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    • 1. 发明专利
    • Catalyst
    • 催化剂
    • JP2012187485A
    • 2012-10-04
    • JP2011052185
    • 2011-03-09
    • Toshiba Corp株式会社東芝
    • KOSHIZAKI KENJIFUKAZAWA TAKAYUKIOSADA NORIKAZU
    • B01J23/755B01J35/10B01J37/02B01J37/08B01J37/16C01B3/40
    • Y02P20/52
    • PROBLEM TO BE SOLVED: To provide a catalyst with metal particles concentrated in high density on the surface of the catalyst, and a method for producing the catalyst.SOLUTION: This catalyst includes a carrier having a sintered structure containing alumina or magnesium as a main component, and particles of one or more kinds of metals selected out of nickel, iron, cobalt and copper, dispersed in the surface and pore wall of the carrier. When pore diameter distribution is measured in a range of 10 nm or more and 1,000 nm or less by a mercury penetration method, a mode diameter is 200 nm or less, and the cumulative pore volume of pores of 10 nm or more and 100 nm or less accounts for 15% or more to the cumulative pore volume of pores in a measuring range.
    • 要解决的问题:提供催化剂在催化剂表面上以高密度浓缩的金属颗粒,以及催化剂的制造方法。 解决方案:该催化剂包括具有以氧化铝或镁为主要成分的烧结结构的载体和分散在表面和孔壁中的镍,铁,钴和铜中选出的一种或多种选自镍,铁,钴和铜的金属的颗粒 的承运人。 当通过汞渗透法在10nm以上且1000nm以下的范围内测定孔径分布时,模式直径为200nm以下,孔的累积孔体积为10nm以上且100nm以下,或 少于测量范围内孔隙累积孔体积的15%以上。 版权所有(C)2013,JPO&INPIT
    • 2. 发明专利
    • Carbon dioxide absorber, carbon dioxide separator, reformer and producing method of carbon dioxide absorber
    • 二氧化碳吸收器,二氧化碳分离器,二氧化碳吸收器的改造器和生产方法
    • JP2009106812A
    • 2009-05-21
    • JP2007279341
    • 2007-10-26
    • Toshiba Corp株式会社東芝
    • IMADA TOSHIHIROKATO YASUHIROKATO MASAHIROKOSHIZAKI KENJIMURAMATSU TAKEHIKO
    • B01J20/10B01D53/14B01D53/62C01B3/38C01B3/56C01B32/50C01B33/32
    • Y02A50/2342Y02C10/04Y02C10/06Y02P20/152
    • PROBLEM TO BE SOLVED: To provide a carbon dioxide absorber which can efficiently absorb low-concentration carbon dioxide at high temperature, a carbon dioxide separator which uses the carbon dioxide absorber, a reformer which uses the carbon dioxide absorber and a producing method of the carbon dioxide absorber. SOLUTION: The carbon dioxide absorber is characterized by containing lithium silicate including lithium orthosilicate and a rubidium compound. The carbon dioxide separator which houses the carbon dioxide absorber and the reformer which houses the carbon dioxide absorber are provided. The producing method of the carbon dioxide absorber has a process of producing the lithium silicate by blending silicon dioxide with lithium carbonate and a process of adding the rubidium compound to the lithium silicate. Otherwise the producing method of the carbon dioxide absorber has a process of producing the lithium silicate by blending silicon dioxide with lithium carbonate and a process of adding the rubidium compound when producing the lithium silicate. COPYRIGHT: (C)2009,JPO&INPIT
    • 解决的问题:提供一种二氧化碳吸收器,其能够高效地吸收低浓度二氧化碳在高温下使用二氧化碳吸收器的二氧化碳分离器,使用二氧化碳吸收器的重整器和制造方法 的二氧化碳吸收器。 解决方案:二氧化碳吸收器的特征在于含有包括原硅酸锂和铷化合物的硅酸锂。 提供容纳二氧化碳吸收器的二氧化碳分离器和容纳二氧化碳吸收器的重整器。 二氧化碳吸收器的制造方法具有通过将二氧化硅与碳酸锂混合来制造硅酸锂的方法,以及将该铷化合物添加到硅酸锂中的工序。 另外,二氧化碳吸收器的制造方法具有通过将二氧化硅与碳酸锂混合来制造硅酸锂的方法,以及在制造硅酸锂时添加铷化合物的方法。 版权所有(C)2009,JPO&INPIT
    • 3. 发明专利
    • Method for regenerating absorbing material
    • 吸收材料再生方法
    • JP2008221082A
    • 2008-09-25
    • JP2007060661
    • 2007-03-09
    • Toshiba Corp株式会社東芝
    • KOSHIZAKI KENJIMURAMATSU TAKEHIKOKATO MASAHIROKATO YASUHIRO
    • B01D53/14B01J20/02C01B3/32C01B37/00H01M8/06
    • B01J35/0006B01J20/10B01J20/3433B01J20/3483B01J23/755B01J23/78B01J23/94C01B3/323C01B3/56C01B2203/0233C01B2203/0425C01B2203/0475C01B2203/1011C01B2203/1229Y02C10/06Y02P20/52Y02P20/584Y10S502/514
    • PROBLEM TO BE SOLVED: To provide a method for regenerating an absorbing material where carbon dioxide is released from an absorbing material, and further, carbon precipitated on the absorbing material can be removed. SOLUTION: Regarding the method where the inside of a reformer containing a gas introduction part for introducing a gaseous starting material and water vapor and an exhaust part for a reforming reaction gas is filled with an absorbing material for absorbing carbon dioxide containing a catalyst and lithium silicate, a gaseous starting material and water vapor are fed into the reformer through the gas introduction part, so as to cause water vapor reforming reaction, carbon dioxide by-produced together with hydrogen is absorbed with the absorbing material, and, after the absorbing capacity of carbon dioxide by the absorbing material is deteriorated, the carbon dioxide is released from the absorbing material, so as to regenerate the absorbing material, the temperature in the reformer is set to ≥625°C, and also, an inert gas or an inert gas containing carbon dioxide by 5 vol.% is fed into the reformer as a treatment gas through the exhaust part in such a manner that its direction is made opposite to the feed direction of the gaseous starting material and the water vapor. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:提供一种再生吸收材料的方法,其中二氧化碳从吸收材料中释放,并且还可以除去沉积在吸收材料上的碳。 解决方案:关于包含用于引入气态原料和水蒸汽的气体引入部分的重整器的内部和用于重整反应气体的排气部分的内部填充有用于吸收含有催化剂的二氧化碳的吸收材料的方法 并且通过气体导入部将气态原料和水蒸气的硅酸锂供给到重整器中,从而引起水汽重整反应,与氢一起副产生的二氧化碳被吸收材料吸收,在 吸收材料的二氧化碳吸收能力下降,二氧化碳从吸收材料中释放出来,从而再生吸收材料,将重整器中的温度设定为≥625℃,还可以使用惰性气体或 将含有5体积%的二氧化碳的惰性气体作为处理气体通过排气部以其方向为ma的方式供给到重整器 与气态原料和水蒸汽的进料方向相反。 版权所有(C)2008,JPO&INPIT
    • 7. 发明专利
    • Catalyst, and method for producing the same
    • 催化剂及其生产方法
    • JP2012187484A
    • 2012-10-04
    • JP2011052184
    • 2011-03-09
    • Toshiba Corp株式会社東芝
    • KOSHIZAKI KENJIFUKAZAWA TAKAYUKIOSADA NORIKAZUKUBOKI TAKASHI
    • B01J23/755B01J37/08C01B31/02
    • Y02P20/584
    • PROBLEM TO BE SOLVED: To provide a recyclable catalyst and a method for producing the same.SOLUTION: This catalyst is a molding of a ceramics sintered body having a first portion and a second portion. The first portion has a sintered structure of an oxide of first metal which is one or more kinds of metals selected from a group consisting of aluminum, magnesium, chromium and manganese, and particles of second metal which is one or more kinds of metals selected from a group consisting of nickel, iron, cobalt and copper, dispersed on the surface of the sintered structure of the oxide of the first metal. The second portion has a sintered structure containing a composite oxide of the first metal and second metal. The first portion exists in a surface layer part of the molding.
    • 要解决的问题:提供可回收的催化剂及其制备方法。 解决方案:该催化剂是具有第一部分和第二部分的陶瓷烧结体的模制品。 第一部分具有第一金属的氧化物的烧结结构,其为选自铝,镁,铬和锰中的一种或多种金属,以及选自以下的一种或多种金属的第二金属颗粒: 由镍,铁,钴和铜组成的组分散在第一金属的氧化物的烧结结构的表面上。 第二部分具有包含第一金属和第二金属的复合氧化物的烧结结构。 第一部分存在于模制品的表层部分中。 版权所有(C)2013,JPO&INPIT