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1. 发明授权

US06818800B2 Methods for providing low-molecular radicals, radical-carrying molecules, a polymerization catalyst containing them and processes for polymerization and polymers produced thereby 有权
标题翻译：提供低分子基团，自由基携带分子，含有它们的聚合催化剂和聚合方法以及由此制备的聚合物的方法
公开(公告)号：US06818800B2
公开(公告)日：2004-11-16
申请号：US10291650
申请日：2002-11-12
申请人： Taizo Ono , Eiji Hayashi , Haruhiko Fukaya , Tetsuo Shimizu
发明人： Taizo Ono , Eiji Hayashi , Haruhiko Fukaya , Tetsuo Shimizu
IPC分类号： C07C2118
CPC分类号： C07C17/04 , C07C17/263 , C07C17/32 , C08F4/00 , C07C19/08 , C07C21/18 , C07C22/08
摘要： The present invention is to provide a method for providing a low-molecular radical which comprises releasing a radical having a lower molecular weight from a super-stable perfluoroalkyl-based radical followed by generating the above super-stable perfluoroalkyl-based radical. The invention is a method for providing a low-molecular radical which comprises a super-stable radical generating reaction for generating a super-stable perfluoroalkyl-based radical from a radical-carrying molecule and a radical releasing reaction for releasing the low-molecular radical from said super-stable perfluoroalkyl-based radical, said radical-carrying molecule being generated as a result of said radical releasing reaction.
摘要翻译：本发明提供一种提供低分子量基团的方法，其包括从超稳定的全氟烷基基团释放具有较低分子量的基团，然后产生上述超稳定的全氟烷基基团。本发明是一种提供低分子量的方法，其包括用于从自由基携带分子产生超稳定全氟烷基基团的超稳定自由基产生反应和用于从所述超分子自由基释放低分子量的自由基释放反应，稳定的全氟烷基基团，所述自由基携带分子是由于所述自由基释放反应产生的。

2. 发明申请

US20050197514A1 Highly branched perfluoroolefins, super-stable perfluoroalkyl radicals and production methods thereof 审中-公开
标题翻译：高分支全氟烯烃，超稳定全氟烷基及其制备方法
公开(公告)号：US20050197514A1
公开(公告)日：2005-09-08
申请号：US11123035
申请日：2005-05-06
申请人： Taizo Ono , Masakazu Nishida , Masaharu Okazaki , Kazumi Toriyama , Tetsuo Shimizu
发明人： Taizo Ono , Masakazu Nishida , Masaharu Okazaki , Kazumi Toriyama , Tetsuo Shimizu
IPC分类号： C07B61/00 , C07C17/04 , C07C17/26 , C07C17/263 , C07C19/08 , C07C21/18
CPC分类号： C07C17/04 , C07C17/263 , C07C19/08 , C07C21/18
摘要： The present invention is to provide a method for producing a highly branched perfluoroolefin conveniently in a high yield, a novel highly branched perfluoroolefin, a method for producing a super-stable perfluoroalkyl radical and a novel super-stable perfluoroalkyl radical. The present invention is a production method of a perfluoroolefin which comprises reacting a hexafluoropropene trimer with a trialkylperfluoroalkylsilane in an aprotic polar solvent using a fluoride ion as a catalyst.
摘要翻译：本发明提供一种以高产率方便地制备高支化全氟烯烃的方法，一种新型高支化全氟烯烃，一种制备超稳定全氟烷基的方法和一种新的超稳定全氟烷基。本发明是一种全氟烯烃的制造方法，其特征在于，使用氟离子作为催化剂，使六氟丙烯三聚物与三烷基全氟烷基硅烷在非质子极性溶剂中反应。

3. 发明授权

US06710214B2 Highly branched perfluoroolefins, super-stable perfluoroalkyl radicals and production methods thereof 有权
标题翻译：高分支全氟烯烃，超稳定全氟烷基及其制备方法
公开(公告)号：US06710214B2
公开(公告)日：2004-03-23
申请号：US10291699
申请日：2002-11-12
申请人： Taizo Ono , Masakazu Nishida , Masaharu Okazaki , Kazumi Toriyama , Tetsuo Shimizu
发明人： Taizo Ono , Masakazu Nishida , Masaharu Okazaki , Kazumi Toriyama , Tetsuo Shimizu
IPC分类号： C07C2118
CPC分类号： C07C17/04 , C07C17/263 , C07C19/08 , C07C21/18
摘要： The present invention is to provide a method for producing a highly branched perfluoroolefin conveniently in a high yield, a novel highly branched perfluoroolefin, a method for producing a super-stable perfluoroalkyl radical and a novel super-stable perfluoroalkyl radical. The present invention is a production method of a perfluoroolefin which comprises reacting a hexafluoropropene trimer with a trialkylperfluoroalkylsilane in an aprotic polar solvent using a fluoride ion as a catalyst.
摘要翻译：本发明提供一种以高产率方便地生产高支化全氟烯烃的方法，一种新型高支化全氟烯烃，一种制备超稳定全氟烷基的方法和一种新型超稳定全氟烷基。本发明是一种使用氟离子作为催化剂使六氟丙烯三聚物与三烷基全氟烷基硅烷在非质子极性溶剂中反应的全氟烯烃的制备方法。

4. 发明授权

US09127114B2 Curable fluorine-containing polymer composition 有权
标题翻译：可固化含氟聚合物组合物
公开(公告)号：US09127114B2
公开(公告)日：2015-09-08
申请号：US12445354
申请日：2007-10-12
申请人： Katsuhiko Imoto , Tetsuo Shimizu , Tatsuya Morikawa , Masayuki Hayashi , Tomohiro Iimura , Peter Cheshire Hupfield
发明人： Katsuhiko Imoto , Tetsuo Shimizu , Tatsuya Morikawa , Masayuki Hayashi , Tomohiro Iimura , Peter Cheshire Hupfield
IPC分类号： C08G18/81 , C09D127/18 , C09D127/12 , C09D127/20 , C08G18/62 , C08G77/442 , C08L83/04 , C09D131/02 , C08G77/04 , C08G77/12 , C08K5/5419 , C08L27/12 , C08L31/02
CPC分类号： C08G18/8108 , C08G18/6279 , C08G77/045 , C08G77/12 , C08G77/442 , C08K5/5419 , C08L27/12 , C08L31/02 , C08L83/04 , C09D127/12 , C09D127/18 , C09D127/20 , C09D131/02 , C08L2666/04 , C08L2666/14
摘要： There is provided a curable fluorine-containing polymer composition which is quickly cured at relatively low temperatures by hydrosilylation reaction and provides a coating film which has high hardness, excellent solvent resistance and flexibility. The curable fluorine-containing polymer composition comprises a fluorine-containing polymer comprising a fluorinated ethylenic monomer unit and a non-fluorinated ethylenic monomer unit, in which a part or the whole of the non-fluorinated ethylenic monomer units is a unit represented by the formula: wherein R1 is hydrogen or methyl; R2 is a hydrocarbon group having ethylenic C═C; X is —C(O)NH— or —C(O)—; R3 is —O—, —O[CH(R4)]mO—, —(CH2)mO—, —OC(O)—(CH2)mO— or —(CH2)mOC(O)—(CH2)nO—, where R4 is —H, —OH, —CH2OH or —O—X—R2, a siloxane compound having hydrogen atom bonded to silicon atom, and a catalyst for hydrosilylation reaction.
摘要翻译：提供一种通过氢化硅烷化反应在相对低的温度下快速固化的可固化含氟聚合物组合物，并提供具有高硬度，优异的耐溶剂性和柔性的涂膜。可固化含氟聚合物组合物包含含有氟化乙烯性单体单元和非氟化乙烯性单体单元的含氟聚合物，其中一部分或全部未氟化烯属单体单元为式其中R1是氢或甲基; R2是具有烯属C = C的烃基; X是-C（O）NH-或-C（O） - ; R 3是-O-，-O [CH（R 4）] m O - ， - （CH 2）m O - ， - OC（O） - （CH 2）m O-或 - （CH 2）mOC（O） - （CH 2）其中R4是-H，-OH，-CH2OH或-O-X-R2，具有与硅原子键合的氢原子的硅氧烷化合物和氢化硅烷化反应的催化剂。

5. 发明授权

US08562893B2 Molding method and molding device for forming impeller 有权
标题翻译：成型方法和成型装置用于形成叶轮
公开(公告)号：US08562893B2
公开(公告)日：2013-10-22
申请号：US13284225
申请日：2011-10-28
申请人： Masami Natsume , Tetsuo Shimizu , Tomoo Sagawa
发明人： Masami Natsume , Tetsuo Shimizu , Tomoo Sagawa
IPC分类号： B29C45/44
CPC分类号： B29C45/4471 , B29L2031/08
摘要： A molding method for forming an impeller, includes a mold clamping process having a first mold for forming one side of blades, a second mold firmly clamped with the first mold, and a core arranged at the first mold relative to the blades, the mold clamping process clamping the first mold to the second mold in a state where the core is arranged between the first mold and the second mold, an injecting process injecting resin in a cavity obtained by the mold clamping process, and a mold removing process including the steps of releasing at least the first mold from the clamped state obtained by the mold clamping process to generate an opened portion in the first mold after the resin is hardened, rotating the core about a rotational axis toward the opened portion of the first mold, and separating the core from the resin-molded impeller.
摘要翻译：一种用于形成叶轮的成型方法，包括：模具夹紧工艺，其具有用于形成叶片的一侧的第一模具，与第一模具牢固夹紧的第二模具和相对于叶片在第一模具处布置的芯部，模具夹紧在芯部布置在第一模具和第二模具之间的状态下，将第一模具夹紧到第二模具中，在通过模具夹紧工艺获得的模腔中注入树脂注入工艺，以及脱模工艺，包括以下步骤：至少将第一模具从通过合模过程获得的夹紧状态释放，以在树脂硬化之后在第一模具中产生开口部分，使芯围绕旋转轴线朝向第一模具的开口部分旋转，芯从树脂模制叶轮。

6. 发明授权

US08137800B2 Porous multilayered hollow-fiber membrane and process for producing the same 有权
标题翻译：多孔多层中空纤维膜及其制造方法
公开(公告)号：US08137800B2
公开(公告)日：2012-03-20
申请号：US12089729
申请日：2006-10-11
申请人： Hirokazu Fujimura , Noboru Kubota , Masatoshi Hashino , Tetsuo Shimizu
发明人： Hirokazu Fujimura , Noboru Kubota , Masatoshi Hashino , Tetsuo Shimizu
IPC分类号： B32B3/10 , B29C44/22 , B32B5/22
CPC分类号： B01D69/087 , B01D69/085 , B01D69/088 , B01D69/12 , B01D71/26 , B01D71/34 , B01D2325/24 , D01D5/24 , D01D5/247 , D01D5/34 , D01F1/08 , D01F6/04 , D01F6/12 , Y10T428/249975 , Y10T428/249986 , Y10T428/2913 , Y10T428/2929
摘要： A porous hollow fiber membrane which has high blocking performance and high water permeability suitable for filtration and the like and exhibits excellent strength, and a process for stably producing the porous hollow fiber membrane are disclosed. The process utilizes a hollow fiber molding nozzle having two or more circular discharge ports which are disposed concentrically. Multilayer melt-extrusion is performed by discharging molten mixtures which include a thermoplastic resin and an organic liquid and differ in composition from the adjacent discharge ports. The resulting product is cooled to solidify to obtain a hollow fiber. The organic liquid is then removed from the hollow fiber by extraction to produce a porous hollow fiber membrane. The molten mixture discharged from at least one circular discharge port includes an inorganic fine powder in addition to the thermoplastic resin and the organic liquid. The inorganic fine powder is removed by extraction after cooling in addition to the organic liquid.
摘要翻译：本发明公开了一种多孔中空纤维膜，它具有优异的阻隔性能和高透水性，适用于过滤等，并且具有优异的强度，以及稳定地生产多孔中空纤维膜的方法。该方法利用具有同心设置的两个或更多个圆形排出口的中空纤维成型喷嘴。通过排出包括热塑性树脂和有机液体的熔融混合物并且与相邻排出口的组成不同，进行多层熔融挤出。将所得产物冷却固化，得到中空纤维。然后通过萃取从中空纤维中除去有机液体，生成多孔中空纤维膜。从至少一个圆形排出口排出的熔融混合物除了热塑性树脂和有机液体之外还包括无机细粉末。除了有机液体之外，通过萃取除去无机细粉末。

7. 发明授权

US08093518B2 Switching element relying on nanogap electrodes 有权
标题翻译：依靠纳米胶片电极的开关元件
公开(公告)号：US08093518B2
公开(公告)日：2012-01-10
申请号：US11992883
申请日：2006-09-25
申请人： Yasuhisa Naitoh , Masayo Horikawa , Hidekazu Abe , Tetsuo Shimizu , Wataru Mizutani , Shigeo Furuta , Masatoshi Ono , Tsuyoshi Takahashi
发明人： Yasuhisa Naitoh , Masayo Horikawa , Hidekazu Abe , Tetsuo Shimizu , Wataru Mizutani , Shigeo Furuta , Masatoshi Ono , Tsuyoshi Takahashi
IPC分类号： H01H1/02
CPC分类号： H01L45/1226 , H01L45/04 , H01L45/12
摘要： A switching element 100 includes an insulating substrate 10, a first electrode 20 provided on the insulating substrate 10, a second electrode 30 provided on the insulating substrate 10, and an interelectrode gap 40 provided between the first electrode 20 and the second electrode 30, a distance G between the first electrode 20 and the second electrode 30 being 0 nm
摘要翻译：开关元件100包括绝缘基板10，设置在绝缘基板10上的第一电极20，设置在绝缘基板10上的第二电极30和设置在第一电极20和第二电极30之间的电极间间隙40，第一电极20和第二电极30之间的距离G为0nm

8. 发明授权

US08022383B2 Two-terminal resistance switching element with silicon, and semiconductor device 失效
标题翻译：具有硅的两端电阻开关元件和半导体器件
公开(公告)号：US08022383B2
公开(公告)日：2011-09-20
申请号：US12213054
申请日：2008-06-13
申请人： Yasuhisa Naitoh , Yukinori Morita , Masayo Horikawa , Tetsuo Shimizu
发明人： Yasuhisa Naitoh , Yukinori Morita , Masayo Horikawa , Tetsuo Shimizu
IPC分类号： H01L47/00
CPC分类号： H01L45/1226 , H01L45/04 , H01L45/1206 , H01L45/1253
摘要： A two-terminal resistance switching element, wherein two silicon films each doped with an impurity are arranged with a gap width in the order of nanometers. The gap width is in the range of from 0.1 nm to 100 nm. A semiconductor device can be obtained by providing the two-terminal resistance switching element in a memory, a storage device or other device.
摘要翻译：两端电阻开关元件，其中每个掺杂有杂质的两个硅膜以间距宽度排列成几毫米数量级。间隙宽度在0.1nm至100nm的范围内。可以通过在存储器，存储装置或其他装置中提供两端电阻开关元件来获得半导体器件。

9. 发明申请

US20110025984A1 PROJECTOR 有权
标题翻译：投影机
公开(公告)号：US20110025984A1
公开(公告)日：2011-02-03
申请号：US12844952
申请日：2010-07-28
申请人： Kunihiko Takagi , Kaname Nagatani , Akira Egawa , Tetsuo Shimizu , Joji Karasawa , Fumihide Sasaki
发明人： Kunihiko Takagi , Kaname Nagatani , Akira Egawa , Tetsuo Shimizu , Joji Karasawa , Fumihide Sasaki
IPC分类号： G03B21/16
CPC分类号： G03B21/16
摘要： A projector includes: spatial light modulation devices; and a cooling duct configured to flow a cooling air for sequentially cooling the spatial light modulation devices, the cooling duct has a first flow path formed by portions including the light entrance surface of at least one of the spatial light modulation devices for the respective color lights, a second flow path formed by portions including the light exit surface of the corresponding spatial light modulation device, and a junction area where the cooling air flowing through the first flow path and the cooling air flowing through the second flow path join each other, and the junction area is disposed at a downstream position of the cooling air with respect to the spatial light modulation device provided for a predetermined color light whose light amount is the maximum in the respective color lights that enter the light entrance surface.
摘要翻译：投影机包括：空间光调制装置; 以及冷却管道，其构造成使冷却空气流动以顺序地冷却空间光调制装置，所述冷却管道具有由包括用于各个颜色的光的至少一个空间光调制装置的光入射面的部分形成的第一流路由包括相应的空间光调制装置的光出射表面的部分形成的第二流路和流过第一流路的冷却空气和流经第二流路的冷却空气相互结合的接合区域，以及接合区域相对于为进入光入射面的各色光中的光量最大的预定色光设置的空间光调制装置设置在冷却空气的下游位置。

10. 发明申请

US20100314010A1 HIGH-STRENGTH HOT-ROLLED STEEL SHEET AND METHOD FOR MANUFACTURING SAME 有权
标题翻译：高强度热轧钢板及其制造方法
公开(公告)号：US20100314010A1
公开(公告)日：2010-12-16
申请号：US12866513
申请日：2009-02-04
申请人： Shinjiro Kaneko , Kaneharu Okuda , Tetsuo Shimizu , Noriaki Moriyasu , Masahide Watabe
发明人： Shinjiro Kaneko , Kaneharu Okuda , Tetsuo Shimizu , Noriaki Moriyasu , Masahide Watabe
IPC分类号： C21D8/02 , C22C38/14 , C22C38/02 , C22C38/04 , C22C38/06
CPC分类号： C22C38/04 , C21D1/20 , C21D8/0226 , C21D8/0263 , C21D9/46 , C21D2211/002 , C21D2211/004 , C21D2211/005 , C22C38/02 , C22C38/06 , C22C38/14
摘要： A high-strength hot-rolled steel sheet has a tensile strength (TS) of 540 to 780 MPa, only small variations in strength, and excellent uniformity in strength using a general-purpose Ti-containing steel sheet, which is inexpensive. The high-strength hot-rolled steel sheet includes, on a mass percent basis, 0.05%-0.12% C, 0.5% or less Si, 0.8%-1.8% Mn, 0.030% or less P, 0.01% or less S, 0.005%-0.1% Al, 0.01% or less N, 0.030%-0.080% Ti, and the balance being Fe and incidental impurities. The microstructure have a bainitic ferrite fraction of 70% or more, and the amount of Ti present in a precipitate having a size of less than 20 nm is 50% or more of the value of Ti* calculated using formula (1): Ti*=[Ti]−48/14×[N] (1) where [Ti] and [N] represent a Ti content (percent by mass) and a N content (percent by mass), respectively, of the steel sheet.
摘要翻译：高强度热轧钢板的拉伸强度（TS）为540〜780MPa，强度变化小，使用廉价的通用含Ti钢板的强度均匀性优异。高强度热轧钢板以质量％计含有0.05％-0.12％C，0.5％以下Si，0.8％-1.8％Mn，0.030％以下P，0.01％以下S，0.005 ％-0.1％Al，0.01％以下N，0.030％-0.080％Ti，余量为Fe和附带杂质。显微组织具有70％以上的贝氏体铁素体分数，并且存在于尺寸小于20nm的析出物中的Ti的量为使用式（1）计算的Ti *值的50％以上：Ti * = [Ti] -48 / 14×[N]（1）其中[Ti]和[N]分别表示钢板的Ti含量（质量％）和N含量（质量％）。

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