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1. 发明授权

US06172132B2 Antifouling coating composition, coating film formed from said antifoulding coating composition, antifouling method using said antifouling coating composition and hull or underwater structure coated with said coating film 失效
标题翻译：防污涂料组合物，由所述防泡涂料组合物形成的涂膜，使用所述防污涂料组合物的防污方法和涂有所述涂膜的船体或水下结构
公开(公告)号：US06172132B2
公开(公告)日：2001-01-09
申请号：US09089516
申请日：1998-06-03
申请人： Naoya Nakamura , Yasuto Hikiji , Yasuyuki Kiseki , Makoto Tsuboi
发明人： Naoya Nakamura , Yasuto Hikiji , Yasuyuki Kiseki , Makoto Tsuboi
IPC分类号： C08K600
CPC分类号： C08K5/03 , C09D5/1668 , C09D143/04 , C08L43/04 , C08L2666/32
摘要： An antifouling coating composition can inhibit or prevent fouling of hulls of ships and other underwater structures. The coating composition includes (A) an antifouling agent, (B) a film-forming copolymer having a number average molecular weight of 1,000 to 50,000, and structural units derived from a trialkylsilyl ester of polymerizable unsaturated carboxylic acid in an amount of 20 to 65% by weight, based on the copolymer, and (C) chlorinated paraffin having 8 to 30 carbon atoms, number average molecular weight of 200 to 1200 and a chlorination ratio of from 35 to 75% by weight. Zinc flower may also be included in the antifouling coating composition in place of or in addition to the antifouling agent (A).
摘要翻译：防污涂料组合物可以抑制或防止船舶和其他水下结构体的结垢。涂料组合物包括（A）防污剂，（B）数均分子量为1,000〜50,000的成膜共聚物和衍生自20〜65的聚合性不饱和羧酸的三烷基甲硅烷基酯的结构单元（C）碳原子数为8〜30的氯化石蜡，数均分子量为200〜1200，氯化率为35〜75重量％。除了防污剂（A）以外，锌花也可以包含在防污涂料组合物中。

2. 发明授权

US6110990A Antifouling coating composition, coating film formed from said antifouling coating composition, antifouling method using said antifouling coating composition and hull or underwater structure coated with said coating film 失效
标题翻译：防污涂料组合物，由所述防污涂料组合物形成的涂膜，使用所述防污涂料组合物的防污方法和涂有所述涂膜的船体或水下结构
公开(公告)号：US6110990A
公开(公告)日：2000-08-29
申请号：US776662
申请日：1997-01-30
申请人： Naoya Nakamura , Yasuto Hikiji , Yasuyuki Kiseki , Makoto Tsuboi
发明人： Naoya Nakamura , Yasuto Hikiji , Yasuyuki Kiseki , Makoto Tsuboi
IPC分类号： C08K5/03 , C09D5/16 , C09D143/04 , C08K3/00 , C08K5/00
CPC分类号： C08K5/03 , C09D143/04 , C09D5/1668
摘要： An antifouling coating composition includes (A) antifouling agent, (B) film forming copolymer of 1000 to 50,000 in number average molecular weight, and structural units derived from a trialkylsilyl ester of polymerizable unsaturated carboxylic acid in an amount of 20 to 65% by weight, and (C) chlorinated paraffin. The composition may also contain one or more of (D) (meth)acrylic ester polymer of 1000 to 100,000 in number average molecular weight; (E) inorganic dehydrating agent, (F) flake pigment, (G) zinc flower. In other embodiments the composition includes above components (A), (B) and (D) wherein (B):(D)=100:10 to 500. Coating films formed from the above antifouling coating compositions, such as on a hull or an underwater structure, are excellent in cracking resistance, resistance to peeling from ship bottom materials and primer layers, antifouling properties and consumability (self-polishing properties). Further, these antifouling coating compositions are excellent in storage stability.
摘要翻译： PCT No.PCT / JP96 / 01479 Sec。 371日期1997年1月30日 102（e）日期1997年1月30日PCT提交1996年5月31日PCT公布。 WO96 / 38508 PCT公开号 1996年12月5日，防污涂料组合物包括（A）防污剂，（B）数均分子量为1000〜50,000的成膜共聚物和20重量％的聚合性不饱和羧酸的三烷基甲硅烷基酯的结构单元至65重量％，和（C）氯化石蜡。该组合物还可含有数均分子量为1000至100,000的（D）（甲基）丙烯酸酯聚合物中的一种或多种; （E）无机脱水剂，（F）片状颜料，（G）锌花。在其它实施方案中，组合物包括上述组分（A），（B）和（D），其中（B）：（D）= 100:10至500.由上述防污涂料组合物形成的涂膜，例如在船体或水下结构，耐龟裂性，耐船底材和底漆层的剥离性，防污性和消耗性（自抛光性）优异。此外，这些防污涂料组合物的储存稳定性优异。

3. 发明授权

US06458878B1 SILYL (METH) ACRYLATE COPOLYMERS, PROCESSES FOR PREPARING THE SAME, ANTIFOULING PAINT COMPOSITIONS CONTAINING THE SILYL (METH) ACRYLATE COPOLYMERS, ANTIFOULING COATING FILMS FORMED FROM THE ANTIFOULING PAINT COMPOSITIONS, ANTIFOULING METHODS USING THE ANTIFOULING PAINT COMPOSITIONS, AND HULLS OR UNDERWATER STRUCTURES COATED WITH THE ANTIFOULING COATING FILMS 有权
标题翻译：硅烷（甲基）丙烯酸酯共聚物，其制备方法，防止含有（甲基）丙烯酸酯共聚物的涂料组合物，由抗蚀涂料组合物形成的防粘涂膜，使用防油漆组合物的防腐方法，以及包装的HULLS或水下结构防喷涂膜
公开(公告)号：US06458878B1
公开(公告)日：2002-10-01
申请号：US09472229
申请日：1999-12-27
申请人： Makoto Tsuboi , Eiichi Yoshikawa , Hidetaka Arimura , Fumio Hamazu , Naoya Nakamura , Yasuto Hikiji , Masaaki Oya , Satoshi Hiyoshi , Yukio Kozono
发明人： Makoto Tsuboi , Eiichi Yoshikawa , Hidetaka Arimura , Fumio Hamazu , Naoya Nakamura , Yasuto Hikiji , Masaaki Oya , Satoshi Hiyoshi , Yukio Kozono
IPC分类号： C08K318
CPC分类号： C09D5/1668 , C08F230/08
摘要： Disclosed is a silyl (meth)acrylate copolymer which comprises 20 to 80% by weight of (a) silyl (meth)acrylate constituent units (I), 0.01 to 40% by weight of (b) acrylic unsaturated monomer constituent units (II) and 5 to 79.9% by weight of Ĉ unsaturated monomer constituent units other than the constituent units (a) and (b). Also disclosed is a process for preparing the silyl (meth)acrylate copolymer, an antifouling paint composition comprising the copolymer, a coating film formed from the paint composition, a hull with the coating film and an antifouling method using the paint composition.
摘要翻译：公开了（甲基）丙烯酸甲硅烷酯结构单元（I）为20〜80重量％（甲基）丙烯酸甲酯共聚物，（b）丙烯酸不饱和单体构成单元（II）为0.01〜40重量％和5〜79.9重量％的除构成单元（a）和（b）以外的不饱和单体构成单元。还公开了（甲基）丙烯酸甲硅烷酯共聚物的制备方法，包含共聚物的防污涂料组合物，由涂料组合物形成的涂膜，涂膜的船体和使用该涂料组合物的防污涂法。

4. 发明授权

US06828030B2 (POLY)OXYALKYLENE BLOCK SILYL ESTER COPOLYMER, ANTIFOULING COATING COMPOSITION, ANTIFOULING COATING FORMED FROM ANTIFOULING COATING COMPOSITION, ANTIFOULING METHOD USING ANTIFOULING COATING COMPOSITION AND HULL OR UNDERWATER STRUCTURE COVERED WITH ANTIFOULING COATING 有权
标题翻译：（POLY）聚氧乙烯嵌段硅氧烷共聚物，防粘涂料组合物，防止涂料组合物形成的防粘涂料，使用防涂层组合物的防止方法以及用抗反射涂层覆盖的船体或水下结构
公开(公告)号：US06828030B2
公开(公告)日：2004-12-07
申请号：US09983181
申请日：2001-10-23
申请人： Hidetaka Arimura , Satoshi Hiyoshi , Naoya Nakamura , Makoto Tsuboi
发明人： Hidetaka Arimura , Satoshi Hiyoshi , Naoya Nakamura , Makoto Tsuboi
IPC分类号： B32B2520
CPC分类号： C08L71/02 , C08F293/005 , C08G65/336 , C08G81/025 , C08L53/00 , C09D5/1668 , C09D153/00 , Y10S525/926 , Y10T428/31663 , C08L2666/02 , C08L2666/04
摘要： A (poly)oxyalkylene block silyl ester copolymer comprising silyl ester copolymer block units (A) and block units (B), the block units (a) comprising (a) component units derived from a polymerizable unsaturated carboxylic acid silyl ester, and (b) polymerizable unsaturated monomer units other than the component units (a), the block units (B) derived from particular mercapto compounds, and an antifouling paint comprising the (poly)oxyalkylene block silyl ester copolymer. The copolymer enables the formation of an antifouling coating film which exhibits less cracking tendency, excellent adherence, less peeling tendency and controlled hydrolysis rate resulting in excellent antifouling performance and properties.
摘要翻译：包含甲硅烷基酯共聚物嵌段单元（A）和嵌段单元（B）的（聚）氧化烯嵌段甲硅烷基酯共聚物，嵌段单元（a）包含（a）源自聚合性不饱和羧酸甲硅烷基酯的组分单元和（b ）聚合性不饱和单体单元，来自特定巯基化合物的嵌段单元（B）和包含（聚）氧化烯嵌段甲硅烷基酯共聚物的防污涂料。该共聚物能够形成防污涂膜，其显示较少的开裂倾向，优异的粘附性，较少的剥离倾向和受控的水解速率，从而获得优异的防污性能和性能。

5. 发明授权

US07557148B2 Cyclic carboxylic acid compound and use thereof 有权
标题翻译：环状羧酸化合物及其用途
公开(公告)号：US07557148B2
公开(公告)日：2009-07-07
申请号：US10581039
申请日：2004-11-26
申请人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
发明人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
IPC分类号： C07C62/30 , C09D5/16
CPC分类号： C07C403/02 , C07C61/22 , C07C61/29 , C07C61/35 , C07C69/75 , C07C2601/16 , C07C2602/44 , C09D5/1662
摘要： A novel cyclic carboxylic acid formed by the addition reaction of an unsaturated carboxylic acid with a conjugated diene compound and a metal salt thereof are disclosed. A compounding agent (A) for an antifouling paint comprising one or more substances selected from the novel cyclic carboxylic acid, a derivative of the cyclic carboxylic acid (except a metal salt), a metal salt of the cyclic carboxylic acid and a metal salt of a derivative of the cyclic carboxylic acid, and an antifouling paint composition comprising the compounding agent (A) and a copolymer (B) for a self-polishing type antifouling paint are also disclosed. The antifouling paint composition can form an antifouling coating film which is a small burden to the environment, is uniformly eroded at a given rate, is capable of maintaining excellent antifouling performance for a long period of time and is applicable to ships or the like used in the highly fouling sea area.
摘要翻译：公开了通过不饱和羧酸与共轭二烯化合物及其金属盐的加成反应形成的新型环状羧酸。一种用于防污涂料的配混剂（A），其包含一种或多种选自新型环状羧酸，环状羧酸衍生物（金属盐除外），环状羧酸的金属盐和金属盐环状羧酸的衍生物，以及包含配合剂（A）和用于自抛光型防污涂料的共聚物（B））的防污涂料组合物。防污涂料组合物可以形成对环境负担小的防污涂膜，以给定的速率均匀地侵蚀，能够长时间保持优异的防污性能，适用于船舶等高度污染的海域。

6. 发明授权

US06916860B2 Antifouling coating composition, coating film therefrom, base material covered with the coating film and antifouling method 有权
标题翻译：防污涂料组合物，涂膜，涂膜覆盖的基材和防污方法
公开(公告)号：US06916860B2
公开(公告)日：2005-07-12
申请号：US10375005
申请日：2003-02-28
申请人： Masaaki Oya , Naoya Nakamura , Makoto Tsuboi
发明人： Masaaki Oya , Naoya Nakamura , Makoto Tsuboi
IPC分类号： B63B59/04 , C08K5/09 , C09D5/16 , C09D143/00 , C09D143/04
CPC分类号： C09D5/1656 , C08K5/09 , C09D5/1668 , C09D143/00
摘要： An antifouling coating composition comprising (A) a silyl ester copolymer containing constituent units derived from a polymerizable unsaturated carboxylic acid silyl ester; (B) a carboxylic acid; (C) a bivalent or trivalent metal compound; and (D) a dehydrating agent. It is preferred that the component (C) be contained in an amount of 1.2 equivalents or more, in terms of the number of equivalents of metal as a constituent of the component (C), per equivalent of carboxyl group of the carboxylic acid (B); that the component (C) be a bivalent metal compound; and that the component (C) be a compound of at least one metal selected from the group consisting of zinc, copper, magnesium, calcium and barium. From the antifouling coating composition, there can be obtained an antifouling coating film which exhibits less cracking tendency, excellent adherence so as to ensure less peeling tendency and desirably controlled hydrolysis rate so as to be excellent in antifouling performance, in particular, antifouling properties in highly fouling environment and long-term antifouling properties. With respect to the provided antifouling coating composition, its storage stability is high, its concentration can be increased, the amount of solvent used therefor can be reduced, and its applicability is high.
摘要翻译：一种防污涂料组合物，其包含（A）含有衍生自可聚不饱和羧酸甲硅烷基酯的构成单元的甲硅烷基酯共聚物; （B）羧酸; （C）二价或三价金属化合物; 和（D）脱水剂。相对于作为（C）成分的成分的金属的当量数，羧酸（B）的羧基的当量，优选为1.2当量以上）; 组分（C）是二价金属化合物; 并且组分（C）是选自锌，铜，镁，钙和钡中的至少一种金属的化合物。从防污涂料组合物可以获得防污涂层，其具有较小的开裂倾向，优异的粘附性，以确保较低的剥离倾向和所需的控制水解速率，从而具有优异的防污性能，特别是高防污性污染环境和长期防污性能。对于所提供的防污涂料组合物，其保存稳定性高，其浓度可以提高，因此可以降低其用量，适用性高。

7. 发明申请

US20070105976A1 Cyclic carboxylic acid compound and use thereof 有权
标题翻译：环状羧酸化合物及其用途
公开(公告)号：US20070105976A1
公开(公告)日：2007-05-10
申请号：US10581039
申请日：2004-11-26
申请人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
发明人： Takahiro Nishiguchi , Naoya Nakamura , Makoto Tsuboi
IPC分类号： C09D5/16 , C07C62/30
CPC分类号： C07C403/02 , C07C61/22 , C07C61/29 , C07C61/35 , C07C69/75 , C07C2601/16 , C07C2602/44 , C09D5/1662
摘要： [Means to solve problem] A novel cyclic carboxylic acid formed by the addition reaction of an unsaturated carboxylic acid with a conjugated diene compound and a metal salt thereof are disclosed. A compounding agent (A) for an antifouling paint comprising one or more substances selected from the novel cyclic carboxylic acid, a derivative of the cyclic carboxylic acid (except a metal salt), a metal salt of the cyclic carboxylic acid and a metal salt of a derivative of the cyclic carboxylic acid, and an antifouling paint composition comprising the compounding agent (A) and a copolymer (B) for a self-polishing type antifouling paint are also disclosed. [Effect] The antifouling paint composition can form an antifouling coating film which is a small burden to the environment, is uniformly eroded at a given rate, is capable of maintaining excellent antifouling performance for a long period of time and is applicable to ships or the like used in the highly fouling sea area.
摘要翻译： [解决问题的方法]公开了通过不饱和羧酸与共轭二烯化合物及其金属盐的加成反应形成的新型环状羧酸。一种用于防污涂料的配混剂（A），其包含一种或多种选自新型环状羧酸，环状羧酸衍生物（金属盐除外），环状羧酸的金属盐和金属盐环状羧酸的衍生物，以及包含配合剂（A）和用于自抛光型防污漆的共聚物（B））的防污涂料组合物。 [效果]防污涂料组合物可以形成对环境负担小的防污涂膜，以规定的速度均匀地侵蚀，能够长时间保持优异的防污性能，适用于船舶或像在高度污染的海域使用。

8. 发明授权

US08221862B2 Polyphenylene sulfide resin composition, process for producing the same, and molded article 有权
标题翻译：聚苯硫醚树脂组合物，其制造方法和成型品
公开(公告)号：US08221862B2
公开(公告)日：2012-07-17
申请号：US12293199
申请日：2007-03-14
申请人： Kei Saitoh , Naoya Nakamura , Atsushi Ishio
发明人： Kei Saitoh , Naoya Nakamura , Atsushi Ishio
IPC分类号： B29D22/00 , B29D23/00 , B32B1/08
CPC分类号： C08L79/08 , B29C47/1063 , B29C47/364 , B29C47/6087 , C08G75/0213 , C08G75/0259 , C08G75/23 , C08K5/1515 , C08K5/17 , C08K5/29 , C08L81/02 , C08L81/06 , Y10T428/1352 , Y10T428/139 , Y10T428/1397 , Y10T428/2973 , C08L81/00 , C08L2666/20
摘要： A polyphenylene sulfide resin composition including 100 parts by weight of a resin composition that consists of 99 to 60 wt % of a polyphenylene sulfide resin (a), and 1 to 40 wt % of at least one type of noncrystalline resin (b) selected from the group consisting of polyetherimide resin and polyether sulfone resin and 0.1 to 10 parts by weight of a compound (c) containing at least one group selected from epoxy group, amino group and isocyanate group, wherein the non-crystalline resin (b) forms an island phase and the number-average dispersed particle size of the noncrystalline resin (b) is 1,000 nm or less.
摘要翻译： 1.一种聚苯硫醚树脂组合物，其包含100重量份由99〜60重量％的聚苯硫醚树脂（a）组成的树脂组合物和1〜40重量％的至少一种非结晶性树脂（b），其选自由聚醚酰亚胺树脂和聚醚砜树脂组成的组和0.1〜10重量份含有至少一个选自环氧基，氨基和异氰酸酯基的基团的化合物（c），其中非结晶性树脂（b）形成岛相和非结晶性树脂（b）的数均分散粒径为1000nm以下。

9. 发明授权

US07166931B2 Uninterruptible power supply apparatus 有权
标题翻译：不间断电源设备
公开(公告)号：US07166931B2
公开(公告)日：2007-01-23
申请号：US10954073
申请日：2004-09-30
申请人： Yoshiaki Okui , Shouichi Oota , Naoya Nakamura
发明人： Yoshiaki Okui , Shouichi Oota , Naoya Nakamura
IPC分类号： H02J7/00
CPC分类号： H02J9/062 , Y10T307/625
摘要： The uninterruptible power supply apparatus comprises an AC switch for turning on/off the AC power that is input from a commercial AC power source; a storage battery; a power conversion device; a load device connected to the output end of the AC switch; an output AC voltage detection unit for detecting an output AC voltage that is output from the AC switch; and an abnormality detection circuit for detecting that the detected output AC voltage is outside predefined upper and lower limits; wherein said AC switch turns off in accordance with a signal detected by said abnormality detection circuit. Further comprises a restoration circuit for generating a restoration signal when the AC voltage detected by an input AC voltage detection unit exceeds at least a lower-limit AC voltage setting that is increased gradually or continuously in accordance with a load factor computed by a load factor computation circuit.
摘要翻译：不间断电源装置包括用于接通/关闭从商用AC电源输入的AC电力的AC开关; 蓄电池; 电力转换装置; 连接到交流开关输出端的负载装置; 输出AC电压检测单元，用于检测从AC开关输出的输出AC电压; 以及异常检测电路，用于检测所检测的输出AC电压在预定的上限和下限之外; 其中所述AC开关根据由所述异常检测电路检测到的信号而断开。还包括恢复电路，用于当由输入AC电压检测单元检测到的AC电压超过至少一个根据负载因子计算计算的负载因子逐渐或连续地增加的下限AC电压设置时，产生恢复信号电路。

10. 发明授权

US09290662B2 Method for producing thermoplastic resin composition, thermoplastic resin composition, and molded article 有权
标题翻译：热塑性树脂组合物的制造方法，热塑性树脂组合物和成型体
公开(公告)号：US09290662B2
公开(公告)日：2016-03-22
申请号：US13819202
申请日：2011-10-18
申请人： Hideki Matsumoto , Kei Saito , Naoya Nakamura
发明人： Hideki Matsumoto , Kei Saito , Naoya Nakamura
IPC分类号： C08L81/04 , C08L79/08 , C08L81/06 , C08K5/54
CPC分类号： C08L81/04 , B29B7/38 , B29B7/482 , B29B7/489 , B29C47/0004 , B29C47/0023 , B29C47/6056 , B29C47/6087 , B29K2065/00 , B29K2079/085 , C08J5/005 , C08J2379/08 , C08J2381/04 , C08J2381/06 , C08J2479/08 , C08J2481/04 , C08J2481/06 , C08K5/54 , C08L79/08 , C08L81/06 , Y10T428/139 , Y10T428/1397
摘要： The present invention provides a thermoplastic resin composition which is produced by a method which includes melt-kneading: (a) a polyphenylene sulfide resin, with (b) a polyetherimide resin or a polyethersulfone resin. The thermoplastic resin composition contains 99 to 1% by weight of the component (a) and 1 to 99% by weight of the component (b) based on 100% by weight of the total amount of the component (a) and the component (b). The melt-kneading step is conducted by employing an extruder provided with an elongational flow zone which is a zone in which melt-kneading is performed while being allowed to undergo elongational flow, wherein the flow effect pressure drop is from 50 to 1,000 kg/cm2 and is determined by subtracting the pressure value (P0) of the molten resin in the elongational flow zone from the pressure value (P) of the molten resin before entering the elongational flow zone.
摘要翻译：本发明提供一种热塑性树脂组合物，其通过熔融捏合（a）聚苯硫醚树脂与（b）聚醚酰亚胺树脂或聚醚砜树脂的方法制备。基于组分（a）和组分（a）的总量的100重量％，热塑性树脂组合物含有组分（a）99至1重量％和组分（b）1至99重量％ b）。通过使用具有伸长流动区域的挤出机进行熔融捏合步骤，所述伸长流动区域是在进行熔融捏合的同时进行伸长流动的区域，其中流动效应压降为50至1,000kg / cm 2 并且通过从进入伸长流动区域之前的熔融树脂的压力值（P）减去伸长流动区域中的熔融树脂的压力值（P0）来确定。

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