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1. 发明授权

US08748543B2 Polylactic acid film 失效
标题翻译：聚乳酸薄膜
公开(公告)号：US08748543B2
公开(公告)日：2014-06-10
申请号：US13119671
申请日：2009-09-29
申请人： Shigeyoshi Masuda , Kohei Endo , Kinji Hasegawa
发明人： Shigeyoshi Masuda , Kohei Endo , Kinji Hasegawa
IPC分类号： C08G63/91
CPC分类号： C08J5/18 , C08J2367/04 , C08L67/04 , C08L2205/02 , G02F1/13363 , C08L2666/18
摘要： The polylactic acid film is obtained by melt extruding polylactic acid (A) prepared by melt kneading together polylactic acid (B) which comprises an L-lactic acid unit as the main ingredient and polylactic acid (C) which comprises a D-lactic acid unit as the main ingredient in a specific weight ratio, wherein the polylactic acid film has: (a) a stereocomplex crystal rate (S) defined by the following equation (i) of 90% or more: S={(ΔHmsc/(ΔHmsc+ΔHmh)}×100 (i) (in the above equation, ΔHmh is the melting enthalpy of a low-melting point crystal melting peak at a temperature lower than 190° C. obtained by differential scanning calorimeter (DSC) measurement and ΔHmsc is the melting enthalpy of a high-melting point crystal melting peak at a temperature of 190° C. or higher obtained by DSC measurement), (b) a haze of 10% or less, and (c) a haze change of 5% or less after it is heated at 140° C. for 10 minutes.
摘要翻译：通过熔融挤出通过熔融捏合聚乳酸（A）得到的聚乳酸薄膜，其中聚乳酸（A）是以包含L-乳酸单元为主要成分的聚乳酸（B）和包含D-乳酸单元的聚乳酸（C）作为主成分，其中聚乳酸膜具有：（a）由下式（i）定义的立体络合物结晶速率（S）为90％以上：S = {（＆Dgr; Hmsc /（＆Dgr; Hmsc +＆Dgr; Hmh）}×100（i）（在上式中，＆Dgr; Hmh是通过差示扫描量热计获得的低于190℃的低熔点晶体熔融峰的熔融焓（DSC）测定和＆Dgr Hmsc是通过DSC测定得到的温度为190℃以上的高熔点结晶熔融峰的熔融焓），（b）10％以下的雾度和（ c）在140℃加热10分钟后，雾度变化为5％以下。

2. 发明申请

US20110224342A1 POLYLACTIC ACID FILM 失效
标题翻译：聚酰胺薄膜
公开(公告)号：US20110224342A1
公开(公告)日：2011-09-15
申请号：US13119671
申请日：2009-09-29
申请人： Shigeyoshi Masuda , Kohei Endo , Kinji Hasegawa
发明人： Shigeyoshi Masuda , Kohei Endo , Kinji Hasegawa
IPC分类号： C08L67/04 , C08K5/521 , B29C55/12
CPC分类号： C08J5/18 , C08J2367/04 , C08L67/04 , C08L2205/02 , G02F1/13363 , C08L2666/18
摘要： The polylactic acid film is obtained by melt extruding polylactic acid (A) prepared by melt kneading together polylactic acid (B) which comprises an L-lactic acid unit as the main ingredient and polylactic acid (C) which comprises a D-lactic acid unit as the main ingredient in a specific weight ratio, wherein the polylactic acid film has: (a) a stereocomplex crystal rate (S) defined by the following equation (i) of 90% or more: S={(ΔHmsc/(ΔHmsc+ΔHmh)}×100 (i) (in the above equation, ΔHmh is the melting enthalpy of a low-melting point crystal melting peak at a temperature lower than 190° C. obtained by differential scanning calorimeter (DSC) measurement and ΔHmsc is the melting enthalpy of a high-melting point crystal melting peak at a temperature of 190° C. or higher obtained by DSC measurement), (b) a haze of 10% or less, and (c) a haze change of 5% or less after it is heated at 140° C. for 10 minutes.
摘要翻译：通过熔融挤出通过熔融捏合聚乳酸（A）而得到的聚乳酸薄膜，该聚乳酸（A）通过以包含L-乳酸单元为主要成分的聚乳酸（B）和包含D-乳酸单元的聚乳酸作为主要成分，其中聚乳酸膜具有：（a）由下式（i）定义的立体络合物结晶速率（S）为90％以上：S = {（＆Dgr; Hmsc /（＆Dgr; Hmsc +＆Dgr; Hmh）}×100（i）（在上式中，＆Dgr; Hmh是通过差示扫描量热计获得的低于190℃的低熔点晶体熔融峰的熔融焓（DSC）测定和＆Dgr Hmsc是通过DSC测定得到的温度为190℃以上的高熔点结晶熔融峰的熔融焓），（b）10％以下的雾度和（ c）在140℃加热10分钟后，雾度变化为5％以下。

3. 发明申请

US20120232209A1 HIGHLY INSULATING FILM 审中-公开
标题翻译：高绝缘膜
公开(公告)号：US20120232209A1
公开(公告)日：2012-09-13
申请号：US13512515
申请日：2010-11-26
申请人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa , Masanori Nishiyama
发明人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa , Masanori Nishiyama
IPC分类号： H01B3/42 , H01B3/46 , C08L83/00 , B32B5/16 , C08L71/12
CPC分类号： H01G4/18 , C08J5/18 , C08J2325/04 , C08K3/013 , C08K5/005 , C08L25/06 , C08L71/12 , C08L83/04 , C08L2205/03 , C08L2666/14 , C08L25/04
摘要： Provided is a highly insulating film having excellent electrical characteristics (breakdown voltage), heat resistance, and handling properties such as windability and processability. The highly insulating film is a biaxially stretched film made of a styrene polymer having a syndiotactic structure as a main component. The highly insulating film contains specific inert fine particles A, antioxidant, and polymer Y having a glass transition temperature Tg by DSC of 130° C. or more each in a specific amount, and has a refractive index in the thickness direction of 1.5750 or more and 1.6350 or less.
摘要翻译：提供了具有优异的电特性（击穿电压），耐热性和诸如缠绕性和加工性的处理性能的高绝缘膜。高绝缘膜是以间同立构结构为主要成分的苯乙烯聚合物制成的双轴拉伸膜。高绝缘膜含有特定的惰性微粒A，抗氧化剂和DSC，DSC为130℃以上，特定量的玻璃化转变温度Tg的聚合物Y，其厚度方向的折射率为1.5750以上和1.6350以下。

4. 发明申请

US20100178483A1 INSULATING FILM 有权
标题翻译：绝缘膜
公开(公告)号：US20100178483A1
公开(公告)日：2010-07-15
申请号：US12665618
申请日：2008-06-19
申请人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa
发明人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa
IPC分类号： B32B27/04 , B32B27/32 , B32B5/02
CPC分类号： H01G4/18 , C08J5/18 , C08J2325/06 , H01G4/224 , Y10S428/91 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/31855
摘要： An object of the present invention is to provide an insulating film having a high breakdown voltage and excellent heat resistance and handling properties.The present invention is a biaxially oriented insulating film which contains (i) a styrene-based polymer having a syndiotactic structure and (ii) particles and which has a refractive index in the thickness direction of 1.6050 to 1.6550.
摘要翻译：本发明的目的是提供具有高击穿电压和优异的耐热性和操作性能的绝缘膜。本发明是一种双轴取向绝缘膜，其包含（i）具有间同立构结构的苯乙烯类聚合物和（ii）粒子，其厚度方向的折射率为1.6050〜1.6550。

5. 发明授权

US10438746B2 Insulating film 有权
公开(公告)号：US10438746B2
公开(公告)日：2019-10-08
申请号：US13512515
申请日：2010-11-26
申请人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa , Masanori Nishiyama
发明人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa , Masanori Nishiyama
IPC分类号： C08L71/12 , H01G4/18 , C08J5/18 , C08L25/06 , C08K5/00 , C08L83/04 , C08K3/013
摘要： Provided is a highly insulating film having excellent electrical characteristics (breakdown voltage), heat resistance, and handling properties such as windability and processability. The highly insulating film is a biaxially stretched film made of a styrene polymer having a syndiotactic structure as a main component. The highly insulating film contains specific inert fine particles A, antioxidant, and polymer Y having a glass transition temperature Tg by DSC of 130° C. or more each in a specific amount, and has a refractive index in the thickness direction of 1.5750 or more and 1.6350 or less.

6. 发明授权

US08859087B2 Insulating film 有权
标题翻译：绝缘膜
公开(公告)号：US08859087B2
公开(公告)日：2014-10-14
申请号：US12665618
申请日：2008-06-19
申请人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa
发明人： Shigeyoshi Masuda , Dai Nakagawa , Kinji Hasegawa
IPC分类号： C08J5/18 , H01G4/224 , B32B27/04 , B32B27/32 , H01G4/18
CPC分类号： H01G4/18 , C08J5/18 , C08J2325/06 , H01G4/224 , Y10S428/91 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/31855
摘要： The present invention is to provide an insulating film having a high breakdown voltage and excellent heat resistance and handling properties. The present invention is a biaxially oriented insulating film which contains (i) a styrene-based polymer having a syndiotactic structure and (ii) particles and which has a refractive index in the thickness direction of 1.6050 to 1.6550.
摘要翻译：本发明提供一种具有高击穿电压和优异的耐热性和操作性能的绝缘膜。本发明是一种双轴取向绝缘膜，其包含（i）具有间同立构结构的苯乙烯类聚合物和（ii）粒子，其厚度方向的折射率为1.6050〜1.6550。

7. 发明授权

US4233354A Printed polyester films 失效
标题翻译：印花聚酯薄膜
公开(公告)号：US4233354A
公开(公告)日：1980-11-11
申请号：US935850
申请日：1978-08-22
申请人： Kinji Hasegawa , Yukio Mitsuishi , Shigeyoshi Masuda
发明人： Kinji Hasegawa , Yukio Mitsuishi , Shigeyoshi Masuda
IPC分类号： C08L67/00 , B41M1/30 , B65D65/00 , B65D65/02 , C08G63/00 , C08G63/66 , C08J5/18 , C08J7/04 , C08L67/02 , B32B5/16 , B32B27/36
CPC分类号： C08J5/18 , B41M1/30 , C08J2367/02 , Y10T428/24802 , Y10T428/24893 , Y10T428/24901 , Y10T428/31786
摘要： A printed polyester film comprising(I) a biaxially oriented polyester film containing more than 2% by weight to 10% by weight of polyethylene glycol having a molecular weight of 5,000 to 200,000 and a density of 1.390 to 1.410, said film being composed of a polyester in which at least 80% by weight of the entire structural units consists of an ethylene terephthalate unit, and(II) a printed layer formed by a printing ink containing a cellulose derivative as a binder, said printed layer being applied to at least a part of the surface of the film (I),and a process for preparation thereof.
摘要翻译：一种印刷聚酯膜，其包含（I）含有超过2重量％至10重量％的分子量为5,000至200,000和密度为1.390至1.410的聚乙二醇的双轴取向聚酯膜，所述膜由聚酯，其中整个结构单元的至少80重量％由对苯二甲酸乙二醇酯单元组成，和（II）由含有纤维素衍生物作为粘合剂的印刷油墨形成的印刷层，所述印刷层至少施加至薄膜（I）表面的一部分及其制备方法。

8. 发明授权

US5814385A Laminated polyester film to be laminated onto metal plate 失效
标题翻译：层压在金属板上的层压聚酯薄膜
公开(公告)号：US5814385A
公开(公告)日：1998-09-29
申请号：US617759
申请日：1996-03-15
申请人： Takeo Asai , Kinji Hasegawa , Mitsumasa Ono
发明人： Takeo Asai , Kinji Hasegawa , Mitsumasa Ono
IPC分类号： B32B27/36 , B32B1/02 , B32B15/08 , B32B27/08
CPC分类号： B32B27/36 , Y10T428/1355 , Y10T428/24355 , Y10T428/24975 , Y10T428/25 , Y10T428/31786
摘要： A laminated polyester film comprising an aromatic copolyester layer having a surface roughness of 2 to 13 nm and a polyester layer having a surface roughness (Ra) of at least 15 nm. This laminated polyester film has improved impact resistance particularly at low temperatures and improved taste-retaining property while retaining the excellent moldability, heat resistance, retort sterilization resistance and flavor-retaining property possessed by copolyester films.
摘要翻译： PCT No.PCT / JP94 / 01185 Sec。 371日期：1996年3月15日 102（e）1996年3月15日PCT PCT 1994年7月19日PCT公布。公开号WO96 / 02387 日期：1996年2月1日，包括表面粗糙度为2〜13nm的芳香族共聚酯层和表面粗糙度（Ra）为15nm以上的聚酯层的层压聚酯膜。该层压聚酯薄膜特别是在低温下具有改善的耐冲击性，并且在保持共聚酯薄膜所具有的优异的成型性，耐热性，耐蒸煮灭菌性和香味保持性的同时，具有改善的保持性。

9. 发明授权

US5686510A Biaxially oriented polyester film for lamination onto metal sheet 失效
标题翻译：用于层压在金属板上的双轴取向聚酯膜
公开(公告)号：US5686510A
公开(公告)日：1997-11-11
申请号：US339876
申请日：1994-11-10
申请人： Takeo Asai , Kinji Hasegawa , Mitsumasa Ono
发明人： Takeo Asai , Kinji Hasegawa , Mitsumasa Ono
IPC分类号： B29C55/12 , B29K67/00 , B29L7/00 , B32B15/08 , B32B15/09 , B32B27/36 , C08J5/18 , C08K3/00 , C08K3/22 , C08K3/36 , C08L67/00 , C08L67/02 , B32B27/06
CPC分类号： C08J5/18 , B32B15/08 , B32B27/36 , C08K3/22 , C08K3/36 , C08J2367/02 , Y10T428/1355 , Y10T428/31681 , Y10T428/31786
摘要： A biaxially oriented polyester film made of a polyester composition, (A) which polyester composition comprises (a) an aromatic copolyester having a melting point of 210-245.degree. C., (b) first inert fine solid particles having an average particle diameter of 0.05 to 0.6 .mu.m, and (c) second inert fine solid particles having an average particle diameter of 0.3 to 2.5 .mu.m, the ratio of the average particle diameter of the second inert fine solid particles to the average particle diameter of the first inert fine solid particles being at least 2.5, and the amounts of the components (b) and (c) being 0.01 to 3% by weight and 0.001 to 0.2% by weight, respectively, based on the total weight of the components (a), (b) and (c); (B) which polyester film has a plane orientation coefficient of 0.08 to 0.16; and, (C) which polyester film shows excellent moldability when laminated onto a metal sheet and subjected to deep drawing. A can for drinks, foods, etc. having excellent heat resistance and flavor-retaining property can be produced from a metal sheet onto which the above biaxially oriented polyester film is laminated.
摘要翻译：一种由聚酯组合物制成的双轴取向聚酯膜，（A）该聚酯组合物包含（a）熔点为210-245℃的芳族共聚酯，（b）平均粒径为 0.05〜0.6μm，和（c）平均粒径为0.3〜2.5μm的第二惰性细粒固体颗粒，第二惰性微粒固体颗粒的平均粒径与第一惰性微粒固体颗粒的平均粒径之比细固体颗粒为至少2.5，并且组分（b）和（c）的量分别为基于组分（a）的总重量的0.01至3重量％和0.001至0.2重量％（b）和（c）; （B）该聚酯薄膜的平面取向系数为0.08〜0.16; 和（C）当层压到金属片上并进行深冲压时，该聚酯膜显示出优异的成型性。可以由层叠上述双轴取向聚酯膜的金属板制造具有优异的耐热性和香味保持性的饮料，食品等的罐。

10. 发明授权

US4818581A Biaxially oriented polyester film 失效
标题翻译：双轴取向聚酯薄膜
公开(公告)号：US4818581A
公开(公告)日：1989-04-04
申请号：US89571
申请日：1987-08-26
申请人： Hideo Katoh , Hisashi Hamano , Kinji Hasegawa , Yoshihiro Noumi
发明人： Hideo Katoh , Hisashi Hamano , Kinji Hasegawa , Yoshihiro Noumi
IPC分类号： C08J5/18 , C08K3/36 , B32B27/00
CPC分类号： C08J5/18 , C08K3/36 , C08J2367/02 , Y10S428/90 , Y10T428/24372 , Y10T428/2982 , Y10T428/31786
摘要： A biaxially oriented polyester film formed from an intimate mixture comprising (1) an aromatic polyester, and (2) 0.01 to 4% by weight, based on the aromatic polyester, of spherical fine particles of silica having (a) an average particle diameter of 0.05 to 4 .mu.m, (b) a particle diameter ratio, defined by the ratio of maximum diameter of minimum diameter, of from 1.0 to 1.2, and (c) a relative standard deviation (.sigma.) of particle size, of up to 0.5. A biaxially oriented polyester film formed from an intimate mixture comprising (1) an aromatic polyester, (2) 0.005 to 3% by weight, based on the aromatic polyester, of spherical fine particles of silica having the same properties as the above-mentioned (a), (b) and (c), and (3) 0.005 to 3% by weight, based on the aromatic polyester, of inert fine particles having an average particle diameter of 0.01 to 3 .mu.m and not exceeding the average particle diameter of the spherical fine particles of silica. The biaxially oriented films are useful for a magnetic recording medium.
摘要翻译：一种由包含（1）芳族聚酯和（2）基于芳族聚酯的0.01至4重量％的二氧化硅球形细颗粒形成的双轴取向聚酯膜，其具有（a）平均粒径为 0.05至4μm，（b）由最小直径的最大直径的比定义的粒径比为1.0至1.2，和（c）粒径的相对标准偏差（sigma）至多0.5 。一种由紧密混合物形成的双轴取向聚酯膜，其包含（1）芳族聚酯，（2）0.005至3重量％的基于芳族聚酯的球形二氧化硅微粒，其具有与上述（ a），（b）和（c），（3）0.005〜3重量％的芳族聚酯，平均粒径为0.01〜3μm的惰性微粒，不超过平均粒径的二氧化硅球形细颗粒。双轴取向膜可用于磁记录介质。

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