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    • 3. 发明专利
    • Curable composition and coated article
    • 可固化组合物和涂层物品
    • JP2007231060A
    • 2007-09-13
    • JP2006051759
    • 2006-02-28
    • Shin Etsu Chem Co LtdToyota Industries CorpToyota Motor Corpトヨタ自動車株式会社信越化学工業株式会社株式会社豊田自動織機
    • HIGUCHI KOICHIYAMATANI MASAAKIMURAMATSU HISASHISENBOKU KOICHIWATANABE TOSHIONAGAI TAKAYUKIKONDO TOSHIRO
    • C08L101/10C08K5/3477C08K5/5415
    • C09D183/06C08L83/06C09D143/04C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a curable composition for forming protective coating film free from drawbacks including cracking, debonding and yellowing under long-term use and excellent in weatherability, and to provide a coated article using the composition. SOLUTION: The curable composition comprises (A) a vinyl polymer where hydrolyzable silyl groups and/or SiOH groups and organic ultraviolet-absorbing groups are bound to the side chains, (B) an organic ultraviolet light absorber 500 or higher in molecular weight and 95% or greater in mass residue percentage when kept at 150°C for 24 h under opened state, and (C) an organosilicon compound having in the molecule a nitrogen atom and an alkoxysilyl group. This curable composition, because being markedly improved in light resistance, prevented from the ultraviolet light absorber's being washed away and used as a weatherability-rich binder, gives ultraviolet-absorbing coating film of high water resistance, high solvent resistance and high light resistance. When a weatherability-poor article is coated/cured with this curable composition, the discoloration and/or deterioration of the article is prevented and the article can be imparted with good weatherability. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成保护涂膜的可固化组合物,其不含长期使用下的开裂,脱粘和变黄以及耐候性优良的缺点,并提供使用该组合物的涂布制品。 解决方案:可固化组合物包含(A)其中水解性甲硅烷基和/或SiOH基团和有机紫外线吸收基团与侧链结合的乙烯基聚合物,(B)分子中的有机紫外线吸收剂500以上 重量和95%以上的质量残留百分比,在150℃下保持打开状态24小时,(C)分子内具有氮原子和烷氧基甲硅烷基的有机硅化合物。 该可固化组合物由于耐光性显着提高,防止紫外线吸收剂被洗去并用作耐候脆性粘合剂,得到耐水性高,耐溶剂性高,耐光性高的紫外线吸收性涂膜。 当用这种可固化组合物涂覆/固化耐候性差的制品时,防止了制品的变色和/或变质,并且可赋予制品良好的耐候性。 版权所有(C)2007,JPO&INPIT
    • 4. 发明专利
    • Silicone coating composition and article to be coated
    • 硅胶涂料组合物和待包装的物品
    • JP2005314616A
    • 2005-11-10
    • JP2004136124
    • 2004-04-30
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • HIGUCHI KOICHIYAMATANI MASAAKI
    • C08G77/04C08G77/16C08J7/04C08K5/19C08K5/50C09D7/12C09D183/02C09D183/04
    • C09D183/04C08G77/16C08J7/047C08J2483/04C08K5/19C08K5/50Y10T428/31663
    • PROBLEM TO BE SOLVED: To provide a silicone coating composition which has excellent storage stability, and can form a coating film having high hardness, scratch resistance, adhesiveness, toughness, and crack resistance, and to provide an article to be coated which has this cured coating layer on a surface of its base material. SOLUTION: The silicone coating composition comprises (A) a silicone resin in which at least one kind of alkoxy silane of the formula: (R 1 ) m (R 2 ) n Si(OR 3 ) 4-m-n (wherein R 1 , R 2 are each H or a monovalent hydrocarbon group, R 3 is an alkyl group, m, n are each 0 or 1, and m+n is 0, 1, or 2) and its partially hydrolyzed/condensed material are (co-)hydrolyzed/condensed; (B) a compound which does not include an aromatic group of the formula: [(R 4 )(R 5 )(R 6 )(R 7 )M] + X - (wherein R 4 -R 7 are each an alkyl group, and a total of Taft-Dubois substituent stereo effect coefficient Es is ≤-0.5. M is an ammonium or phosphonium cation, X - is halogen, a hydroxide, or a carboxylate anion), and (C) a solvent. The coating on the cured coating layer is applied on the article to be coated. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供一种具有优异的储存稳定性的硅酮涂料组合物,并且可以形成具有高硬度,耐划伤性,粘合性,韧性和抗裂性的涂膜,并提供一种待涂布的制品 在其基材的表面上具有固化的涂层。 聚硅氧烷涂料组合物包含(A)有机硅树脂,其中至少一种下式的烷氧基硅烷:(R 1 SP< SP>) 其中R 2 )其中R 2 ,R 2 SP 2各自为H或一价烃基,R 3为烷基,m,n各自为0或1,m + n为0,1 ,或2),其部分水解/缩合的材料是(共)水解/缩合的; (B)不包括下式的芳族基团的化合物:[(R SP 5)(R SP 5))(R SP 5) (R 7 )M] + X - (其中R 4 -R > - >均为烷基,Taft-Dubois取代立体效应系数Es的总和≤0.5,M为铵或鏻阳离子,X为卤素,氢氧根或羧酸根 阴离子)和(C)溶剂。 将固化的涂层上的涂层施加在待涂覆的制品上。 版权所有(C)2006,JPO&NCIPI
    • 5. 发明专利
    • Silicone resin composition and article covered with the same
    • 硅胶树脂组合物及其盖章
    • JP2005200546A
    • 2005-07-28
    • JP2004008291
    • 2004-01-15
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • HIGUCHI KOICHIYAMATANI MASAAKI
    • C08G77/14C08G77/06C08G77/16C08G77/18C08J7/04C09D183/04
    • C08J7/047C08G77/06C08G77/16C08G77/18C08J2483/00C09D183/04Y10T428/31663
    • PROBLEM TO BE SOLVED: To provide a silicone resin composition providing a cured product having high hardness and excellent scratch resistance, and also having excellent crack resistance, adhesiveness, water resistance, heat resistance and weather resistance, and effective as a coating agent forming a protective coated film on the surface of an organic resin base material or the like. SOLUTION: The silicone resin composition contains the following silicone resin, a curing catalyst and a solvent as essential components: the silicone resin is obtained by co-hydrolyzing and condensing 1-50 Si-mol% tetraalkoxysilane, 50-99 Si-mol% trialkoxysilane and 0-10 Si-mol% dialkoxysilane by using 1 SiO 3/2 may be 30-80 mol% and the total content of units represented by R 1 SiO 2/2 (OX) and R 1 SiO 1/2 (OX) 2 may be 20-70 mol% in a nuclear magnetic resonance spectrometry. COPYRIGHT: (C)2005,JPO&NCIPI
    • 解决问题的方案:提供一种具有高硬度和优异的耐刮擦性的固化产物的硅树脂组合物,并且还具有优异的抗裂性,粘合性,耐水性,耐热性和耐候性,并且作为涂布剂有效 在有机树脂基材等的表面上形成保护涂膜。 解决方案:硅树脂组合物含有以下有机硅树脂,固化催化剂和溶剂作为必要组分:硅氧烷树脂通过将1-50Si-mol%四烷氧基硅烷,50-99 Si- mol%三烷氧基硅烷和0-10Si-mol%二烷氧基硅烷,使用<100重量份 水基100重量份 总共的烷氧基硅烷具有≥1,500个数均分子量,并且被调节为使得由R 1 SiO 3/2 表示的单元的含量可以为30- 80摩尔%,由R 1表示的单位的总含量SiO 2/2(SB)(OX)和R SP 1 SiO 2 / 在核磁共振光谱法中,2 (OX) 2 可以为20-70mol%。 版权所有(C)2005,JPO&NCIPI
    • 6. 发明专利
    • オルガノゾル及びその製造方法
    • 有机硅及其生产方法
    • JP2015034106A
    • 2015-02-19
    • JP2013165113
    • 2013-08-08
    • 信越化学工業株式会社Shin Etsu Chem Co Ltd
    • MASUDA KOHEIHIGUCHI KOICHI
    • C01B33/148C01G23/00
    • 【課題】無機酸化物コロイド水分散液から出発してオルガノゾルを製造する方法において、容易に実施できて有用性が高く、分級・粉砕等の機械的単位操作を経ずとも良好な分散状態と透明性を兼ね備えたオルガノゾルの製造方法及び該方法により得られるオルガノゾルを提供する。【解決手段】(A)無機酸化物コロイド水分散液を準備する工程、(B)水と完全には相溶せず2相系を形成するアルコールを添加する工程、(C)特定の有機ケイ素化合物及び/又はその(部分)加水分解縮合物を添加する工程、(D)マイクロ波を照射する工程、(E)有機溶媒を添加する工程、(F)共沸蒸留及び/又は限外ろ過によって水を留去する工程、及び必要に応じて(G)水を1,000ppm以下まで除去する工程からなる水性コロイド溶液の溶媒置換を経るオルガノゾルの製造方法。【選択図】図1
    • 要解决的问题:为了提供使用无机氧化物胶体分散体作为原料的有机溶胶的制备方法,易于实施,具有高可用性,优异的分散状态和透明性的有机溶胶,而不进行机械单元操作,例如 分类和粉碎,并提供通过该方法获得的有机溶胶。溶液:有机溶胶的制备方法包括以下步骤:(A)制备无机氧化物胶体分散体; (B)加入与水不完全相容的醇,形成两相体系; (C)加入特定的有机硅化合物和/或(部分)水解缩合物; (D)照射微波; (E)加入有机溶剂; 和(F)通过共沸蒸馏和/或超滤蒸馏除去水分。 制造方法如果需要,包括(G)将水除去至1000ppm以下的步骤来代替胶体溶液的溶剂。
    • 7. 发明专利
    • Aqueous core-shell tetragonal titanium oxide solid-solution dispersion, method for manufacturing the same, ultraviolet-shielding silicone coating composition, and coated object
    • 水性核心壳四氧化钛固体溶液分散体,其制造方法,超紫外线屏蔽硅酮涂料组合物和涂层物体
    • JP2014019611A
    • 2014-02-03
    • JP2012160347
    • 2012-07-19
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • MASUDA KOHEIHIGUCHI KOICHIKOMORI HISATOSHIFURUDATE MANABUINOUE TOMOHIROEIKUCHI KICHIJI
    • C01G23/00
    • G02B1/14B82Y30/00C01G23/002C01P2002/52C01P2002/72C01P2002/84C01P2004/64C01P2004/84C09C1/3684G02B1/105Y10T428/256
    • PROBLEM TO BE SOLVED: To provide an aqueous core-shell tetragonal titanium oxide solid-solution dispersion, a method for manufacturing the aqueous dispersion, an ultraviolet-shielding silicone coating composition including the aqueous dispersion, and a coated object coated with a cured film of the composition.SOLUTION: The present aqueous core-shell tetragonal titanium oxide solid-solution dispersion is provided by dispersing, within an aqueous dispersion medium, a core-shell tetragonal titanium oxide solid-solution having tetragonal titanium oxide particulates with which tin and manganese are solid-solubilized as nuclei and silicon oxide as shells; in this aqueous core-shell tetragonal titanium oxide solid-solution dispersion, average particle diameters of the nuclear particulates and core-shell solid-solution are respectively 30 nm or below and 50 nm or below, and the respective solid-solubilized contents of the tin and manganese in terms of molar ratio are each confined to 10-1,000. There can be provided an ultraviolet-shielding silicone coating composition (hard coating agent) including a particular dispersion yielding a cured film simultaneously realizing a high weather resistance and a high ultraviolet shielding capacity and also excellent in terms of transparency, scratch resistance, and adhesiveness without sacrificing designability.
    • 要解决的问题:提供核 - 壳四方钛氧化物固体水溶液分散体,水分散体的制造方法,包含该水分散体的紫外线屏蔽性硅氧烷涂料组合物和涂有固化膜的涂布体 本发明的水性核 - 壳四方晶氧化钛固溶体分散体是通过在水分散介质中分散具有四方晶氧化钛颗粒的核 - 壳四方钛氧化物固溶体,其中锡和锰是 作为核固体溶解,氧化硅为壳; 在这种核心 - 壳体四方晶氧化钛固溶体分散体中,核粒子和核 - 壳固溶体的平均粒径分别为30nm以下且50nm以下,锡的各固溶体含量 以摩尔比计算的锰各自限制在10-1,000。 可以提供包含产生固化膜的特定分散体的紫外线屏蔽硅涂层组合物(硬涂层剂),同时实现高耐候性和高紫外线屏蔽能力,并且在透明性,耐刮擦性和粘合性方面也优异,而没有 牺牲可设计性。
    • 8. 发明专利
    • Primer composition and coated article
    • 主成分和涂层物品
    • JP2008120986A
    • 2008-05-29
    • JP2007036412
    • 2007-02-16
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • HIGUCHI KOICHIYAMATANI MASAAKI
    • C09D143/04B05D7/24C08J7/04C09D5/00C09D7/12C09D157/06C09D183/00C09D183/08
    • C09D143/04C08J7/047C08J2443/00Y10T428/259Y10T428/31663Y10T428/31667
    • PROBLEM TO BE SOLVED: To provide a primer composition to form a protective coating without weak points such as cracking, debonding and yellowing, for a long period of time, and excellent in weather resistance, and to provide a coated article using the composition. SOLUTION: This primer composition for a polysiloxane hard coating comprises (A) a vinyl polymer having a hydrolyzable silyl group and/or SiOH group and an organic UV absorbing group bonded to its side chain, and (B) fine silica particles dispersed in an organic solvent, the primer layer formed after coating and curing has a coefficient of linear expansion of ≤150×10 -6 /°C. The primer layer formed in such a manner has greatly improved lightfastness and inhibits the loss of a UV absorbing agent on standing. An organic-inorganic composite formed by siloxane crosslinking reduces the coefficient of linear expansion, becomes a binder excellent in weather resistance and thus imparts a UV absorbing protective coating superior in water resistance, solvent resistance and light fastness. The primer composition coated on a product with inferior weather resistance and cured controls decoloration and deterioration of the product, and imparts good weather resistance. COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:提供一种底漆组合物,以长时间形成无裂点,脱粘和变黄等弱点的保护涂层,并且耐候性优异,并且提供使用 组成。 该聚硅氧烷硬质涂层用底漆组合物包含(A)具有水解性甲硅烷基和/或SiOH基的乙烯基聚合物和与其侧链结合的有机UV吸收基,(B)分散的二氧化硅微粒 在有机溶剂中,涂布固化后形成的底漆层的线膨胀系数为≤150×10 -6 /℃。 以这种方式形成的底漆层具有大大改善的耐光性并且抑制了驻留时的紫外线吸收剂的损失。 通过硅氧烷交联而形成的有机 - 无机复合体可降低线膨胀系数,成为耐候性优异的粘合剂,因此赋予耐水性,耐溶剂性和耐光性优异的紫外线吸收保护涂层。 涂覆在耐候性差的产品上的底漆组合物和固化的对照脱色和产品劣化,并赋予良好的耐候性。 版权所有(C)2008,JPO&INPIT
    • 9. 发明专利
    • Silicone coating composition, method for producing the same, and coated article
    • 硅胶涂料组合物,其制造方法和涂层制品
    • JP2008094956A
    • 2008-04-24
    • JP2006278338
    • 2006-10-12
    • Shin Etsu Chem Co Ltd信越化学工業株式会社
    • FURUYA MASAHIROHIGUCHI KOICHIYAMATANI MASAAKI
    • C09D183/00C09D1/00
    • PROBLEM TO BE SOLVED: To provide a coating composition curable into a coating film which can exhibit scratch resistance and UV shielding properties while keeping transparency to visible light and has weather resistance and durability high enough to withstand to long-term outdoor exposure, to provide a method for producing the same, and to provide an article coated with the same. SOLUTION: Provided is a silicone composition comprising (A) a silicone resin prepared by (co)hydrolyzing and/or condensing at least one member selected from an alkoxysilane represented by formula (1): (R 1 ) m (R 2 ) n Si(OR 3 ) 4-m-n (wherein R 1 and R 2 are each independently a hydrogen atom or a substituted or unsubstituted monovalent hydrocarbon group; R 3 is a 1-3C alkyl group; and m and n are each independently 0 or 1, provided that m+n=0, 1, or 2) and a condensate of a partial hydrolyzate thereof, (B) a rutile titanium oxide microparticle dispersion containing a dispersant, (C) a curing catalyst, and (D) a solvent, wherein the dispersion (B), the titanium oxide solids content is 0.1-15 mass% based on the entire weight of the solids constituents in the composition. COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供可涂覆在涂膜中的涂料组合物,其可以显示耐刮擦性和紫外线屏蔽性,同时保持对可见光的透明性并且具有足够高的耐候性和耐久性以耐受长期的室外暴露, 以提供其制造方法,并提供其涂覆的制品。 解决方案:提供一种硅氧烷组合物,其包含(A)通过(共)水解和/或冷凝选自式(1)表示的烷氧基硅烷中的至少一种的硅氧烷树脂:(R 1 SP 1) SP>)(R 2 名词的Si(OR 3 4- MN (其中R 1和R 2各自独立地为氢原子或取代或未取代的单价烃基; R 3为1 -3C烷基; m和n各自独立地为0或1,条件是m + n = 0,1或2)及其部分水解产物的缩合物,(B)含有分散剂的金红石型氧化钛微粒分散体 ,(C)固化催化剂和(D)溶剂,其中基于组合物中固体成分的总重量,分散体(B)的氧化钛固体含量为0.1〜15质量%。 版权所有(C)2008,JPO&INPIT
    • 10. 发明专利
    • Curable composition and coated article
    • 可固化组合物和涂层物品
    • JP2007231059A
    • 2007-09-13
    • JP2006051756
    • 2006-02-28
    • Shin Etsu Chem Co LtdToyota Industries CorpToyota Motor Corpトヨタ自動車株式会社信越化学工業株式会社株式会社豊田自動織機
    • HIGUCHI KOICHIYAMATANI MASAAKIMURAMATSU HISASHISENBOKU KOICHIWATANABE TOSHIONAGAI TAKAYUKIKONDO TOSHIRO
    • C08L83/10C08K5/3477
    • C08J7/047C08J2369/00C08J2483/00C08L83/06C08L101/00C09D143/04C09D183/10Y10T428/31663C08L2666/02
    • PROBLEM TO BE SOLVED: To provide a curable composition for forming protective coating film free from drawbacks including cracking, debonding and yellowing under long-term use and excellent in weatherability, and to provide a coated article using the composition. SOLUTION: The curable composition comprises (A) an organic-inorganic composite where a polysiloxane with hydrolyzable silyl groups and/or SiOH groups and a vinyl polymer are bound to each other via Si-C bond and (B) an organic ultraviolet light absorber 500 or higher in molecular weight and 95% or greater in mass residue percentage when kept at 150°C for 24 h under opened state. This curable composition, because the ultraviolet light absorber is prevented from being washed away owing to siloxane crosslinking and the organic-inorganic composite rich in weatherability is used as a binder, gives ultraviolet-absorbing coating film of high water resistance and solvent resistance. When a weatherability-poor article is coated/cured with this curable composition, the discoloration and/or deterioration of the article is prevented and the article can be imparted with good weatherability. COPYRIGHT: (C)2007,JPO&INPIT
    • 要解决的问题:提供一种形成保护涂膜的可固化组合物,其不含长期使用下的开裂,脱粘和变黄以及耐候性优良的缺点,并提供使用该组合物的涂布制品。 解决方案:可固化组合物包含(A)其中具有可水解甲硅烷基和/或SiOH基的聚硅氧烷和乙烯基聚合物通过Si-C键彼此结合的有机 - 无机复合物,(B)有机紫外线 光吸收剂在150℃下保持24小时,分子量为500以上,质量残留率为95%以上。 该可固化组合物由于防止紫外光吸收剂被硅氧烷交联而被洗涤,并且将具有耐候性的有机 - 无机复合材料用作粘合剂,得到具有高耐水性和耐溶剂性的紫外线吸收涂膜。 当用这种可固化组合物涂覆/固化耐候性差的制品时,防止了制品的变色和/或变质,并且可赋予制品良好的耐候性。 版权所有(C)2007,JPO&INPIT