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1. 发明授权

US06767642B2 Preparation and use of crosslinkable acrylosilane polymers containing vinyl silane monomers 失效
标题翻译：含有乙烯基硅烷单体的交联丙烯硅烷聚合物的制备和应用
公开(公告)号：US06767642B2
公开(公告)日：2004-07-27
申请号：US10095951
申请日：2002-03-11
申请人： Donald A. Paquet, Jr. , Ding-Yu Chung , Isidor Hazan
发明人： Donald A. Paquet, Jr. , Ding-Yu Chung , Isidor Hazan
IPC分类号： B32B2520
CPC分类号： C08F230/08 , Y10T428/31663
摘要： Acrylosilane polymers containing vinyl silanes are prepared by copolymerizing vinyl alkoxy silane monomers predominantly with, or in the alternative, only with acrylate monomers. The polymer so prepared can be used as the main component in the acid etch resistant solvent borne coating compositions and in particular in clear coating compositions for clear coat/color coat finishes for automobiles and trucks.
摘要翻译：含有乙烯基硅烷的丙烯酰硅烷聚合物是通过使乙烯基烷氧基硅烷单体主要与或仅在丙烯酸酯单体中主要共聚而制备的。如此制备的聚合物可用作耐酸蚀性溶剂型涂料组合物中的主要组分，特别是用于汽车和卡车的透明涂层/彩涂层的透明涂料组合物。

2. 发明授权

US06743516B2 Highly durable hydrophobic coatings and methods 有权
标题翻译：高度耐用的疏水涂层和方法
公开(公告)号：US06743516B2
公开(公告)日：2004-06-01
申请号：US09921303
申请日：2001-08-03
申请人： Nestor P. Murphy , Rudolph H. Petrmichl
发明人： Nestor P. Murphy , Rudolph H. Petrmichl
IPC分类号： B32B2520
CPC分类号： C03C17/009 , B05D1/185 , B05D1/60 , C03C17/42 , C03C2217/213 , C03C2217/76 , C03C2218/152 , C09D4/00 , C09D5/002 , Y10T428/31612 , Y10T428/31663 , C08G77/04
摘要： Substrates have a hydrophobic surface coating comprised of the reaction products of a chlorosilyl group containing compound and an alkylsilane. Most preferably the substrate is glass. In one preferred form of the invention, highly durable hydrophobic coatings may be formed by forming a silicon oxide anchor layer or hybrid organo-silicon oxide anchor layer from a humidified reaction product of silicon tetrachloride or trichloromethylsilane, followed by the vapor-deposition of a chloroalkylsilane. Such a silicon oxide anchor layer will advantageously have a root mean square surface roughness of less than about 6.0 nm (preferably less than about 5.0 nm) and a low haze value of less than about 3.0% (preferably less than about 2.0%). Another embodiment of the present invention include the simultaneous humidified vapor deposition of a chlorosilyl group containing compound and a chloroalkylsilane. Specifically, in certain preferred embodiments, the simultaneous vapor deposition onto a glass substrate of silicon tetrachloride (SiCl4) and dimethyldichlorosilane (DMDCS) results in a hydrophobic coating comprised of cross-linked polydimethylsiloxane (PDMSO), which may then be capped with a fluoroalkylsilane (FAS). The cross-linked PDMSO layer may be formed on the surface of the glass substrate, or a silicon oxide anchor layer may be deposited under the cross-linked (PDMSO) layer. SiCl4, trimethylchlorosilane (TMCS), trichloromethylsilane and combinations of these silanes therein may also be simultaneously vapor deposited onto a substrate surface so as to achieve hydrophobic coatings of exceptional durability.
摘要翻译：底物具有由含氯甲硅烷基的化合物和烷基硅烷的反应产物组成的疏水表面涂层。最优选地，基底是玻璃。在本发明的一个优选形式中，可以通过从四氯化硅或三氯甲基硅烷的加湿反应产物形成氧化硅锚定层或混合有机 - 氧化硅锚定层，随后蒸发氯代烷基硅烷。这样的氧化硅锚固层将有利地具有小于约6.0nm（优选小于约5.0nm）的均方根表面粗糙度和小于约3.0％（优选小于约2.0％）的低雾度值。本发明的另一个实施方案包括同时加湿的含氯甲硅烷基化合物和氯烷基硅烷的气相沉积。具体地说，在某些优选实施方案中，同时气相沉积到四氯化硅（SiCl 4）和二甲基二氯硅烷（DMDCS）的玻璃基底上导致疏水涂层由交联的聚二甲基硅氧烷（PDMSO）组成，然后可以用氟代烷基硅烷 FAS）。可以在玻璃基板的表面上形成交联的PDMSO层，或者可以在交联（PDMSO）层下沉积氧化硅锚定层。 SiCl4，三甲基氯硅烷（TMCS），三氯甲基硅烷及其中的这些硅烷的组合也可以同时气相沉积到基材表面上，以达到特殊耐久性的疏水涂层。

3. 发明授权

US06743515B1 Self-adhesive addition-crosslinking silicone compositions 有权
标题翻译：自粘加成交联硅氧烷组合物
公开(公告)号：US06743515B1
公开(公告)日：2004-06-01
申请号：US09687824
申请日：2000-10-13
申请人： Philipp Müller , Frank Achenbach , Georg Eberl
发明人： Philipp Müller , Frank Achenbach , Georg Eberl
IPC分类号： B32B2520
CPC分类号： C08L83/04 , C08G77/06 , C08G77/12 , C08G77/16 , C08G77/20 , C08G77/24 , C08G77/26 , C08G77/28 , C08G77/30 , C08G77/70 , C08K5/5435 , C09D183/04 , Y10T428/31663 , C08L83/00 , C08L2666/44
摘要： The invention relates to self-adhesive addition-crosslinking silicone compositions which comprises (A) diorganopolysiloxanes, (B) organohydrogenpolysiloxanes containing less than 20 SiH bonded hydrogen atoms and less than 12% aryl groups, (C) organosilicon compounds having epoxy groups and hydrolyzable groups and (D) a hydrosilylation catalyst. The compositions are transparent to translucent, exhibit good compositional comparability, and cure to form strongly adhesive elastomers with good physical properties.
摘要翻译：本发明涉及自粘性加成交联硅氧烷组合物，其包含（A）二有机聚硅氧烷，（B）含有少于20个SiH键合氢原子和少于12％芳基的有机氢聚硅氧烷，（C）具有环氧基团和可水解基团的有机硅化合物和（D）氢化硅烷化催化剂。组合物透明至半透明，表现出良好的组成可比性，并固化形成具有良好物理性能的强粘性弹性体。

4. 发明授权

US06617039B1 Nitrogen-free compounds as adhesion promoters for silicon-based scratch-resistant coatings on polycarbonate 失效
标题翻译：无氮化合物作为聚碳酸酯上硅基耐刮涂层的粘合促进剂
公开(公告)号：US06617039B1
公开(公告)日：2003-09-09
申请号：US10009964
申请日：2001-12-12
申请人： Michael Mager , Jürgen Kirsch , Steffen Hofacker
发明人： Michael Mager , Jürgen Kirsch , Steffen Hofacker
IPC分类号： B32B2520
CPC分类号： C08J7/04 , C08J7/047 , C08J2369/00 , C08J2483/02 , C08K5/5419 , C09D169/00 , C09D183/04 , C09D183/08 , Y10T428/31507 , Y10T428/31663 , C08L69/00 , C08L2666/44
摘要： The invention relates to a process for coating a substrate with a nitrogen-free compound corresponding to formula (I) and/or a hydrolysis product or condensation product [R1(R2)j]iSiR3k(OR4)4−k−i (I), wherein i represents the number 1, 2 or 3, j represents an integer from 1 to 10, k represents the number 0, 1 or 2, k+i is ≦3, and R1 represents OH, OR, SH, SR, OOC—R, R represents C1-C10-alkyl or C6-C12-aryl, R2 is an unsubstituted, singly substituted, or doubly substituted methylene group, R3 is a substituted or unsubstituted C1-C10-alkyl or C6-C12-aryl group, R4 represents a C1-C10-alkyl or C6-C12-aryl group, and wherein if j represents from 2 to 10 the methylene groups in the chain may optionally be interrupted once or several times by hetero atoms.
摘要翻译：本发明涉及用对应于式（I）的无氮化合物和/或水解产物或缩合产物来涂覆底物的方法，其中di代表数字1,2或3，j表示1至10的整数，k 表示数字0,1或2，k + i为<= 3，R 1表示OH，OR，SH，SR，OOC-R，R表示C 1 -C 10 - 烷基或C 6 -C 12 - 芳基，R 2为未取代的，单取代或双取代的亚甲基，R 3是取代或未取代的C 1 -C 10 - 烷基或C 6 -C 12 - 芳基，R 4表示C 1 -C 10 - 烷基或C 6 -C 12 - 芳基，其中如果j表示2 至10个链中的亚甲基可以任选地被杂原子间隔一次或几次。

5. 发明授权

US06613440B2 Addition reaction curing type silicone rubber composition and making method 失效
公开(公告)号：US06613440B2
公开(公告)日：2003-09-02
申请号：US09905979
申请日：2001-07-17
申请人： Hiroyasu Hara , Hideki Sugahara , Yoshifumi Inoue , Takashi Aketa
发明人： Hiroyasu Hara , Hideki Sugahara , Yoshifumi Inoue , Takashi Aketa
IPC分类号： B32B2520
CPC分类号： C08K9/06 , C08G77/12 , C08G77/20 , C08L83/04 , Y10T428/31663 , C08L83/00 , C08L2666/54
摘要： An addition reaction curing type silicone rubber composition comprising (A) an alkenyl-containing diorganopolysiloxane, (B) an alkaline earth metal carbonate powder surface treated with a diorganopolysiloxane, (C) an organohydrogenpolysiloxane, and (D) a platinum group metal catalyst has improved storage stability in that it gives off little or no hydrogen gas during storage. The composition has improved adhesion and a good ability to protect electric or electronic parts from corrosion and finds typical use in the sealing of electric or electronic parts.

6. 发明授权

US06599631B2 Polymer-inorganic particle composites 有权
公开(公告)号：US06599631B2
公开(公告)日：2003-07-29
申请号：US09818141
申请日：2001-03-27
申请人： Nobuyuki Kambe , Yigal Do Blum , Benjamin Chaloner-Gill , Shivkumar Chiruvolu , Sujeet Kumar , David Brent MacQueen
发明人： Nobuyuki Kambe , Yigal Do Blum , Benjamin Chaloner-Gill , Shivkumar Chiruvolu , Sujeet Kumar , David Brent MacQueen
IPC分类号： B32B2520
CPC分类号： G02B1/005 , B32B27/08 , C08G18/3897 , C08G83/001 , C08K9/08 , G02B6/10 , H01L35/24 , Y10T428/16 , Y10T428/25 , Y10T428/2913 , Y10T428/2962 , Y10T428/2991 , Y10T428/31663 , Y10T428/31678 , Y10T428/31681 , Y10T428/31692 , Y10T428/31931
摘要： Inorganic particle/polymer composites are described that involve chemical bonding between the elements of the composite. In some embodiments, the composite composition includes a polymer having side groups chemically bonded to inorganic particles. Furthermore, the composite composition can include chemically bonded inorganic particles and ordered copolymers. Various electrical, optical and electro-optical devices can be formed from the composites.

7. 发明授权

US06420037B1 Silicone rubber based coating composition for air bags 失效
标题翻译：用于气囊的硅橡胶基涂料组合物
公开(公告)号：US06420037B1
公开(公告)日：2002-07-16
申请号：US09526953
申请日：2000-03-16
申请人： Yuichi Tsuji , Akito Nakamura
发明人： Yuichi Tsuji , Akito Nakamura
IPC分类号： B32B2520
CPC分类号： C09D183/04 , B60R2021/23514 , C08K7/26 , Y10T428/31663 , C08L83/04 , C08L83/00 , C08L2666/28 , C08L2666/54
摘要： A silicone rubber based coating composition for air bags comprising about 0.1 to 50 wt % of spherical powder with an average particle size of about 10 &mgr;m to 300 &mgr;m.
摘要翻译：一种用于气囊的硅橡胶基涂料组合物，其包含约0.1至50重量％的平均粒径为约10至300μm的球形粉末。

8. 发明授权

US06416861B1 Organosilicon compounds and uses thereof 失效
标题翻译：有机硅化合物及其用途
公开(公告)号：US06416861B1
公开(公告)日：2002-07-09
申请号：US09504217
申请日：2000-02-15
申请人： Younghee Lee , Richard B. Silverman
发明人： Younghee Lee , Richard B. Silverman
IPC分类号： B32B2520
CPC分类号： C07F7/0812 , C07B2200/11 , C07F7/081 , C40B40/00 , Y10T428/2962 , Y10T428/2995
摘要： A compound of the formula: and a resin-bound compound of the formula: and their use in combinatorial chemistry and in the synthesis of compounds comprising at least one aromatic moiety is described, where R1, R2, R3, R4, R5, R6, R7, L1, P, Ar1, and X are as herein defined.
摘要翻译：描述了下式的化合物和下式的树脂结合化合物及其在组合化学中的用途和合成含有至少一个芳族部分的化合物，其中R 1，R 2，R 3，R 4，R 5，R 6， R7，L1，P，Ar1和X如本文所定义。

9. 发明授权

US06391446B1 Textile element made of fibres which contain silicon and procedure for improving their thermal stability 失效
标题翻译：由含有硅的纤维制成的纺织元件和用于提高其热稳定性的方法
公开(公告)号：US06391446B1
公开(公告)日：2002-05-21
申请号：US09457655
申请日：1999-12-09
申请人： Pere Relats Casas
发明人： Pere Relats Casas
IPC分类号： B32B2520
CPC分类号： C03C25/40 , Y10T428/2918 , Y10T428/2933 , Y10T428/2962 , Y10T428/2964 , Y10T442/2033 , Y10T442/223 , Y10T442/2328 , Y10T442/2926 , Y10T442/2975 , Y10T442/2992
摘要： Textile elements made of fibres which contain from 40% to 99.9% silicon dioxide and are coated with a silicone-containing emulsion are disclosed. The emulsion includes an anionically stabilized hydroxylated polydiorganosiloxane contains two hydroxyl groups which are linked with silicone by molecule and colloidal silica. The textile elements demonstrate considerable wear resistance. Methods of preparing the same are also disclosed.
摘要翻译：公开了由含有40％至99.9％的二氧化硅并且涂有含硅氧烷的乳液的由纤维制成的纺织元件。乳液包括阴离子稳定的羟基化聚二有机硅氧烷，其包含两个羟基，其通过分子与硅氧烷连接，并且胶体二氧化硅。纺织品表现出相当大的耐磨性。还公开了制备其的方法。

10. 发明授权

US06828032B2 Insulating layer for a heating element 失效
标题翻译：用于加热元件的绝缘层
公开(公告)号：US06828032B2
公开(公告)日：2004-12-07
申请号：US10122742
申请日：2002-04-15
申请人： Ytsen Wielstra , Jolanda Harma Sagitta Winkel , Rene Henk Van Der Woude
发明人： Ytsen Wielstra , Jolanda Harma Sagitta Winkel , Rene Henk Van Der Woude
IPC分类号： B32B2520
CPC分类号： C09D183/04 , H05B3/148 , H05B3/26 , H05B3/262 , H05B3/265 , H05B3/267 , H05B3/748 , H05B2203/013 , H05B2203/017 , H05B2203/021 , Y10T428/31663 , Y10T428/31721
摘要： A heating element employing a substrate, an electrically insulating layer, and a resistive layer. The electrically insulating layer of the heating element includes a first layer that is obtained by a sol-gel process, and a second layer including a resin.
摘要翻译：采用基板，电绝缘层和电阻层的加热元件。加热元件的电绝缘层包括通过溶胶 - 凝胶法获得的第一层和包含树脂的第二层。

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