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    • 2. 发明授权
    • Epoxidizing agent
    • 环氧化剂
    • US5789606A
    • 1998-08-04
    • US713181
    • 1996-09-12
    • Taizo OnoHaruhiko FukayaMasakazu NishidaTakashi Abe
    • Taizo OnoHaruhiko FukayaMasakazu NishidaTakashi Abe
    • B01J31/02C07B33/00C07B41/04C07B61/00C07C291/04C07D301/03C07D303/08
    • C07D301/14
    • The object of the invention is to provide a novel process for epoxidation of perfluoro-olefins. This invention relates to a process for epoxidizing a perfluoro-olefin, characterized by employing a tertiary amine N-oxide represented by the general formula (I): ##STR1## (wherein R.sup.1, R.sup.2 and R.sup.3 each is a straight-chain or branched alkyl group having 1 to 10 carbon atoms, a lower alkyl group having 1 to 3 carbon atoms, or an aromatic group which may have a nitro group or a cyano group as a substituent; provided that all of R.sup.1, R.sup.2 and R.sup.3 are selected from the above alkyl groups, R.sup.1, R.sup.2 and R.sup.3 may combine with one another directly or through oxygen atoms or nitrogen atoms to form a cyclic compound of 5-7 membered ring), or iodosobenzene. According to the present invention, perfluoro-olefins can be converted to corresponding perfluoroepoxides cheaply and in high yields. Epoxides produced by the process of this invention are utilized as intermediates for syntheses of surface active agents, lubricant oils, water repellents, oil repellents, polymers, and the like.
    • 本发明的目的是提供一种全氟烯烃环氧化的新方法。 本发明涉及一种环氧化全氟烯烃的方法,其特征在于使用由通式(I)表示的叔胺N-氧化物:其中R1,R2和R3各自为直链 或具有1至10个碳原子的支链烷基,具有1至3个碳原子的低级烷基或可以具有硝基或氰基作为取代基的芳族基团;条件是所有R1,R2和R3均为 选自上述烷基,R 1,R 2和R 3可以直接或通过氧原子或氮原子彼此结合形成5-7元环的环状化合物)或碘代苯。 根据本发明,全氟烯烃可以廉价地以高产率转化成相应的全氟环氧化物。 通过本发明方法生产的环氧化物被用作合成表面活性剂,润滑油,防水剂,防油剂,聚合物等的中间体。