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1. 发明授权

US6150457A One-component thermoset coating compositions 有权
标题翻译：单组分热固性涂料组合物
公开(公告)号：US6150457A
公开(公告)日：2000-11-21
申请号：US197912
申请日：1998-11-23
申请人： Sze-Ming Lee , Douglas A. Wicks , Eberhard Koenig , Carol L. Kinney , Karen M. Henderson
发明人： Sze-Ming Lee , Douglas A. Wicks , Eberhard Koenig , Carol L. Kinney , Karen M. Henderson
IPC分类号： C07C243/12 , C07C281/06 , C08G18/10 , C08G18/12 , C08G18/80 , C08G59/40 , C09D175/04 , C09J175/04 , C09K3/10 , C08L61/24 , C07C281/02 , C08L61/28 , C08L77/00 , C08L79/08 , C08L83/00 , C08L83/04
CPC分类号： C08G18/12 , C07C281/06 , C08G18/10 , C08G59/4035 , C09D175/04 , Y10T428/31551 , Y10T428/31663 , Y10T428/31721 , Y10T428/31725 , Y10T428/31855 , Y10T428/31942
摘要： The present invention relates to compounds containing modified hydrazide groups and corresponding to formula I ##STR1## wherein R represents the residue obtained by removing the isocyanate groups from a monomeric polyisocyanate, a polyisocyanate adduct or an NCO prepolymer,X represents OR' or NHR' andR' represents a group which is inert to isocyanate groups under the conditions used to form the compound of formula I andn has a value of 2 to 6.The present invention also relates to one-component, thermoset coating compositions containing the compounds of formula I and a cross-linking component that is reactive with these compounds. Finally, the present invention relates coatings, sealants and adhesives prepared from these thermoset compositions.
摘要翻译：本发明涉及含有改性酰肼基团且对应于式I的化合物，其中R表示通过从单体多异氰酸酯，多异氰酸酯加合物或NCO预聚物中除去异氰酸酯基而获得的残基，X表示OR'或NHR'，R'表示在用于形成式I化合物和n的条件下对异氰酸酯基团呈惰性的基团的值为2至6.本发明还涉及含有式I化合物和一种或多种式I化合物的单组分热固性涂料组合物与这些化合物反应的交联组分。最后，本发明涉及由这些热固性组合物制备的涂料，密封剂和粘合剂。

2. 发明授权

US06127514A One-component thermoset coating compositions 失效
标题翻译：单组分热固性涂料组合物
公开(公告)号：US06127514A
公开(公告)日：2000-10-03
申请号：US197910
申请日：1998-11-23
申请人： Douglas A. Wicks , Sze-Ming Lee , Eberhard Koenig , Carol L. Kinney , Karen M. Henderson
发明人： Douglas A. Wicks , Sze-Ming Lee , Eberhard Koenig , Carol L. Kinney , Karen M. Henderson
IPC分类号： C09K3/10 , C08G18/10 , C08G59/40 , C08G59/50 , C09D163/00 , C09D175/04 , C09J163/00 , C09J175/04 , C08G65/04
CPC分类号： C08G59/4035 , C08G18/10 , Y10T428/31551
摘要： The present invention relates to one-component, thermoset compositions containinga) compounds containing modified hydrazide groups and corresponding to formula I ##STR1## wherein p2 R represents the residue obtained by removing the isocyanate groups from a monomeric polyisocyanate, a polyisocyanate adduct or an NCO prepolymer,X represents OR' or NHR' andR' represents a group which is inert to isocyanate groups under the conditions used to form the compound of formula I andn has a value of 2 to 6,b) compounds containing two or more epoxy groups andc) a basic catalyst.The present invention also relates to coatings, adhesives and sealants prepared from these thermoset compositions.
摘要翻译：本发明涉及含有a）含有改性酰肼基团且对应于式I的化合物的单组分热固性组合物，其中p2R表示通过从单体多异氰酸酯，多异氰酸酯加合物或NCO预聚物除去异氰酸酯基团获得的残基，X 表示OR'或NHR'，R'表示在用于形成式I化合物的条件下对异氰酸酯基团呈惰性的基团，n表示2〜6的数值，b）含有2个以上环氧基和c ）碱性催化剂。本发明还涉及由这些热固性组合物制备的涂料，粘合剂和密封剂。

3. 发明授权

US06455631B1 Aqueous polyurethane dispersions containing modified hydrazide groups and their use in one-component thermoset compositions 有权
标题翻译：含有改性酰肼基团的水性聚氨酯分散体及其在单组分热固性组合物中的用途
公开(公告)号：US06455631B1
公开(公告)日：2002-09-24
申请号：US09728004
申请日：2000-12-01
申请人： Harald Blum , Lyubov K. Gindin , Karen M. Henderson , Patricia B. Jacobs , Sze-Ming Lee , Brian Long , Robert A. Sylvester , Douglas A. Wicks
发明人： Harald Blum , Lyubov K. Gindin , Karen M. Henderson , Patricia B. Jacobs , Sze-Ming Lee , Brian Long , Robert A. Sylvester , Douglas A. Wicks
IPC分类号： C08J303
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/0866 , C08G18/283 , C09D175/04 , Y10T428/31511 , Y10T428/31551 , Y10T428/31663 , Y10T428/31721 , Y10T428/31725 , Y10T428/31855 , Y10T428/31942 , C08G18/3834 , C08L2666/16
摘要： The present invention relates to aqueous polyurethane dispersions wherein the polyurethanes contain terminal hydrazide groups and correspond to the formula wherein the terminal, modified hydrazide groups are present in an amount of 1 to 25% by weight [calculated as C(O)—NH—NH—C(O), MW 84], based on the weight of the polyurethanes, and wherein X represents OR′ or NHR′, R represents the residue obtained by removing the isocyanate groups from an NCO prepolymer, R′ represents a group which is inert to Isocyanate groups under the conditions used to form the polyurethane of in formula I, R″ represents a divalent, linear or branched aliphatic group containing 2 to 10 carbon atoms, provided that there are at least two carbons between the oxygen atoms, wherein the aliphatic group may optionally be substituted by heteroatoms to form ether or ester groups, m is 0 or 1 and n is 2 to 4.
摘要翻译：本发明涉及水性聚氨酯分散体，其中聚氨酯含有末端酰肼基团并且对应于末端的肟基，改性的酰肼基团的存在量为1至25重量％[按C（O）-NH-NH- C（O），MW 84]，基于聚氨酯的重量，其中X表示OR'或NHR'，R表示通过从NCO预聚物中除去异氰酸酯基而获得的残基，R'表示惰性基团在用于形成式I的聚氨酯的条件下，与异氰酸酯基团反应，R“表示含有2至10个碳原子的二价，直链或支链脂族基团，条件是氧原子之间至少有两个碳，其中脂族基团可任选被杂原子取代以形成醚或酯基，m为0或1，n为2至4。

4. 发明授权

US06362359B1 One-component thermoset coating compositions 失效
标题翻译：单组分热固性涂料组合物
公开(公告)号：US06362359B1
公开(公告)日：2002-03-26
申请号：US09727630
申请日：2000-12-01
申请人： Sze-Ming Lee , Karen M. Henderson , Patricia B. Jacobs , Robert A. Sylvester , Douglas A. Wicks
发明人： Sze-Ming Lee , Karen M. Henderson , Patricia B. Jacobs , Robert A. Sylvester , Douglas A. Wicks
IPC分类号： C07C28102
CPC分类号： C07C281/02 , C08G18/3834 , C08G18/8058 , Y10T428/31511 , Y10T428/31551 , Y10T428/31663 , Y10T428/31721 , Y10T428/31725 , Y10T428/31855 , Y10T428/31942
摘要： The present invention relates to compounds containing modified hydrazide groups and corresponding to formula I wherein R represents the residue obtained by removing the isocyanate groups from a monomeric polyisocyanate, a polyisocyanate adduct or an NCO prepolymer, X represents OR′ or NHR′ and R′ represents a group which is inert to isocyanate groups under the conditions used to form the compound of formula I, R″ represents a divalent, linear or branched aliphatic group containing 2 to 10 carbon atoms, provided that there are at least two carbons between the oxygen atoms wherein the aliphatic group may optionally be substituted by heteroatoms to form ether or ester groups, and n is 2 to 6.
摘要翻译：本发明涉及含有改性酰肼基团且对应于式I的化合物，其中R表示通过从单体多异氰酸酯，多异氰酸酯加合物或NCO预聚物中除去异氰酸酯基而获得的残基，X表示OR'或NHR'，R'表示在用于形成式I化合物的条件下对异氰酸酯基团是惰性的，R“表示含有2至10个碳原子的二价，直链或支链脂族基团，条件是氧原子之间至少有两个碳原子，脂族基团可任选被杂原子取代以形成醚或酯基，并且n为2-6。

5. 发明授权

US06455632B1 Aqueous polyurethane dispersions containing secondary amide groups and their use in one-component thermoset compositions 有权
标题翻译：含有仲酰胺基团的水性聚氨酯分散体及其在单组分热固性组合物中的用途
公开(公告)号：US06455632B1
公开(公告)日：2002-09-24
申请号：US09730079
申请日：2000-12-05
申请人： Lyubov K. Gindin , Karen M. Henderson , Sze-Ming Lee , Brian Long
发明人： Lyubov K. Gindin , Karen M. Henderson , Sze-Ming Lee , Brian Long
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/0866 , C08G18/12 , C08G18/283 , C08G18/3825 , C08G18/4238 , Y10T428/31551 , C08G18/3231
摘要： The present invention relates to aqueous polyurethane dispersions containing secondary amide groups in the backbone of the polyurethane, wherein the secondary amide groups (calculated as NH—CO—, MW 43) are present in an amount of 1 to 14% by weight, based on the weight of the polyurethanes, and correspond to the formula —X1—R1—NH—C(O)—R2—X2— (I) wherein X1, and X2 are the same or different and represent the groups obtained by removing a hydrogen atom from a hydroxy group or a primary or secondary amino group and R1and R2 are the same or different and represent linear or branched hydrocarbon groups that are optionally substituted by groups that do not contain isocyanate-reactive hydrogen atoms. The present invention also relates to aqueous, one-component, thermoset compositions containing the polyurethanes with amide groups in the backbone and a cross-linking component that is reactive with amide groups. Finally, the present invention relates to coatings, sealants and adhesives prepared from these aqueous, one-component, thermoset compositions.
摘要翻译：本发明涉及在聚氨酯主链中含有仲酰胺基团的含水聚氨酯分散体，其中仲酰胺基团（以NH-CO-，MW 43计算）的存在量为1至14重量％，基于聚氨酯的重量，对应于X 1和X 2的化学式相同或不同，表示通过从羟基或伯或仲氨基除去氢原子而获得的基团，R 1和R 2相同或不同，表示直链或任选被不含有异氰酸酯反应性氢原子的基团取代的支链烃基。本发明还涉及包含在主链中具有酰胺基团的聚氨酯的含水单组分热固性组合物和交联组分，与酰胺基反应。最后，本发明涉及由这些水性单组分热固性组合物制备的涂料，密封剂和粘合剂。

6. 发明授权

US06444746B1 Aqueous polyurethane dispersions containing pendant amide groups and their use in one-component thermoset compositions 有权
标题翻译：含有侧酰胺基团的水性聚氨酯分散体及其在单组分热固性组合物中的用途
公开(公告)号：US06444746B1
公开(公告)日：2002-09-03
申请号：US09730085
申请日：2000-12-05
申请人： Lyubov K. Gindin , Karen M. Henderson , Sze-Ming Lee , Brian Long
发明人： Lyubov K. Gindin , Karen M. Henderson , Sze-Ming Lee , Brian Long
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/0866 , C08G18/12 , C08G18/3271 , C08G18/4238 , C08G18/758 , Y10T428/31551 , C08G18/3231
摘要： The present invention relates to aqueous polyurethane dispersions containing amide groups that are pendant to the backbone of the polyurethane, wherein the amide groups (calculated as NH—CO—, MW43) are present in an amount of 1 to 14% by weight, based on the weight of the polyurethanes. The present invention also relates to aqueous, one-component, thermoset compositions containing the polyurethanes with amide groups in the backbone and a cross-linking component that is reactive with amide groups. Finally, the present invention relates to coatings, sealants and adhesives prepared from these aqueous, one-component, thermoset compositions.
摘要翻译：本发明涉及含有悬浮于聚氨酯主链的酰胺基团的水性聚氨酯分散体，其中酰胺基（按NH-CO-，MW43计算）的存在量为1至14重量％，基于聚氨酯的重量。本发明还涉及包含在主链中具有酰胺基的聚氨酯和与酰胺基反应的交联组分的含水单组分热固性组合物。最后，本发明涉及由这些水性单组分热固性组合物制备的涂料，密封剂和粘合剂。

7. 发明授权

US06552157B2 Polyurethanes containing secondary amide groups and their use in one-component thermoset compositions 失效
标题翻译：含有仲酰胺基团的聚氨酯及其在单组分热固性组合物中的用途
公开(公告)号：US06552157B2
公开(公告)日：2003-04-22
申请号：US09730080
申请日：2000-12-05
申请人： Charles A. Gambino , Karen M. Henderson , Patricia B. Jacobs , Sze-Ming Lee , Robert A. Sylvester
发明人： Charles A. Gambino , Karen M. Henderson , Patricia B. Jacobs , Sze-Ming Lee , Robert A. Sylvester
IPC分类号： C08G1832
CPC分类号： C08G18/3825 , C09D175/12 , Y10T428/31551
摘要： The present invention relates to polyurethanes containing secondary amide groups in the backbones of the polyurethanes, wherein the secondary amide groups (calculated as NH—CO—, MW 43) are present in an amount of 1 to 14% by weight, based on the weight of the polyurethanes, and correspond to the formula —X1—R1—NH—C(O)—R2—X2— (I) wherein X1 and X2 are the same or different and represent the groups obtained by removing a hydrogen atom from a hydroxy group or a primary or secondary amino group and R1 and R2 are the same or different and represent linear or branched hydrocarbon groups that are optionally substituted by groups that do not contain isocyanate-reactive hydrogen atoms. The present invention also relates to one-component, thermoset compositions containing the polyurethanes with secondary amide groups in the backbone and a cross-linking component that is reactive with amide groups. Finally, the present invention relates to coatings, sealants and adhesives prepared from these one-component, thermoset compositions.
摘要翻译：本发明涉及在聚氨酯的主链中含有仲酰胺基团的聚氨酯，其中仲酰胺基团（以NH-CO-，MW 43计算）的存在量为基于重量的1至14重量％的氨基甲酸酯，并且对应于肟基X 1和X 2相同或不同，表示通过从羟基或伯或仲氨基除去氢原子获得的基团，R 1和R 2相同或不同，表示直链或支链任选被不含有异氰酸酯反应性氢原子的基团取代的烃基。本发明还涉及含有在主链中具有仲酰胺基团的聚氨酯和含有异氰酸酯反应性氢原子的反应性的交联组分的单组分热固性组合物酰胺基。最后，本发明涉及由这些单组分热固性组合物制备的涂料，密封剂和粘合剂。

8. 发明授权

US06911501B1 Process for preparing aspartates 有权
标题翻译：天冬氨酸的制备方法
公开(公告)号：US06911501B1
公开(公告)日：2005-06-28
申请号：US10761643
申请日：2004-01-21
申请人： Karsten Danielmeier , Charles A. Gambino , Rolf Gertzmann , Richard R. Roesler , Terrell D. Wayt , Michele E. Vargo , Edward P. Squiller , Karen M. Henderson
发明人： Karsten Danielmeier , Charles A. Gambino , Rolf Gertzmann , Richard R. Roesler , Terrell D. Wayt , Michele E. Vargo , Edward P. Squiller , Karen M. Henderson
IPC分类号： C07D207/40 , C07D207/416 , C08G18/00 , C08G18/38 , C08G18/79 , C09D175/04 , C08F283/04 , C08G73/10
CPC分类号： C07D207/416 , C08G18/3821 , C08G18/792 , C09D175/04
摘要： The present invention relates to novel aspartates, their method of production and the use of these aspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers. The aspartates are prepared by first reacting a di- or polyamine with an unsaturated ester and then reacting the resultant product with a maleimide.
摘要翻译：本发明涉及新型天冬氨酸盐，其制备方法和这些天冬氨酸盐作为双组分聚氨酯涂料组合物中多异氰酸酯的反应性组分和用于制备聚氨酯预聚物的用途。天冬氨酸酯通过首先使二胺或多胺与不饱和酯反应，然后使所得产物与马来酰亚胺反应来制备。

9. 发明授权

US06887964B2 Moisture-curable, polyether urethanes with reactive silane groups and their use as sealants, adhesives and coatings 有权
标题翻译：具有反应性硅烷基团的水分固化型聚醚聚氨酯及其作为密封剂，粘合剂和涂料的用途
公开(公告)号：US06887964B2
公开(公告)日：2005-05-03
申请号：US10690955
申请日：2003-10-22
申请人： Kurt C. Frisch , Derek L. Crawford , Richard R. Roesler , Karen M. Henderson , Michael D. Strohecker
发明人： Kurt C. Frisch , Derek L. Crawford , Richard R. Roesler , Karen M. Henderson , Michael D. Strohecker
IPC分类号： C08G18/10 , C08G18/12 , C08G18/28 , C08G18/38 , C08G18/48 , C08G18/71 , C08G65/336 , C08L71/02 , C09D175/04 , C09J175/04 , C09J175/12 , C08G77/26
CPC分类号： C08G18/718 , C08G18/10 , C08G18/12 , C08G18/283 , C08G18/289 , C08G18/3893 , C08G18/4866 , C08G65/336 , C08G2190/00 , C08L71/02 , C09D175/04 , C09J175/04 , C09J175/12 , Y10S528/901 , C08G18/307
摘要： A moisture-curable, alkoxysilane-functional polyether urethanes containing a) 20 to 90% by weight, based on the weight of a) and b), of a polyether urethane containing two or more reactive silane groups and one or more polyether segments, wherein the polyether segments have a number average molecular weight of at least 3000 and a degree of unsaturation of less than 0.04 milliequivalents/g, provided that the sum of the number average molecular weights of all of the polyether segments per molecule averages 6000 to 20,000, and wherein the reactive silane groups are incorporated as the reaction product of an isocyanate group with a compound corresponding to the formula b) 10 to 80% by weight, based on the weight of a) and b), of a polyether urethane containing one reactive silane group and one or more polyether segments having a number average molecular weight of 1000 to 15,000.
摘要翻译：含有a）基于a）和b）重量的20-90％重量的含有两个或更多个反应性硅烷基团和一个或多个聚醚链段的聚醚聚氨酯的湿固化型烷氧基硅烷官能聚醚聚氨酯，其中聚醚片段的数均分子量至少为3000，不饱和度小于0.04毫当量/克，条件是每个分子中所有聚醚链段的数均分子量之和平均为6000至20,000，而其中反应性硅烷基团作为异氰酸酯基团与对应于式b）的化合物的反应产物引入含有一个反应性硅烷的聚醚聚氨酯的基于a）和b）的重量为10至80重量％基团和一个或多个数均分子量为1000至15,000的聚醚链段。

10. 发明授权

US06974874B2 Reduction of monomer content and stabilization of polyaziridines 有权
标题翻译：单体含量的降低和多氮杂环丁烷的稳定化
公开(公告)号：US06974874B2
公开(公告)日：2005-12-13
申请号：US10285486
申请日：2002-10-31
申请人： Lanny D. Venham , Myron W. Shaffer , Karsten Danielmeier , Karen M. Henderson
发明人： Lanny D. Venham , Myron W. Shaffer , Karsten Danielmeier , Karen M. Henderson
IPC分类号： C08G73/00 , C08G73/02 , C07D203/12
CPC分类号： C08G73/0206 , C08G73/00
摘要： The invention relates to a process for reducing the monomeric aziridine content in a polyaziridine forming reaction mixture by adding to the polyaziridine forming reaction mixture an excess of a carbodiimide scavenger wherein the excess is based on the equivalent ratio of scavenger to monomeric aziridine, and to a product obtained by this process and to a coating composition containing the product obtained by the process.
摘要翻译：本发明涉及通过向聚氮氮丙啶形成反应混合物中加入过量的碳二亚胺清除剂来降低形成聚氮氮丙啶的反应混合物中的单体氮丙啶含量的方法，其中过量基于清除剂与单体氮丙啶的当量比，通过该方法获得的产物和含有通过该方法获得的产物的涂料组合物。

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