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1. 发明申请

US20070148518A1 Polymer electrolyte and use thereof 审中-公开
标题翻译：聚合物电解质及其用途
公开(公告)号：US20070148518A1
公开(公告)日：2007-06-28
申请号：US10583606
申请日：2004-12-21
申请人： Shigeru Sasaki , Toru Onodera , Arihiro Yashiro , Mitsunori Nodono
发明人： Shigeru Sasaki , Toru Onodera , Arihiro Yashiro , Mitsunori Nodono
IPC分类号： H01M8/10 , H01M10/40
CPC分类号： C08G65/48 , C08G75/23 , C08J5/2256 , C08J2365/02 , C08J2371/12 , H01B1/122 , H01M8/04197 , H01M8/1009 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1067 , H01M2300/0082
摘要： An aromatic polymer electrolyte that when directly used in a methanol fuel cell, excels in methanol shutoff, etc. There is provided a polymer electrolyte comprising polymer main chains containing oxygen elements and/or sulfur elements and aromatic carbon rings and, directly bonded to some or all of the aromatic carbon rings of the entirety of the polymer electrolyte including side chains, ion exchange groups, wherein the ratio (R) of the number of aromatic condensed polycyclic carbon rings to the total number of aromatic carbon rings of the entirety of the polymer electrolyte including side chains (sum of the number of aromatic monocyclic carbon rings and the number of aromatic condensed polycyclic carbon rings) satisfies the formula: 1>R≧0.15.
摘要翻译：一种直接用于甲醇燃料电池中的芳族聚合物电解质，具有优异的甲醇截止等优点。提供了包含含有氧元素和/或硫元素和芳族碳环的聚合物主链的聚合物电解质，并且直接键合到一些或包括侧链的整个聚合物电解质的所有芳族碳环，离子交换基团，其中芳族稠合多环碳环数与全部聚合物的芳族碳环总数的比率（R）包括侧链的电解质（芳族单环碳环的数目和芳族稠合多环碳环的数量之和）满足下式：1> R> = 0.15。

2. 发明申请

US20110311899A1 POLYMER, POLYARYLENE BLOCK COPOLYMER, POLYELECTROLYTE, POLYELECTROLYTE MEMBRANE, AND FUEL CELL 审中-公开
标题翻译：聚合物，聚烯烃嵌段共聚物，聚电解质，聚电解质膜和燃料电池
公开(公告)号：US20110311899A1
公开(公告)日：2011-12-22
申请号：US12993675
申请日：2009-05-21
申请人： Toru Onodera , Taisuke Nakamura , Sho Kanesaka , Arihiro Yashiro , Takashi Yamada , Masamitsu Ishitobi , Shigeru Sasaki , Isao Kaito , Akira Kaito , Yuko Kaito
发明人： Toru Onodera , Taisuke Nakamura , Sho Kanesaka , Arihiro Yashiro , Takashi Yamada , Masamitsu Ishitobi , Shigeru Sasaki , Isao Kaito , Akira Kaito , Yuko Kaito
IPC分类号： B01J39/18 , H01M8/10
CPC分类号： C08J5/2256 , C08G61/12 , C08G2261/1452 , C08G2261/312 , C08G2261/3444 , C08G2261/354 , C08G2261/412 , C08G2261/516 , C08J2365/00 , H01B1/122 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M2008/1095 , H01M2300/0082
摘要： The polymer electrolyte membrane according to the present invention comprises a polymer electrolyte having ion-exchange groups, wherein Sp and Snp satisfy a relationship expressed by the following expression (I): Sp/Snp≦0.42 (I) where Sp represents the total of peak areas obtained by measurement of a 13C-solid state nuclear magnetic resonance spectrum of the polymer electrolyte membrane, the polymer electrolyte membrane having been subjected to a first immersion treatment comprising immersing the polymer electrolyte membrane in 5 mmol/L iron (II) chloride tetrahydrate aqueous solution at 25° C. for 1 hour, and thereafter drying the polymer electrolyte membrane at 25° C. at 10 hPa or lower for 12 hours; and Snp represents the total of peak areas obtained by measurement of a 13C-solid state nuclear magnetic resonance spectrum of the polymer electrolyte membrane, the polymer electrolyte membrane before the first immersion treatment having been subjected to a second immersion treatment comprising immersing the polymer electrolyte membrane in water at 25° C. for 1 hour, and thereafter drying the polymer electrolyte membrane at 25° C. at 10 hPa or lower for 12 hours.
摘要翻译：本发明的高分子电解质膜包含具有离子交换基团的高分子电解质，其中，Sp和Snp满足由下式（I）表示的关系：Sp / Snp＆nlE; 0.42（I）其中Sp表示峰的总和通过测量聚合物电解质膜的13 C-固态核磁共振谱获得的区域，已经进行了第一次浸渍处理的聚合物电解质膜，包括将聚合物电解质膜浸入5mmol / L氯化铁（II）四水合物水溶液溶液在25℃下搅拌1小时，然后在10小时或更低温度下在25℃下干燥高分子电解质膜12小时; Snp表示通过测定高分子电解质膜的13 C-固体核磁共振谱得到的峰面积的总和，第一浸渍处理前的高分子电解质膜进行了第二浸渍处理，包括浸渍聚合物电解质膜在25℃的水中1小时，然后将聚合物电解质膜在25℃，10hPa以下干燥12小时。

3. 发明申请

US20100209810A1 POLYMER ELECTROLYTE COMPOSITION 审中-公开
标题翻译：聚合物电解质组合物
公开(公告)号：US20100209810A1
公开(公告)日：2010-08-19
申请号：US12678666
申请日：2008-09-22
申请人： Arihiro Yashiro , Shigeru Sasaki
发明人： Arihiro Yashiro , Shigeru Sasaki
IPC分类号： H01M8/10 , B01J31/06
CPC分类号： C08L87/005 , C08G8/10 , C08G8/12 , C08G10/02 , C08G65/4012 , C08G75/23 , C08J5/2275 , C08J2351/00 , C08J2361/06 , C08L51/003 , C08L53/00 , C08L61/06 , C08L81/06 , H01B1/122 , H01M8/1025 , H01M8/1027 , H01M8/1032 , H01M8/1039 , H01M8/1072 , H01M2008/1095 , H01M2300/0082 , Y02P70/56 , C08L2666/02 , C08L81/00 , C08L2666/16
摘要： Disclosed is a polymer electrolyte composition containing components (A) and (B). (A) a polymer electrolyte containing a segment having an ion-exchange group and a segment having substantially no ion-exchange groups, which is obtained using block copolymerization or graft copolymerization as a copolymerization method (B) a condensate of a phenol and an aldehyde compound
摘要翻译：公开了含有成分（A）和（B）的高分子电解质组合物。（A）含有具有离子交换基团的链段和基本上不含离子交换基团的链段的聚合物电解质，其使用嵌段共聚或接枝共聚作为共聚方法得到（B）苯酚和醛的缩合物复合

4. 发明授权

US06828407B2 Polymer electrolyte composition and uses thereof 失效
标题翻译：聚合物电解质组合物及其用途
公开(公告)号：US06828407B2
公开(公告)日：2004-12-07
申请号：US10341500
申请日：2003-01-14
申请人： Shigeru Sasaki , Arihiro Yashiro , Yasuaki Hidaka , Takumi Taniguchi
发明人： Shigeru Sasaki , Arihiro Yashiro , Yasuaki Hidaka , Takumi Taniguchi
IPC分类号： C08G5900
CPC分类号： H01M8/1032 , C08G65/48 , C08G75/23 , C08G2650/02 , C08J5/2256 , C08J2371/12 , C08K5/521 , H01M8/1025 , H01M8/1027 , H01M8/106 , H01M8/1081 , H01M2300/0082 , H01M2300/0094 , Y02P70/56 , C08L71/12
摘要： The present invention provides a polymer electrolyte composition excellent in radical resistance and/or proton conductivity. The polymer electrolyte composition comprises an aromatic polymer phosphonic acid derivative represented by the following formula (1); and at least one selected from the group consisting of a phosphoric acid derivative and a polymer electrolyte. (wherein -Z- represents —SO2— or —CO—, x and y each represent 0.01-0.99 provided that the sum of x and y is 1, —Ar— represents a divalent aromatic group of 4-18 carbon atoms which may contain a hetero atom and may contain one or more substituents, n represents the average number of substituents per unit structure of polymeric moiety containing the aromatic group and is a positive number of 8 or less, and R and R′ each independently represent a hydrogen atom or an alkyl group).
摘要翻译：本发明提供了具有优异的自由基电阻和/或质子传导性的聚合物电解质组合物。聚合物电解质组合物包含由下式（1）表示的芳族聚合物膦酸衍生物; 和选自磷酸衍生物和聚合物电解质中的至少一种（其中-Z-表示-SO2-或-CO-，x和y各自表示0.01-0.99，条件是x和y的和为 1，-Ar-表示可以含有杂原子并且可以含有一个或多个取代基的4-18个碳原子的二价芳族基团，n表示每单位结构的含芳族基团的聚合物部分的取代基的平均数，正数为8以下，R和R'各自独立地表示氢原子或烷基。

5. 发明申请

US20110151355A1 POLYMER, POLYMER ELECTROLYTE AND USE OF SAME 审中-公开
标题翻译：聚合物，聚合物电解质及其用途
公开(公告)号：US20110151355A1
公开(公告)日：2011-06-23
申请号：US13059529
申请日：2009-08-13
申请人： Arihiro Yashiro , Shigeru Sasaki
发明人： Arihiro Yashiro , Shigeru Sasaki
IPC分类号： H01M8/10 , C08G75/20 , C08J5/22 , B01J31/06
CPC分类号： C08G61/10 , C08J5/2256 , C08J2365/02 , C08J2371/12 , C08J2381/06 , H01B1/122 , H01M4/8668 , H01M8/1004 , H01M8/1023 , H01M8/1027 , H01M8/1032
摘要： The present invention provides a polymer, a polymer electrolyte and the use thereof. The polymer has, as a structural unit, a phenylene group in which two or three hydrogen atoms each have been substituted with a group represented by the following formula (A), and is insoluble in water: wherein A1 represents a group represented by formula (1a), formula (1b) or formula (1c) below, and the two or three A1 groups may be the same as or different from each other, wherein R10 and R11 each independently represents a hydrogen atom, an alkyl group of 1 to 20 carbon atoms, or an aryl group of 6 to 20 carbon atoms, R12 represents a hydrogen atom, an alkyl group of 1 to 20 carbon atoms, or an aryl group of 6 to 20 carbon atoms, M represents a metal ion or an ammonium ion, and in a case where M represents a divalent or higher-valent metal ion, M may be further bonded to another substituent.
摘要翻译：本发明提供聚合物，聚合物电解质及其用途。聚合物作为结构单元具有其中两个或三个氢原子各自被下式（A）表示的基团取代的亚苯基，并且不溶于水：其中A1表示由式（ 1a），式（1b）或式（1c），并且两个或三个A 1基团可以彼此相同或不同，其中R 10和R 11各自独立地表示氢原子，1〜20的烷基碳原子或6〜20个碳原子的芳基，R 12表示氢原子，1〜20个碳原子的烷基或6〜20个碳原子的芳基，M表示金属离子或铵离子，并且在M表示二价或更高价金属离子的情况下，M可以进一步与另一取代基结合。

6. 发明授权

US07226987B2 Aromatic polymer phosphonic acid derivative and process for production the same 失效
标题翻译：芳香族聚合物膦酸衍生物和生产方法相同
公开(公告)号：US07226987B2
公开(公告)日：2007-06-05
申请号：US10844493
申请日：2004-05-13
申请人： Shigeru Sasaki , Arihiro Yashiro , Yasuaki Hidaka
发明人： Shigeru Sasaki , Arihiro Yashiro , Yasuaki Hidaka
IPC分类号： C08G79/02
CPC分类号： H01M8/1025 , B01D71/52 , B01D71/68 , B01D71/82 , C08G65/48 , C08J5/2256 , C08J2371/12 , H01M8/1027 , H01M8/1032 , Y02P70/56
摘要： Provided is an aromatic polymer phosphonic acid derivative in which a phosphonic acid derivative group is directly bound to aromatic ring. Said aromatic polymer phosphonic acid derivative can be produced by brominating a specific aromatic polymer compound with a brominating agent, then acting thereon trialkyl phosphite in the presence of a nickel halide catalyst to give a phosphonic acid di-ester, and further, by hydrolyzing the di-ester. The aromatic polymer phosphonic acid derivative is excellent in radical resistance and used for a solid polymer type fuel cell.
摘要翻译：提供了其中膦酸衍生物基团直接键合到芳族环上的芳族聚合物膦酸衍生物。所述芳族聚合物膦酸衍生物可以通过用溴化剂溴化特定的芳族聚合物化合物，然后在卤化镍催化剂的存在下在其上作用于亚磷酸三烷基酯上，得到膦酸二酯，并且还可以通过水解二 -酯。芳香族聚合物膦酸衍生物的耐自由基性优异，用于固体高分子型燃料电池。

7. 发明申请

US20060258758A1 Aromatic-polyether-type ion-conductive ultrahigh polymer, intermediate thereof, and processes for producing these 失效
公开(公告)号：US20060258758A1
公开(公告)日：2006-11-16
申请号：US10554707
申请日：2004-04-23
申请人： Toru Onodera , Shigeru Sasaki
发明人： Toru Onodera , Shigeru Sasaki
IPC分类号： C08J5/20
CPC分类号： H01M8/1025 , C08L71/123 , C09D171/12 , H01B1/122 , H01M8/1004 , Y02P70/56
摘要： An aromatic-polyether-type ion conductive polymer membrane having improved mechanical strength is provided. An aromatic-polyether-type ion-conductive ultrahigh molecular weight polymer having an ion exchange capacity of 0.1 meq/g or higher and a structure comprising an aromatic-polyether-type ultrahigh molecular weight polymer in which an acid group introduced, said aromatic-polyether-type ultrahigh molecular weight polymer having at least one structural unit selected from those represented by the following formulas (1) and (2) and the sum of the number a of the structural unit of the formula (1) and the number b of the structural unit of the formula (2) being 2 or larger: Ar1—Om—Ar1 (1) Ar2—On—Ar2 (2)

8. 发明授权

US08211576B2 Block copolymers and use thereof 有权
标题翻译：嵌段共聚物及其用途
公开(公告)号：US08211576B2
公开(公告)日：2012-07-03
申请号：US10573783
申请日：2004-09-24
申请人： Toru Onodera , Shigeru Sasaki , Daizaburo Yashiki
发明人： Toru Onodera , Shigeru Sasaki , Daizaburo Yashiki
IPC分类号： B01D71/80 , C08G65/40 , C08G75/23
CPC分类号： H01M8/1058 , B01D71/80 , C08G65/40 , C08G75/23 , C08J5/2256 , C08J2371/12 , H01M4/8605 , H01M8/1025 , H01M8/1027 , H01M8/1032 , Y10S525/906
摘要： A block copolymer comprising at least one segment having an acid group which is represented by the following formula (1) and at least one segment substantially free from acid groups which comprises repeating units represented by the following formula (2) is provided: (wherein, m represents an integer of 10 or more, Ar1, Ar2 and Ar3 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms or aryloxy group having 6 to 10 carbon atoms, at least one of Ar1 and Ar2 having an acid group, and Ar3 may have an acid group or may be free from acid groups. Y represents —CO— or —SO2—, and Y's may be different from each other.) (wherein, n represents an integer of 10 or more, Ar4 and Ar5 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms, aryloxy group having 6 to 10 carbon atoms or flouro group. Z represents —CO— or —SO2—, and Z's may be different from each other). The block copolymer exerts more excellent performances as the polymer electrolyte in fuel cells and the like.
摘要翻译：提供了包含至少一个具有由下式（1）表示的酸基的片段和至少一个基本上不含酸基的片段的嵌段共聚物，该片段包含由下式（2）表示的重复单元：（其中， m表示10以上的整数，Ar 1，Ar 2和Ar 3各自独立地表示任选被具有1〜10个碳原子的烷基，具有1〜10个碳原子的烷氧基，2〜6个碳原子的芳基， 10个碳原子或具有6〜10个碳原子的芳氧基，具有酸基的Ar1和Ar2中的至少一个和Ar3可以具有酸基或可以不含酸基，Y表示-CO-或-SO2-，并且Y可以彼此不同。）（其中，n表示10以上的整数，Ar 4和Ar 5各自独立地表示任选被具有1〜10个碳原子的烷基取代的二价芳基，烷氧基havi 具有1至10个碳原子，具有6至10个碳原子的芳基，具有6至10个碳原子的芳氧基或氟基。 Z表示-CO-或-SO 2 - ，Z可以彼此不同）。嵌段共聚物作为燃料电池等中的高分子电解质具有更优异的性能。

9. 发明申请

US20090253015A1 POLYARYLENE BLOCK COPOLYMER AND USE THEREOF 审中-公开
标题翻译：聚烯烃嵌段共聚物及其用途
公开(公告)号：US20090253015A1
公开(公告)日：2009-10-08
申请号：US11817835
申请日：2006-03-09
申请人： Toru Onodera , Takashi Yamada , Shigeru Sasaki , Katsuhiro Suenobu , Takashi Kamikawa , Noriyuki Hida
发明人： Toru Onodera , Takashi Yamada , Shigeru Sasaki , Katsuhiro Suenobu , Takashi Kamikawa , Noriyuki Hida
IPC分类号： H01M8/10 , B01J41/12 , C08J5/22
CPC分类号： H01M8/1058 , C08G61/12 , H01B1/122 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M2300/0082 , Y02P70/56
摘要： Provided is a block copolymer comprising one or more segments having an acid group and one or more segments having substantially no acid group, wherein the segment having an acid group is represented by the following formula (1): wherein m represents an integer of 10 or more, Ar1, Ar2 and Ar3 each independently represent a divalent aromatic group, these divalent aromatic groups may be substituted by an alkyl group having 1-10 carbon atoms, an alkoxy group having 1-10 carbon atoms, an aryl group having 6-10 carbon atoms or an aryloxy group having 6-10 carbon atoms; at least one of Ar1 and Ar2 has an acid group, Ar3 may or may not have an acid group; Y represents —CO— or —SO2—, a plurality of Ys may be different from each other, and the segment having substantially no acid group has a repeating unit represented by the following formula (2): wherein n represents an integer of 10 or more, Ar4 and Ar5 each independently represent a divalent aromatic group, these divalent aromatic groups may be substituted by an alkyl group having 1-10 carbon atoms, an alkoxy group having 1-10 carbon atoms, an aryl group having 6-10 carbon atoms, an aryloxy group having 6-10 carbon atoms or a fluoro group; Z represents —CO—, or —SO2—, a plurality of Zs may be different from each other. It shows more excellent performance as a polymer electrolyte in fuel cells and the like.
摘要翻译：本发明提供含有一个或多个具有酸基和一个或多个基本上不含酸基的链段的嵌段共聚物，其中具有酸基的链段由下式（1）表示：其中m表示整数10或更优选Ar 1，Ar 2和Ar 3各自独立地表示二价芳族基团，这些二价芳族基团可以被具有1-10个碳原子的烷基，具有1-10个碳原子的烷氧基，6-10 碳原子或具有6-10个碳原子的芳氧基; Ar 1和Ar 2中的至少一个具有酸基，Ar 3可以具有或不具有酸基; Y表示-CO-或-SO2-，多个Y可以彼此不同，并且基本上没有酸基的链段具有由下式（2）表示的重复单元：其中n表示整数10或此外，Ar 4和Ar 5各自独立地表示二价芳族基团，这些二价芳基可以被具有1-10个碳原子的烷基，具有1-10个碳原子的烷氧基，具有6-10个碳原子的芳基取代，具有6-10个碳原子的芳氧基或氟基; Z表示-CO-或-SO 2 - ，多个Z可以彼此不同。作为燃料电池等中的高分子电解质，表现出更优异的性能。

10. 发明申请

US20070083010A1 Block copolymers and use thereof 有权
标题翻译：嵌段共聚物及其用途
公开(公告)号：US20070083010A1
公开(公告)日：2007-04-12
申请号：US10573783
申请日：2004-09-24
申请人： Toru Onodera , Shigeru Sasaki , Daizaburo Yashiki
发明人： Toru Onodera , Shigeru Sasaki , Daizaburo Yashiki
IPC分类号： C08F297/02
CPC分类号： H01M8/1058 , B01D71/80 , C08G65/40 , C08G75/23 , C08J5/2256 , C08J2371/12 , H01M4/8605 , H01M8/1025 , H01M8/1027 , H01M8/1032 , Y10S525/906
摘要： A block copolymer comprising at least one segment having an acid group which is represented by the following formula (1) and at least one segment substantially free from acid groups which comprises repeating units represented by the following formula (2) is provided: (wherein, m represents an integer of 10 or more, Ar1, Ar2 and Ar3 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms or aryloxy group having 6 to 10 carbon atoms, at least one of Ar1 and Ar2 having an acid group, and Ar3 may have an acid group or may be free from acid groups. Y represents —CO— or —SO2—, and Y's may be different from each other.) (wherein, n represents an integer of 10 or more, Ar4 and Ar5 represent each independently a divalent aromatic group which is optionally substituted by an alkyl group having 1 to 10 carbon atoms, alkoxy group having 1 to 10 carbon atoms, aryl group having 6 to 10 carbon atoms, aryloxy group having 6 to 10 carbon atoms or fluoro group. Z represents —CO— or —SO2—, and Z's may be different from each other). The block copolymer exerts more excellent performances as the polymer electrolyte in fuel cells and the like.
摘要翻译：提供了包含至少一个具有由下式（1）表示的酸基的片段和至少一个基本上不含酸基的片段的嵌段共聚物，该片段包含由下式（2）表示的重复单元：（其中， m表示10以上的整数，Ar 1，Ar 2和Ar 3各自独立地表示任选被碳原子数1〜10的烷基，碳原子数1〜10的烷氧基，碳原子数6〜10的芳基或碳原子数6〜10的芳氧基，Ar 1〜具有酸基的Ar 2和Ar 3可以具有酸基或可以不含酸基，Y表示-CO-或-SO 2 （其中，n表示10以上的整数，Ar 4和Ar 5表示各自独立地表示）二价芳族基团任选被具有1至10个碳原子的烷基，具有1至10个碳原子的烷氧基，具有6至10个碳原子的芳基，具有6至10个碳原子的芳氧基或氟基团取代。 Z表示-CO-或-SO 2 - ，Z可以彼此不同）。嵌段共聚物作为燃料电池等中的高分子电解质具有更优异的性能。

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