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1. 发明授权

US06635599B1 Mixed metal catalyst, its preparation by co-precipitation, and its use 有权
标题翻译：混合金属催化剂，其共沉淀制备及其用途
公开(公告)号：US06635599B1
公开(公告)日：2003-10-21
申请号：US09482811
申请日：2000-01-13
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Hermannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Hermannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J2300
CPC分类号： B01J23/8885 , B01J23/85 , B01J23/883 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/082 , B01J37/20 , C10G45/08 , C10G49/04
摘要： The present invention relates to a process for the preparation of a hydroprocessing catalyst, to the catalyst composition obtainable by said process, and to the use of said catalyst composition in hydroprocessing applications. The process comprises the steps of combining and reacting at least one Group VIII non-noble metal component in solution and at least two Group VIB metal components in solution in a reaction mixture to obtain an oxygen-stable precipitate, and sulfiding the precipitate.
摘要翻译：本发明涉及一种制备加氢处理催化剂的方法，可通过所述方法获得的催化剂组合物以及所述催化剂组合物在加氢处理应用中的用途。该方法包括以下步骤：将至少一种溶液中的第VIII族非贵金属组分和至少两种VIB族金属组分混合并在反应混合物中溶解，得到氧稳定的沉淀物，并使沉淀物硫化。

2. 发明授权

US06534437B2 Process for preparing a mixed metal catalyst composition 有权
公开(公告)号：US06534437B2
公开(公告)日：2003-03-18
申请号：US09836101
申请日：2001-04-17
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J27043
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for preparing a catalyst composition comprising bulk catalyst particles comprising at least one Group VIII non-noble metal and at least two Group VIB metals. The process comprises combining and reacting at least one Group VIII non-noble metal component with at least two Group VIB metal components in the presence of a protic liquid, with at least one of the metal components remaining at least partly in the solid state during the entire process. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of said bulk catalyst particles, with the solubility of those of the metal components which are at least partly in the solid state during the reaction being less than 0.05 mol/100 ml water at 18° C. The invention also covers a catalyst composition made by that process and a process for the hydroprocessing of a hydrocarbon feedstock by contacting the feedstock with that catalyst at hydroprocessing conditions.

3. 发明授权

US07608558B2 Hydrotreating catalyst containing a group V metal 有权
标题翻译：含有V族金属的加氢处理催化剂
公开(公告)号：US07608558B2
公开(公告)日：2009-10-27
申请号：US11579391
申请日：2005-04-19
申请人： Sonja Eijsbouts , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Stuart Leon Soled , Sabato Miseo
IPC分类号： C10G45/08 , B01J23/887
CPC分类号： B01J23/8877 , B01J37/0009 , B01J37/0236 , B01J37/20 , C10G45/08
摘要： The present invention pertains to a sulfur-containing catalyst composition suitable for the hydrotreating of hydro-carbon feeds which comprises a Group VIB metal component selected from molybdenum, tungsten, and mixtures thereof, a Group V metal component selected from vanadium, niobium, tantalum, and mixtures thereof, and a Group VIII metal component selected from nickel, cobalt, iron, and mixtures thereof, the metal components (calculated as oxides) making up at least 50 wt. % of the catalyst, wherein the molar ratio between the metal components satisfies the following formula: (Group VIB+Group V):(Group VIII)=0.5-2:1. This catalyst has been found to show a high activity in sulfur removal in combination with good aromatics removal properties.
摘要翻译：本发明涉及适用于加氢处理含氢催化剂组合物的含氢催化剂组合物，该组合物包含选自钼，钨及其混合物的VIB族金属组分，选自钒，铌，钽，和它们的混合物，以及选自镍，钴，铁及其混合物的VIII族金属组分，所述金属组分（以氧化物计）占组合物的至少50重量％。％的催化剂，其中金属组分之间的摩尔比满足下式：（VIB + V族）（VIII族）= 0.5-2:1。已经发现该催化剂显示出除去高硫的高活性，同时具有良好的芳族化合物去除性能。

4. 发明授权

US06652738B2 Process for preparing a mixed metal catalyst composition 有权
标题翻译：制备混合金属催化剂组合物的方法
公开(公告)号：US06652738B2
公开(公告)日：2003-11-25
申请号：US10346018
申请日：2003-01-16
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： C10G4504
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for the hydroprocessing of a hydrocarbon feedstock wherein said feedstock is contacted at hydroprocessing conditions with a catalyst composition which comprises bulk catalyst particles which comprise at least one Group VIII non-noble metal and at least two Group VIB metals. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of the bulk catalyst particles. The metals are present in the catalyst composition in their oxidic and/or sulfidic state. The catalyst composition has an X-ray diffraction pattern in which the characteristic full width at half maximum does not exceed 2.5° when the Group VIB metals are molybdenum, tungsten, and, optionally, chromium, or does not exceed 4.0° when the Group VIB metals are molybdenum and chromium or tungsten and chromium.
摘要翻译：本发明涉及烃原料的加氢处理方法，其中所述原料在加氢处理条件下与催化剂组合物接触，所述催化剂组合物包含包含至少一种VIII族非贵金属和至少两种VIB族金属的本体催化剂颗粒。 VIII族和VIB族金属包含约50wt。％至约100重量％以体积催化剂颗粒的总重量计算的氧化物％。金属以其氧化和/或硫化态存在于催化剂组合物中。催化剂组合物具有X射线衍射图，其中当VIB族金属为钼，钨和任选的铬时，半峰的特征全宽度不超过2.5°，当VIB族VIB金属为不超过4.0°时金属是钼和铬或钨和铬。

5. 发明申请

US20050040080A1 Process for upgrading naphtha 有权
标题翻译：石脑油升级工艺
公开(公告)号：US20050040080A1
公开(公告)日：2005-02-24
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth Riley , Stuart Soled , Sabato Miseo , Frans Plantenga , Marinus Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth Riley , Stuart Soled , Sabato Miseo , Frans Plantenga , Marinus Cerfontain , Sonja Eijsbouts , Eelko Brevoord
IPC分类号： B01J23/00 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/888 , B01J37/03 , B01J37/08 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G47/12 , C10G49/04 , C10G65/02 , C10G65/04 , C10G65/08 , C10G65/12 , C10G67/04 , C10G45/00
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译：一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。

6. 发明授权

US07648941B2 Bulk bimetallic catalysts, method of making bulk bimetallic catalysts and hydroprocessing using bulk bimetallic catalysts 有权
标题翻译：散装双金属催化剂，制造块状双金属催化剂的方法和使用散装双金属催化剂的加氢处理
公开(公告)号：US07648941B2
公开(公告)日：2010-01-19
申请号：US11586399
申请日：2006-10-25
申请人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts , Frans L. Plantenga
发明人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts , Frans L. Plantenga
IPC分类号： B01J23/00 , C10G47/00 , C10G49/04
CPC分类号： C10G45/08 , B01J23/883 , B01J23/888 , B01J23/8885 , B01J35/1014 , B01J35/1038 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/038 , B01J37/20
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst comprising a Group VIII metal and a Group VIB metal.
摘要翻译：本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。该催化剂是包含VIII族金属和VIB族金属的本体催化剂。

7. 发明授权

US07776205B2 Process to upgrade hydrocarbonaceous feedstreams 有权
标题翻译：改进含烃原料流的方法
公开(公告)号：US07776205B2
公开(公告)日：2010-08-17
申请号：US11096499
申请日：2005-04-01
申请人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts
发明人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts
IPC分类号： C10G27/00 , C10G45/04 , C10G45/60 , C10G11/02 , C10G11/04 , C10G47/02 , C10G47/04 , C10G35/00 , C10G35/06 , B01J38/22 , B01J35/02 , B01J8/08
CPC分类号： C10G45/08 , B01J23/8877 , B01J23/888 , B01J37/0009 , B01J37/04 , C10G45/38 , C10G45/50 , C10G45/60 , C10G47/02 , C10G49/04
摘要： The instant invention relates to a process to produce liquid products through the hydroprocessing of hydrocarbonaceous feedstreams in the presence of a bulk metal hydroprocessing catalyst.
摘要翻译：本发明涉及在本体金属加氢催化剂存在下通过烃类原料流的加氢处理来生产液体产物的方法。

8. 发明授权

US08062508B2 Hydroprocessing using bulk bimetallic catalysts 有权
标题翻译：使用散装双金属催化剂的加氢处理
公开(公告)号：US08062508B2
公开(公告)日：2011-11-22
申请号：US11586398
申请日：2006-10-25
申请人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts , Frans L. Plantenga
发明人： Stuart L. Soled , Sabato Miseo , Sonja Eijsbouts , Frans L. Plantenga
IPC分类号： C10G45/00
CPC分类号： B01J23/883 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/08 , C10G45/04 , C10G45/08 , C10G65/04 , C10G65/12
摘要： The invention relates to a process for upgrading hydrocarbonaceous feedstreams by hydroprocessing using bulk bimetallic catalysts. More particularly, the invention relates to a catalytic hydrotreating process for the removal of sulfur and nitrogen from a hydrocarbon feed such as a fuel or a lubricating oil feed. The catalyst is a bulk catalyst containing a Group VIII metal and a Group VIB metal.
摘要翻译：本发明涉及通过使用大量双金属催化剂的加氢处理来改质含烃原料流的方法。更具体地说，本发明涉及一种用于从诸如燃料或润滑油进料的烃进料中除去硫和氮的催化加氢处理方法。催化剂是含有VIII族金属和VIB族金属的本体催化剂。

9. 发明申请

US20070227949A1 Hydrotreating Catalyst Containing a Group V Metal 有权
标题翻译：含有V族金属的加氢精制催化剂
公开(公告)号：US20070227949A1
公开(公告)日：2007-10-04
申请号：US11579391
申请日：2005-04-19
申请人： Sonja Eijsbouts , Stuart Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Stuart Soled , Sabato Miseo
IPC分类号： C10G45/08 , B01J23/887 , B01J37/20
CPC分类号： B01J23/8877 , B01J37/0009 , B01J37/0236 , B01J37/20 , C10G45/08
摘要： The present invention pertains to a sulfur-containing catalyst composition suitable for the hydrotreating of hydro-carbon feeds which comprises a Group VIB metal component selected from molybdenum, tungsten, and mixtures thereof, a Group V metal component selected from vanadium, niobium, tantalum, and mixtures thereof, and a Group VIII metal component selected from nickel, cobalt, iron, and mixtures thereof, the metal components (calculated as oxides) making up at least 50 wt. % of the catalyst, wherein the molar ratio between the metal components satisfies the following formula: (Group VIB+Group V):(Group VIII)=0.5-2:1. This catalyst has been found to show a high activity in sulfur removal in combination with good aromatics removal properties.
摘要翻译：本发明涉及适用于加氢处理含氢催化剂组合物的含氢催化剂组合物，该组合物包含选自钼，钨及其混合物的VIB族金属组分，选自钒，铌，钽，和它们的混合物，以及选自镍，钴，铁及其混合物的VIII族金属组分，所述金属组分（以氧化物计）占组合物的至少50重量％。％的催化剂，其中金属组分之间的摩尔比满足下式：（VIB + V族）（VIII族）= 0.5-2:1。已经发现该催化剂显示出除去高硫的高活性，同时具有良好的芳族化合物去除性能。

10. 发明授权

US07229548B2 Process for upgrading naphtha 有权
标题翻译：石脑油升级工艺
公开(公告)号：US07229548B2
公开(公告)日：2007-06-12
申请号：US10677697
申请日：2003-10-02
申请人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
发明人： Kenneth L. Riley , Stuart L. Soled , Sabato Miseo , Frans L. Plantenga , Marinus Bruce Cerfontain , Sonja Eijsbouts , Eelko Brevoord
IPC分类号： C10G45/00 , C10G65/02
CPC分类号： C10G65/12 , B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , C07C29/16 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G2400/10 , C10G2400/14 , C08F240/00
摘要： A method for upgrading a naphtha feed to a naphtha product containing less than about 10 wppm of nitrogen and less than about 15 wppm sulfur, the method comprising contacting said naphtha feed with hydrogen in the presence of a bulk multimetallic catalyst under effective reactor conditions to hydrodesulfurize and hydrodenitrogenize said naphtha feed to produce said naphtha product, wherein said bulk multimetallic catalyst comprises at least one Group VIII non-noble metal and at least two Group VIB metals.
摘要翻译：一种将石脑油进料升级成含有小于约10wppm氮和小于约15wppm硫的石脑油产品的方法，所述方法包括在有效反应器条件下在大量多金属催化剂存在下使所述石脑油进料与氢气接触以加氢脱硫并且对所述石脑油进料进行加氢脱氮以产生所述石脑油产品，其中所述本体多金属催化剂包含至少一种第VIII族非贵金属和至少两种VIB族金属。

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