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    • 2. 发明授权
    • Water and oil repellent composition
    • 防水防油组成
    • US06716944B2
    • 2004-04-06
    • US10317991
    • 2002-12-13
    • Takashige MaekawaMinako ShimadaShuichiro SugimotoRyuji Seki
    • Takashige MaekawaMinako ShimadaShuichiro SugimotoRyuji Seki
    • C08F11800
    • C09K3/18
    • A water and oil repellent composition which can impart an excellent water and oil repellency to an object, even if it is processed at a low temperature, and which can achieve a water and oil repellent treatment providing a soft hand. The water and oil repellent composition which has as an essential component a copolymer consisting essentially of polymerized units of the following monomer (a) and polymerized units of the following monomer (b). monomer (a): an Rf monomer wherein the melting point of fine crystals derived from the Rf groups of the homopolymer does not exist or is at most 50° C. monomer (b): a monomer having no Rf group, wherein the melting point of fine crystals derived from the side chains of the homopolymer is at least 30° C.
    • 即使在低温下进行处理也能够使物品具有优异的拒水拒油性的斥水斥油剂组合物,能够实现提供软手的拒水拒油处理。 具有以下单体(a)的聚合单元和以下单体(b)单体的聚合单元共聚物作为基本组分的斥水斥油剂组合物。单体(a):R f单体,其中 衍生自均聚物的R f基团的细晶体的熔点不存在或至多为50℃。单体(b):不具有R f基团的单体,其中衍生的细晶体的熔点 来自均聚物的侧链为至少30℃
    • 9. 发明申请
    • COPOLYMER, METHOD FOR ITS PRODUCTION, AND WATER/OIL REPELLENT COMPOSITION
    • 共聚物,其生产方法和水/油组合物
    • US20110071248A1
    • 2011-03-24
    • US12958906
    • 2010-12-02
    • Kazunori SugiyamaToyomichi ShimadaNobuyuki OtozawaYuuichi OomoriMinako Shimada
    • Kazunori SugiyamaToyomichi ShimadaNobuyuki OtozawaYuuichi OomoriMinako Shimada
    • C08F214/18C08L27/12C08F220/24
    • C08F214/18C08F214/202C08F214/222C08F216/1408C08F220/26C08F220/36C08F220/58C08F222/10C08F2220/1891C08F214/08
    • To provide a copolymer which is capable of providing an article surface with a dynamic water repellency and which has extremely excellent washing durability of water repellency and oil repellency, while placing little burden on the environment; a method for its production; and a water/oil repellent composition.A copolymer comprising structural units of the monomer (a) and structural units of the monomer (b), wherein the total of the content of structural units based on the monomer (a) and the content of structural units based on the monomer (b) is at least 85 mass % of all structural units (100 mass %), and the molar ratio ((a)/(b)) of the content of structural units based on the monomer (a) to the content of structural units based on the monomer (b) is from 0.12 to 3; and a water/oil repellent composition containing such a copolymer. Monomer (a): a compound represented by (Z—Y)n—X, wherein Z is a C1-6 polyfluoroalkyl group or the like, Y is a bivalent organic group or a single bond, n is 1 or 2, and when n is 1, and X is a polymerizable unsaturated group. Monomer (b): a halogenated olefin.
    • 为了提供一种共聚物,其能够提供具有动态拒水性的物品表面,并且在环境上施加很小的负担的情况下具有非常优异的防水性和拒油性的洗涤耐久性。 一种生产方法; 和斥水斥油剂组合物。 包含单体(a)的结构单元和单体(b)的结构单元的共聚物,其中基于单体(a)的结构单元的含量和基于单体(b)的结构单元的含量的总和 基于单体(a)的结构单元的含量与基于单体(a)的结构单元的含量相比,所有结构单元(100质量%)的至少85质量%和结构单元的含量((a)/(b) 单体(b)为0.12〜3; 和含有这种共聚物的斥水斥油剂组合物。 单体(a):由(Z-Y)n -X表示的化合物,其中Z为C1-6多氟烷基等,Y为二价有机基团或单键,n为1或2,当 n为1,X为可聚合不饱和基团。 单体(b):卤代烯烃。