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    • 3. 发明专利
    • METHOD AND APPARATUS FOR DECOMPOSING SAMPLE
    • JPH06160256A
    • 1994-06-07
    • JP20366592
    • 1992-07-30
    • TOSHIBA CORP
    • TAKENAKA MIYUKIHAYASHI MASARUMATSUNAGA HIDEKIKOZUKA SHOJIYABUKI MOTOO
    • G01N1/28G01N30/02G01N30/06
    • PURPOSE:To decompose a sample efficiently by cooling gas produced by heating solvent for decomposing the sample in an enclosed vessel and absorbing the gas into pure water contained while being spaced apart therefrom thereby decomposing the sample immersed in the pure water by means of the solvent absorbed into the pure water. CONSTITUTION:Cover 1a of an enclosed vessel 1 is removed and an acid liquid A is injected therein. A container 3 is then set above the vessel 1 and pure water is filled in the container 3. A sample is then immersed in the pure water and the cover 1a is applied onto the container 3 thus closing the container tightly. Botton part of the vessel 1 is then heated by heating means 7 thus heating the acid liquid A. Consequently, the acid liquid A evaporates and intrudes through a vent 3a into the container 3. Since the interior of the container 3 is cooled forcibly by means of a cooling pipe 5, the acid vapor is absorbed into the pure water in the container 3 thus recovering a high purity acid liquid A. In this regard, impurities in the acid liquid A do not evaporate because of the atmospheric pressure and thereby extremely high purity acid vapor is obtained. The sample is decomposed by the high purity acid liquid A to produce a solution causing no external contamination.
    • 8. 发明专利
    • METHOD FOR DECOMPOSING PCB
    • JPH09253478A
    • 1997-09-30
    • JP6958996
    • 1996-03-26
    • TOSHIBA CORP
    • YABUKI MOTOOSAKAI KIMITOTANAKA AKIRAENDO HIROSHI
    • A62D3/36A62D3/38A62D101/22B01J19/00G01N1/28A62D3/00
    • PROBLEM TO BE SOLVED: To decompose and make harmless PCB by means of a simple apparatus by vaporizing PCB in a first heat process and heating the vaporized PCB together with oxygen and steam in a second heat process at a specified temperature or above. SOLUTION: PCB stored in a PCB container is transferred to a sample table 4 within a quartz tube 7 through a pump 6 and heated by means of a first heating means 3 to be vaporized. The vaporized PCB is transferred to a heating position of a second heating means 1 together with steam and oxygen supplied to the quartz tube from a steam generating means 9 and an oxygen cylinder 10. The PCB together with the steam and oxygen is heated at a temperature of 700 deg.C or higher to be decomposed into carbon dioxide, steam and hydrogen chloride, which are then transferred to a neutralization container 13 containing a neutralizing solution 12 to neutralize the hydrogen chloride. Hydrogen chloride gas and the like which have not been absorbed in the neutralization tank 13 are cooled in a cooling tower 14 before organic constituents are absorbed by active carbon 15. The PCB can be made harmless by such a simple apparatus.