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1. 发明专利

JP2005179547A Resin composition for manufacturing automotive exterior part 审中-公开
标题翻译：用于制造汽车外部部件的树脂组合物
公开(公告)号：JP2005179547A
公开(公告)日：2005-07-07
申请号：JP2003424076
申请日：2003-12-22
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , IWAKI MITSUJI , NAKAMURA MITSURU , SUZUKI MASAMI , MURAMATSU SHIGERU , SEKITO TAKESHI , YASUNAGA KENICHI
IPC分类号： B62D25/16 , C08K3/04 , C08K3/34 , C08K5/524 , C08K5/5393 , C08L77/00
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for manufacturing automotive exterior parts excellent in the balance among fluidity, heat resistance, impact resistance, rigidity and a linear expansion coefficient and also excellent in electroconductivity, good coating adhesion and stagnation thermal stability (thermal stability when retained in a molten state for long hours).
SOLUTION: The resin composition for manufacturing automotive exterior parts comprises a modified product {a component (A)} obtained by reacting, in a molten state, (A1) a polyphenylene ether, (A2) a hydrogenated product of a block copolymer comprising a vinyl aromatic compound polymer block A and a conjugated diene compound polymer block B, (A3) an unsaturated acid anhydride and/or an unsaturated acid and (A4) a radical initiator, and, incorporated therewith, a polyamide {a component (B)}, a pentaerythritol phosphite compound {a component (C)}, a phosphonite compound {a component (D)}, magnesium silicate (talc) {a component (E)}, electroconductive carbon black {a component (F)} and an ethylene-vinyl alcohol copolymer {a component (G)}, each in a specific ratio.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：解决问题的方案：提供流动性，耐热性，耐冲击性，刚性和线性膨胀系数之间的平衡优异的汽车外用部件的树脂组合物，并且还具有优异的导电性，良好的涂层附着力和停滞热稳定性（长时间保持在熔融状态时的热稳定性）。解决方案：用于制造汽车外部部件的树脂组合物包括通过使熔融状态下的（A1）聚苯醚（A2）与嵌段共聚物的氢化产物（A2）反应获得的改性产物äa组分（A）乙烯基芳族化合物聚合物嵌段A和共轭二烯化合物聚合物嵌段B，（A3）不饱和酸酐和/或不饱和酸和（A4）自由基引发剂，并且与其结合，聚酰胺ä组分（B）} ，季戊四醇亚磷酸酯化合物ä组分（C）}，亚膦酸酯化合物组分（D）}，硅酸镁（滑石）组分（E）}，导电炭黑组分（F）}和乙烯 - 乙烯醇共聚物 äa组分（G）}，每个以具体的比例。版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2004231686A Resin composition for producing exterior automotive trim 审中-公开
公开(公告)号：JP2004231686A
公开(公告)日：2004-08-19
申请号：JP2003018622
申请日：2003-01-28
申请人： Daihatsu Motor Co Ltd , Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , ダイハツ工業株式会社 , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , YASUNAGA KENICHI , SEKITO TAKESHI , FUTAI MASAHITO , YAMAGUCHI SUSUMU , KUSHIRO TAKAHIRO
IPC分类号： C08L77/02 , C08K3/04 , C08K3/34 , C08K5/09 , C08L29/04 , C08L53/02 , C08L71/12
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for producing an exterior automotive trim having excellent impact resistance, fluidity, dimensional stability, electroconductivity, appearance, coating adhesiveness, etc.
SOLUTION: The resin composition is obtained by dry blending 95-100 pts. wt. of a composition with 0.2-5 pts. wt. of an ethylene-vinyl alcohol copolymer. The composition is prepared by previously melt kneading and pelletizing 10-60 pts. wt. of a modified resin (A) obtained by reacting polyphenylene ether (PPE) (A1) with a hydrogenated material (A2) of a styrene-ethylene-butylene-styrene (SEBS) block copolymer and an unsaturated acid anhydride and/or an unsaturated acid (A3) in a molten state with 10-60 pts. wt. of polyamide 6 (B) having specific physical properties, 10-40 pts. wt. of pellets (C) prepared by melt kneading electroconductive carbon black having specified physical properties with the polyamide 6 and 8-20 pts. wt. of calcium metasilicate (D) having the surface treated with an aminosilane coupling agent and specific physical properties.
COPYRIGHT: (C)2004,JPO&NCIPI

3. 发明专利

JP2004230927A Resin composition for manufacture of automobile exterior parts 审中-公开
公开(公告)号：JP2004230927A
公开(公告)日：2004-08-19
申请号：JP2003018627
申请日：2003-01-28
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , SEKITO TAKESHI , YASUNAGA KENICHI
IPC分类号： B62D29/04 , C08K3/04 , C08K7/02 , C08K9/04 , C08L53/02 , C08L71/12 , C08L77/02
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for manufacture of automobile exterior parts having excellent impact resistance, fluidity, dimension stability, conductivity, appearance and coating adhesiveness.
SOLUTION: This resin composition for manufacture of automobile exterior parts is obtained by previously melting and kneading the modified resin (A), which is obtained by reacting PPE (A1), hydrogen additive of SEBS (A2), conductive carbon black having a small specific surface area (A3) and unsaturated acid anhydride and/or unsaturated acid (A4) in the melting condition, of 10-60 parts weight, polyamide 6 (B) having a specified physical property of 10-60 parts weight, pellets (C) obtained by melting and kneading conductive carbon black (C1) having a large specific surface area and the polyamide 6 (C2) of 10-40 parts weight, and metasilicic calucium (D) having a specified physical property of 8-20 parts weight to form the pellet-type composition, and dry-blending ethylene-vinylalcohol copolymer (E) of 0.2-5 parts weight in relation to the pellet-type composition of 95-100 parts weight. This resin composition has a specified micro structure. The described characteristics are thereby obtained.
COPYRIGHT: (C)2004,JPO&NCIPI

4. 发明专利

JP2004231685A Resin composition for producing exterior automotive trim 审中-公开
公开(公告)号：JP2004231685A
公开(公告)日：2004-08-19
申请号：JP2003018618
申请日：2003-01-28
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , YASUNAGA KENICHI , SEKITO TAKESHI
IPC分类号： C08L77/02 , C08K3/04 , C08K3/34 , C08K5/09 , C08L29/04 , C08L53/02 , C08L71/12
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for producing an exterior automotive trim having excellent impact resistance, fluidity, dimensional stability, electroconductivity, appearance, coating adhesiveness, etc.
SOLUTION: The resin composition is obtained by dry blending 100 pts. wt. of a resin composition with 0.2-5 pts. wt. of an ethylene-vinyl alcohol copolymer (F). The above resin composition is prepared by previously melt kneading and pelletizing 10-60 pts. wt. of a modified material (A) obtained by reacting polyphenylene ether (PPE) (A1) with a hydrogenated material (A2) of a styrene-ethylene-butylene-styrene (SEBS) block copolymer and an unsaturated acid anhydride and/or an unsaturated acid (A3) in a specific proportion in a molten state with 10-60 pts. wt. of polyamide 6 (B) having specific physical properties, 10-40 pts. wt. of pellets (C) prepared by melt kneading electroconductive carbon black (C1) having specified physical properties with the polyamide 6 (B) in a specific proportion, 0.01-10 pts. wt. of a carboxylic acid having ≥2 carboxy groups or its derivative (D) and 8-20 pts. wt. of calcium metasilicate (E) having specific physical properties.
COPYRIGHT: (C)2004,JPO&NCIPI

5. 发明专利

JP2004231684A Resin composition for producing exterior automotive trim 审中-公开
公开(公告)号：JP2004231684A
公开(公告)日：2004-08-19
申请号：JP2003018613
申请日：2003-01-28
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , SEKITO TAKESHI , YASUNAGA KENICHI
IPC分类号： C08L77/02 , C08K3/04 , C08K3/16 , C08K3/34 , C08K5/09 , C08L29/04 , C08L53/02 , C08L71/12
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for producing an exterior automotive trim having excellent impact resistance, fluidity, dimensional stability, electroconductivity, appearance, coating adhesiveness, etc.
SOLUTION: The resin composition is obtained by dry blending 100 pts. wt. of a resin composition with 0.2-5 pts. wt. of an ethylene-vinyl alcohol copolymer (F). The above resin composition is prepared by previously melt kneading and palletizing 10-60 pts. wt. of a modified resin (A) obtained by reacting polyphenylene ether (PPE) (A1) with a hydrogenated material (A2) of a styrene-ethylene-butylene-styrene (SEBS) block copolymer and an unsaturated acid anhydride and/or an unsaturated acid (A3) in a specific proportion in a molten state with 10-60 pts. wt. of polyamide 6 (B) having specific physical properties, 10-40 pts. wt. of pellets (C) prepared by melt kneading electroconductive carbon black (C1) having specified physical properties with the polyamide 6 (B) in a specific proportion, 10-40 pts. wt. of pellets (D) obtained by melt kneading a uniform mixture (D1) of potassium iodide with cuprous iodide with the polyamide 6 (B) in a specific proportion and 8-20 pts. wt. of calcium metasilicate (E) having specific physical properties.
COPYRIGHT: (C)2004,JPO&NCIPI

6. 发明专利

JP2004231683A Resin composition for producing exterior automotive trim 审中-公开
公开(公告)号：JP2004231683A
公开(公告)日：2004-08-19
申请号：JP2003018608
申请日：2003-01-28
申请人： Daihatsu Motor Co Ltd , Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , ダイハツ工業株式会社 , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , YASUNAGA KENICHI , SEKITO TAKESHI , FUTAI MASAHITO , YAMAGUCHI SUSUMU , KUSHIRO TAKAHIRO
IPC分类号： C08L77/02 , C08K3/04 , C08K3/34 , C08K5/09 , C08L29/04 , C08L53/02 , C08L71/12
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for producing an exterior automotive trim having excellent impact resistance, fluidity, dimensional stability, electroconductivity, appearance, coating adhesiveness, etc.
SOLUTION: The resin composition is obtained by dry blending 95-100 pts. wt. of a resin composition with 0.2-5 pts. wt. of an ethylene-vinyl alcohol copolymer (E). The above resin composition is prepared by previously melt kneading and pelletizing 10-60 pts. wt. of a modified resin (A) obtained by reacting polyphenylene ether (PPE) (A1) with a hydrogenated material (A2) of a styrene-ethylene-butylene-styrene (SEBS) block copolymer and an unsaturated acid anhydride and/or an unsaturated acid (A3) in a molten state with 10-60 pts. wt. of polyamide 6 (B) having specific physical properties, 10-40 pts. wt. of pellets (C) prepared by melt kneading electroconductive carbon black having specified physical properties with the polyamide 6 and 8-20 pts. wt. of calcium metasilicate (D) having specific physical properties.
COPYRIGHT: (C)2004,JPO&NCIPI

7. 发明专利

JP2004230926A Resin composition for manufacture of automobile exterior parts 审中-公开
公开(公告)号：JP2004230926A
公开(公告)日：2004-08-19
申请号：JP2003018625
申请日：2003-01-28
申请人： Mitsubishi Engineering Plastics Corp , Toyota Motor Corp , トヨタ自動車株式会社 , 三菱エンジニアリングプラスチックス株式会社
发明人： TAKAGI KIYOJI , NAKAMURA MITSURU , IWAKI MITSUJI , SEKITO TAKESHI , YASUNAGA KENICHI
IPC分类号： B62D29/04 , C08K3/04 , C08K7/02 , C08K9/04 , C08L53/02 , C08L71/12 , C08L77/02
摘要： PROBLEM TO BE SOLVED: To provide a resin composition for manufacture of automobile exterior parts having excellent impact resistance, flowing ability, dimension stability, conductivity, appearance and coating adhesiveness.
SOLUTION: This resin composition for manufacture of automobile exterior part is formed by previously melting and kneading the modified resin (A), which is obtained by reacting PPE (A1), a hydrogen additive of SEBS (A2), conductive carbon black (A3) and unsaturated acid anhydride and/or unsaturated acid (A4) in the melting condition, of 10-60 parts weight, polyamide 6 (B) having a specified physical property of 10-60 parts weight, pellet (C) obtained by melting and kneading the hollow carbon fibril (C1) and the polyamide 6 (C2) of 10-40 parts weight, metasilicic acid calcium (D) having a specified physical property of 8-20 parts weight, together to form pellets, and dry-blending ethylene-vinylalcohol copolymer (E) of 0.2-5 parts weight in relation to the pellets of 95-100 parts weight. The resin composition having the described characteristic is thereby obtained.
COPYRIGHT: (C)2004,JPO&NCIPI

8. 发明专利

JP2013082942A Polyester resin composition, and resin-made substrate obtained by molding the same 审中-公开
标题翻译：聚酯树脂组合物和通过模塑其获得的树脂基材
公开(公告)号：JP2013082942A
公开(公告)日：2013-05-09
申请号：JP2013015143
申请日：2013-01-30
申请人： Mitsubishi Engineering Plastics Corp , 三菱エンジニアリングプラスチックス株式会社
发明人： NAKAMURA MITSURU , TAKADA SEIICHI , EGAWA MAKOTO , HIRONO MASAKI
IPC分类号： C08L67/02 , B29C45/00 , C08K5/521 , C08L51/04 , C08L69/00
摘要： PROBLEM TO BE SOLVED: To provide a resin-made substrate combining excellent impact resistance, chemical resistance, high cycle property, dimensional stability and fluidity with the designability of glossiness, depth and color tone giving posh metal tones.SOLUTION: The resin-made substrate has a metal deposit layer and a hard coat layer in this order provided on a surface of a hollow resin molding prepared by molding a polyester resin composition by a gas assist molding method, wherein the polyester resin composition contains a polyester resin (A), a polycarbonate resin (B), and a thermoplastic elastomer (C) in predetermined amounts, and the thermoplastic elastomer is a specific core/shell-type graft copolymer.
摘要翻译：要解决的问题：提供具有优异的耐冲击性，耐化学性，高循环性，尺寸稳定性和流动性的树脂制基材，具有赋予多种金属色调的光泽度，深度和色调的可设计性。解决方案：树脂制基板依次设有金属沉积层和硬涂层，该金属沉积层和硬涂层设置在通过气辅助模压法成型聚酯树脂组合物制备的中空树脂模制件的表面上，其中聚酯树脂组合物含有预定量的聚酯树脂（A），聚碳酸酯树脂（B）和热塑性弹性体（C），热塑性弹性体是特定的核/壳型接枝共聚物。版权所有（C）2013，JPO＆INPIT

9. 发明专利

JP2011068137A Hollow molded article 有权
标题翻译：中空成型文章
公开(公告)号：JP2011068137A
公开(公告)日：2011-04-07
申请号：JP2010269324
申请日：2010-12-02
申请人： Mitsubishi Engineering Plastics Corp , 三菱エンジニアリングプラスチックス株式会社
发明人： KOKUBO AKIHIRO , NAKAMURA MITSURU , IWAKI MITSUJI
IPC分类号： B29C51/10 , B29C51/26 , B29K71/00 , B29L31/30
摘要： PROBLEM TO BE SOLVED: To provide a twin composite molded article in which bonding strength at the thermally fused section of a thermoplastic resin sheet is large, an unfavorable shaping and wrinkles are not generated, excellent appearance is presented, and in addition, a deflection temperature at loading is high, and which is suitable for in-line coating.
SOLUTION: The thermoplastic resin hollow molded article is shaped in such a manner that two pieces of sheets are used, and closely joined to a die surface. In the thermoplastic resin hollow molded article, the thermoplastic resin is a polyphenylene ether resin composition (A-2). (1) The deflection temperatures at loading as the two pieces of the sheet materials are 120°C or higher. (2) When a temperature at which storage elasticity E' becomes 3×10
8 Pa is taken as Th, and a temperature at which the storage elasticity E' becomes 1×10
7 Pa is taken as Ts, (Ts-Th) is 20°C or lower. Also, (3) when hot plate weldable temperatures of the two pieces of the sheets are taken as Tw, (Tw-Ts) is 15°C or lower for the hollow molded article.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：解决问题的方案为了提供热塑性树脂片材的热熔融部分的接合强度大的双组份成型体，不会产生不利的成型和皱纹，外观优异，另外，加载时的挠曲温度高，适合于在线涂布。解决方案：热塑性树脂中空成型制品成形为使用两片，并与模具表面紧密接合。在热塑性树脂中空成型体中，热塑性树脂为聚苯醚树脂组合物（A-2）。（1）作为两片片材的负载时的挠曲温度为120℃以上。（2）当存储弹性E'变为3×10 8 Pa的温度取为Th时，储存弹性E'变为1×10 SP> Pa取为Ts，（Ts-Th）为20℃以下。另外，（3）当两片片材的热板焊接温度为Tw时，对于中空成形品，（Tw-Ts）为15℃以下。版权所有（C）2011，JPO＆INPIT

10. 发明专利

JP2009035616A Thermoplastic resin composition and resin molded product 有权
标题翻译：热塑性树脂组合物和树脂模制产品
公开(公告)号：JP2009035616A
公开(公告)日：2009-02-19
申请号：JP2007200348
申请日：2007-08-01
申请人： Mitsubishi Engineering Plastics Corp , 三菱エンジニアリングプラスチックス株式会社
发明人： NAKAMURA MITSURU , IWAKI MITSUJI , MURAMATSU SHIGERU , NAKANO HIROSHI
IPC分类号： C08L69/00 , C08K3/34 , C08L67/00
摘要： PROBLEM TO BE SOLVED: To provide a thermoplastic resin composition which are excellent with good balance, in terms of rigidity, fluidity, impact resistance and residence thermal stability. SOLUTION: The thermolastic resin composition comprises a total of 100 pts.wt. of 10-90 pts.wt. of an aromatic polycarbonate resin (A component) and 90-10 pts.wt. of a thermoplastic polyester resin (B component) and 1-150 pt(s).wt. of wollastonite (C component). When the micromorphology of this composition is observed by electron microscope, there is such a micromorphology as to be composed of a continuous phase (hereafter referred to as "sea phase") and a discrete phase (hereafter, referred to as "island phase"), and the wollastonite (C component) is present mainly in the aromatic polycarbonate resin (A component) phase. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供在刚性，流动性，耐冲击性和停留热稳定性方面具有良好平衡优异的热塑性树脂组合物。解决方案：热塑性树脂组合物包含总共100重量份 10-90磅的芳族聚碳酸酯树脂（A成分）和90〜10重量份的热塑性聚酯树脂（B组分）和1-150pt（s）的硅灰石（C成分）。当通过电子显微镜观察该组合物的微观形态时，存在由连续相（以下称为“海相”）和离散相（以下称为“岛相”）组成的微观形态，，硅灰石（C成分）主要存在于芳香族聚碳酸酯树脂（A成分）相中。版权所有（C）2009，JPO＆INPIT

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