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1. 发明授权

US06872324B2 Aqueous dispersion 有权
标题翻译：水分散体
公开(公告)号：US06872324B2
公开(公告)日：2005-03-29
申请号：US10354034
申请日：2003-01-30
申请人： Takashige Maekawa , Minako Shimada , Ryuji Seki , Taiki Hoshino
发明人： Takashige Maekawa , Minako Shimada , Ryuji Seki , Taiki Hoshino
IPC分类号： C08F2/24 , C08F36/04 , C08K5/00 , C09D133/06 , C09D133/16 , C09K3/18 , D06M15/21 , D06M15/256 , D06M15/263 , D06M15/277 , C14C9/00 , C08F136/16 , C08F236/16 , D06M15/347
CPC分类号： D06M15/21 , C08K5/0008 , C09D133/06 , C09D133/16 , C09K3/18 , D06M15/256 , D06M15/263 , D06M15/277 , D06M2200/11 , D06M2200/12 , C08L33/16
摘要： An aqueous dispersion comprising a polymer (a) having a repeating unit (A) which comprises four carbon atoms connected in a linear chain and which has one double bond at the second position and a polyfluoroalkyl group bonded to an arbitrary carbon atom, and a surfactant (B) having a hydrophile-lipophile balance of at least 10, wherein the polymer (a) is dispersed in an aqueous medium by the surfactant (B).
摘要翻译：一种水分散体，其包含具有重复单元（A）的聚合物（a），所述重复单元（A）包含连接在直链上且在第二位置具有一个双键的四个碳原子和与任意碳原子键合的多氟烷基，表面活性剂（B）具有至少10的亲水 - 亲油平衡，其中聚合物（a）通过表面活性剂（B）分散在水性介质中。

2. 发明授权

US08609795B2 Water and oil repellent composition 有权
标题翻译：防水防油组成
公开(公告)号：US08609795B2
公开(公告)日：2013-12-17
申请号：US11940577
申请日：2007-11-15
申请人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
发明人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
IPC分类号： C08F118/00
CPC分类号： D06M15/256 , C08F218/08 , C08F220/18 , C08F220/22 , C08F220/24 , C08F220/34 , C08F220/36 , C08F230/08 , C09K3/18 , D06M15/263 , D06M2200/00 , D06M2200/11 , D06M2200/12 , D06M2200/50
摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.
摘要翻译：具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。作为必要成分的防水斥油剂组合物，其含有含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：含有Rf基的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自Rf基团的微晶，玻璃化转变点至少为20℃。单体（b）：不具有Rf基团的单体并具有可交联的官能团。

3. 发明授权

US06716944B2 Water and oil repellent composition 有权
标题翻译：防水防油组成
公开(公告)号：US06716944B2
公开(公告)日：2004-04-06
申请号：US10317991
申请日：2002-12-13
申请人： Takashige Maekawa , Minako Shimada , Shuichiro Sugimoto , Ryuji Seki
发明人： Takashige Maekawa , Minako Shimada , Shuichiro Sugimoto , Ryuji Seki
IPC分类号： C08F11800
CPC分类号： C09K3/18
摘要： A water and oil repellent composition which can impart an excellent water and oil repellency to an object, even if it is processed at a low temperature, and which can achieve a water and oil repellent treatment providing a soft hand. The water and oil repellent composition which has as an essential component a copolymer consisting essentially of polymerized units of the following monomer (a) and polymerized units of the following monomer (b). monomer (a): an Rf monomer wherein the melting point of fine crystals derived from the Rf groups of the homopolymer does not exist or is at most 50° C. monomer (b): a monomer having no Rf group, wherein the melting point of fine crystals derived from the side chains of the homopolymer is at least 30° C.
摘要翻译：即使在低温下进行处理也能够使物品具有优异的拒水拒油性的斥水斥油剂组合物，能够实现提供软手的拒水拒油处理。具有以下单体（a）的聚合单元和以下单体（b）单体的聚合单元共聚物作为基本组分的斥水斥油剂组合物。单体（a）：R f单体，其中衍生自均聚物的R f基团的细晶体的熔点不存在或至多为50℃。单体（b）：不具有R f基团的单体，其中衍生的细晶体的熔点来自均聚物的侧链为至少30℃

4. 发明申请

US20050267241A1 Water and oil repellent composition 审中-公开
标题翻译：防水防油组成
公开(公告)号：US20050267241A1
公开(公告)日：2005-12-01
申请号：US11106641
申请日：2005-04-15
申请人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
发明人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
IPC分类号： C09K3/18 , C08F18/20
CPC分类号： D06M15/256 , C08F218/08 , C08F220/18 , C08F220/22 , C08F220/24 , C08F220/34 , C08F220/36 , C08F230/08 , C09K3/18 , D06M15/263 , D06M2200/00 , D06M2200/11 , D06M2200/12 , D06M2200/50
摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.
摘要翻译：具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水防油处理。作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。

5. 发明申请

US20080076862A1 WATER AND OIL REPELLENT COMPOSITION 有权
标题翻译：水和油组合物
公开(公告)号：US20080076862A1
公开(公告)日：2008-03-27
申请号：US11940577
申请日：2007-11-15
申请人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
发明人： Shuichiro Sugimoto , Minako Shimada , Toyomichi Shimada , Ryuji Seki , Takashige Maekawa
IPC分类号： C08F18/20
CPC分类号： D06M15/256 , C08F218/08 , C08F220/18 , C08F220/22 , C08F220/24 , C08F220/34 , C08F220/36 , C08F230/08 , C09K3/18 , D06M15/263 , D06M2200/00 , D06M2200/11 , D06M2200/12 , D06M2200/50
摘要： A water and oil repellent composition having excellent durability, which can impart excellent water and oil repellency to an object, even in a process at low temperatures, and which enables water and oil repellent treatment providing a soft hand. A water and oil repellent composition which comprises, as an essential component, a copolymer containing polymerization units of the following monomer (a) and polymerization units of the following monomer (b): monomer (a): an Rf group-containing monomer which forms a photopolymer having no melting point or a melting point of at most 55° C. attributable to fine crystals derived from the Rf groups and having a glass transition point of at least 20° C. monomer (b): a monomer having no Rf group and having a cross-linkable functional group.
摘要翻译：具有优异的耐久性的防油斥油剂组合物，即使在低温下也能赋予物体优异的拒水拒油性，能够提供柔软的防水和防油处理。作为必要成分的防油斥油剂组合物，含有下述单体（a）的聚合单元和下述单体（b）的聚合单元的共聚物：单体（a）：R f 含有基团的单体，其形成不含熔点或熔点至多55℃的光聚合物，归因于衍生自R f F基团的微晶，玻璃化转变点为至少20℃单体（b）：不具有R f F基团且具有可交联官能团的单体。

6. 发明授权

US07485688B2 Water and oil producing composition 有权
标题翻译：防水防油组成
公开(公告)号：US07485688B2
公开(公告)日：2009-02-03
申请号：US11524918
申请日：2006-09-22
申请人： Takashige Maekawa , Shuichiro Sugimoto , Minako Shimada , Kyouichi Kaneko , Harutaka Naruse , Yuuichi Nakajima
发明人： Takashige Maekawa , Shuichiro Sugimoto , Minako Shimada , Kyouichi Kaneko , Harutaka Naruse , Yuuichi Nakajima
IPC分类号： C08F118/00
CPC分类号： D06M15/263 , C08F214/18 , C08L27/00 , C08L35/00 , C09D133/00 , D06M15/267 , D06M15/27 , D06M15/277 , D06M15/333 , D06M15/3568 , D06M2200/11 , D06M2200/12 , D21H19/20 , D21H21/16 , C08L2666/06
摘要： The present invention provides a water and oil proofing composition which imparts excellent water and oil resistance and comprises a fluorocopolymer comprising polymerized units of (Z-Y)nX (wherein Z: a C1-6 perfluoroalkyl group or the like, Y: an alkylene group or the like, n: 1 or 2, X: a polymerizable unsaturated group), polymerized units of CH2═CR1-G-(R2O)q—R3 (wherein R1: a hydrogen atom or the like, R2: a C2-4 alkylene group or the like, q: an integer of from 1 to 50, G: —COO(CH2)r— (r: an integer of from 0 to 4), R3: a hydrogen atom or the like, and polymerized units of CH2═CR4-M-Q-NR5R6 (wherein R4: a hydrogen atom or the like, Q: a C2-4 alkylene group or the like, R5 and R6: C1-8 alkyl groups or the like) and an aqueous medium.
摘要翻译：本发明提供一种具有优异耐水耐油性的防油防油组合物，其含有含有（ZY）nX（其中Z：C1-6全氟烷基等）的聚合单元的含氟共聚物，Y：亚烷基或类似于n：1或2，X：可聚合不饱和基团），CH2-CR1-G-（R2O）q-R3的聚合单元（其中R1：氢原子等，R2：C2-4亚烷基 q：1〜50的整数，G：-COO（CH 2）r - （r：0〜4的整数），R 3：氢原子等， CR4-MQ-NR5R6（其中R4：氢原子等，Q：C2-4亚烷基等，R5和R6：C1-8烷基等）和水性介质。

7. 发明申请

US20070015867A1 Water and oil producing composition 有权
标题翻译：防水防油组成
公开(公告)号：US20070015867A1
公开(公告)日：2007-01-18
申请号：US11524918
申请日：2006-09-22
申请人： Takashige Maekawa , Shuichiro Sugimoto , Minako Shimada , Kyouichi Kaneko , Harutaka Naruse , Yuuichi Nakajima
发明人： Takashige Maekawa , Shuichiro Sugimoto , Minako Shimada , Kyouichi Kaneko , Harutaka Naruse , Yuuichi Nakajima
IPC分类号： C08L27/12
CPC分类号： D06M15/263 , C08F214/18 , C08L27/00 , C08L35/00 , C09D133/00 , D06M15/267 , D06M15/27 , D06M15/277 , D06M15/333 , D06M15/3568 , D06M2200/11 , D06M2200/12 , D21H19/20 , D21H21/16 , C08L2666/06
摘要： The present invention provides a water and oil proofing composition which imparts excellent water and oil resistance. A composition which comprises a fluorocopolymer comprising polymerized units of (Z-Y)nX (wherein Z: a C1-6 perfluoroalkyl group or the like, Y: an alkylene group or the like, n: 1 or 2, X: a polymerizable unsaturated group), polymerized units of CH2═CR1-G-(R2O)q—R3 (wherein R1: a hydrogen atom or the like, R2: a C2-4 alkylene group or the like, q: an integer of from 1 to 50, G: —COO(CH2)r— (r: an integer of from 0 to 4), R3: a hydrogen atom or the like) and polymerized units of CH2═CR4-M-Q-NR5R6 (wherein R4: a hydrogen atom or the like, Q: a C2-4 alkylene group or the like, R5 and R6: C1-8 alkyl groups or the like) and an aqueous medium.
摘要翻译：本发明提供赋予耐油和耐油性优异的防油防油组合物。一种组合物，其包含含有（ZY）N X的聚合单元的含氟共聚物（其中Z：C 1-6烷基全氟烷基等，Y：亚烷基或类似物，n = 1或2，X为可聚合不饱和基团），CH 2 2 -CR 1 -G-（R 2）2的聚合单元，其中R 1是氢原子等，R 2，R 2，R 3，R 3，：C 2-4亚烷基等，q：1〜50的整数，G：-COO（CH 2）2，（R：0〜4的整数），R 3，氢原子等）和CH 2的基团的聚合单元 4其中R 4为氢原子等，Q为C 1 -C 6烷基，亚> 2-4个亚烷基等，R 5和R 6：C 1-8烷基或类似物）和水性介质。

8. 发明授权

US06860926B2 Fluorine-containing compound, and water and oil repellent composition 失效
标题翻译：含氟化合物，防水防油组合物
公开(公告)号：US06860926B2
公开(公告)日：2005-03-01
申请号：US09976435
申请日：2001-10-15
申请人： Minako Ishikawa , Takashige Maekawa , Ryuji Seki , Shoji Furuta , Kazuya Oharu
发明人： Minako Ishikawa , Takashige Maekawa , Ryuji Seki , Shoji Furuta , Kazuya Oharu
IPC分类号： C03C17/28 , C03C17/32 , C03C25/24 , C03C25/26 , C07C69/62 , C07C69/63 , C07C311/09 , C09K3/18 , D06M13/236 , D06M15/277 , C07C311/24
CPC分类号： D06M15/277 , C03C17/28 , C03C17/32 , C03C25/25 , C03C25/26 , C07C69/62 , C07C69/63 , C07C311/09 , C09K3/18 , D06M13/236 , D06M2200/10 , D06M2200/11 , D06M2200/12
摘要： The following fluorine-containing compound is presented which is capable of providing dry soil resistance when incorporated to a water and oil repellent.Rf1R2OCOCH2CHR1COOR3Rf2 (wherein each of Rf1 and Rf2 which are independent of each other, is a C3-22 polyfluoroalkyl group, R1 is a hydrogen atom or a C1-10 alkyl group, and each of R2 and R3 which are independent of each other, is a C1-4 alkylene group, etc.).
摘要翻译：提供以下含氟化合物，其在掺入拒水拒油剂时能够提供干性土壤抗性。R 1 R 2 OCOCH 2 CHR 1 COOR 3 R f（其中每个R 彼此独立的和R f2是C3-22多氟烷基，R 1是氢原子或C 1-10烷基，R 2和R 3中的每一个 >彼此独立，是C 1-4亚烷基等）。

9. 发明授权

US08557939B2 Antifouling composition, method for its production and article treated therewith 有权
标题翻译：防污组合物，其生产方法和用其处理的制品
公开(公告)号：US08557939B2
公开(公告)日：2013-10-15
申请号：US12622949
申请日：2009-11-20
申请人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
发明人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
IPC分类号： C08F18/20
CPC分类号： D06M15/277 , C08F220/24 , C08F220/28 , D06M2200/11 , D06M2200/12
摘要： To provide an antifouling composition which is a fluorine-type antifouling composition using a short chain perfluoroalkyl group and which is excellent in antifouling properties and water/oil repellency and presents good durability against washing. An antifouling composition comprising a fluorocopolymer which comprises from 30 to 65 mass % of polymerized units (a) having a C1-6 perfluoroalkyl group, from 1 to 67 mass % of polymerized units (b1) having —(C2H4O)— and from 3 to 34 mass % of polymerized units (b2) having —(C4H8O)—, wherein the content of —(C2H4O)— is from 20 to 65 mass %, and the content of —(C4H8O)— is from 2 to 13 mass %.
摘要翻译：提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其防污性和拒水拒油性优异，耐洗涤性好。包含含氟共聚物的防污组合物，其含有30〜65质量％的具有C1-6全氟烷基的聚合单元（a），1〜67质量％的具有 - （C 2 H 4 O）的聚合单元（b1） 34质量％的具有 - （C 4 H 8 O） - 的聚合单元（b2），其中 - （C 2 H 4 O）的含量为20〜65质量％， - （C 4 H 8 O）的含量为2〜13质量％。

10. 发明申请

US20100076168A1 ANTIFOULING COMPOSITION, METHOD FOR ITS PRODUCTION AND ARTICLE TREATED THEREWITH 有权
标题翻译：抗反射组合物及其生产方法及其处理方法
公开(公告)号：US20100076168A1
公开(公告)日：2010-03-25
申请号：US12626739
申请日：2009-11-27
申请人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
发明人： Hiroyuki Hara , Shuichiro Sugimoto , Takao Hirono , Takashige Maekawa
IPC分类号： C08F220/22
CPC分类号： D06M15/263 , C09D5/1637 , C09D133/16 , C09K3/22 , D06M15/267 , D06M15/27 , D06M15/273 , D06M15/277 , D06M15/285 , D06M16/00 , D06M2200/11 , D06M2200/12
摘要： To provide an antifouling composition which is an fluorine-type antifouling composition using a short chain perfluoroalkyl group and which can be made in the form of an aqueous dispersion containing substantially no volatile organic solvent and has excellent soil release properties.An antifouling composition comprising a fluorocopolymer which comprises from 30 to 70 mass % of polymerized units (a′) having a C1-6 perfluoroalkyl group, from 20 to 69 mass % of polymerized units (b′) having an alkylene oxide chain and from 1 to 10 mass % of polymerized units (c′) having an amino group, and which has anionic groups at its main chain terminals.
摘要翻译：提供一种使用短链全氟烷基的氟型防污组合物的防污组合物，其可以基本上不含挥发性有机溶剂的水性分散体的形式制成，并且具有优异的防污性能。含有含氟共聚物的防污组合物，其含有30〜70质量％的具有C1-6全氟烷基的聚合单元（a'），20〜69质量％的具有环氧烷烃链的聚合单元（b'）和1 至10质量％的具有氨基的聚合单元（c'），并且在其主链末端具有阴离子基团。

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