
CPC分类号： C09D5/1675 , C09D183/04
摘要： A non-toxic antifouling coating composition containing 50 to 99% by weight as the resin solid content of (A) a reaction-curable silicone resin composition and 1 to 50% by weight a solid content of (B) a silicone resin having an average molecular weight of 250 to 30,000, a viscosity of 20 to 50,000 centistokes and alkoxy group at its molecular terminal, and represented by the general formula (I): ##EQU1## where R is hydrogen atom, alkyl group having 1-10 carbon atoms, aryl group or aralkyl group, R.sup.1 is bivalent aliphatic hydrocarbon group having 1-10 carbon atoms, which may be bonded directly or through ether group, ester group or --NH--group, R.sup.2 is lower alkyl group having 1-6 carbon atoms, X and Y are represented respectively as 0.01.ltoreq.X
摘要翻译：作为（A）可反应固化性硅酮树脂组合物的树脂固体成分含有50〜99重量％的无毒性防污涂料组合物和1〜50重量％的固体成分（B）具有平均值的有机硅树脂分子量为250〜30,000，其分子末端的粘度为20〜50,000厘沲和烷氧基，并由通式（I）表示：其中R是氢原子，具有1-10个碳原子，芳基或芳烷基，R1是可以直接或通过醚基，酯基或-NH-基团键合的具有1-10个碳原子的二价脂族烃基，R2是具有1-6个碳原子的低级烷基原子，X和Y分别表示为0.01≤X<4.0,0.01≤y≤4.0且0.02≤X+ Y <4。

5. 发明授权

US4908061A Antifouling coating 失效
标题翻译：防污涂料
公开(公告)号：US4908061A
公开(公告)日：1990-03-13
申请号：US245391
申请日：1988-08-30
申请人： Kiyoshi Nanishi , Hiroyuki Nakayama
发明人： Kiyoshi Nanishi , Hiroyuki Nakayama
IPC分类号： C09D5/16
CPC分类号： C09D5/1625 , Y10S428/907
摘要： Disclosed is an antifouling coating which contains a phosphorus nitride compound and/or a halogenated phosphorus nitride compound and a coating resin as the major components, and which is non-toxic and has excellent long-term antifouling properties when coated on underwater substrates, for example, underwater structures such as ships, fishing nets, and the like.
摘要翻译：公开了一种防污涂料，其包含氮化磷化合物和/或卤化氮化物化合物和涂料树脂作为主要成分，并且是无毒的并且当涂覆在水下基材上时具有优异的长期防污性能，例如，水下结构如船舶，渔网等。

6. 发明授权

US4486280A Self-curing modified epoxy resin composition and aqueous dispersion thereof 失效
标题翻译：自固化改性环氧树脂组合物及其水分散体
公开(公告)号：US4486280A
公开(公告)日：1984-12-04
申请号：US508564
申请日：1983-06-28
申请人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara , Shigenori Egusa , Kiyoshi Nanishi
发明人： Fumio Hosoi , Takashi Sasaki , Miyuki Hagiwara , Shigenori Egusa , Kiyoshi Nanishi
IPC分类号： C08G59/00 , C08F2/52 , C08F283/10 , C08G59/02 , C08G59/17 , C08G59/40 , C08L63/00 , C08L63/10
CPC分类号： C08F283/10
摘要： A self-curing epoxy resin composition is, herein, disclosed produced by irradiating with an electron beam a mixture of 85 to 97 wt % of an epoxy resin and 3 to 15 wt % of a quaternary alkyl ammonium salt of .alpha.,.beta.-unsaturated carboxylic acid or a neutralized product of an .alpha.,.beta.-unsaturated carboxylic acid and a tertiary amine.
摘要翻译：本文公开了一种自固化环氧树脂组合物，其通过用电子束照射85-97重量％的环氧树脂和3-15重量％的α，β-不饱和羧酸的季烷基铵盐，酸或α，β-不饱和羧酸和叔胺的中和产物。

7. 发明授权

US4291137A One-pack high solid coating composition 失效
标题翻译：一包高固体涂料组合物
公开(公告)号：US4291137A
公开(公告)日：1981-09-22
申请号：US71795
申请日：1979-08-31
申请人： Yasushi Nakate , Hiroshi Iwai , Kiyoshi Nanishi
发明人： Yasushi Nakate , Hiroshi Iwai , Kiyoshi Nanishi
IPC分类号： C08L33/00 , C08G12/42 , C08L33/02 , C08L33/04 , C08L61/00 , C08L61/20 , C09D133/04 , C09D133/08 , C08L63/00
CPC分类号： C08G12/42 , C09D133/08 , C08L61/20
摘要： A one-pack high solid coating composition consisting essentially of (I) 100 parts by weight of an acrylic resin which is a copolymer having a glass transition temperature of -21.degree. to -50.degree. C. and a hydroxyl number of 40 to 280 and being prepared from (a) one or more members selected from hydroxyalkyl acrylates and methacrylates of the general formula ##STR1## wherein R is a hydrogen atom or a methyl group and R.sub.1 is a divalent alkyl group having 2 to 5 carbon atoms, and (b) one or more members selected from alkyl acrylates and methacrylates of the general formula ##STR2## wherein R is as defined above and R.sub.2 is a monovalent alkyl group having 1 to 12 carbon atoms, and glycidyl acrylates and methacrylates of the general formula ##STR3## wherein R is as defined above and R.sub.3 is a divalent alkyl group having 1 to 5 carbon atoms, (II) 20 to 160 parts by weight of an amino-formaldehyde resin etherified with a monohydric alcohol having 1 to 4 carbon atoms, and (III) 0.5 to 6 parts by weight, per 100 parts by weight of the total of the acrylic resin as component (I) and the etherified amino-formaldehyde resin as component (II) combined, of a blocked acid catalyst, said amount of the blocked acid catalyst being expressed in the amount of its acid.
摘要翻译：一种单组分高固体涂料组合物，其基本上由（I）100重量份的丙烯酸树脂组成，该丙烯酸树脂是玻璃化转变温度为-21℃至-50℃，羟值为40至280的共聚物，以及由（a）选自丙烯酸羟烷基酯和通式为“IMAGE”的甲基丙烯酸酯的一种或多种成分制备，其中R是氢原子或甲基，R 1是具有2至5个碳原子的二价烷基，和（b ）一种或多种选自通式“IMAGE”的丙烯酸烷基酯和甲基丙烯酸烷基酯的成员，其中R如上所定义，R 2是具有1至12个碳原子的一价烷基，以及通式为“IMAGE”的丙烯酸缩水甘油酯和甲基丙烯酸酯，其中R如上定义，R 3是具有1至5个碳原子的二价烷基，（II）20至160重量份用醚化的具有1至4个碳原子的一元醇的氨基甲醛树脂和（III ）0.5〜6重量份，作为组分（I）的丙烯酸树脂和作为组分（II）的醚化氨基甲醛树脂的合并的100重量份的封闭的酸催化剂，所述封闭的酸催化剂的量以它的酸。

8. 发明授权

US5990191A Granular carrier for immobilizing microbial cells and apparatus for producing the granular carrier 失效
标题翻译：用于固定微生物细胞的颗粒载体和用于生产颗粒载体的装置
公开(公告)号：US5990191A
公开(公告)日：1999-11-23
申请号：US77330
申请日：1998-05-27
申请人： Makoto Kikuta , Hitoshi Izumida , Kiyoshi Nanishi , Toshirou Hirama
发明人： Makoto Kikuta , Hitoshi Izumida , Kiyoshi Nanishi , Toshirou Hirama
IPC分类号： C08F251/00 , C08F290/06 , C12N11/04 , C12N11/10 , C08J3/14
CPC分类号： C12N11/04 , C08F251/00 , C08F290/06 , C08F290/062 , C12N11/10
摘要： A microorganism cells-immobilizing granular carrier and its manufacturing system.Said microorganism cells-immobilizing granular carrier, which has a specific gravity of 1.00 to 1.20, and which has a contact angle of 2.degree. to 30.degree. formed between the carrier surface and n-paraffin, and which has a surface suitable for the attachment of a microorganism, is obtained by dripping a liquid composition containing a hydrophilic photo-curable resin having (a) at least two ethylenically-unsaturated bonds in one molecule, (b) photopolymerization initiator, and (c) water-soluble macromolecular polysaccharide capable of gelatinizing through contact with alkaline metal ions or polyvalent metal ions, into an aqueous medium containing alkaline metal ions or polyvalent metal ions to gelatinize the composition; and irradiating the composition with ultraviolet radiation so as to harden said composition.
摘要翻译： PCT No.PCT / JP96 / 03439 Sec。 371日期：1998年5月27日 102（e）日期1998年5月27日PCT 1996年11月22日PCT PCT。公开号WO97 / 19978 日期1997年6月5日微生物细胞固定颗粒载体及其制造系统。在载体表面和正链烷烃之间形成的具有比重为1.00〜1.20的接触角为2〜30°的所述微生物细胞固定型粒状载体，其具有适于附着的表面通过在一分子中滴加含有（a）至少两个烯键式不饱和键的亲水性光固化性树脂的液体组合物，（b）光聚合引发剂和（c）能够凝胶化的水溶性高分子多糖，通过与碱金属离子或多价金属离子接触进入含有碱金属离子或多价金属离子的水性介质中使凝胶化; 并用紫外线照射组合物以使所述组合物硬化。

9. 发明授权

US5426135A Composition for forming soil preventing coating 失效
标题翻译：防止涂层的成分
公开(公告)号：US5426135A
公开(公告)日：1995-06-20
申请号：US177934
申请日：1994-01-06
申请人： Osamu Isozaki , Kiyoshi Nanishi , Hisashi Isaka
发明人： Osamu Isozaki , Kiyoshi Nanishi , Hisashi Isaka
IPC分类号： C08F8/42 , C08F8/46 , C08G77/442 , C09D5/16 , C09D135/00 , C09D183/06 , C09D183/10 , C09D201/08 , C09D201/10
CPC分类号： C08G77/442 , C08F8/42 , C08F8/46 , C09D135/00 , C09D183/06 , C09D183/10 , C09D201/08 , C09D201/10 , C09D5/165
摘要： The present invention provides a soil preventing coating forming composition which consists essentially of a resin having at least two acid anhydride groups in the molecule on the average, the acid anhydride groups being represented by the formula ##STR1## wherein R is a C.sub.1-40 monovalent hydrocarbon group or a monovalent chain polysiloxane group represented by the formula ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and are each alkyl, cycloalkyl, aryl, aralkyl or ##STR3## group, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are the same or different and are each alkyl, cycloalkyl, aryl or aralkyl, n is an integer of 1 to 6, m is an integer of 0 or 1, p is an integer of 2 to 50, and q is an integer of 0 to 50.
摘要翻译：本发明提供一种防污涂层形成组合物，其基本上由分子中具有至少两个酸酐基团的树脂组成，平均酸酐基由式碳基团表示，或由式式（II）其中R 1和R 2相同或不同并且各自为烷基，环烷基，芳基，芳烷基或者基团，R 3，R 4，R 5，R 6和R 7相同或不同，各自为烷基，环烷基，芳基或芳烷基，n为1〜6的整数，m为0或1的整数，p为2〜50的整数，q为0〜50的整数。

10. 发明授权

US4221683A Low temperature curing high solid coating composition 失效
标题翻译：低温固化高固体涂料组合物
公开(公告)号：US4221683A
公开(公告)日：1980-09-09
申请号：US886898
申请日：1978-03-15
申请人： Yasusi Nakate , Hiroshi Iwai , Kiyoshi Nanishi
发明人： Yasusi Nakate , Hiroshi Iwai , Kiyoshi Nanishi
IPC分类号： C08L61/20 , C09D133/06 , C09D161/20 , C08L33/14 , C08L61/32
CPC分类号： C09D133/066 , C09D161/20 , C08L61/20
摘要： A low temperature curing high solid coating composition which comprises: (I) acrylic resin having a glass transition temperature of 20.degree. to -50.degree. C. and a hydroxyl value of 40 to 280, which is obtained by copolymerizing the monomer mixture comprising (a) acrylic ester and/or methacrylic ester, and if necessary, (b) acrylic acid or methacrylic acid, (II) amino-formaldehyde resin which is etherified with a monohydric alcohol, (III) an acid catalyst, and if necessary, (IV) cellulose derivatives and/or (V) metallic coordination compounds of titanium, zirconium and/or aluminium.The coating composition of the invention is characterized in that it has a high solid content and is cured at a low temperature and the obtained coating film has quite excellent properties of durability, hardness and chemical resistance.
摘要翻译：一种低温固化高固体涂料组合物，其包含：（I）玻璃化转变温度为20〜-50℃，羟基值为40〜280的丙烯酸树脂，其通过使包含（a ）丙烯酸酯和/或甲基丙烯酸酯，如果需要，（b）丙烯酸或甲基丙烯酸，（II）与一元醇醚化的氨基甲醛树脂，（III）酸催化剂，如果需要，（IV ）纤维素衍生物和/或（V）钛，锆和/或铝的金属配位化合物。本发明的涂料组合物的特征在于其固体含量高，在低温下固化，所得涂膜具有相当优异的耐久性，硬度和耐化学性能。

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