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1. 发明申请

US20120258321A1 METAL-CROSSLINKED ORGANOPOLYSILOXANE-THIO BLOCK VINYL COPOLYMER AND ANTIFOULING COATING COMPOSITION CONTAINING THE METAL-CROSSLINKED COPOLYMER 有权
标题翻译：金属交联的有机聚硅氧烷 - 硫代烯烃共聚物和防腐涂料组合物含有金属交联共聚物
公开(公告)号：US20120258321A1
公开(公告)日：2012-10-11
申请号：US13516406
申请日：2010-12-16
申请人： Takaharu Doumae , Yoshio Yamada , Masaaki Oya , Fumio Hamazu , Makoto Tsuboi
发明人： Takaharu Doumae , Yoshio Yamada , Masaaki Oya , Fumio Hamazu , Makoto Tsuboi
IPC分类号： C08F30/08 , B32B27/30 , C08K5/5425 , C09D5/16 , C08L53/00 , C08K5/5419
CPC分类号： C08G77/442 , C08F290/148 , C08K3/10 , C08L51/085 , C08L2312/00 , C09D5/1675 , C09D151/085 , C09D183/10 , Y10T428/31663 , C08F220/06 , C08F220/18
摘要： The object of the present invention is to provide a silicone-based copolymer which has excellent long-term antifouling property even in a dry-wet alternate portion of a ship and the like or a portion thereof near the surface of water, is excellent also in mechanical strength and recoatability and exhibits high antifouling performance even if an antifouling agent is not added, and an antifouling coating composition containing the copolymer. The present invention provides, as the silicon-based copolymer, a metal-crosslinked organopolysiloxane-thio block vinyl copolymer [D] wherein an organopolysiloxane-thio block vinyl copolymer [C] having a carboxylic acid-containing vinyl copolymer block [A] formed from constitutional units derived from a polymerizable unsaturated carboxylic acid (a1) and constitutional units derived from at least one other polymerizable unsaturated monomer (a2) copolymerizable with the polymerizable unsaturated carboxylic acid, and a specific organopolysiloxane-thio block [B] is crosslinked with a divalent metal [M].
摘要翻译：本发明的目的是提供即使在船舶等的干湿交替部分或其表面附近的部分也具有优异的长期防污性能的硅氧烷类共聚物也是优异的机械强度和可再涂性，即使不添加防污剂也显示出高的防污性能，以及含有该共聚物的防污涂料组合物。本发明提供作为硅系共聚物的金属交联的有机聚硅氧烷 - 硫嵌段乙烯基共聚物[D]，其中含有含羧酸的乙烯基共聚物嵌段[A]的有机聚硅氧烷 - 硫嵌段乙烯基共聚物[C]由衍生自聚合性不饱和羧酸（a1）的结构单元和与可聚合不饱和羧酸共聚的至少一种其它可聚合不饱和单体（a2）的结构单元和特定的有机聚硅氧烷 - 硫嵌段[B]与二价金属[M]。

2. 发明授权

US08846821B2 Metal-crosslinked organopolysiloxane-thio block vinyl copolymer and antifouling coating composition containing the metal-crosslinked copolymer 有权
标题翻译：金属交联的有机聚硅氧烷 - 硫代嵌段乙烯基共聚物和含有金属交联共聚物的防污涂料组合物
公开(公告)号：US08846821B2
公开(公告)日：2014-09-30
申请号：US13516406
申请日：2010-12-16
申请人： Takaharu Doumae , Yoshio Yamada , Masaaki Oya , Fumio Hamazu , Makoto Tsuboi
发明人： Takaharu Doumae , Yoshio Yamada , Masaaki Oya , Fumio Hamazu , Makoto Tsuboi
IPC分类号： C08F8/42 , C08J3/24 , C08F290/14 , C08G77/442 , C09D5/16 , C09D151/08 , C08L51/08 , C09D183/10 , C08K3/00
CPC分类号： C08G77/442 , C08F290/148 , C08K3/10 , C08L51/085 , C08L2312/00 , C09D5/1675 , C09D151/085 , C09D183/10 , Y10T428/31663 , C08F220/06 , C08F220/18
摘要： The object of the present invention is to provide a silicone-based copolymer which has excellent long-term antifouling property even in a dry-wet alternate portion of a ship and the like or a portion thereof near the surface of water, is excellent also in mechanical strength and recoatability and exhibits high antifouling performance even if an antifouling agent is not added, and an antifouling coating composition containing the copolymer. The present invention provides, as the silicon-based copolymer, a metal-crosslinked organopolysiloxane-thio block vinyl copolymer [D] wherein an organopolysiloxane-thio block vinyl copolymer [C] having a carboxylic acid-containing vinyl copolymer block [A] formed from constitutional units derived from a polymerizable unsaturated carboxylic acid (a1) and constitutional units derived from at least one other polymerizable unsaturated monomer (a2) copolymerizable with the polymerizable unsaturated carboxylic acid, and a specific organopolysiloxane-thio block [B] is crosslinked with a divalent metal [M].
摘要翻译：本发明的目的是提供即使在船舶等的干湿交替部分或其表面附近的部分也具有优异的长期防污性能的硅氧烷类共聚物也是优异的机械强度和可再涂性，即使不添加防污剂也显示出高的防污性能，以及含有该共聚物的防污涂料组合物。本发明提供作为硅系共聚物的金属交联的有机聚硅氧烷 - 硫嵌段乙烯基共聚物[D]，其中含有含羧酸的乙烯基共聚物嵌段[A]的有机聚硅氧烷 - 硫嵌段乙烯基共聚物[C]由衍生自聚合性不饱和羧酸（a1）的结构单元和与可聚合不饱和羧酸共聚的至少一种其它可聚合不饱和单体（a2）的结构单元和特定的有机聚硅氧烷 - 硫嵌段[B]与二价金属[M]。

3. 发明申请

US20100278876A1 HIGH-SOLID ANTIFOULING PAINT COMPOSITION, ANTIFOULING COATING FILM, BASE MATERIAL WITH COATING FILM, ANTIFOULING BASE MATERIAL, METHOD FOR FORMING COATING FILM ON SURFACE OF BASE MATERIAL, ANTIFOULING METHOD FOR BASE MATERIAL, AND HIGH-SOLID MULTI-PACKAGE ANTIFOULING PAINT COMPOSITION SET 审中-公开
标题翻译：高固体防粘涂料组合物，防粘涂膜，基材，涂料膜，抗碱基材料，基材表面涂布膜的方法，基材抗反射方法和高固体多包装防锈涂料组合物
公开(公告)号：US20100278876A1
公开(公告)日：2010-11-04
申请号：US12159411
申请日：2006-12-15
申请人： Takaharu Doumae , Masaaki Oya , Junji Niimoto , Makoto Tsuboi
发明人： Takaharu Doumae , Masaaki Oya , Junji Niimoto , Makoto Tsuboi
IPC分类号： A01N25/34 , A01N37/00 , A01P15/00 , B05D3/02
CPC分类号： C09D5/1668 , C09D5/165 , C09D133/02 , C08L2666/04
摘要： Disclosed is a high-solid antifouling paint composition characterized by including: (A) a carboxyl group-containing copolymer that has a structural unit derived from an unsaturated carboxylic acid monomer (a1) and a structural unit derived from an other unsaturated compound monomer (a2) copolymerizable with the unsaturated carboxylic acid monomer (a1), and has a weight average molecular weight of 1,000 to 6,000 as measured with GPC, (B) a polyvalent metal compound capable of reacting with the carboxyl group of the carboxyl group-containing copolymer (A), and (C) an antifouling agent. The high-solid antifouling paint composition of the present invention provides an antifouling coating film that imposes less environmental burden, affects human bodies less, and has excellent antifouling performance, excellent persistence thereof and excellent mechanical strength.
摘要翻译：本发明公开了一种高固体防污涂料组合物，其特征在于包括：（A）具有衍生自不饱和羧酸单体（a1）的结构单元和衍生自其它不饱和化合物单体（a2）的结构单元的含羧基共聚物）可与不饱和羧酸单体（a1）共聚，并且用GPC测定的重均分子量为1,000〜6000，（B）能够与含羧基的共聚物的羧基反应的多价金属化合物 A），（C）防污剂。本发明的高固体防污涂料组合物提供了一种防污涂层，其施加较少的环境负担，更少地影响人体，并且具有优异的防污性能，优异的持久性和优异的机械强度。

4. 发明授权

US06458878B1 SILYL (METH) ACRYLATE COPOLYMERS, PROCESSES FOR PREPARING THE SAME, ANTIFOULING PAINT COMPOSITIONS CONTAINING THE SILYL (METH) ACRYLATE COPOLYMERS, ANTIFOULING COATING FILMS FORMED FROM THE ANTIFOULING PAINT COMPOSITIONS, ANTIFOULING METHODS USING THE ANTIFOULING PAINT COMPOSITIONS, AND HULLS OR UNDERWATER STRUCTURES COATED WITH THE ANTIFOULING COATING FILMS 有权
标题翻译：硅烷（甲基）丙烯酸酯共聚物，其制备方法，防止含有（甲基）丙烯酸酯共聚物的涂料组合物，由抗蚀涂料组合物形成的防粘涂膜，使用防油漆组合物的防腐方法，以及包装的HULLS或水下结构防喷涂膜
公开(公告)号：US06458878B1
公开(公告)日：2002-10-01
申请号：US09472229
申请日：1999-12-27
申请人： Makoto Tsuboi , Eiichi Yoshikawa , Hidetaka Arimura , Fumio Hamazu , Naoya Nakamura , Yasuto Hikiji , Masaaki Oya , Satoshi Hiyoshi , Yukio Kozono
发明人： Makoto Tsuboi , Eiichi Yoshikawa , Hidetaka Arimura , Fumio Hamazu , Naoya Nakamura , Yasuto Hikiji , Masaaki Oya , Satoshi Hiyoshi , Yukio Kozono
IPC分类号： C08K318
CPC分类号： C09D5/1668 , C08F230/08
摘要： Disclosed is a silyl (meth)acrylate copolymer which comprises 20 to 80% by weight of (a) silyl (meth)acrylate constituent units (I), 0.01 to 40% by weight of (b) acrylic unsaturated monomer constituent units (II) and 5 to 79.9% by weight of Ĉ unsaturated monomer constituent units other than the constituent units (a) and (b). Also disclosed is a process for preparing the silyl (meth)acrylate copolymer, an antifouling paint composition comprising the copolymer, a coating film formed from the paint composition, a hull with the coating film and an antifouling method using the paint composition.
摘要翻译：公开了（甲基）丙烯酸甲硅烷酯结构单元（I）为20〜80重量％（甲基）丙烯酸甲酯共聚物，（b）丙烯酸不饱和单体构成单元（II）为0.01〜40重量％和5〜79.9重量％的除构成单元（a）和（b）以外的不饱和单体构成单元。还公开了（甲基）丙烯酸甲硅烷酯共聚物的制备方法，包含共聚物的防污涂料组合物，由涂料组合物形成的涂膜，涂膜的船体和使用该涂料组合物的防污涂法。

5. 发明授权

US06916860B2 Antifouling coating composition, coating film therefrom, base material covered with the coating film and antifouling method 有权
标题翻译：防污涂料组合物，涂膜，涂膜覆盖的基材和防污方法
公开(公告)号：US06916860B2
公开(公告)日：2005-07-12
申请号：US10375005
申请日：2003-02-28
申请人： Masaaki Oya , Naoya Nakamura , Makoto Tsuboi
发明人： Masaaki Oya , Naoya Nakamura , Makoto Tsuboi
IPC分类号： B63B59/04 , C08K5/09 , C09D5/16 , C09D143/00 , C09D143/04
CPC分类号： C09D5/1656 , C08K5/09 , C09D5/1668 , C09D143/00
摘要： An antifouling coating composition comprising (A) a silyl ester copolymer containing constituent units derived from a polymerizable unsaturated carboxylic acid silyl ester; (B) a carboxylic acid; (C) a bivalent or trivalent metal compound; and (D) a dehydrating agent. It is preferred that the component (C) be contained in an amount of 1.2 equivalents or more, in terms of the number of equivalents of metal as a constituent of the component (C), per equivalent of carboxyl group of the carboxylic acid (B); that the component (C) be a bivalent metal compound; and that the component (C) be a compound of at least one metal selected from the group consisting of zinc, copper, magnesium, calcium and barium. From the antifouling coating composition, there can be obtained an antifouling coating film which exhibits less cracking tendency, excellent adherence so as to ensure less peeling tendency and desirably controlled hydrolysis rate so as to be excellent in antifouling performance, in particular, antifouling properties in highly fouling environment and long-term antifouling properties. With respect to the provided antifouling coating composition, its storage stability is high, its concentration can be increased, the amount of solvent used therefor can be reduced, and its applicability is high.
摘要翻译：一种防污涂料组合物，其包含（A）含有衍生自可聚不饱和羧酸甲硅烷基酯的构成单元的甲硅烷基酯共聚物; （B）羧酸; （C）二价或三价金属化合物; 和（D）脱水剂。相对于作为（C）成分的成分的金属的当量数，羧酸（B）的羧基的当量，优选为1.2当量以上）; 组分（C）是二价金属化合物; 并且组分（C）是选自锌，铜，镁，钙和钡中的至少一种金属的化合物。从防污涂料组合物可以获得防污涂层，其具有较小的开裂倾向，优异的粘附性，以确保较低的剥离倾向和所需的控制水解速率，从而具有优异的防污性能，特别是高防污性污染环境和长期防污性能。对于所提供的防污涂料组合物，其保存稳定性高，其浓度可以提高，因此可以降低其用量，适用性高。

6. 发明申请

US20070105976A1 Cyclic carboxylic acid compound and use thereof 有权
标题翻译：环状羧酸化合物及其用途
公开(公告)号：US20070105976A1
公开(公告)日：2007-05-10
申请号：US10581039
申请日：2004-11-26
申请人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
发明人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
IPC分类号： C09D5/16 , C07C62/30
CPC分类号： C07C403/02 , C07C61/22 , C07C61/29 , C07C61/35 , C07C69/75 , C07C2601/16 , C07C2602/44 , C09D5/1662
摘要： [Means to solve problem] A novel cyclic carboxylic acid formed by the addition reaction of an unsaturated carboxylic acid with a conjugated diene compound and a metal salt thereof are disclosed. A compounding agent (A) for an antifouling paint comprising one or more substances selected from the novel cyclic carboxylic acid, a derivative of the cyclic carboxylic acid (except a metal salt), a metal salt of the cyclic carboxylic acid and a metal salt of a derivative of the cyclic carboxylic acid, and an antifouling paint composition comprising the compounding agent (A) and a copolymer (B) for a self-polishing type antifouling paint are also disclosed. [Effect] The antifouling paint composition can form an antifouling coating film which is a small burden to the environment, is uniformly eroded at a given rate, is capable of maintaining excellent antifouling performance for a long period of time and is applicable to ships or the like used in the highly fouling sea area.
摘要翻译： [解决问题的方法]公开了通过不饱和羧酸与共轭二烯化合物及其金属盐的加成反应形成的新型环状羧酸。一种用于防污涂料的配混剂（A），其包含一种或多种选自新型环状羧酸，环状羧酸衍生物（金属盐除外），环状羧酸的金属盐和金属盐环状羧酸的衍生物，以及包含配合剂（A）和用于自抛光型防污漆的共聚物（B））的防污涂料组合物。 [效果]防污涂料组合物可以形成对环境负担小的防污涂膜，以规定的速度均匀地侵蚀，能够长时间保持优异的防污性能，适用于船舶或像在高度污染的海域使用。

7. 发明授权

US06828030B2 (POLY)OXYALKYLENE BLOCK SILYL ESTER COPOLYMER, ANTIFOULING COATING COMPOSITION, ANTIFOULING COATING FORMED FROM ANTIFOULING COATING COMPOSITION, ANTIFOULING METHOD USING ANTIFOULING COATING COMPOSITION AND HULL OR UNDERWATER STRUCTURE COVERED WITH ANTIFOULING COATING 有权
标题翻译：（POLY）聚氧乙烯嵌段硅氧烷共聚物，防粘涂料组合物，防止涂料组合物形成的防粘涂料，使用防涂层组合物的防止方法以及用抗反射涂层覆盖的船体或水下结构
公开(公告)号：US06828030B2
公开(公告)日：2004-12-07
申请号：US09983181
申请日：2001-10-23
申请人： Hidetaka Arimura , Satoshi Hiyoshi , Naoya Nakamura , Makoto Tsuboi
发明人： Hidetaka Arimura , Satoshi Hiyoshi , Naoya Nakamura , Makoto Tsuboi
IPC分类号： B32B2520
CPC分类号： C08L71/02 , C08F293/005 , C08G65/336 , C08G81/025 , C08L53/00 , C09D5/1668 , C09D153/00 , Y10S525/926 , Y10T428/31663 , C08L2666/02 , C08L2666/04
摘要： A (poly)oxyalkylene block silyl ester copolymer comprising silyl ester copolymer block units (A) and block units (B), the block units (a) comprising (a) component units derived from a polymerizable unsaturated carboxylic acid silyl ester, and (b) polymerizable unsaturated monomer units other than the component units (a), the block units (B) derived from particular mercapto compounds, and an antifouling paint comprising the (poly)oxyalkylene block silyl ester copolymer. The copolymer enables the formation of an antifouling coating film which exhibits less cracking tendency, excellent adherence, less peeling tendency and controlled hydrolysis rate resulting in excellent antifouling performance and properties.
摘要翻译：包含甲硅烷基酯共聚物嵌段单元（A）和嵌段单元（B）的（聚）氧化烯嵌段甲硅烷基酯共聚物，嵌段单元（a）包含（a）源自聚合性不饱和羧酸甲硅烷基酯的组分单元和（b ）聚合性不饱和单体单元，来自特定巯基化合物的嵌段单元（B）和包含（聚）氧化烯嵌段甲硅烷基酯共聚物的防污涂料。该共聚物能够形成防污涂膜，其显示较少的开裂倾向，优异的粘附性，较少的剥离倾向和受控的水解速率，从而获得优异的防污性能和性能。

8. 再颁专利

USRE31094E Apparatus for controlling heating time utilizing humidity sensing 失效
标题翻译：用于使用湿度感测控制加热时间的装置
公开(公告)号：USRE31094E
公开(公告)日：1982-11-30
申请号：US162774
申请日：1980-06-25
申请人： Tetsu Kobayashi , Takato Kanazawa, deceased , Makoto Tsuboi
发明人： Tetsu Kobayashi , Takato Kanazawa, deceased , Makoto Tsuboi
IPC分类号： H05B6/68
CPC分类号： H05B6/6458
摘要： Apparatus for controlling heating time for food placed in a cooking apparatus such as a microwave oven in which heating time required for the humidity of the food which varies with the heating of the food to reach a representative humidity value after abrupt change with a positive gradient is measured, and the product of the measured heating time multiplied by a predetermined heating time coefficient which is inherent in the particular food is added to the measured heating time so that the sum represents the total required heating time for the food.

9. 发明授权

US4335293A Heating control apparatus by humidity detection 失效
标题翻译：湿度检测加热控制装置
公开(公告)号：US4335293A
公开(公告)日：1982-06-15
申请号：US157171
申请日：1980-06-06
申请人： Tetsu Kobayashi , Takato Kanazawa , Makoto Tsuboi
发明人： Tetsu Kobayashi , Takato Kanazawa , Makoto Tsuboi
IPC分类号： G05D22/02 , H05B1/02 , H05B6/68
CPC分类号： H05B1/0263 , G05D22/02 , H05B6/6458
摘要： A heating control apparatus in microwave ovens controls heating of food by detecting water vapor generated by heating a food to sense a varying relative humidity by a humidity sensor and determining a critical point of the heating condition of the food by detecting a time point when the relative humidity rises from a minimum value beyond a predetermined threshold value thereby to determine a proper total heating time of the food. To allow accurate humidity sensing, a cleaning device is provided in proximity to the humidity sensor such that the cleaning device is actuated for an appropriate time period at a proper timing to insure proper performance of the humidity sensor.
摘要翻译：微波炉中的加热控制装置通过检测通过加热食物而产生的水蒸气来控制食物的加热，以通过湿度传感器感测变化的相对湿度，并通过检测食物的相对湿度的时间点来确定食物的加热条件的临界点湿度从最小值上升超过预定阈值，从而确定食物的合适的总加热时间。为了允许精确的湿度感测，在湿度传感器附近提供清洁装置，使得清洁装置在适当的时间被致动适当的时间段以确保湿度传感器的适当的性能。

10. 发明授权

US6110990A Antifouling coating composition, coating film formed from said antifouling coating composition, antifouling method using said antifouling coating composition and hull or underwater structure coated with said coating film 失效
标题翻译：防污涂料组合物，由所述防污涂料组合物形成的涂膜，使用所述防污涂料组合物的防污方法和涂有所述涂膜的船体或水下结构
公开(公告)号：US6110990A
公开(公告)日：2000-08-29
申请号：US776662
申请日：1997-01-30
申请人： Naoya Nakamura , Yasuto Hikiji , Yasuyuki Kiseki , Makoto Tsuboi
发明人： Naoya Nakamura , Yasuto Hikiji , Yasuyuki Kiseki , Makoto Tsuboi
IPC分类号： C08K5/03 , C09D5/16 , C09D143/04 , C08K3/00 , C08K5/00
CPC分类号： C08K5/03 , C09D143/04 , C09D5/1668
摘要： An antifouling coating composition includes (A) antifouling agent, (B) film forming copolymer of 1000 to 50,000 in number average molecular weight, and structural units derived from a trialkylsilyl ester of polymerizable unsaturated carboxylic acid in an amount of 20 to 65% by weight, and (C) chlorinated paraffin. The composition may also contain one or more of (D) (meth)acrylic ester polymer of 1000 to 100,000 in number average molecular weight; (E) inorganic dehydrating agent, (F) flake pigment, (G) zinc flower. In other embodiments the composition includes above components (A), (B) and (D) wherein (B):(D)=100:10 to 500. Coating films formed from the above antifouling coating compositions, such as on a hull or an underwater structure, are excellent in cracking resistance, resistance to peeling from ship bottom materials and primer layers, antifouling properties and consumability (self-polishing properties). Further, these antifouling coating compositions are excellent in storage stability.
摘要翻译： PCT No.PCT / JP96 / 01479 Sec。 371日期1997年1月30日 102（e）日期1997年1月30日PCT提交1996年5月31日PCT公布。 WO96 / 38508 PCT公开号 1996年12月5日，防污涂料组合物包括（A）防污剂，（B）数均分子量为1000〜50,000的成膜共聚物和20重量％的聚合性不饱和羧酸的三烷基甲硅烷基酯的结构单元至65重量％，和（C）氯化石蜡。该组合物还可含有数均分子量为1000至100,000的（D）（甲基）丙烯酸酯聚合物中的一种或多种; （E）无机脱水剂，（F）片状颜料，（G）锌花。在其它实施方案中，组合物包括上述组分（A），（B）和（D），其中（B）：（D）= 100:10至500.由上述防污涂料组合物形成的涂膜，例如在船体或水下结构，耐龟裂性，耐船底材和底漆层的剥离性，防污性和消耗性（自抛光性）优异。此外，这些防污涂料组合物的储存稳定性优异。

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