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1. 发明授权

US06635599B1 Mixed metal catalyst, its preparation by co-precipitation, and its use 有权
标题翻译：混合金属催化剂，其共沉淀制备及其用途
公开(公告)号：US06635599B1
公开(公告)日：2003-10-21
申请号：US09482811
申请日：2000-01-13
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Hermannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Hermannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J2300
CPC分类号： B01J23/8885 , B01J23/85 , B01J23/883 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/082 , B01J37/20 , C10G45/08 , C10G49/04
摘要： The present invention relates to a process for the preparation of a hydroprocessing catalyst, to the catalyst composition obtainable by said process, and to the use of said catalyst composition in hydroprocessing applications. The process comprises the steps of combining and reacting at least one Group VIII non-noble metal component in solution and at least two Group VIB metal components in solution in a reaction mixture to obtain an oxygen-stable precipitate, and sulfiding the precipitate.
摘要翻译：本发明涉及一种制备加氢处理催化剂的方法，可通过所述方法获得的催化剂组合物以及所述催化剂组合物在加氢处理应用中的用途。该方法包括以下步骤：将至少一种溶液中的第VIII族非贵金属组分和至少两种VIB族金属组分混合并在反应混合物中溶解，得到氧稳定的沉淀物，并使沉淀物硫化。

2. 发明授权

US06534437B2 Process for preparing a mixed metal catalyst composition 有权
公开(公告)号：US06534437B2
公开(公告)日：2003-03-18
申请号：US09836101
申请日：2001-04-17
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J27043
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for preparing a catalyst composition comprising bulk catalyst particles comprising at least one Group VIII non-noble metal and at least two Group VIB metals. The process comprises combining and reacting at least one Group VIII non-noble metal component with at least two Group VIB metal components in the presence of a protic liquid, with at least one of the metal components remaining at least partly in the solid state during the entire process. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of said bulk catalyst particles, with the solubility of those of the metal components which are at least partly in the solid state during the reaction being less than 0.05 mol/100 ml water at 18° C. The invention also covers a catalyst composition made by that process and a process for the hydroprocessing of a hydrocarbon feedstock by contacting the feedstock with that catalyst at hydroprocessing conditions.

3. 发明授权

US07608558B2 Hydrotreating catalyst containing a group V metal 有权
标题翻译：含有V族金属的加氢处理催化剂
公开(公告)号：US07608558B2
公开(公告)日：2009-10-27
申请号：US11579391
申请日：2005-04-19
申请人： Sonja Eijsbouts , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Stuart Leon Soled , Sabato Miseo
IPC分类号： C10G45/08 , B01J23/887
CPC分类号： B01J23/8877 , B01J37/0009 , B01J37/0236 , B01J37/20 , C10G45/08
摘要： The present invention pertains to a sulfur-containing catalyst composition suitable for the hydrotreating of hydro-carbon feeds which comprises a Group VIB metal component selected from molybdenum, tungsten, and mixtures thereof, a Group V metal component selected from vanadium, niobium, tantalum, and mixtures thereof, and a Group VIII metal component selected from nickel, cobalt, iron, and mixtures thereof, the metal components (calculated as oxides) making up at least 50 wt. % of the catalyst, wherein the molar ratio between the metal components satisfies the following formula: (Group VIB+Group V):(Group VIII)=0.5-2:1. This catalyst has been found to show a high activity in sulfur removal in combination with good aromatics removal properties.
摘要翻译：本发明涉及适用于加氢处理含氢催化剂组合物的含氢催化剂组合物，该组合物包含选自钼，钨及其混合物的VIB族金属组分，选自钒，铌，钽，和它们的混合物，以及选自镍，钴，铁及其混合物的VIII族金属组分，所述金属组分（以氧化物计）占组合物的至少50重量％。％的催化剂，其中金属组分之间的摩尔比满足下式：（VIB + V族）（VIII族）= 0.5-2:1。已经发现该催化剂显示出除去高硫的高活性，同时具有良好的芳族化合物去除性能。

4. 发明授权

US06652738B2 Process for preparing a mixed metal catalyst composition 有权
标题翻译：制备混合金属催化剂组合物的方法
公开(公告)号：US06652738B2
公开(公告)日：2003-11-25
申请号：US10346018
申请日：2003-01-16
申请人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
发明人： Sonja Eijsbouts , Bob Gerardus Oogjen , Harmannus Willem Homan Free , Marinus Bruce Cerfontain , Kenneth Lloyd Riley , Stuart Leon Soled , Sabato Miseo
IPC分类号： C10G4504
CPC分类号： B01J35/002 , B01J23/85 , B01J23/8885 , B01J35/0053 , B01J35/008 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0009 , B01J37/0236 , B01J37/031 , B01J37/20 , C10G49/04
摘要： The invention pertains to a process for the hydroprocessing of a hydrocarbon feedstock wherein said feedstock is contacted at hydroprocessing conditions with a catalyst composition which comprises bulk catalyst particles which comprise at least one Group VIII non-noble metal and at least two Group VIB metals. The Group VIII and Group VIB metals comprise from about 50 wt. % to about 100 wt. %, calculated as oxides, of the total weight of the bulk catalyst particles. The metals are present in the catalyst composition in their oxidic and/or sulfidic state. The catalyst composition has an X-ray diffraction pattern in which the characteristic full width at half maximum does not exceed 2.5° when the Group VIB metals are molybdenum, tungsten, and, optionally, chromium, or does not exceed 4.0° when the Group VIB metals are molybdenum and chromium or tungsten and chromium.
摘要翻译：本发明涉及烃原料的加氢处理方法，其中所述原料在加氢处理条件下与催化剂组合物接触，所述催化剂组合物包含包含至少一种VIII族非贵金属和至少两种VIB族金属的本体催化剂颗粒。 VIII族和VIB族金属包含约50wt。％至约100重量％以体积催化剂颗粒的总重量计算的氧化物％。金属以其氧化和/或硫化态存在于催化剂组合物中。催化剂组合物具有X射线衍射图，其中当VIB族金属为钼，钨和任选的铬时，半峰的特征全宽度不超过2.5°，当VIB族VIB金属为不超过4.0°时金属是钼和铬或钨和铬。

5. 发明授权

US09943832B2 Bulk catalyst composition comprising bulk metal oxide particles 有权
公开(公告)号：US09943832B2
公开(公告)日：2018-04-17
申请号：US12743153
申请日：2008-12-04
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk Jan Tromp , Stuart Leon Soled , Sabato Miseo
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Paul Joseph Maria Lebens , Frans Lodewijk Plantenga , Bob Gerardus Oogjen , Henk Jan Tromp , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J23/888 , B01J23/85 , B01J37/03 , B01J37/20 , C10G49/04 , B01J21/16 , B01J35/00 , B01J37/00
CPC分类号： B01J23/8885 , B01J21/16 , B01J23/85 , B01J23/888 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/20 , C10G49/04
摘要： The invention relates to a process for preparing bulk metal oxide particles comprising the steps of combining in a reaction mixture (i) dispersible nanoparticles having a dimension of less than about 1 μm upon being dispersed in a liquid, (ii) at least one Group VIII non-noble metal compound, (iii) at least one Group VIB metal compound, and (iv) a protic liquid; and reacting the at least one Group VIII non-noble metal compound and the at least one Group VIB metal in the presence of the nanoparticles. It also relates to bulk metal hydroprocessing catalysts obtainable by such method.

6. 发明授权

US08067331B2 Bulk catalyst comprising nickel tungsten metal oxidic particles 有权
标题翻译：包含镍钨金属氧化物颗粒的散装催化剂
公开(公告)号：US08067331B2
公开(公告)日：2011-11-29
申请号：US12091322
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Marinus Bruce Cerfontain , Frans L. Plantenga , Eelco Titus Carel Vogt , Jacobus Nicolaas Louwen , Stuart Leon Soled , Sabato Miseo , Kenneth L. Riley
IPC分类号： C10G45/04
CPC分类号： B01J23/888 , B01J23/002 , B01J35/002 , B01J37/0009 , B01J37/03 , B01J37/10 , B01J37/20 , B01J2523/00 , C10G45/08 , C10G2300/202 , B01J2523/69 , B01J2523/847 , B01J2523/68 , B01J2523/56
摘要： The invention relates to a nickel tungsten bulk catalyst, to a process for the manufacture of said catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurisation and hydrodenitrogenation of hydrocarbon feedstock. The catalyst comprises nickel tungsten metal oxidic particles obtainable by a process comprising forming a slurry of a first solid metal compound comprising Group VNI metal nickel and a second solid metal compound comprising Group VIB metal tungsten in a protic liquid, reacting the first and second solid metal compounds at elevated temperature whereby the first and second solid metal compounds remain at least partly in the solid state during the entire reaction to form the nickel tungsten oxidic bulk catalyst.
摘要翻译：本发明涉及镍钨体积催化剂，制备所述催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。该催化剂包括可通过以下工艺获得的镍钨金属氧化物颗粒，所述方法包括在质子液体中形成包含VNI族金属镍的第一固体金属化合物和包含第VIB族金属钨的第二固体金属化合物的浆料，使第一和第二固体金属化合物在高温下由此第一和第二固体金属化合物在整个反应期间保持至少部分为固体状态以形成镍钨氧化物本体催化剂。

7. 发明授权

US5728644A Dispersed metal sulfide catalysts for hydroprocessing 失效
标题翻译：用于加氢处理的分散金属硫化物催化剂
公开(公告)号：US5728644A
公开(公告)日：1998-03-17
申请号：US524228
申请日：1995-09-05
申请人： Teh Chung Ho , Stuart Leon Soled , Sabato Miseo , Gary Brice Mc Vicker , Michel Daage , Viktor Buchholz
发明人： Teh Chung Ho , Stuart Leon Soled , Sabato Miseo , Gary Brice Mc Vicker , Michel Daage , Viktor Buchholz
IPC分类号： B01J31/22 , B01J23/887 , B01J23/889 , B01J27/051 , B01J37/08 , B01J37/20 , C07B35/02 , C10G45/46 , C10G45/50 , B01J27/047 , B01J23/63 , B01J31/00
CPC分类号： B01J37/086 , B01J23/887 , B01J23/8878 , B01J23/8892 , B01J27/051 , B01J37/20 , C10G45/46 , C10G45/50
摘要： The present invention is directed toward a catalyst composition comprising a catalyst prepared by a process comprising: (a) impregnating an oxide precursor selected from the group consisting of rare earth oxide precursors, yttria precursors and mixtures thereof, onto an inorganic refractory oxide support; (b) drying said support at a temperature of about 100.degree. to about 120.degree. C. followed by calcining said support at a temperature of about 400.degree. to about 600.degree. C.; and (c) compositing or depositing on said support of step (b), a catalyst precursor salt represented by (ML)(Mo.sub.y W.sub.1-y O.sub.4).sub.a wherein M comprises Cr and/or one or more divalent promoter metals selected from the group consisting of Mn, Fe, Co, Ni, Cu, Zn and mixtures thereof, wherein y is any value ranging from 0 to 1, and wherein L is one or more neutral, nitrogen-containing ligands at least one of which is a chelating polydentate ligand; a=1 when chromium is not one of the promoter metals and 0.5.ltoreq.a.ltoreq.3 when Cr is one of the promoter metals. (d) sulfiding said deposited or composited supports of step (c) with an excess amount of sulfur in the form of one or more sulfur bearing compounds and at a temperature of at least about 250.degree. C. to form catalysts. In a preferred embodiment, the process will further comprise decomposing the composited or deposited supports of step (c) in a nonoxidizing atmosphere at a temperature of at least about 250.degree. C. prior to said sulfiding step (d). In a second aspect of the invention there is provided an improved aromatics hydrogenation process.
摘要翻译：本发明涉及一种催化剂组合物，其包含通过以下方法制备的催化剂，所述催化剂包括：（a）将选自稀土氧化物前体，氧化钇前体及其混合物的氧化物前体浸渍到无机耐火氧化物载体上; （b）在约100至约120℃的温度下干燥所述载体，然后在约400至约600℃的温度下煅烧所述载体; 和（c）在步骤（b）的所述载体上合成或沉积由（ML）（MoyW1-yO4）a表示的催化剂前体盐，其中M包含Cr和/或一种或多种选自以下的二价助催化剂金属： Mn，Fe，Co，Ni，Cu，Zn及其混合物，其中y是0至1的任何值，并且其中L是一种或多种中性含氮配体，其中至少一种是螯合多齿配体; 当Cr不是助催化剂金属之一时，a = 1，当Cr是助催化剂金属之一时，a = 1。（d）用一种或多种带硫化合物形式的过量硫磺和至少约250℃的温度硫化所述步骤（c）的沉积或复合载体以形成催化剂。在优选的实施方案中，该方法还包括在所述硫化步骤（d）之前，在至少约250℃的温度下，在非氧化气氛中分解步骤（c）的复合或沉积的载体。在本发明的第二方面，提供了一种改进的芳族化合物氢化方法。

8. 发明授权

US08394263B2 Bulk catalyst comprising metal oxidic particles and a process for the manufacture thereof 有权
标题翻译：包含金属氧化物颗粒的散装催化剂及其制造方法
公开(公告)号：US08394263B2
公开(公告)日：2013-03-12
申请号：US12091327
申请日：2006-10-25
申请人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Stuart Leon Soled , Sabato Miseo
发明人： Sona Eijsbouts-Spickova , Robertus Gerardus Leliveld , Stuart Leon Soled , Sabato Miseo
IPC分类号： B01J23/755
CPC分类号： B01J37/20 , B01J23/85 , B01J23/8885 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1061 , B01J37/0009 , B01J37/0045 , B01J37/10 , C10G45/08 , C10G2300/202
摘要： The invention relates to a bulk catalyst having improved activity in hydrodesulphurization, in particular in relatively low Group VIII over Group VIB metal molar ratios. The bulk catalyst comprises metal oxidic particles comprising one or more Group VIB metals and one or more-Group VIII metals which metal oxidic particles are obtainable by a process comprising the steps of reacting the compounds comprising one or more Group VIB metals and compounds comprising one or more Group VIII metals in hydrothermal conditions at a reaction temperature above the boiling temperature of the protic liquid, preferably in an autoclave at a reaction pressure above atmospheric pressure and. The invention also relates to the corresponding sulphided catalyst, to a process for the manufacture of said bulk catalyst and to the use of said catalyst for the hydrotreatment, in particular the hydrodesulphurization and hydrodenitrogenation of hydrocarbon feedstock.
摘要翻译：本发明涉及具有改进的加氢脱硫活性的本体催化剂，特别是在VIB族金属摩尔比相对较低的第VIII族。本体催化剂包含包含一种或多种VIB族金属和一种或多种VIII族金属的金属氧化物颗粒，该金属氧化物颗粒可通过包括以下步骤的方法获得，所述方法包括使包含一种或多种VIB族金属的化合物与包含一种或多种反应温度高于质子液体沸点温度的水热条件下，优选在反应压力高于大气压的高压釜中。本发明还涉及相应的硫化催化剂，制备所述本体催化剂的方法以及所述催化剂用于加氢处理的用途，特别是烃原料的加氢脱硫和加氢脱氮。

9. 发明授权

US07875742B2 Hydrogenation processes 有权
标题翻译：氢化工艺
公开(公告)号：US07875742B2
公开(公告)日：2011-01-25
申请号：US12712793
申请日：2010-02-25
申请人： Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
发明人： Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
IPC分类号： C07C69/74
CPC分类号： C08F8/04 , B01J23/462 , B01J23/75 , B01J35/0053 , B01J35/0066 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0203 , B01J37/08 , B01J37/082 , C07C29/19 , C07C67/303 , C07C69/75
摘要： The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.
摘要翻译：本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物，特别是不饱和有机化合物的方法，所述催化剂包含一种或多种催化活性金属施加到多孔催化剂载体。一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物，特别是金属的胺络合物衍生。分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。

10. 发明授权

US07288182B1 Hydroprocessing using bulk Group VIII/Group VIB catalysts 有权
标题翻译：使用本体VIII / VIB族催化剂进行加氢处理
公开(公告)号：US07288182B1
公开(公告)日：2007-10-30
申请号：US09869984
申请日：2000-01-14
申请人： Stuart Leon Soled , Sabato Miseo , Roman Krycak , Hilda B. Vroman , Teh Chung Ho , Kenneth Lloyd Riley
发明人： Stuart Leon Soled , Sabato Miseo , Roman Krycak , Hilda B. Vroman , Teh Chung Ho , Kenneth Lloyd Riley
IPC分类号： C10G73/02 , C10G11/00 , B01J29/70 , B01J23/00 , B01J23/70
CPC分类号： B01J23/002 , B01J23/85 , B01J23/88 , B01J23/883 , B01J23/8878 , B01J23/888 , B01J23/8885 , B01J37/03 , B01J37/082 , B01J2523/00 , C08F8/00 , C08F8/04 , C08F8/50 , C10G45/08 , C10G45/16 , C10G47/04 , C10G65/04 , C10G65/08 , C10G65/12 , C10G2400/10 , C10G2400/14 , C08F240/00 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/842 , B01J2523/67 , B01J2523/31 , B01J2523/41
摘要： A process for hydroprocessing petroleum and chemical feedstocks by use of a bulk multimetallic catalyst comprised of at least one Group VIII non-noble metal and at least one, preferably two Group VIB metal wherein the ratio of Group VIB metal to Group VIII metal is from about 10:1 to 1:10.
摘要翻译：通过使用由至少一种VIII族非贵金属和至少一种，优选两种VIB族金属组成的本体多金属催化剂加氢处理石油和化学原料的方法，其中VIB族金属与VIII族金属的比例为约 10：1到1:10。

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